Review Materials

Chemistry
July 23, 2017

Answer the following questions correctly.

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1. At STP, which substance is a noble gas?
a. ammonia b. chlorine
c. neon d. nitrogen
2. Which term identifies a type of chemical reaction?
a. decomposition b. sublimation
c. distillation d. vaporization
3. Which subatomic particles are paired with their charges?
a. electron–positive, neutron–negative, proton–neutral
b. electron–negative, neutron–neutral, proton–positive
c. electron–negative, neutron–positive, proton–neutral
d. electron–neutral, neutron–positive, proton–negative.
4. Silver (Ag) has two isotopes. Which of the following are the correct symbols for the
two isotopes for the two isotopes of silver (Z=47) where one has 60 neutrons and the other has 62?
a. 107 105
47𝐴𝑔 𝑎𝑛𝑑 47𝐴𝑔 b. 107 109
47𝐴𝑔 𝑎𝑛𝑑 47𝐴𝑔
c. 47𝐴𝑔 𝑎𝑛𝑑 47𝐴𝑔
107 107
d. 47𝐴𝑔 𝑎𝑛𝑑 105
105
47𝐴𝑔
5. All elements on the periodic table are arrange in order of increasing
a. mass no. b. electronegativity c. atomic no. d. bond energy
6. Which of the following are chemical processes?
a. rusting of iron b. freezing of water c. compression of oxygen gas d. expansion of ice

7. A monoatomic (X) ion has a charge of +3. The nucleus of the ion has a mass number of 45.
The number of neutrons in the nucleus is 1.14 times that of the number protons. Find
the number of electrons in atom X.
a. 30 b. 23
c. 18 d. 21
8. What is the weight of 3.01 × 1023 molecules of ammonia?
(N=14.00 g/mol, H= 1.01 g/mol) Avogadros No.: 6.023 x 1023 molecules per mole
a. 4.2 g b. 8.5 g
c. 17.0 g d. 5.8 g
9. Which states of matter are significantly compressible?
a. gases b. liquids
c. solids d. none of the above
10. The element X has three naturally occurring isotopes. The masses (amu) and % abundances
of the isotopes are given in the table below. The average atomic mass of the element is ________ amu.

a. 219.7 b. 220.4
c. 220.42 d. 218.5
11. Which atoms will bond when valence electrons are transferred from one atom to the other
a. O and Se b. O and H
c. O and Sr d. O and P
12. In the periodic table, the elements touching the steplike line are known as
a. transition elements b. noble gases
c. metalloids d. nonmetals
13. The atoms in a sample of an element are in excited states. A bright line spectrum is produced
when these atoms
a. absorb energy b. emits energy
 c. absorb positrons d. emit positrons
13. A mass of gas is under a pressure of 760 mmHg and occupies a volume of 525 mL. If the
Pressure were doubled, what volume the gas now occupy? Assume the temperature is constant.
a. 262.5 mL b. 262.5 dm3
c. 262.5 L d. 262.5 m3
14. Given the balanced equation:
F2 + energy → F + F
Which statement describes what occurs during this reaction?
a. Energy is absorbed as a bond is formed.
b. Energy is absorbed as a bond is broken.
c. Energy is released as a bond is formed.
d. Energy is released as a bond is broken.
15. Of the choices below, which one is not an ionic compound?
a. PCl5 b. NaCl
c. RbCl d. KCl
16. P and Q are two elements which form P2Q3, PQ2 molecules. If 0.15 mole of P2Q3 and PQ2 weighs 15.9 g
and 9.3 g respectively, what are atomic weights of P and Q?
a. P=32, Q= 18 b. P=40, Q=20
c. P= 26, Q=18 d. P=36, Q= 18
17. Which formula/name pair is incorrect?
a. FeSO4, iron(II) sulphate b.Fe2(SO3)3, iron(III) sulfite
c. FeS, iron(II) sulphide d. Fe2(SO4)3, iron(III) sulfide
18. Which formula represents an unsaturated organic compound?
a. CH4 b. C3H8 c. C2H4 d. C4H10
19. A chloride of iron contains 34.5% by mass of iron. Determine the empirical formula of the chloride.
a. Fe2Cl3 b. FeCl2
c. Fe3Cl d. FeCl3
20. A sample of CH2F2 with a mass of 19 g contains ________ atoms of F
(Use: Avogadro’s No. 6.022 X 1023 atoms/mol, C= 12.01 g/mol, H=1.01 g/mol, F=19.00 g/mol)
a. 2.2 × 1023 b. 38 × 1023
c. 3.3 × 1024 d. 4.4 ×1023
21. Which one of the following molecular formulas is also an empirical formula?
a. C6H6O2 b. C2H6SO
c. H2O2 d. H2P4O6
22. What is the empirical formula of a compound that contains 27.0% S, 13.4% O, and 59.6% Cl
by mass?
a. SOCl b. SOCl2
c. S2OCl d. SO2Cl
23. A compound has the empirical formula CH2O, and a molar mass of 60. What is its molecular formula?
a. C3H4O6 b. C3H4O2
c. C4H8O6 d. C2H4O2
24. An atom, X, has a proton number of 16. Deduce the electron configuration of this atom.
a. 1s2, 2s2, 2p6, 3s2,3p4. b. 1s2, 2s2, 3p6, 2s2,3p4
c. 1s2, 2s2, 2p6, 3s4,3p2 d. 1s2, 2s2, 2p4, 3s4,3p4
25. The ratio of chromium to iron to carbon varies among the different types of stainless
Steel. Therefore, stainless steel is classified as
a. a compound b. an element
c. a mixture d. a substance
26. Calculate the volume occupied by 8.8 g of CO 2 at 31.1oC and 1 bar pressure. R= 0.080206 bar-L/mol-K
a. 5.05 L b. 5.05 mL c.2.05 mL d. 2.05 L
27. Calculate the weight of CH4 in a 9L cylinder at 16 bar and 27oC. (R=0.083 bar-L/K).
a. 76.8 g b. 103.6 g
c. 92.5 g d. 46.5 g
28. Equal volumes of two gases A and B diffuses through a porous pot in 20 and 10 seconds
respectively. If the molar mass of A be 80 g/mole, find the molar mass of B.
a. 50 g/mol b. 40 g/mol
c. 30 g/mol d. 20 g/mol
29. The densities of an unknown gas and O2 were find 0.2579 kg/m3 and 0.2749 kg/m3 at
the same P and T. Calculate the molecular weight of unknown gas.
a. 30.02 g/mol b. 60.02 g/mol
c. 15.01 g/mol d. 45.01 g/mol
30. Which one of the following is an endothermic process?
a. ice melting b. water freezing
c. boiling soup d. both a and c
31. Use the given standard enthalpies of formation to calculate ΔH° for the following reaction
 3 Fe2O3(s) + CO(g) → 2 Fe3O4(s) + CO2(g).

a +47.2 kJ b -577.2 kJ
c -47.2 kJ d -5213.4 kJ

32. When the following equation is balanced, the coefficients are ________.
C8H18 + O2 → CO2 + H2O
a. 2, 3, 4, 4 b. 1, 4, 8, 9
c. 2, 12, 8, 9 d. 2, 25, 16, 18
33. Of the reactions below, which one is not a combination reaction?
a. C + O2 → CO2 b. 2Mg + O2 → 2MgO
c. 2N2 + 3H2 → 2NH3 d. 2CH4 + 4O2 → 2CO2 + 4H2O
34. When a hydrocarbon burns in air, a component produced is ________.
a. oxygen b. nitrogen
c. carbon d. water
35. Of the reactions below, which one is a decomposition reaction?
a. NH4Cl → NH3 + HCl b. 2Mg + O2 → 2MgO
c. 2CH4 + 4O2 → 2CO2 + 4H2O d. Cd(NO3)2 + Na2S → CdS + 2NaNO3
36. When the following equation is balanced, the coefficient of HCl is ________.
CaCO3 (s) + HCl (aq) → CaCl2 (aq) + CO2 (g) + H2O (l)
a. 1 b. 2
c. 3 d. 4
37. Calcium carbide (CaC2) reacts with water to produce acetylene (C2H2)
CaC2 (s) + 2H2O (g) → Ca(OH)2 (s) + C2H2 (g)
The complete reaction of 57.4 g of CaC 2 requires consumption of ________ g of H2O.
(Use C=12.01 g/mol, Ca=40.08g/mol, H=1.01 g/mol, O= 16.00 g/mol)
a. 0.895 b. 64.1
c. 32.3 d. 1.79
38. New industrial plants for acetic acid react liquid methanol with carbon monoxide in the presence of a catalyst.
CH3OH(l) + CO(g) → HC2H3O2(l)
In an experiment, 15.0 g of methanol and 10.0 g of carbon monoxide were placed in a reaction vessel.
If the actual yield is 19.1 g, what is the percentage yield?
a. 32.4% b. 55.6%
c. 89.1% d. 27.8%
39. The number of moles of solute present in 1 kg of a solvent is called its
a. molality b. molarity
c. normality d. formality
40. Fluids that mix with or dissolved in each other in all proportions are called.
a. compressible fluids b. miscible fluids
c. immiscible fluids d. flash fluids
41. A sample of 0.892 g of potassium chloride (KCl) is dissolved in 54.6 g of water.
What is the percent by mass of KCl in the solution? (K= 39.10 g/mol, Cl= 35.45 g/mol)
a. 2.65% b. 1.61%
c. 3.56% d. 4.65%
42. Calculate the molality of a solution made by dissolving 45.0 g of glucose C 6H12O6, in
500.0 g of water. (Use: C=12.01 g/mol, H=1.01 g/mol, O=16.00 g/mol).
a. 0.500 molal b. .25 molal
c. 1.50 molal d. 2.00 molal
43. What is the mole fraction of glucose in a solution made of 7.59 g of glucose, C 6H12O6,
dissolved in 125 g of water? (Use C=12.01 g/mol, H=1.01 g/mol, O=16 g/mol)
a. 0.009 b. 0.006
c. 0.16 d. 0.606
44. The magnitudes of Kf and of Kb depend on the identity of the ________.
a. solute b. solvent
c. solution d. system
45. AT 300 K, 36 g of glucose per liter in its solution has an osmotic pressure of 4.98 bar.
If the osmotic pressure of solution is 1.52 bar at the same temperature, what would be its concentration?
a. 1.6 molar b. 0.6 molar
c. 1.06 molar d. 0.06 molar
46. What are the boiling point and freezing point of a solution containing 5.70 g of sugar
C12H12O11, in 50 g of water. (Use C=12.01 g/mol, H=1.01 g/mol, O=16 g/mol, kf=1.853 oC/m, kb=0.515oC/m)
a.100.17oC,-0.618oC b. 100.71oC, -0.618oC
c. 100.17 C, 0.618 C
o o d. 101.17oC, -0.618oC
47. The element X forms the chloride XCL4 containing 75% Cl, by mass. What is element X?
a. Titanium b. Aluminum c. Silver d. Magnesium
48. What volume of of 0.0797 M KMnO4 is necessary to convert 9.13 g of KI to I 2 in the reaction below?
Assume that H2SO4 is present in excess.
 2KMnO4 + 10KI + 8H2SO4 6K2SO4 +2MnSO4 +5I2 +8H2O
a. 3.138 L b. 2.138 L c. 1.138 L d. 0.138 L
49. In the reaction of 277 g CCl4 with an excess of HF, 187 g CCl2F2 is obtained.
What is the percent yield of this reaction?
CCl4 + 2HF CCl2F2 +2HCl
a. 66.1% b. 76.1% c. 86.1% d. 96.1%
50. What is the final temperature ( in oC) of 1.24 g of water with an initial temperature of 20.0 oC after
6.052 J of heat is added to it?
a. 21.2 oC b. 12.2 oC c. 22.2 oC d. 31.2 oC
51. A sample of N2(g) effuses through a tiny hole in 38s. What must be the molar mass of gas that
requires 64s to effuse under identical conditions?
a. 67 g/mol b. 79g/mol c. 89g/mol d. 69g/mol
52. The reaction A product is first order in A. If 1.60 g A is allowed to decompose for 38 min,
the mass of A remaining undecomposed is found to be 0.40 g. What is the half life of this reaction?
a. 19 min b. 20 min c. 21 min d. 22 min
53. A reaction is 50% complete in 30.0 min. How long after its start will the reaction be 75% complete
if it is zero order.
a. 65 min b. 55 min c. 45 min d. 35min
54. The equilibrium concentration are measured in the given reaction at 300 oK:
2Cu +2(aq) + Sn+2(aq) = 2Cu+2(aq) + Sn+4(aq)
[Cu+]eq= 0.148 M, [Sn+2]eq=0.124 M and, [Sn+4]eq= 0.176 M. What is the equilbrium concentration
of Cu+2(aq)?
a. 0.145 M b. 0.245 M c. 0.215 M d. 0.415 M
55. What volume of water is required to make 0.20 N solution from 1600 mL of 0.2050 N solution?
a. 20 mL b. 40 mL c. 80 mL d. 160 mL
56. How many electrons may enter the orbital denoted by 2p, 1s, 3p, 3d
a. 2, 2, 6, 10 b. 2, 4, 6, 10 c. 2, 2, 2, 6 d. 2, 2, 6, 6
57. Determine the ox. no. of underlined atom in each of the following; (solve each letter pls)
a. KCrO3Cl b. K2FeO4 c. Ba(H2PO2)2 d. Ni(CO)4 e. (NH4)6Mo7O24
58. Identify the oxidized and reduced species in the following reactions:
1. CH4(g) + 4Cl2(g) CCl4(g) + 4HCl(g)
2. I2(aq) + 2S203 (aq)
-2 2I-(aq) + S406-2
59. Calculate the half-life of a first order reaction from their rate of constants given below;(solve each no pls)
1) 1. 200s-1 2) 2. 2 min-1 3) 4 year-1
60. The combustion of 5.00 g of coke raised the temperature of water of 1.00 kg of water from 10◦C to 47◦C.
Calculate the heating value of coke.
a. 7.4kcal/g b. 4.7 kcal/g c. 14.7 kcal/g d. 1.7 kcal/g