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CPE 615
ASSIGNMENT 2
EH220 6B
GROUP MEMBERS:
Formula :
𝜇𝑚∆𝐻𝑐
𝑚 𝑇𝑁𝑇 =
TNT equivalent is a convention for 𝐸𝑇𝑁𝑇
𝑚 - mass of hydrocarbon
Formula :
2. Estimation of overpressure
𝑟
𝑧𝑒 = 1
𝑚 𝑇𝑁𝑇 3
Where:
3. When a liquid boil it turns into a gas. The resulting gas takes up far
more space than the liquid did.
Water example
For example, a tank of pressurized liquid water held at 204.4 °C (400 °F)
might be pressurized to 1.7 MPa (250 psi) above atmospheric ("gauge")
pressure. If the tank containing the water were to rupture, there would for a
brief moment exist a volume of liquid water which would be at
Gas containers are usually equipped with relief valves that vent off
excess pressure, but the tank can still fail if the pressure is not
released quickly enough.
An appropriately sized relief valve will allow the liquid inside to boil
slowly, maintaining a constant pressure in the vessel until all the
liquid has boiled and the vessel empties.
In August 1959 the Kansas City Fire Department suffered its 2nd
largest loss of life in the line of duty, when a 25,000 gallon (95,000
litre) gas tank exploded during a fire on Southwest Boulevard killing
five firefighters. This was the first time BLEVE was used to
describe a burning fuel tank.
Outflow Model
Types of Outflow Models
1. Flow of Mechanical energy balance describes the various energy forms associated with
liquid flowing fluids:
through a
𝑑𝑃 𝑢̅2 𝑔 𝑊𝑠
hole ∫ + ∆( ) + ∆𝑧 + 𝐹 = −
𝜌 2𝛼𝑔𝑐 𝑔𝑐 𝑚̇
Where
P: Pressure (force/area)
𝑑𝑃 ∆𝑃
∫ =
𝜌 𝜌
For limited aperture release, assume constant gauge pressure,Pg . The external
pressure is atmospheric (ΔP=Pg), work shaft,W s =0, and velocity of the fluid within
the process unit is assumed negligible. The change in elevation of the fluid during
the discharge through the hole is also negligible, Δz=0. Hence, frictional losses in
the leak are approximated by a constant discharge coefficient C1;
∆𝑃 ∆𝑃
− − 𝐹 = 𝐶12 (− )
𝜌 𝜌
2𝑔𝑐𝑃𝑔
𝑢̅ = 𝐶1 √𝛼√
𝜌
Figure 3.1: Liquid escaping through a hole in a process unit. The energy og the
liquid resulting from its pressure in the vessel is converted to kinetic energy, with
some frictional flow losses in the hole
For fluid exiting the leak;
2𝑔𝑐 𝑃𝑔
𝑢̅ = 𝐶𝑜 √
𝜌
𝑔𝑐 𝑃𝑔
𝑢̅ = 𝐶1 √𝛼√2 ( + 𝑔ℎ𝐿 )
𝜌
𝑔𝑐 𝑃𝑔
𝑢̅ = 𝐶𝑜 √2 ( + 𝑔ℎ𝐿 )
𝜌
𝑔𝑐 𝑃𝑔
𝑄𝑚 = 𝜌𝑢̅𝐴 = 𝜌𝐴𝐶𝑜 √ + 𝑔ℎ𝐿
𝜌
For tank of constant cross-sectional area,At ,total mass of liquid in the tank above
the leak is 𝑚 = 𝜌𝐴𝑡 ℎ𝐿 .
𝑑ℎ𝐿 𝐶𝑜 𝐴 𝑔𝑐 𝑃𝑔
=− √2 ( + 𝑔ℎ𝐿 )
𝑑𝑡 𝐴𝑡 𝜌
ℎ𝐿
𝑑ℎ𝐿 𝐶𝑜 𝐴 𝑡
∫ =− ∫ 𝑑𝑡
ℎ𝐿𝑜 𝐴𝑡 0
𝑔𝑐 𝑃𝑔
√2 + 2𝑔ℎ𝐿
𝜌
1 𝑔𝑐 𝑃𝑔 1 𝑔𝑐 𝑃𝑔 𝐶𝑜 𝐴
√2 + 2𝑔ℎ𝐿 − √2 + 2𝑔ℎ𝐿𝑜 = − 𝑡
𝑔 𝜌 𝑔 𝜌 𝐴𝑡
𝐶𝑜 𝐴 𝑔𝑐 𝑃𝑔 𝑔 𝐶𝑜 𝐴 2
ℎ𝐿 = ℎ𝐿𝑜 − 𝑡√2 + 2𝑔ℎ𝐿𝑜 𝑡 + ( 𝑡)
𝐴𝑡 𝜌 2 𝐴𝑡
𝑔𝑐 𝑃𝑔 𝜌𝑔𝐶𝑜2 𝐴2
𝑄𝑚 = 𝜌𝐶𝑜 𝐴√2 ( + 2𝑔ℎ𝐿𝑜 ) − 𝑡
𝜌 𝐴𝑡
1 𝐴𝑡 𝑔𝑐 𝑃𝑔 2𝑔𝑐 𝑃𝑔
𝑡𝑐 = ( ) [√2 ( + 2𝑔ℎ𝐿𝑜 ) − √ ]
𝐶𝑜 𝑔 𝐴 𝜌 𝜌
1 𝐴𝑡
𝑡𝑐 = ( ) √2𝑔ℎ𝐿𝑜
𝐶𝑜 𝑔 𝐴
For a general equation to represent the draining time for any vessel of any
geometry, assume that the head space above the liquid is at atmospheric
pressure. Hence;
𝑑𝑚 𝑑𝑉
=𝜌 = −𝜌𝐴𝐶𝑜 √2𝑔ℎ𝐿
𝑑𝑡 𝑑𝑡
𝑉2 𝑡
1 𝑑𝑉
− ∫ = ∫ 𝑑𝑡
𝐴𝐶𝑜 √2𝑔 𝑉1 √ℎ𝐿 0
𝑉2
1 𝑑𝑉
𝑡= ∫
𝐴𝐶𝑜 √2𝑔 𝑉1 √ℎ𝐿
𝜋𝐷 2
For vessel with the shape of vertical cylinder, 𝑑𝑉 = 4
𝑑ℎ𝐿 . Hence;
𝜋𝐷 2 𝑑ℎ𝐿
𝑡= ∫
4𝐴𝐶𝑜 √2𝑔 √ℎ𝐿
If the hole is at the bottom of the vessel, the equation above is integrated from
h=0 to h=ho. Hence:
𝜋𝐷 2 2ℎ𝐿𝑜 1 𝜋𝐷 2
𝑡= √ = ( ) √2𝑔ℎ𝐿𝑜
4𝐴𝐶𝑜 𝑔 𝐶𝑜 𝑔 4𝐴
3. Flow of Combination of flow of incompressible liquids through pipes by mechanical
liquids energy balance and incompressible fluid assumption gives;
through
∆𝑃 ∆𝑢̅2 𝑔 𝑊𝑠
pipes + + ∆𝑧 + 𝐹 = −
𝜌 2𝛼𝑔𝑐 𝑔𝑐 𝑚̇
𝑈2
𝐹 = 𝐾𝑓 ( )
2𝑔𝑐
Where Kf : Excess head loss due to the pipe or pipe fitting (dimensionless)
4𝑓𝐿
𝐾𝑓 =
𝑑
1 √𝑓 1 𝜀
= (10−0.25/√𝑓 − )
𝑅𝑒 1.255 3.7 𝑑
1 𝑑
= 4𝑙𝑜𝑔 (3.7 )
√𝑓 𝜀
1 𝑅𝑒√𝑓
= 4𝑙𝑜𝑔
√𝑓 1.255
For smooth pipes with Re<100,000;
𝑓 = 0.079𝑅𝑒 −1/4
A single equation has been proposed by Chen to provide the friction factor,f over
the entire range of Reynolds number shown in Figure 3.2. This equation is;
1 𝜀/𝑑 5.0452𝑙𝑜𝑔𝐴
= −4𝑙𝑜𝑔 ( − )
√𝑓 3.7065 𝑅𝑒
Where
(𝜀/𝑑)1.1098 5.8506
𝐴=[ + 0.8981 ]
2.8257 𝑅𝑒
2-K Method
𝐾1 1
𝐾𝑓 = + 𝐾∞ (1 + )
𝑅𝑒 𝐼𝐷𝑖𝑛𝑐ℎ𝑒𝑠
Table 3.2: 2-K Constants for Loss Coefficient in Fittings and Valves
For pipe entrances and exit, equation of this method is modified;
𝐾1
𝐾𝑓 = + 𝐾∞
𝑅𝑒
For pipe entrances, K1=160 and 𝐾∞ =0.50 for normal entrances. For a Borda-type
pipe connection to a tank where the pipe sticks up into the bottom of the tank a
short distance, 𝐾∞ =1.0. For pipe exits, K1=0 and 𝐾∞ =1.0.
For high Reynolds number (Re>10,000), Kf=𝐾∞ . For low Reynolds number
(Re<50), Kf= K1/Re.
In 2-K Method, the discharge coefficient for liquid discharge through a hole is:
1
𝐶𝑜 =
√1 + ∑ 𝐾𝑓
For a simple hole in a tank with no pipe connections or fittings the friction is
caused only by the entrance and exit effects of the hole. For Reynolds numbers
greater than 10,000, Kf = 0.5 for the entrance and Kf = 1.0 for the exit. Thus Σ Kf
= 1.5, and from Equation 4-40, Co = 0.63, which nearly matches the suggested
value of 0.61.
4. Flow of Assuming negligible potential energy changes and no shaft work results in a
gases or reduced form of the mechanical energy balance describing compressible flow
vapors through holes:
through
𝑑𝑃 𝑢̅2
holes ∫ + ∆( )+𝐹 =0
𝜌 2𝛼𝑔𝑐
Figure 3.3: A free expansion gas leak. The gas expands isentropically through the
hole. The gas properties (P, T) and velocity change during the expansion.
A discharge coefficient is defined as;
𝑑𝑃 𝑑𝑃
−∫ − 𝐹 = 𝐶12 (− ∫ )
𝜌 𝜌
𝑃
𝑑𝑃 𝑢̅2
𝐶12 ∫ + =0
𝑃𝑜 𝜌 2𝛼𝑔𝑐
𝑃
𝑃𝑣 𝛾 = = 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
𝑣𝛾
The velocity of the fluid at any point during the isentropic expansion;
(𝛾−1)
𝛾 𝑃𝑜 𝑃 𝛾
𝑢̅2 = 2𝑔𝑐 𝐶𝑜2 [1 − ( ) ]
𝛾 − 1 𝜌𝑜 𝑃𝑜
Where Rg is the ideal gas constant, and To is the temperature of the source.
Using the continuity equation,
𝑄𝑚 = 𝜌𝑢̅𝐴
𝑃 1/𝛾
Where 𝜌 = 𝜌𝑜 (𝑃 ) . Hence ;
𝑜
For many safety studies the maximum flow rate of vapor through the hole is
require. This is determine by differentiating equation above with respect to P/Po
and setting the derivative equal to zero. The result is solved for the pressure ratio
resulting in the maximum flow:
𝑃𝑐ℎ𝑜𝑐𝑘𝑒𝑑 2 𝛾/(𝛾−1)
=( )
𝑃𝑜 𝛾+1
𝛾𝑔𝑐 𝑀 2 (𝛾+1)/(𝛾−1)
(𝑄𝑚 )𝑐ℎ𝑜𝑐𝑘𝑒𝑑 = 𝐶𝑜 𝐴𝑃𝑜 √ ( )
𝑅𝑔 𝑇𝑜 𝛾 + 1
Where
𝜕𝑃
𝑎 = √𝑔𝑐 ( )
𝜕𝜌 𝑠
Adiabatic Flows
𝑑𝑃 𝑢̅𝑑𝑢̅ 𝑔 𝛿𝑊𝑠
+ + 𝑑𝑧 + 𝑑𝐹 = −
𝜌 𝛼𝑔𝑐 𝑔𝑐 𝑚
𝑔
𝑑𝑧 ≈ 0
𝑔𝑐
2𝑓𝑢̅2 𝑑𝐿
𝑑𝐹 =
𝑔𝑐 𝑑
For this open steady flow process the total energy balance is given by
𝑢̅𝑑𝑢̅ 𝑔 𝛿𝑊𝑠
𝑑ℎ + + 𝑑𝑧 = 𝛿𝑞 −
𝛼𝑔𝑐 𝑔𝑐 𝑚
where h is the enthalpy of the gas and q is the heat. The following assumptions
are invoked:
𝑚 2𝑔𝑐 𝜌1 (𝑃1 − 𝑃2 )
𝐺= = 𝑌𝑔 √
𝐴 ∑ 𝐾𝑓
where
ΣKf: Excess head loss terms, including pipe entrances and exits, pipe lengths,
and fittings (unitless)
𝛾 ∑ 𝐾𝑓 𝑃1
𝑌𝑔 = 𝑀𝑎1 √ ( )
2 𝑃1 − 𝑃2
Table 3.5: Correlations for the Expansion Factor Yg and the Sonic Pressure Drop
Ratio (P1 – P2 )/P1 as a Function of the Pipe Loss ΣK for Adiabatic Flow
Conditions
Isothermal Flows
𝑔
Assume 𝑔 𝑑𝑧 ≈ 0,
𝑐
2𝑓𝑢̅2 𝑑𝐿
𝑑𝐹 =
𝑔𝑐 𝑑
Assume constant f,
𝛿𝑊𝑠 = 0
1
𝑀𝑎𝑐ℎ𝑜𝑐𝑘𝑒𝑑 =
√𝛾
This result is shown by starting with the mechanical energy balance and
rearranging it into the following form:
𝑑𝑃 2𝑓𝐺 2 1 2𝑓𝐺 2 1
− = [ 2 ] = ( )
𝑑𝐿 𝑔𝑐 𝜌𝑑 𝑢̅ 𝜌 𝑔𝑐 𝜌𝑑 1 − 𝛾𝑀𝑎2
1 − (𝑔 𝑃)
𝑐
1 1 4𝑓𝐿
𝑙𝑛 ( 2) − ( 2 − 1) + 𝑑 = 0
𝛾𝑀𝑎1 𝛾𝑀𝑎1
𝑚̇ 𝑔𝑐 𝜌1 𝑃1
𝐺= =√
𝑎 ∑𝐾
Table 3.6: Correlations for the Expansion Factor Yg and the Sonic Pressure Drop
Ratio (P1 – P2 )/P1 as a Function of the Pipe Loss ΣK for Isothermal Flow
Conditions