The standard coal analysis

1:Range

The standard coal analysis, determination of total sulfur in coal, heat and chemical analysis
of coal ash.

This standard applies to coal combustion analysis

2: reference standard

"GB / T212 "method of analysis of the coal industry

".GB / T213 "Determination of calorific value of coal

".GB / T214 "Determination of total sulfur in coal

".GB / T176 "chemical analysis of cement

3: Analysis of the coal

3.1: Determination of moisture

3.1.1 accurately weight 1.000g sample, put in a constant weight weighing bottle, put into
pre-heated oven at 105 ~ 110 ℃,open the lid, for one hour, remove the weighing bottle
and close, placed in the dryer to cool to room temperature (about 20 minutes), weight

3.1.2 Check drying, every 30 minutes, until no more reduce than 0.0010g. In the latter
case, increase in mass calculated. When moisture 2.00% or less, do not have to check the
dried sample

Moisture is calculated as follows:

m  m1
Wad   100
m

Where: Mad ------ air-dried coal sample moisture %

m -------- Air-dried sample mass (g)

m1 ----- After drying sample mass (g

3.2 :Determination of Ash.

Accurately weight 1.000g sample, burned into ash to constant weight pave dish
placed on heated electric furnace, and then the furnace temperature later moved 800 to
900 ℃ coal ash samples until no black particles, burning for one hour, remove to cool 5
minutes in the air, then into a dryer to cool to room temperature (about 20 minutes)
.weighing

Ash is calculated as follows

 m1
Aad %   100
m

Where: Aad-- air-dried coal ash %

M ---- sample mass (g)

M1 ----- After burning coal ash mass (g)

3.3 Determination of volatile matter

Fine sample weight 1.000g in crucible, has been burned into the constant weight of volatile
,matter

,Gently vibrating crucible

,Pave the coal samples

,Put the lid cover

,Placed in a crucible holder

,Quickly into the pre-heated to about 920 ℃ muffle furnace

,Shut the door

,And timing

,Burning exactly for 7 minutes (later into the crucible and shelves

,There after kept at 900 ± 10

,Otherwise, the test set aside

.)Heating temperature recovery time includes the time included

,Remove the crucible from the furnace

,Cooling in air for 5 minutes

.Into a dry vessel cooled to room temperature (about 20 minutes), weighing

Volatile matter is calculated as follows

m  m1
Vad %   100  M ad
m

Where: Vad - air drying volatile group %

M ----- sample mass (g)

M1 ----- Residue after ignition mass (g)

Wad --- moisture analysis base

3.4 Calculate air dried base fixed carbon

Fixed carbon is calculated using the following formula

FCad＝ 100 －（W ad＋A ad＋ V ad）

Where: FCad - air-dried base percentage of fixed carbon content %

Wad------ moisture air dried group %

Aad ---- air drying base ash %

Vad - air drying volatile matter group %

3.5 coal calorific value calculation

3.5.1 Calculation analysis of bituminous coal calorific empirical formula

(Unit: J / g)

Qnet.ad =35859.9－ 73.7Vad－395.7A ad－702.0M ad+173.6CRC

Where: Qnet.ad - Analysis of calorific value

Mad - air-dried coal moisture content %

Aad - air-dried coal ash content %

Vad - air-dried coal volatile content %

CRC - coke residue characteristics.

3.5.2 Calculated matter anthracite low calorific formula (unit: J / g)

Q net.ad ＝34813.7－24.7V ad －382.2A ad －563.0M ad

Where: Mad-- air-dried coal moisture %

Aad-- air-dried coal ash %

Vad-- air-dried coal volatile matter %

3.5.3 )High ash Aad> 45 % anthracite calorific formula (unit: J / g

Qnet.ad =330FC ad+146V ad－ 10.5A ad－ 25.1M ad

 3.5.4. High ash Aad > 45 % bituminous coal calorific formula (unit: J / g)

Qnet.ad =339FC ad+197V ad－ 12.5A ad－ 25.1M ad

3.5.5 Identification of the characteristics of coal residue

(Determination of volatile coke residue characteristics of the resulting time-pressed to

distinguish between strong provisions)

1. Full powdered

2. Adhesion - a light touch with a finger Serve powdered or substantially powdered

3. Weak bonding - by pressing with a finger that is broken into small pieces

4. Not fused adhesive - to beat it fragmented into small pieces with your fingers on the coke
residue matte, lower surface silvery shiny is not obvious

5. Not expansion of fusion bonding - coke residue form a flat cake, coal grain boundaries is
not easy to distinguish, the surface of silver-white metallic luster, under coke residue surface
of the silver-white luster is more obvious

6. Melt adhesive micro-expansion - with a finger pressure is not broken, the coke residue,
silver-white metallic shiny on the lower surface, but on the surface of coke residue, with a
smaller expansion of bulb

7. Expansion of the fusion bonding - on coke residue, the lower surface of silver-white
metallic luster, expansion of height of not more than 15 mm

8. Strong expansion of the fusion bonding - coke residue on the lower surface of silver-white
metallic luster, expanded height greater than 15 mm

Vad

K ＞10- ＞13.5- ＞17- ＞20- ＞23- ＞29- ＞32- ＞35- ＞38-

＞42
13.5 17 20 23 29 32 35 38 42
焦渣特
征

1 84.0 80.5 80.0 78.5 76.5 76.5 73.0 73.0 73.0 72.5

2 84.0 83.5 82.0 81.0 78.0 78.0 77.5 76.5 75.5 74.5

3 84.5 84.5 83.5 82.5 81.0 80.0 79.0 78.5 78.0 76.5

4 84.5 85.0 84.0 83.0 82.0 81.0 80.0 79.5 79.0 77.5

5-6 84.5 85.0 85.0 84.0 83.5 82.5 81.5 81.0 80.0 79.5

7 84.5 85.0 85.0 85.0 84.5 84.0 83.0 82.5 82.0 81.0
8 --- 85.0 85.0 85.5 85.0 84.5 83.5 83.0 82.5 82.0

4. Determination of total sulfur in coal

4.1 Determination of total sulfur chemical process

4.1.1 Reagents

Ai Shika mixture -2 parts by weight of magnesium oxide and a mass mix of sodium
carbonate

2 g / L methyl red ethanol solution

Hydrochloric acid (1 + 1)

10 % barium chloride solution

10 % silver nitrate solution

4.1.2 Analysis steps

Accurately weighed sample 0.5000g, placed in a 30mL porcelain crucible, add 2g Ai Shika
mixture and mix, then 1g mixed reagent to the sample surface covered, first on the electric
heating for half an hour after incubation, into low , L high-temperature furnace temperature
gradually to 800 ℃ ~ 850 ℃ and held for 1.5 to 2 hours, then remove cooling, the
agglomerated material with a glass rod pound loose, check black particles, if not burned
black particles, then a small amount of mixed reagent Ai Shika covered on sinter, continue to
burn until no black particles at the same temperature, then transferred to a beaker sinter,
washed with water, the crucible, adding 100 ~ 150mL hot water, crushed with a glass rod
lumps, and boil for 15 minutes, then filtered and the residue washed with water in a beaker
three times Shifting funnel, then hot water wash-fifth

Adjust the volume of the filtrate 200 ~ 300mL, three drops of methyl red was added
dropwise, with hydrochloric acid (1 + 1) neutralized and excess 1mL, heated to boiling.
10mL10% barium chloride solution was then added dropwise, under stirring and continue to
boil 5 minutes, placing the heat for 2 to 3 hours or overnight, filtered with a slow filter, the
precipitate was washed with warm water. The precipitate all moved on paper. Wash until no
chloride reacted. The precipitate and filter paper moved together with constant weight has
been burned porcelain ashing crucible, fired at 800 ~ 850 ℃ high temperature oven for 1
.hour, cooled weighed. So repeatedly, until constant weight

The percentage of the total sulfur content is calculated as follows

m1  0.1975
S%   100
m

Where: m - sample mass (g)

m1 - precipitation mass (g)

5. Determination of calorific value of coal

5.1 Test Equipment

DM3100 type oxygen bomb calorimeter

6. Chemical analysis of ash

Chemical analysis coal ash the same chemical analysis of clay