Nomenclatura y conversiones de unidades de concentración en ABSORCION y

DESORCION de un componente.
FASE GASEOSA:

Fracción molar (1): = = = = [=] 01

.

Relación molar: = = = [=] 0

∙
Fracción peso: = = = [=] 01
∙ ( )∙ .

Relación molar: = [=] 0

Presión total: = +
.
Densidad molar: =( )∙ =( )∙ = [=] [=]
. . .

, .
Densidad total: = = . = =( [=]
. ∙ ⁄ ∙ )∙( , ) .

Densidad parcial: ̅ = ̅ = ̅ ∙ = ∙ =( ∙ )∙

=( ∙ )∙

= ∙ ∙ [=]
.

.
̅ = ∙ = ∙ [=]
.

Densidad masa: ̅ = ∙ = [=]

.

Fracción molar (2): = = [=] 01

. .

Fracción peso (2): = [=] 01

.

%mol: 10 ∙

%peso: 10 ∙

ppm : 10 ∙

= ̅ ∙ .
[=]
. . .

ppm : 10 ∙

FASE LIQUIDA:

PM mezcla: = ∙ + (1 − )∙ [=]
 .
ppm : = ̅ [=]
. . .

Fracción molar (2): = [=] 01

. .

= =
1−

. .
Densidad molar: = ̅ [=]
. . . .

=( )∙ = ∙ = ∙ ̅

Densidad masa: ̅ = ∙ [=]

. .

Densidad parcial: = ̅ ∙ ̅ = ∙ =( ∙ )∙ ̅
̅
= ∙ ∙ ̅ [=]
.

̅ =( )∙

En la interfase: = ∙

= ∙ o = ∙

=( )∙

= ∙ = ∙
∗
En el equilibrio: = ∙
∗
= ∙
∗ ∗
= ∙ o = ∙
∗ ∗
= ∙ o = ∙

∗ ∗[ ]=
= ∙  ∙ = ∙

∗
= ∗

1
= = = =
Recuperaciones: =

Gastos: = ∙ = ∙ = ∙ (1 + )

= ∙ (1 + )

= (1 − )∙
= ∙ (1 + )

∙ ̅ = ∙
∗
Balance de masa: = ∙( − )= ∙( − )= , ∙( − )

Velocidades de transferencia A o flujos molares de A:

Pesos moleculares: = ∙( )+ ∙ (1 − )

∗ ∗
∆ ∆
= = , = = [=] o = [=] Absorción
∆ ∆
 =

∗ ∗
∆ ∆
= = = [=] o = [=] Desorción
∆ ∆

COEFICIENTES DE TRANSFERENCIA DE MASA:

=( )∙ =
−

=( )∙ ∙ =
−

= (1 − )(1 − )

= ∙( )=
−

= ∙( )= =( )
=( )⁄ ( ⁄ )
= ∙( ), ver definición abajo

=( )(1 − )(1 − )=
−

( ) −
̅ =
̅ − ̅
=( )( ) =( )∙( − )⁄ ( ⁄ )

= y = =
 ∗
−
= ∙( )= ∗ ∙( )
−

= ∙( )

∗) ∗)
=( ) ∙ (1 − )(1 − =( )∙ ( − = ∗
−

= ∙( )= ∙

Para soluciones diluidas: ≈

= ∗ =( )
−

RESUMEN:

Coeficiente de transferencia de masa local entre fases

GAS LIQUIDO

→ ∙ =( ∙ ) × → ( ∙ ) =( ∙ ) ×

∙a =( ∙ a)loc × PT ( ∙ a)loc = ( L ∙ a)loc × CTL

loc G P
CTG =
R∙T
→ ∙ =( ∙ ) × ( ∙ ) =( ∙ ) ×
ρL
CTL =
∙a =( ∙ a)loc × CTG PML PMMezcla
loc C
( L ∙ a)loc = ( ∙ a)loc ×
ρL
→ ∙ = ∙ ×
→ ( ∙ ) =( ∙ ) ×
PMMezcla
∙a = ∙a × PMMezcla
loc loc PMA ( ∙ a)loc = ( ∙ a)loc ×
PMA
( ∙ )
→ ( ∙ ) =
∙ → ( ∙ ) =( ∙ ) ×
̅ ̅
( C ∙ a)loc
( G ∙ a)loc =
R∙T 1
( L ∙ a)loc = ( L ∙ a)loc ×
PMA
→ ( ∙ ) =( ∙ ) ×
→ ( ∙ ) =( ∙ ) ×
1
( C ∙ a)loc = ( C ∙ a)loc ×
PMA PMLS
( X ∙ a)loc = ( X ∙ a)loc ×
PMA
→ ( ∙ ) =( ∙ ) ×
: , , , [=] ó
, , , [=] ó
PMGS
( Y ∙ a)loc = ( Y ∙ a)loc ×
PMA

Coeficientes de transferencia de masa local entre dos fases

RESISTENCIAS: = + y 1= +

1 1
= +
 1 1
= +

1 1
= +

1 1 1
= +
∙( )

= +
1 1 1
= +
∙
1 1 1 1 1
= + =
∙
1 1 1
= +
∙
Para la resistencia gaseosa:
1 1 1
∙ ∙
= = = =
1 1 1

1 1
∙( )
= = = =
1 1 ∙( )

Para la resistencia líquida:

1
∙
= = =
1 1

1
∙
= = = =
1 1
RESUMEN:
ABSORCIÓN DESORCIÓN

= + = +
( ∙ ) ×( ∙ ) ( ∙ ) ( ∙ ) ( ∙ ) ×( ∙ )
1 1 1 1 1 1
= + = +
(K ∙ a)loc m × ∙a ( ∙ a)loc (K ∙ a)loc ( ∙ a)loc m × ∙a
loc loc

1 1 1 1 1 1
= + = +
(K L ∙ a)loc m ×( G ∙ a)loc ( L ∙ a)loc (K L ∙ a)loc ( L ∙ a)loc m ×( G ∙ a)loc

1 1 1 1 1 1
= + = +
(K L ∙ a)loc m ×( C ∙ a)loc ( L ∙ a)loc (K L ∙ a)loc ( L ∙ a)loc m ×( C ∙ a)loc

´ ´
= + = +
( ∙ ) ( ∙ ) ( ∙ ) ( ∙ ) ( ∙ ) ( ∙ )

1 m´ 1 1 1 m´
= + = +
K ∙a ( ∙ a)loc ∙a K ∙a ∙a ( ∙ a)loc
loc loc loc loc

ABSORCIÓN DESORCIÓN
´
1 m 1 1 1 m´
= + = +
(K G ∙ a)loc ( L ∙ a)loc ( G ∙ a)loc (K G ∙ a)loc ( G ∙ a)loc ( L ∙ a)loc
´
1 m 1 1 1 m´
= + = +
(K C ∙ a)loc ( L ∙ a)loc ( C ∙ a)loc (K C ∙ a)loc ( C ∙ a)loc ( L ∙ a)loc
( ∙ ) = ×( ∙ ) ( ∙ ) = ×( ∙ )

(K ∙ a)loc = m × K ∙a (K ∙ a)loc = m × K ∙a
loc loc

(K L ∙ a)loc = m × (K G ∙ a)loc (K L ∙ a)loc = m × (K G ∙ a)loc

(K L ∙ a)loc = m × (K C ∙ a)loc (K L ∙ a)loc = m × (K C ∙ a)loc

¨
( ∙ ) ¨
( ∙ )
=− =−
( ∙ ) ( ∙ )
( ∙ a)loc ( ∙ a)loc
m¨ =− m¨ =−
∙a ∙a
loc loc

( L ∙ a)loc ( L ∙ a)loc
m¨ =− m¨ =−
( G ∙ a)loc ( G ∙ a)loc
( L ∙ a)loc ( L ∙ a)loc
m¨ =− m¨ =−
( C ∙ a)loc ( C ∙ a)loc

Flujos molares específicos de A o velocidades de transferencia de masa de A, :

ABSORCION:
= ( − )=( )( − )=( )( − )∙

( ∗) ∗
= − =( ) −

=( ) − =( ) − =( )( − )=( ) −
1− 1−

∗
=( )( − )=( ) − =( )( − )=( )( − )
 ∗)
̅ ̅
= ( − =( )( − )=( ) − =( ) −

̅ ̅ ∗ ∗
=( ) ̅ − ̅ =( ̅ )( ̅ − ̅ ) = ( )( − )=( )( − )

∗) ∗ ∗ ∗)
=( )( − =( )( − )=( )( − )= ( −
∗) ∗ ∗ )=(
=( )( − =( )( − )=( )∙ ∙( − )( − )

DESORCION: (Cambia el orden del subíndice i y el superíndice * respecto a la absorción)

∗) ∗ ∗
=( )( − =( )( − )=( ) − =( )( − )

RESUMEN:
ABSORCIÓN DESORCIÓN
∗ ∗
( ∙ ) = ∙ − = ∙ − ( ∙ ) =( ∙ ) − =( ∙ ) −

∗ ∗
= K ∙a An − An = ∙a An − Ai = (K ∙ a)loc An − An =( ∙ a)loc An − Ai
loc loc

∗ ∗
=( ∙ ) − =( ∙ ) − =( ∙ ) − =( ∙ ) −

= (K Y ∙ a)loc YA n − YA∗ n = ( Y ∙ a)loc YA n − YA i = (K X ∙ a)loc XA n − X A∗ n = ( X ∙ a)loc XA n − X A i

∗ ∗
=( ∙ ) − ∙ =( ∙ ) − ∙ =( ∙ ) − ∙ =( ∙ ) − ∙

∗ ∗
=( ∙ ) − ∙ =( ∙ ) − ∙ = (K L ∙ a)loc An − An ∙ CTL n
=( L ∙ a)loc An − Ai ∙ CTL n

= (K C ∙ a)loc An − ∗
An ∙ CTG n =( C ∙ a)loc An − Ai ∙ CTG n = ∙ ∗
− = ∙ −

∗ ∗
=( ∙ ) − =( ∙ ) − = K ∙a An − = ∙a Ai −
loc loc

∗ ∗
= (K ∙ a)loc An − An =( ∙ a)loc Ai − An =( ∙ ) − =( ∙ ) −

∗
=( ∙ ) − =( ∙ ) − = (K Y ∙ a)loc YA∗ n − =( Y ∙ a)loc YA i −

= (K X ∙ a)loc XA∗ n − XA n = ( X ∙ a)loc XA i − X A n =( ∙ ) ∗

− ∙ =( ∙ ) − ∙

= ( DESORCIÓN
∙ ) ∗
− ∙ =( ∙ ) − ∙ =( ∙ ) ∗
− ∙ =( ∙ ) − ∙
´
= (K L ∙ a)loc
1 ∗
An − 1∙ CTL n = (mL ∙ a)loc Ai − ∙ CTL n
= (K C ∙ a)loc ∗
An − ∙( ̅ ) =( C ∙ a)loc Ai − ∙( ̅ )
= +
(K ∙ a) ( ∙ a) ( ∙ a)
 DISEÑO BÁSICO DIFUSIONAL DE TORRES EMPACADAS PARA LA
ADSORCÓN ISOTÉRMICA E ISOBÁRICA DE UN COMPONENTE A
RÉGIMEN PERMANENTE
Diseño de columnas. Dc, Zc.
ABSORCIÓN:

FASE GAS:
(1 − ∗)
+ (1 − )
(1 − ) =
(1 − ∗ )
(1 − )

∗ ∗
∗
( − ) −( − )
( − ) = ∗
( − )
∗
( − )

=( ) ∗( )

( )
( ) =
( ∗ ) ∗ (1 − )

1
( ) = ∗) + (−1)
( − 2(−1) (1 − )

1 (1 + )
( ) = ∗ +
( − ) 2 (1 + )

FASE LIQUIDA:

=( ) ∗( )

(1 − ) − (1 − ∗)
(1 − ) =
(1 − )
(1 − ∗ )

( )
( ) =
( ∗ ) ∗ (1 − )
 1 (1 − )
( ) = ∗ −
( − ) 2 (1 − )

1 (1 − )
( ) = ∗ −
( − ) 2 (1 − )

AGOTAMIENTO:

FASE GAS:

=( ) ∗( )

(1 − ) − (1 − ∗)
(1 − ) =
(1 − )
(1 − ∗ )

( )
) =
( ∗ ) ∗ (1 − )

1 (1 + )
( ) = ∗ +
( − ) 2 (1 + )

1 (1 + )
( ) = ∗ +
( − ) 2 (1 + )

FASE LIQUIDA:

=( ) ∗( )

(1 − ∗)
− (1 − )
(1 − ) =
(1 − ∗ )
(1 − )

( )
( ) =
( ∗ ) ∗ (1 − )

1 (1 − )
( ) = ∗ +
( − ) 2 (1 − )
 1 (1 + )
( ) = ∗ −
( − ) 2 (1 + )

ABSORCION SOLUCIONES DILUIDAS:

FASE GAS:

( ) = ∗) = ∗
( − ( − )

(1 − )∗ − (1 − )∗
(1 − ) =
2

z= ∗
∗ ∗ (1 − ) ( − )

∗ ∗
∗
( − ) −( − )
( − ) = ∗
( − )
∗
( − )

z= ∗
( ∗ ) ∗ ( − )

( − )
( ) = ∗
( − )

Donde:
∗
∗
( − ) −( ∗ − )
( − ) =
( ∗− )
( ∗− )

FASE LIQUIDA:

=( ) ∗( )
−
= ∗ ∗
( ∗ ) ( − )

AGOTAMIENTO SOLUCIONES DILUIDAS:

z= ∗
( ∗ ) ( − )
 ∗( )
z= ∗ = ∗
( ∗ ) ∗ ( − ) ( ∗ ) ∗ ( − )
∗ −
= ∗
( ∗ ) ( − )

(1 − )∗ − (1 − )∗
(1 − ) =
2
Ecuaciones opcionales:

Absorción:

( ) =
( ∗ ) ∗ (1 − )

AGOTAMIENTO:

( ) =
( ∗ ) ∗ (1 − )