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100
95
Temperature oC
90
85
80
75
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Mole fraction of ethanol in liquid/vapor
Figure Phase diagram for ethanol and water mixture at 1.013 kPa
Mole fraction of ethanol in vapor, y
Coker, 2009 ©
0.9
0.8
0.7
0.6 x-y
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Mole fraction of ethanol in liquid, x
Figure M-39. VLE diagram for the mixture ethanol and water at 1.013 kPa.
Vapor-Liquid equilibrium data for ethanol and water at 1 atm, y and x in Mole fraction by A.K. Coker
R.H. Perry, C.H. Chilton and S.O. Kirkpatrick (Eds.), Chemical Engineering Handbook, 4th ed. New York McGraw-Hill, p 13-5,
xEtoh xw yEtoh yw T, oC
0 1 0 1 100
0.019 0.981 0.17 0.83 95.5
0.0721 0.9279 0.3891 0.6109 89
0.099 0.9034 0.4375 0.5625 86.7
0.1238 0.8762 0.4704 0.5296 85.3
0.1661 0.8339 0.5089 0.4911 84.1
0.2337 0.7663 0.5445 0.4555 82.7
0.2608 0.7392 0.558 0.442 82.3
0.3273 0.6727 0.5826 0.4174 81.5
0.3965 0.6035 0.6122 0.3878 80.7
0.5198 0.4802 0.6599 0.3401 79.7
0.5732 0.4268 0.6841 0.3159 79.3
0.6763 0.3237 0.7385 0.2615 78.74
0.7472 0.2528 0.7815 0.2185 78.41
0.8943 0.1057 0.8943 0.1057 78.15
1 0 1 0 78.3
0 100 75
0.17 95.5 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.3891 89 xE or yE
0.4375 86.7
0.4704 85.3
0.5089 84.1
0.5445 82.7
0.558 82.3
0.5826 81.5
0.6122 80.7
0.6599 79.7
0.6841 79.3
0.7385 78.74
0.7815 78.41
0.8943 78.15
1 78.3
xEtoh yEtoh
M o le fractio n o f eth an o l in v ap o r, y E
0 0
0.019 0.17
0.0721 0.3891
0.099 0.4375
0.1238 0.4704
0.1661 0.5089
0.2337 0.5445
0.2608 0.558 Figure 10- Vapor-Liquid Equilibrium diagram for ethanol-water at 101.3 kPa
0.3273 0.5826
0.3965 0.6122 1 Azeotrope
0.5198 0.6599 0.9
0.5732 0.6841
0.8
0.6763 0.7385
0.7472 0.7815 0.7
0.8943 0.8943 0.6
1 1 0.5
0.4
0 0
0.17 0.17 0.3
0.3891 0.3891 0.2
0.4375 0.4375
0.1
0.4704 0.4704
0.5089 0.5089 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.5445 0.5445
Mole fraction of ethanol in liquid, xE
0.558 0.558
0.5826 0.5826
0.6122 0.6122
0.6599 0.6599
0.6841 0.6841
0.7385 0.7385
0.7815 0.7815
0.8943 0.8943
1 1
York McGraw-Hill, p 13-5, 1963
T-x-y
9 1
ol-water at 101.3 kPa
0.8 0.9 1
no waktu suhu volume massa pikno
m0 m1 m1-m0 p0
1 34.33 74 30 63.04 87.5 24.46 33.92
2 35.23 74 30 124.86 148.78 23.92 33.92
3 38.12 74 21 61.78 78.94 17.16 33.92
4 40.2 74 30 61.78 85.9 24.12 33.92
5 44.5 74 30 124.86 148.27 23.41 33.92
6 47.58 75 30 63.04 87.88 24.84 33.92
7 50.4 75 30 124.86 149.81 24.95 33.92
8 54.1 75 30 63.04 88.35 25.31 33.92
9 58.1 75 30 124.86 149.16 24.3 33.92
10 1:01:15 75 30 63.04 88.57 25.53 33.92
11 1:04:07 75 30 124.86 149.53 24.67 33.92
12 1:08:10 75 30 63.04 88.06 25.02 33.92
13 1:12:19 75 30 124.86 150.09 25.23 33.92
14 1.16,20 76 30 63.04 88.24 25.2 33.92
15 1:18:23 76 30 124.86 149.38 24.52 33.92
16 1:20:00 75 30 63.04 88 24.96 33.92
17 1:25:50 76 30 124.86 148.39 23.53 33.92
18 1:30:11 75 30 63.04 88.18 25.14 33.92
19 1:34:08 76 30 124.86 148.58 23.72 33.92
20 1:37:58 75 30 63.04 87.91 24.87 33.92
591 484.86
residu R 124.6503
0.945308 31.90285 0.31902851 16.08346 0.129029
68.09715 0.68097149
NM residu 124.6503 0.09053085
0.129029
2 Mr etanol 46 g/mol
1.5 Mr air 18 g/mol
berat pikno kosong 33.92 g mol etanol 25.73804348 mol
berat pikno + isi (campuran) 57.99 g mol air 110.7235556 mol
volume pikno 24.574 cm3 mol feed 136.461599 mol
massa campuran 24.07 g x mol etanol 0.188610156
densitas campuran awal 0.979491 g/ml x mol air 0.811389844
massa campuran feed 3428.217 g % mol etanol 18.8610156 %
Densitas ethanol murni 0.7893 g/cm3 % mol air 81.1389844 %
Densitas air murni 0.996512 g/cm3
massa etanol 1183.95 g
massa air 1993.024 g
3176.974
berat pikno kosong 33.92 g mol etanol 0.693540217 %
berat pikno + isi (campuran) 57.15 g mol air 3.783175 %
volume pikno 24.574 cm3 x etanol residu 0.154921674
massa campuran 23.23 g
densitas campuran awal 0.945308 g/ml
Massa campuran Residu 558.677 g
% massa etanol 31.90285
% massa air 68.09715
berat pikno kosong 61.78 g mol etanol 9.654587466 mol
berat pikno + isi (campuran) 78.94 g mol air 2.156689173 mol
volume pikno 21 cm3 mol destilat 11.81127664 mol
massa campuran 17.16 g x mol etanol 0.817404228
densitas campuran awal 0.817143 g/ml x mol air 0.182595772
massa campuran destilat 482.9314 g % mol etanol 81.74042283 %
% massa etanol 91.96151 g/cm3 % mol air 18.25957717 %
% massa air 8.038492 g/cm3
massa etanol 444.111 g
massa air 38.82041 g
3.5
Axis Title
5
x y T (C) 1/(y-x) 3.3
0 0 100 4.5
0.019 0.17 95.5 6.622517 3.2 4
1/(y-x)
0.0721 0.3891 89 3.154574 3.1 3.5
0.0966 0.4375 86.7 2.933412
3 3
0.1238 0.4704 85.3 2.88517
0.1661 0.5089 84.1 2.917153 2.9 2.5
0.2377 0.5445 82.7 3.259452 2
2.8
0.2608 0.558 82.3 3.364738
1.5
0.3273 0.5826 81.5 3.91696 2.7
0.3965 0.6122 80.7 4.636069 1
2.6
0.5079 0.6564 79.8 6.734007 0.5
0.1 0.12 0.14 0.16 0.18 0.2 0.22 0
0.5198 0.6599 79.7 7.137759 Axis Title
0
0.5732 0.6841 79.3 9.017133 0.05 0.1 0.15 0.2 0.25 0.3
0.6763 0.7385 78.74 16.07717 x
0.7472 0.7815 78.41 29.15452
0.8943 0.8943 78.15 #DIV/0!
1 1 78.3 #DIV/0!
x y 1/y-x
0 0 #DIV/0!
0.02 0.192 5.813953
Chart Title
20
9
7
0.05 0.377 3.058104
0.1 0.527 2.34192 18
8
6
0.2 0.656 2.192982 16
7
0.3 0.713 2.421308 5
14
0.4 0.746 2.890173 6
12
0.5 0.771 3.690037 4
5
0.6 0.794 5.154639 10
4
3
0.7 0.822 8.196721 8
0.8 0.858 17.24138 3
6
2
0.9 0.912 83.33333
2
4
0.94 0.942 500
1
0.96 0.959 -1000 1
2
0.98 0.978 -500 0
1 1 #DIV/0! 0 0.05
0.1
0.1 0.2
0.10.2 0.15
0.3 0.3 0.4
0.2 0.4 0.25
0.5 0.50.6
0.3
0.18 0.2 0.22 0.24 0.26 0.28
Axis Title
0.2 0.25 0.3 0.35 0.4 0.45
x
Chart Title
0.3 0.4
0.2 0.4 0.25
0.5 0.50.6
0.3 0.6
0.35
0.7 0.7
0.8
0.4 0.9
0.45
0.8
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