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4.1.1 Discuss the structure of the Rutherford model of the atom, the existence of the
nucleus and electron orbits
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Module 4 – From Quanta to Quarks
The inability of classical physics to explain the curve associated with black body radiation was a
significant issue. In particular, the UV catastrophe – a result of applying classical physics to black
body emissions – suggested that there is an infinite amount of energy in the universe.
Planck offered a solution to the UV catastrophe, proposing that the energy emitted or absorbed
by the walls of a black body is quantised, occurring in discrete ‘packets’.
– This energy is described by multiples of: .
This was the beginning of the concept of quantised energy and led on to further developments to
give us quantum physics as we currently know it.
Bohr took Rutherford’s model of the atom and built upon it in order to solve some of the
problems associated with the model.
He put forward 3 postulates:
1. Electrons in an atom exist in ‘stationary states’ or stable orbits in which they do not emit
EMR and possess an unexplainable stability.
2. A transition between two stationary states is accompanied by the emission or absorption
of a quantised amount of energy, where:
Bohr’s theoretical equation for the wavelengths of the spectral lines of hydrogen agreed with
earlier empirical formulas of Balmer and Rydberg.
In addition, the hydrogen spectrum and Balmer’s equation for the wavelength of these spectral
lines suggested the existence of certain allowable energy states within the atom.
This significantly influenced Bohr’s development of his model of the atom in which he quantised
electron orbits into allowable energy states.
nd
His 2 postulate explains the origin of spectral lines.
Note:
– An emission spectrum is produced when a gas is excited.
– This can be achieved by heating the gas or by passing an electrical current through a low
pressure gas.
– The light produced when viewed with a spectroscope will be made up of a series of bright
coloured lines.
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Using Bohr’s postulates, together with the energy of electrons calculated from ‘classical’ physics
applied to the Rutherford model, it is possible to derive a theoretical equation for the wavelength
of spectral lines of hydrogen which is the same as the Balmer-Rydberg equation.
In order to derive this equation:
rd
1. Use Bohr’s 3 postulate (the quantisation of angular momentum into multiples of )
together with the energy of protons and electrons (calculated using the electrostatic force
attraction between protons and electrons) to find the specific orbital radii of electrons.
2. Use these radii to calculate the value of the energy within specific electron orbits.
nd
3. To this, apply Bohr’s 2 postulate regarding the transition of electrons to different
energy/stationary states to arrive at Rydberg’s equation.
4.
nd
By Bohr’s 2 postulate, every
transition from a certain energy
level will release a photon of the ( )
−𝐸1
same energy. Hence this When is
𝑐
produces specific wavelengths of ( ) calculated, it agrees
light for the hydrogen spectrum. with the Rydberg
( ) constant.
Bohr’s model and his postulates successfully accounted for the hydrogen emission spectrum and
allowed the theoretical calculation of the wavelengths. The theoretical derivation of Balmer’s
equation provided strong support for the Rutherford-Bohr atomic model of the hydrogen atom.
4.1.6 Discuss the limitations of the Bohr model of the hydrogen atom
4.1.7 Analyse secondary information to identify the difficulties with the Rutherford-
Bohr model, including its inability to completely explain the spectra of larger atoms,
the relative intensity of spectral lines, the existence of hyperfine spectral lines and the
Zeeman effect
The Bohr model introduces quantum theory to the atom but has a number of limitations:
– The Bohr model works reasonably well for atoms with one electron in the outer shell but
cannot explain the emission spectrum of larger atoms.
– Examination of spectra shows that spectral lines are not of equal intensity (indicating that
some types of transitions were more preferred than others) but the Bohr model does not
explain this relative intensity of spectral lines.
In fact, it is the probability of transitions between energy levels that indicates the relative
intensity of spectral lines.
– More careful observation shows that one spectral line consists of smaller hyperfine lines. The
Bohr model cannot account for this.
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The hyperfine lines are actually the result of sub-orbitals or subshells within each principal
atomic orbital.
– When an element is excited and placed in a magnetic field, the emission spectrum produced
shows splitting of a single spectral line into several separated lines, called the Zeeman effect.
The Bohr model cannot account for this.
– The Bohr model is a mixture of classical and quantum physics, which, in itself, is a problem.
The value of for each stationary state or orbit of the Bohr atom is the principal quantum number
of that orbit.
The Balmer series includes any emission from atoms due to electron transitions occurring as
visible light ( ).
This occurs when an electrons transitions from a stationary state , to .
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4.2.1 Describe the impact of de Broglie’s proposal that any kind of particle has both
wave and particle properties
De Broglie proposed that all particles (not just photons) have both wave and particle
properties. The wavelength of any particle is determined by:
Impacts:
– It provided a quantum exploration of Bohr’s model of the atom which previously relied on
classical physics.
– It was able to explain the stability of electrons in stationary states in Bohr’s atom in terms of
allowable standing waves.
– This wave-particle duality of matter was able to explain the properties and interactions of
atoms and small particles, acting as a starting block from which the theory of quantum
mechanics was developed by scientists such as Heisenberg, Pauli, Schrodinger and Born.
4.2.2 Define diffraction and identify that interference occurs between waves that
have been diffracted
Diffraction is the bending or spreading out of waves that have encountered an object or an
opening with size of the order of magnitude of the wavelength of the wave.
Waves that have been diffracted will constructively and destructively interfere to form a pattern of
light and dark patches known as an interference pattern.
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4.2.4 Explain the stability of the electron orbits in the Bohr atom using de Broglie’s
hypothesis
De Broglie proposed that all matter has both wave and particle properties.
The wavelength of a particle is determined by:
De Broglie explained the stability of electrons in
stationary states by suggesting that only orbits made
up of a whole number of wavelengths of the electron
are able to exist, making a standing wave pattern.
– Each orbit (stationary state) was occupied by an
integral number of wavelengths that fitted
around the circumference of the orbit. The
circumference of a circular orbit is and hence
an integral number of wavelengths: .
rd
– This enabled a mathematical derivation for Bohr’s 3 postulate – the quantisation of angular
momentum – adding rationality to this postulate.
As electrons are now standing waves, they are no longer moving charges, and hence will not emit
EMR. Standing waves do not propagate, and therefore are stable and will not lose any energy.
Intermediate electron energy levels containing a non-integer number of wavelengths would cause
electrons to destructively interfere with themselves, and hence they would be unstable and
undergo decay.
st
In this way, de Broglie’s hypothesis could explain the stability of electron orbits (Bohr’s 1
postulate) using quantum physics.
4.2.5 Gather, process, analyse and present information and use available evidence to
assess the contributions made by Heisenberg and Pauli to the development of atomic
theory
Heisenberg:
– Heisenberg founded matrix mechanics, a mathematical system which is applied to physical
quantities.
Applying matrix mechanics provides an explanation for the nature of small particles (e.g.
subatomic particles such as electrons and protons) and their interactions.
Matrix mechanics was able to successfully predict and mathematically explain the
emission spectra of many elements, not just hydrogen, and also solve the problems
with Bohr’s model (such as the differences in intensity between spectral lines, hyperfine
structures, and the Zeeman effect).
– Heisenberg was also able to explain bond formation (ionic and covalent), and the behaviour
of ferromagnetic materials.
– Heisenberg also put forward his uncertainty principle, which stated that uncertainty is an
inherent property of quantum mechanics.
If the position of an object is known accurately, then its momentum cannot be known
accurately.
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This principle explains the uncertain, probabilistic nature of atomic behaviour and
interactions, and has come to be a central feature of quantum theory today (e.g. Bohr’s
planetary model with electrons in fixed orbits was abandoned in favour of ‘electron
clouds’ or ‘orbitals’, where an electron’s position is a statistical probability).
Pauli:
– Pauli proposed the Pauli Exclusion Principle which states that no two electrons may exist in
the same quantum state or have the same quantum numbers in an atom.
These quantum numbers are principal, angular momentum, magnetic and spin quantum
numbers.
This exclusion principle could explain the electron distributions in atoms and the
position of elements on the periodic table.
– Pauli also proposed the existence of the nearly massless, neutrally charged neutrino, and in
doing so, enhanced our understanding of nuclear transmutations and explained the
continuous spectrum of beta decay.
– Pauli also predicted Rydberg’s constant, and introduced the concept of spin to the electron.
4.3.1 Define the components of the nucleus (protons and neutrons) as nucleons and
contrast their properties
They are both bound by the strong nuclear force into atomic nuclei.
The nucleus described by Rutherford was simply a concentrated mass of positive charge, around
which electrons orbited. The composition and internal structure of the nucleus was unknown at
the time.
Protons were the first nucleons to be discovered, in a similar way to the discovery of electrons.
The charge-to-mass ratio of the protons was measured in a discharge tube containing hydrogen
ions (which are simply protons).
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Natural transmutation occurs when radioactive elements spontaneously decay over time to
transform to more stable elements.
– Alpha ( ) decay:
Alpha decay refers to an unstable nucleus emitting an alpha particle (energetic helium
nuclei). It occurs for elements with large unstable nuclei (if their atomic number 83).
−
−
– Beta ( ) decay:
−
decay: The −
particle is identical to an electron. −
decay occurs when the ratio of
neutrons to protons is too high. It involves the transformation of a neutron into a proton,
an electron and an antineutrino ̅ .
−
decay: The particle is identical to an anti-electron (positron). decay involves the
transformation of a proton into a neutron, a positron and a neutrino .
Note:
» An antineutrino accompanies the emission of the electron ( − ).
» A neutrino accompanies the emission of the anti-electron (positron) ( ).
» Neutrino and anti-neutrino, as well as electron and positron, are known as matter
and anti-matter pairs. When matter meets anti-matter, they annihilate each other’s
mass completely. This mass is converted to energy in the form of gamma rays,
according to .
– Gamma ( ) radiation:
Gamma radiation is the highest frequency electromagnetic radiation in the EMR spectrum.
After the emission of an or particle, the daughter (resultant) nucleus is left in an
excited state. The change in energy from this excited energy state to the ground state of
the nucleus results in the emission of a gamma ray, a high energy photon.
Gamma radiation is pure energy and does not change the atomic number or the atomic
mass , so it is not a transmutation.
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– Chadwick allowed the neutrons to strike a block of (proton-rich) paraffin wax and collide with
and knock out protons (these protons had very high energy).
– Protons were ejected from the paraffin wax and since they have charge, their momentum and
kinetic energy could be measured by the detector.
For a proton to be ejected at 5 , the equivalent incident gamma radiation would need
50 energy. However, the energy of the incident alpha particles was measured to be
5 only.
The problem was the 10 fold increase in energy, which violated the principle of
conservation of energy. This led to much debate as to whether the conservation laws held
true on a subatomic scale.
Chadwick, however, assumed that these laws did apply and was able to calculate the mass of the
neutron by applying the principles of conservation of energy and conservation of momentum to
the interaction of a neutral particle with a proton.
– He did so by measuring the recoil of nuclei of hydrogen and nitrogen atoms in the paraffin
wax after interacting with the neutral radiation.
– He found the mass of the particle to be times that of a proton.
– He named this heavy, neutral particle the neutron.
4.3.5 Discuss Pauli’s suggestion of the existence of neutrino and relate it to the need
to account for the energy distribution of electrons emitted in -decay
When particles are emitted from a source, their energies are identical or vary predictably.
When considering radiation, it was expected that
-decay emitted from a particular radioactive
species would be emitted with a set energy.
However, it was established by Chadwick (using a
Geiger ‘point counter’ to detect beta particles) that
particles were emitted with different energies,
which seemed to violate the law of conservation of
energy. This finding led to considerable debate as
to whether particles had a continuous spectrum.
In an effort to explain this continuous range of
energies in radiation, Pauli predicted the
existence of another subatomic particle, the neutrino, which accompanied decay and could
account for the varying levels of energy. The neutrino carried away a variable fraction of energy
(that was less than the maximum kinetic energy possible for an ejected beta particle) during
decay so that the total energy of the decay is always conserved.
Pauli described the neutrino as neutral, nearly massless, highly penetrative, travelling at the
speed of light with momentum, energy and spin and proposed that the number of electrons
and neutrinos was not constant, but they could be created and destroyed when neutrons and
protons turned into one another.
−
decay: −
decay:
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4.3.7 Account for the need for the strong nuclear force and describe its properties
Therefore, the ratio of the forces acting between two protons in a nucleus is:
This indicates that the force due to gravitational attraction is considerably smaller than the force
of electrostatic repulsion. Thus, it would seem impossible for the nucleus to hold together its
protons, unless another force (stronger than electrostatic repulsion) exists between nucleons to
keep them from flying apart.
This force is the strong nuclear force (a fundamental force of nature), responsible for holding the
nucleons together inside the nucleus.
Properties of the strong nuclear force:
– It is independent of charge (i.e. acts between all nucleons with the same force).
This is supported by evidence that protons and neutrons are equally likely to be ejected
from a nucleus in a collision.
– At distances corresponding to the
diameter of a nucleon, it is a very strongly
attractive force (much stronger than
electrostatic forces). However, it becomes
strongly repulsive at smaller distances. At
larger distances, its strength rapidly
decreases.
– It is a short range force acting between
adjacent nucleons only (over distances of
-15
10 ).
This is supported by evidence based on the observed stability of the nucleus.
– It exists only between nucleons (and their nearest neighbour nucleons).
– It favours the binding of pairs of nucleons with opposite spin and pairs of pairs of nucleons
each pair having total spin of zero.
– It is carried by gluons (pi-mesons/pions).
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4.3.8 Explain the concept of a mass defect using Einstein’s equivalence between mass
and energy
Loss of mass (mass defect)
therefore emits energy
Total mass of Total mass of the
constituent nucleons nucleus
Requires energy (binding energy)
therefore gains mass
In an atom, mass of all the individual nucleons actual mass of the nucleus.
The mass defect is the difference between the mass of a nucleus and the total mass of its
constituent nucleons. This mass defect is due to the energy required to overcome the binding
energy in order to separate the atom into its constituent nucleons.
Thus, the binding energy is the energy equivalent of the mass defect of the nucleus.
According to , the energy put into the system to separate nucleons is transformed into
mass, making the final particles heavier. This creates and is equivalent to the mass defect. Bond
formation (when nucleons combine) liberates energy, which carries some of the mass away with it.
The stability of the nucleus is indicated by the average binding energy per nucleon. This is the
total binding energy of a nucleus divided by the number of nucleons:
binding energy Eb
Binding energy per nucleon
atomic mass number
– has quite a high binding energy per
nucleon, which makes it very stable and
explains why alpha particles (rather
than single protons) are ejected from
nuclei in alpha decay.
This concept of binding energy and mass
defect allows for energy changes in nuclear
reactions.
Nuclear fission is the splitting of atoms;
nuclear fusion is the joining of atoms.
From the graph, either splitting high-mass
nuclei or fusing lighter nuclei will increase the
binding energy per nucleon.
The nuclear binding energy of elements increases with increasing number of nucleons until Fe-56.
Heavier atoms become less stable (and so have lower binding energy).
Fermi observed that if various elements are bombarded by neutrons, new, heavy elements are
produced by nuclear fusion. Fermi explained that the neutral neutron would experience no
electrostatic force when approaching a nuclear surface, and so can penetrate and interact with the
charged nucleus.
However, when Fermi bombarded uranium (atomic number 92) with new neutrons, a number of
unidentifiable products were formed. Later analysis of one of these products identified it as
barium ( 56). This suggested that the uranium nucleus, having absorbed a neutron, could split
into smaller atoms with the release of energy. This process was named nuclear fission.
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4.3.11 Compare requirements for controlled and uncontrolled nuclear chain reactions
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Fissile mass:
– A fissile material is a substance able to undergo nuclear fission.
– A critical mass is the smallest amount of a fissile material needed for a sustained
nuclear chain reaction. This mass depends on the material’s nuclear properties, density,
shape, purity, temperature and its surroundings.
– If a fissile material has subcritical mass, too many neutrons escape to be effective in sustaining
a reaction (i.e. neutron multiplication factor 1).
– If a fissile mass is supercritical, the reaction will be uncontrolled.
felt rings
soaked in
source of ethanol
radiation
(𝛼, 𝛽 or 𝛾)
dry ice
A cloud chamber is a device used to detect the ionising radiation. It allows for observation and
manipulation of radiation in order to assess its properties.
The Wilson Cloud Chamber consists of a chamber filled with the vapour of a polar substance (e.g.
ethanol). This vapour is supercooled by dry ice and kept supersaturated by felt rings, soaked in
ethanol, on the sides of the chamber.
Radiation enters through the side of the chamber and a Perspex window is located at the top of
the chamber for viewing.
When ionising radiation enters the chamber, it strikes the vapour particles, causing ionisation. The
surrounding polar vapour particles are attracted to the ionised particle, causing droplets of
precipitation to form. This forms a visible track of droplets along the path of the radiation through
the chamber.
The nature of the track is characteristic of the type of radiation:
– particles (highly ionising and heavy) create thick and straight paths.
– particles (less ionising and much lighter) create more faint and zigzag tracks as they are
easily deflected.
– rays (least ionising) produce very faint trails as they do not interact strongly with matter.
A magnetic field or electric field may also be applied to the chamber at 90° to the plane of the
movement of the radiation. and particles will curve in opposite directions, while rays will
pass straight through.
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control rods
steam
outlet
fuel heat
rods exchanger
moderator water
inlet
coolant
Fission reactors are based on several principles of nuclear fission reactions, and require certain
parts to function:
1. Fissile material
The fissile (fissionable) material is used in the form of fuel rods.
The fissile fuel (e.g. U-235) must be enriched to a critical mass such that there is enough
material present for the reaction to be self-sustaining.
2. Moderator (e.g. graphite, normal or heavy water (deuterium))
The neutrons produced by fission are fast neutrons with too much energy to interact with
nuclei and cause fission.
Fission is most effectively induced by slow neutrons, which spend more time in the
vicinity of the nucleus and are thus more easily captured.
» The moderator absorbs some of their energy and brings neutrons into thermal
equilibrium with their surroundings so they are within an energy range most likely to
cause the fission of the fuel-material.
» Therefore, the moderator must be made of a material which does not absorb
neutrons or undergo fission/fusion, but allows collisions between neutrons and
moderator atoms to slow them down.
3. Control rods (e.g. cadmium, boron)
Control rods are used in order to ensure the fission reaction is controlled, and a steady
amount of energy is released.
They control the number of neutrons which are allowed to collide with U-235 by
absorbing them and not undergoing any fusion/fission reactions.
Extra neutrons are absorbed by the control rods so that the number of neutrons present
for each of the subsequent fission reactions remains roughly constant.
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Neutron scattering is a powerful method of analysing or probing the internal structure and
properties of matter using neutrons.
This involves elastic or inelastic collisions with the molecules to be studied and hence, the
neutrons scatter in directions determined by both the neutron’s wavelength and the structure of
the molecule. The interference patterns produced by the neutrons can be interpreted to give
insight into the internal structure of matter.
How it is carried out:
graphite cylinder
monoenergetic
– Some nuclear reactors are designed
neutron beam
so that a beam of low-energy
neutrons is allowed to pass through
a small graphite cylinder in the neutron beam
reactor
shield wall. core crystal
– After many collisions with carbon
atoms in the graphite, the neutrons
emerge with a range of low
energies.
– They are then reflected off the surface of a crystal, and a single monoenergetic beam is
selected, which can then be diffracted by other materials to study their structure.
– The scattering of neutrons can be detected by a diffractometer or spectrometer.
Properties of neutrons:
1. Neutrons have no charge, so do not experience electrostatic forces and so are not deflected
by the nucleus. Therefore they interact with the nucleus by collision only and so can penetrate
the interior of the nucleus, providing more precise measurements of interatomic distances.
2. Slow neutrons have a de Broglie wavelength that is comparable to the spacing between
atoms in molecules. Thus, they can be scattered by these crystals and produce interference
patterns which obey Bragg’s Law. The interatomic distances and the structure of the material
can then be mathematically calculated.
3. Neutrons have a magnetic moment that makes them an ideal tool for studying magnetic
structures and materials.
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4. Neutrons have energy similar to the vibrational energy of atoms in liquids and solids,
allowing the detailed study of the motion of atoms in molecules.
5. Neutrons can be used to study materials without causing destruction.
6. Neutrons interact strongly with nuclei. This varies for different nuclei, making it possible to
study isotopes of lighter elements.
The disadvantage of neutron scattering is that a nuclear reactor is required to produce the
neutrons.
4.4.3 Discuss the key features and components of the standard model of matter,
including quarks and leptons
The standard model of matter is a description of the fundamental units making up matter and
all matter interactions. It describes 12 basic subatomic particles and the forces between them:
- Known as Bosons
- ‘Carry’ different forces
Quarks Leptons Force Particle
Gravity Graviton
6 ‘flavours’ of quarks: 6 ‘flavours’ of leptons: (not yet
Flavour Charge Flavour Charge discovered *)
Baryons Mesons
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The standard model of matter state that all matter is composed of small elementary particles that
exist by themselves or group together to form subatomic particles and to transmit force.
– Quarks are fundamental particles – the smallest particles that cannot be broken down further.
All quarks, and thus all hadrons, act through strong nuclear force, which enables protons and
neutrons to form the nucleus of an atom.
– This is the reason for the strong nuclear force to act equally between proton-proton, proton-
neutron and neutron-neutron, since all are made from different numbers of the same quarks.
All leptons interact through weak nuclear force, and the charged leptons also interact through
electromagnetic force (which binds negatively charged electrons to positively charged protons in
the nucleus).
Usefulness & Applications:
– The standard model of matter is useful for explaining the large number of particles and
particle interactions which exist within the universe.
– This can also be used to explain what happened at the time of the Big Bang and predict what
may happen at the end of the Universe (the ‘Big Crunch’).
There are, however, a number of disadvantages with the standard model of matter.
– The standard model is a quantum-mechanical model, while Einstein’s theory of general
relativity is not (i.e. they are incompatible). Thus, the force of gravity cannot be incorporated.
– The model does not (yet) give a reason for the mass of particles.
Note: The proposed mass particle is Higgs boson. Recent research has discovered a boson
whose behaviour is consistent with a Higgs boson, although further testing is required to
confirm its properties.
– The model does not give reasons for the number of particles (e.g. 6 flavours of quarks or
leptons).
– The model is not a grand unifying theory (which unites all four fundamental forces).
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Module 4 – From Quanta to Quarks
– Probe the interior of protons and neutrons to gain an understanding of their structure at a
quark level.
Various collisions of high energy particles using particle accelerators have allowed physicists to
infer the existence of over 200 sub-atomic particles and the fundamental forces binding them.
This provided physicists with the experimental evidence that led to the standard model of
matter.
Cyclotron:
– A cyclotron is composed of two conducting
‘D’s placed inside a uniform magnetic field
which passes perpendicular to their surface.
The ‘D’s are each attached to one terminal of
an AC source.
– The charged particle that is to be accelerated
originates within the gap between the 2 ‘D’s.
When the particle is within this gap, the electric
field accelerates the particle towards one ‘D’.
– Once the particle reaches the edge of the ‘D’, the electric field is switched to the opposite
direction, allowing the particle to be once again accelerated. This alternating electric field
arises as a result of an alternating voltage source attached to the two ‘D’s.
– The magnetic field within the two ‘D’s keeps the charged particles moving in a circular path,
which increases in radius as the velocity of particles increases. This magnetic interaction is
mediated by the motor effect ( ) and the radius is determined by the laws of circular
motion ( ).
– Eventually, the particle reaches the outer edge of the two ‘D’s where it escapes the cyclotron
to be directed towards a target. A pulse of particles is produced.
Linear Accelerator:
– Linear accelerators are constructed using
conducting tubes, each attached to
alternating terminals of an AC source.
– The charged particle that is to be
accelerated originates before the first tube.
When the particle is outside/in between
tubes, the electric field is switched on.
– This accelerates the particle towards the first tube.
– Once it enters the tube, the electric field is switched off, and the particle travels in a straight
line (due to inertia) until it reaches the other end of the tube.
– At this point, the electric field is switched on again, but now in the opposite direction.
– This causes the particle to be accelerated in the same direction due to the attraction and
repulsion towards the next tube, accelerating it across the gap.
– Once it enters the next tube, the electric field is switched off, and the process is repeated.
– In the accelerator, the frequency of the AC is constant, but the velocity of the particle is
increasing.
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– Thus, the particle will travel increasing distances in the time it takes for the AC to undergo one
‘oscillation’, which requires the conducting tubes to increase in length.
– Once the length of the tube becomes impractical to add anymore, the particle is allowed to
strike the target.
– A beam or pulse of particles can be produced.
Synchrotron:
– Synchrotrons use multiple magnets placed around the circumference of a circle, with electric
fields placed between each magnet. The electric field accelerates particles around the circle,
and each magnet deflects the particle by a small degree.
– Particles are accelerated in bursts, and both the frequency of the accelerating potential
(oscillating AC source) and the strength of the magnetic field are varied as the particles are
accelerated, keeping the orbital radius constant. Often, a beam of charged particles is
accelerated by a linear accelerator, and then fed into the synchrotron for further acceleration.
4.4.6 Identify data sources, and gather, process, and analyse information to describe
the use of a named isotope in medicine, a named isotope in agriculture and a named
isotope in engineering
Medicine:
– Technetium-99m is used in diagnostic imaging.
– It is used in imaging of many organs of the body, e.g. the circulatory system and the heart.
– The fission of uranium produces molybdenum-99, which undergoes continuous beta decay to
form technetium-99m:
−
– Use:
Tc-99m is used as a diagnostic tracer to detect abnormal blood clots, constrictions and
other circulation disorders.
For example, when imaging the circulatory system, Tc-99m is combined with a tin
compound, and then incorporated into a blood serum. It is then injected into the blood
stream and travels with the circulatory system.
This allows abnormalities to be visualised or detected in blood flow (e.g. clots,
constrictions, dilations) using a scintillation counter.
– Properties related to its use:
Tc-99m has a short half-life of 6 hours so it is rapidly eliminated from the body to
cause minimal exposure and damage to tissue due to radiation.
It emits gamma radiation which is detectable from outside the human body, and causes
the least amount of ionisation compared with and radiation.
Tc-99m has a number of oxidation states that allows it to react to form a range of
biologically active compounds which bind to the organ of interest.
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Engineering:
– Sodium-24 is produced in a nuclear reactor by neutron bombardment of the naturally
occurring sodium-23.
– Use:
Sodium-24 is used in detecting leakage from underground water pipes. It is
introduced into the water pipes as a compound such as and undergoes
continuous decay to emit beta and gamma radiation.
The radiation (mainly ) is then detected at ground level, with any abnormal distributions
or increase level of the radiation detected indicating a leakage.
– Properties related to its use:
Sodium-24 is a co-emitter of beta and gamma radiation. The gamma radiation is
penetrative enough to reach the surface so that it can be detected.
It has a short half-life of 15 hours, which is long enough for the process of detecting the
leakages but does not stay in the water system long enough to cause harm to end users.
Agriculture
– Cobalt-60 is used in gamma ray food irradiation in agricultural settings.
– The stable isotope cobalt-59 is placed in a nuclear reactor and absorbs a neutron to produce
cobalt-60. Co-60 decays with the emission of beta and gamma radiation, killing bacteria and
disease causing organisms which cause food poisoning and rot foods like fruit, vegetables
and meat. This prevents the spread of food-borne diseases that are central to food poisoning.
– Use:
Co-60 is enclosed in 2 steel layers and placed inside a chamber with thick, concrete walls.
Food is passed through the chamber on a conveyor belt, and is exposed to the radiation
for a specific length of time. The conveyor belt is timed so that the amount of gamma
radiation is significant enough to kill bacteria, but not enough to make food radioactive.
The gamma radiation kills food-poisoning bacteria/micro-organisms, allowing the food to
be preserved longer. An example is the irradiation of wheat.
– Properties related to its use:
Co-60 emits gamma radiation which is energetic enough to kill micro-organisms in food.
It has a long half-life (5.5 years) so does not require replacement often.
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Module 4 – From Quanta to Quarks
4.4.7 Gather, process and analyse information to assess the significance of the
Manhattan Project to society
The Manhattan Project, code-named the “Manhattan Engineering District”, was a US effort during
WWII to build the first nuclear weapon. This research was with the assistance of the UK and
Canada in response to the possibility of Nazi Germany developing nuclear weapons.
This project was commenced following its recommendation by Albert Einstein.
This has many political, scientific, environmental and ethical impacts.
Assessment: The Manhattan Project was of great significance to society in both positive and
negative ways:
Advantages Disadvantages
Nuclear weaponry led to the early conclusion of More than 100,000 people were killed in the 1945
WWII, sparing many lives, and allowing nations bombings of Hiroshima and Nagasaki. There were
to restabilise. thousands more deaths due to cancer caused by
radiation in the years following.
Nuclear fission research led to the development There are a range of issues regarding nuclear
of nuclear power generated from nuclear wastes (which are difficult to dispose of and emit
reactors. harmful radiation) and the exposure of plant
This had several important impacts: workers to radiation.
Reduced the consumption of fossil fuels There is also the danger of explosions occurring,
Provided society with an alternative power such as Chernobyl and Three Mile Island.
source
Created jobs in nuclear power plants.
Further research has allowed nuclear reactors to Workers using radioisotopes are at great danger of
be harnessed for the production of radiation exposure.
radioisotopes for use in industries, agriculture
and medicine.
In medicine, this has led to new methods of
diagnostic imaging and treatment, saving
lives.
In industry, radioisotopes allow precise
measurements and imaging to be made.
Countries are aware of the destructive power of The destructive potential of nuclear weapons has
nuclear weaponry, and may avoid this in the given mankind the ability to destroy itself.
future.
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