X,Y-T

66

64

62

60
Y VS T EXPERIMENTAL

Axis Title
X VS T EXPERIMENTAL
X1 VS T TEORICO
T

Y1 VS T TEORICO
58

56

54

52
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X,Y
 X VS Y

Axis Title

0 0.2 0.4 0.6 0.8 1 1.2

1 1.2

0.9

1
0.8

0.7
0.8

0.6
X VS Y EXPERIMENTAL

Axis Title
X1 VS Y1 TEORICO
0.5 0.6
Y

0.4

0.4
0.3

0.2
0.2

0.1

0 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Y
 ALUMNA:

TERMODINAMICA DE LOS RPOCES

mmHg 760

X1 X2 T(C) T(K)
ACETONA CLOROFORMO 0.01 0.99 61.8587118 0
A 7.02447 A 6.90328 0.1 0.9 62.8799455 321.155
B 1161 B 1163.03 0.2 0.8 63.6999901 336.85499
C 224 C 227.4 0.3 0.7 64.0753994 316.155
0.4 0.6 63.9456001 337.1006
0.5 0.5 63.3204399 336.47544
ACETONA-CLOROFORMO 0.6 0.4 62.2729 335.4279
A12 -0.3051 0.7 0.3 60.9160538 334.071054
A21 -0.2676 0.8 0.2 59.3756434 332.530643
0.9 0.1 57.7679431 330.922943
0.99 0.01 56.3419987 329.496999

Datos experimentales
T°C T°K x1 y1
62.7 335.85 0.1013 0.074
63.55 336.7 0.1792 0.1428
63.95 337.1 0.2528 0.2221
64.4 337.55 0.3022 0.2814
64.55 337.7 0.3697 0.3724
64.25 337.4 0.4418 0.4695
63.55 336.7 0.5268 0.5862
62.3 335.45 0.6318 0.707
61.8 334.95 0.6683 0.7526
61.27 334.42 0.702 0.7852
60.8 333.95 0.7315 0.8123
60.1 333.25 0.7605 0.8376
59.3 332.45 0.8137 0.8793
57.95 331.1 0.8946 0.9411
57.1 330.25 0.9433 0.9699
56.7 329.85 0.9652 0.9822
 FACULTAD DE INGENIERIA QUIMICA
ESCUELA ACADEMICA PROFESIONAL DE INGENIERIA QUIMICA AMBIENTAL

PALOMINO FERNANDEZ, Lisbet Yanina

ERMODINAMICA DE LOS RPOCESOS QUIMICOS

0
2 1

a1 a2 Pvp1 Pvp2 Y1 Y2 Y1+Y2

0.50316053 0.99994365 918.381287 763.051904 0.006080174 0.993919499 0.99999967
0.57404244 0.99438102 949.469336 788.31428 0.071715223 0.928284579 0.9999998
0.65213273 0.9777128 975.0261508 809.070098 0.167328018 0.832671779 0.9999998
0.72698592 0.950551 986.9044773 818.713475 0.283210129 0.716789791 0.99999992
0.79609336 0.91378747 982.7847281 815.369122 0.411783365 0.588216387 0.99999975
0.85723521 0.8686016 963.1311535 799.410951 0.543177589 0.456822125 0.99999971
0.90862357 0.81639756 930.8918949 773.22005 0.667760779 0.332239455 1.00000023
0.94899954 0.75873204 890.4007962 740.300761 0.77828021 0.2217197 0.99999991
0.97767835 0.6972376 846.1254356 704.271841 0.870777393 0.129222318 0.99999971
0.994544 0.63354698 801.7852268 668.15355 0.944302125 0.055698245 1.00000037
0.99994685 0.57564187 764.0113269 637.353356 0.995172381 0.004827464 0.99999985
 X VS Y

Axis Title

0 0.2 0.4 0.6 0.8 1 1.2

1 1.2

0.9

1
0.8

0.7
0.8

0.6
X VS Y EXPERIMENTAL

Axis Title
X1 VS Y1 TEORICO
0.5 0.6
y

0.4

0.4
0.3

0.2
0.2

0.1

0 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x
 X,Y-T
66

64

62

60
Y VS T EXPERIMENTAL
X VS T ESPERIMENTAL
X1 VS Y1 TEORICO
T

Y1 VS T TEORICO
58

56

54

52
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X, Y
 UNIVERSIDAD NACIONAL DEL CENTRO DEL PERU

ESCUELA ACADEMICA PROFESIONAL DE INGENIERIA QUIMICA AMBIENTAL

ALUMNA: PALOMINO FERNANDEZ Lisbet Yanina
ECUACION DE VAN LAAR
ACETONA CLOROFORMO
A 7.02447 A 6.90328
B 1161 B 1163.03
C 224 C 227.4

P 760

A12 -0.3045
A21 -0.2709

X1 X2 T(°C) T(K) a1 a2
0.01 0.99 61.8591427 335.009143 0.50384679 0.99992139
0.1 0.9 62.9376914 336.087691 0.57459435 0.99234041
0.2 0.8 63.8949981 337.044998 0.65228929 0.97042967
0.3 0.7 64.423494 337.573494 0.72662154 0.93619527
0.4 0.6 64.4071103 337.55711 0.79523957 0.89185005
0.5 0.5 63.8221014 336.972101 0.85606341 0.83972015
0.6 0.4 62.7359124 335.885912 0.90739286 0.7820986
0.7 0.3 61.2794117 334.429412 0.94797886 0.72113098
0.8 0.2 59.6083475 332.758348 0.97705651 0.65873472
0.9 0.1 57.8705563 331.020556 0.99434213 0.59655032
0.99 0.01 56.3504001 329.5004 0.99994438 0.54188108

DATOS EXPERIMENTALES
T°C T°K x1 y1
62.7 335.85 0.1013 0.074
63.55 336.7 0.1792 0.1428
63.95 337.1 0.2528 0.2221
64.4 337.55 0.3022 0.2814
64.55 337.7 0.3697 0.3724
64.25 337.4 0.4418 0.4695
63.55 336.7 0.5268 0.5862
62.3 335.45 0.6318 0.707
61.8 334.95 0.6683 0.7526
61.27 334.42 0.702 0.7852
60.8 333.95 0.7315 0.8123
 60.1 333.25 0.7605 0.8376
59.3 332.45 0.8137 0.8793
57.95 331.1 0.8946 0.9411
57.1 330.25 0.9433 0.9699
56.7 329.85 0.9652 0.9822
QUIMICA AMBIENTAL

AN LAAR

Pvp1 Pvp2 Y1 Y2 Y1+Y2

918.394233 763.062427 0.00608855 0.99391107 0.99999963
951.251589 789.762068 0.07191892 0.92808096 0.99999988
981.182312 814.068233 0.16842493 0.8315747 0.99999963
998.019688 827.735324 0.28625629 0.71374385 1.00000014
997.494339 827.308958 0.4174984 0.58250174 1.00000015
978.877495 812.197042 0.55130342 0.4486962 0.99999963
945.035364 784.71218 0.67698816 0.32301174 0.9999999
901.105592 749.006506 0.78678992 0.21320992 0.99999983
852.700304 709.624373 0.87698566 0.12301427 0.99999993
804.559299 670.414349 0.94737696 0.05262314 1.0000001
764.229686 637.531486 0.99545436 0.00454561 0.99999997
 X VS Y

Axis Title

0 0.2 0.4 0.6 0.8 1 1.2

1 1.2

0.9

1
0.8

0.7
0.8

0.6
X VS Y EXPERIMENTAL

Axis Title
X1 VS Y1
0.5 0.6
y

0.4

0.4
0.3

0.2
0.2

0.1

0 0
0 0.1 0.2 0.3 x 0.4 0.5 0.6 0.7 0.8 0.9 1
 X,Y-T

Axis Title

0 0.2 0.4 0.6 0.8 1 1.2

66 70

68
64

66

62
64

62 Y VS T
60 X VS T EXPERIMENTAL

Axis Title
X1 VS T TEORICO
60 Y1 VS T
T

58
58

56
56

54

54
52

52 50
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X,Y
 UNIVERSIDAD NACIONAL DEL CENTRO DEL PERU

ESCUELA PROFESIONAL DE INGENIERIA QUIMICA AMBIENTAL

ECUACION DE WILSON
ACETONA CLOROFORMO
A 7.02447 A 6.90328 VOL.MOLAR1 67.38
B 1161 B 1163.03 VOL MOLAR2 78.218
C 224 C 227.4

P 760
R 1.987207

Y12-Y11 -72.2
Y12-Y22 -332.23
X1 X2 T(°C) T
0.01 0.99 61.9309188 335.080919
0.1 0.9 63.7828621 336.932862
0.2 0.8 65.6599217 338.809922
0.3 0.7 66.9046885 340.054689
0.4 0.6 67.2274947 340.377495
0.5 0.5 66.5644184 339.714418
0.6 0.4 65.0614191 338.211419
0.7 0.3 62.9920143 336.142014
0.8 0.2 60.6590318 333.809032
0.9 0.1 58.325478 331.475478
0.99 0.01 56.3881465 329.538146

DATOS EXPERIMENTALES
T°C T°K x1 y1
62.7 335.85 0.1013 0.074
63.55 336.7 0.1792 0.1428
63.95 337.1 0.2528 0.2221
64.4 337.55 0.3022 0.2814
64.55 337.7 0.3697 0.3724
64.25 337.4 0.4418 0.4695
63.55 336.7 0.5268 0.5862
62.3 335.45 0.6318 0.707
61.8 334.95 0.6683 0.7526
61.27 334.42 0.702 0.7852
60.8 333.95 0.7315 0.8123
 60.1 333.25 0.7605 0.8376
59.3 332.45 0.8137 0.8793
57.95 331.1 0.8946 0.9411
57.1 330.25 0.9433 0.9699
56.7 329.85 0.9652 0.9822
ON DE WILSON

A12 A21 a1 a2 Pvp1 Pvp2 y1 y2

1.2937957 1.91188361 0.320230372 0.99984581 920.55274 764.816968 0.003878802 0.99612112
1.29302485 1.90664765 0.412083362 0.98581069 977.638602 811.191198 0.053009027 0.9469906
1.29225262 1.90141348 0.51634186 0.94834913 1038.2966 860.410994 0.141083158 0.85891581
1.29174546 1.89798214 0.617801616 0.89423357 1080.12024 894.316214 0.263407906 0.73659119
1.29161458 1.8970974 0.712235976 0.82870227 1091.17864 903.276787 0.409040362 0.59095857
1.29188371 1.89891702 0.796448519 0.75591666 1068.55869 884.946108 0.559902623 0.44009573
1.29249787 1.90307453 0.868043957 0.67930924 1018.64427 844.470594 0.698074742 0.30192457
1.29335294 1.90887478 0.925225151 0.60178787 952.930593 791.125937 0.812069404 0.18793026
1.29433032 1.91552168 0.96670453 0.52578518 882.889351 734.190829 0.898413826 0.10158596
1.29532246 1.92228745 0.991706948 0.45323683 816.949137 680.509907 0.95941674 0.04058318
1.29615741 1.92799572 0.999917741 0.39208576 765.211355 638.332289 0.996706482 0.00329317
y1+y2
0.99999992
0.99999963
0.99999897
0.9999991
0.99999893
0.99999835
0.99999931
0.99999966
0.99999979
0.99999992
0.99999965