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DOI:
10.1205/cherd.04161
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T
he kinetics of the oxidation of toluene have been studied in close interaction with the
gas –liquid mass transfer occurring in the reactor. Kinetic parameters for a simple
model have been estimated on basis of experimental observations performed under
industrial conditions. The conclusions for the mass transfer and reaction regime on basis of
experimental observations and model calculations are in good agreement: toluene oxidation
under industrial conditions can be characterized as a slow reaction with respect to mass
transfer.
187
188 HOORN et al.
known to inhibit the oxidation (Morimoto and Ogata, 1967) kinetic scheme that has a close resemblance to the toluene
making the operation of a continuous tank reactor more oxidation scheme given in Figure 1. The mass transfer
difficult than it is already. A correlation between R1 and flux for a first-order irreversible reaction according to
R2 was made on basis of the observation that in the the Danckwerts modification of the penetration theory is
oxidation mechanism the primary termination reaction defined by (Westerterp et al., 1984):
takes place between two alkoxy radicals (Russell, 1957; pffiffiffiffiffiffiffiffiffiffiffiffiffiffi
Kondratiev, 1969) whereby alcohol and aldehyde are cA,b
formed in a 1 : 1 ratio. For this reason, the parameters k1 J ¼ kL cA,i 1 þ w2 (6)
1 þ w2
and k2 were replaced by a single parameter k12 giving the
following expressions for the reaction rates: The extremes for small and large Hatta numbers are
convenient for simple evaluations on basis of analytical
R1 ¼ k12 cTOL cO2 (1) solutions.
R2 ¼ k12 cTOL cO2 (2)
w . 2 J ¼ kL cA,i w (7)
R3 ¼ k3 cBALD cO2 (3)
w , 0:3 J ¼ kL (cA,i cA,b ) (8)
R4 ¼ k4 cBALC cO2 (4)
The enhancement factor is the ratio of the flux in pre-
The influence of the catalyst was not included in the rate sence of reaction [equation (6)] and pure physical mass
equations because all experimental data have been per- transfer under identical conditions [expression is equivalent
formed at a constant cobalt concentration. The expression to equation (8)].
for the Hatta number (w) depends on the reaction rate
equation. For a first-order irreversible reaction with respect pffiffiffiffiffiffiffiffiffiffiffiffiffiffi cA,i (cA,b )=(1 þ w2 )
to the absorbing component w is defined by: E ¼ 1 þ w2 (9)
cA,i cA,b
pffiffiffiffiffiffiffiffiffiffi
kD The extremes for small and large Hatta numbers are:
w¼ (5)
kL
w.2 E¼w (10)
For systems consisting of multiple reactions involving w , 0:3 E ¼ 1 (11)
the gaseous component the most commonly applied simpli-
fication is to evaluate the Hatta number on the assumption The Hatta number and the enhancement factor are cal-
that an overall pseudo zero-order or first-order rate equation culated from experimental observations, respectively
is applicable. The model of the xylene oxidation by Cao included in the modelling.
et al. (1994) comprises a zero order reaction for oxygen
where Hatta is calculated according to the correlation of
Hikita and Asai (1964). This approach is also applied by
EXPERIMENTS AND OBSERVATIONS
Suresh et al. (1988) in the modelling of the cyclohexane
oxidation. Pohorecki et al. (2001) apply a first order depen- The reactor and auxiliary equipment for the toluene
dence for oxygen in the cyclohexane oxidation with a oxidation experiments are operated in a continuous mode,
Trans IChemE, Part A, Chemical Engineering Research and Design, 2005, 83(A2): 187–195
MODELLING TOLUENE OXIDATION 189
a schematic drawing of the set-up is given in Figure 2. All oxygen is neglected. The experimentally observed oxygen
equipment is accommodated in an explosion proof facility. transfer rate FGL is related with the flux through the inter-
From the continuous monitoring of the reactor temperature facial area:
and the oxygen concentration in the off-gas during exper-
iments it appeared that small fluctuations are present in FGL ¼ J VR a (12)
the reaction set-up. The standard deviations of the results
of five reference experiments having identical process con- In case w . 2 substitution of the expression for the
ditions are shown in Table 1 as an indication of the extent observed transfer rate gives (taking into account the defi-
of experimental inaccuracies. The range of process vari- nition for the Hatta number):
ables of all experiments is included for comparison. A
number of experiments have been performed with insuffi- 2
1 FGL
cient tracing in part of the piping from the reactor vessel k¼ (13)
to the condenser causing a partial condensation of the D VR a cA,i
vapour and subsequent reflux of components to the reactor.
The rate of oxygen transferred to the liquid phase (FGL) For w , 0.3 the bulk concentration can be calculated
was calculated from the difference between the gas feed from a balance for oxygen in the liquid phase:
and off-gas flow. Both the liquid and the gas phase were
assumed to be ideally mixed; the residence times for the 0 ¼ fV cA,b ð1 1Þ VR k cA,b þ J VR a (14)
liquid were in the order of one hour. To address the gas
phase mixing qualitatively a visual check was performed The outflow of dissolved oxygen is considered to be much
in an glass vessel comprising identical baffle and stirrer smaller than the reaction term and the transfer rate through
configuration. With cyclohexane as liquid at room tempera- the gas – liquid interface; therefore equation (14) can be
ture and nitrogen as gas feed, it was observed that at 1600 simplified to:
rpm stirrer speed a significant amount of gas backmixing
occured into the liquid by means of vortex formation 0 ¼ (1 1) VR k cA,b þ J VR a (15)
around the stirrer and turbulences behind the baffles. In
addition, it was assumed that no oxygen is present in the with the substitution for J [equation (8)]:
liquid feed and the system operates at steady state. The cA,b 1
oxygen concentration in the liquid at saturation was calcu- ¼ (16)
lated according to Henry’s law. The Henry coefficients cA,i 1 þ Al w2
were calculated from gas –liquid equilibirum data retrieved where Al is the Hinterland ratio:
from the Dortmund Data Bank (program version DDBSP
2003; http://www.ddbst.com, president and CEO of (1 1) kL
DDBST is Prof. Dr J. Gmehling, access date 26 November Al ¼ (17)
aD
2004). Typical values are in the range of 1500 – 2000 bar.
The partial pressure of oxygen was determined from the Combining the expression for the bulk concentration
off-gas and condensate composition. In Figure 3 the con- with the flux and the observed conversion rate gives an
version rates for oxygen are shown as function of the equation that can be solved with respect to the kinetic
oxygen concentration in the liquid. The conversion rate rate constant:
for oxygen is defined as the transfer rate of oxygen divided
cA,i
by the liquid volume; in this way the outflow of dissolved FGL ¼ VR a kL cA,i (18)
1 þ Al w2
Solving for k gives:
kL2 FGL
k¼ (19)
Al D VR kL a cA,i FGL
Values for specific surface areas were estimated with the
correlation of Shridhar and Potter (1980), diffusion co-
efficients were estimated with the correlation of Wilke
and Chang (1955). Mass transfer coefficients were esti-
mated for water with the equation of van’t Riet (1979).
To translate the mass transfer coefficients from water to
toluene at reactor conditions, a result from Higbie’s pen-
etration theory was applied:
sffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
kL (toluene, 1508 C) D(toluene, 1508 C)
¼ (20)
kL (water, 258 C) D(water, 258 C)
Trans IChemE, Part A, Chemical Engineering Research and Design, 2005, 83(A2): 187–195
190 HOORN et al.
area was taken as a constant at 300 m2/m3. Under the part of the set-up. A scheme of the model is given in
hypothesis that the reaction is fast, i.e., w . 2, the Figure 4. For an overview on the model equations see
calculated rate constant [equation (13)] is 100 s21 Appendix. The model calculations were performed in
(+56 s21, standard deviation for the experimental obser- Aspen Custom Modeler. Thermodynamic properties for
vations). The corresponding Hatta number on basis of this the liquid phase were calculated with Aspen Plus Proper-
rate constant can then be estimated to be 0.60 + 0.16. ties. The pure component properties were taken from the
This is not in line with the assumption of a fast reaction DIPPR Handbook (http://dippr.byu.edu, American Insti-
with w . 2. For the hypothesis of a slow reaction, i.e., w tute of Chemical Engineers, access date 25 May 2004) or
, 0.3, the calculated rate constant is 2.2 + 3.2 s21 DDBST (http://www.ddbst.com). The interaction between
giving a Hatta number of 0.079 + 0.048 which is in line components was described by the NRTL-model. The
with the assumption made for the Hatta number. Therefore, thermodynamic property files generated in Aspen Plus
it is concluded that on basis of the experimental obser- were included in the ACM file. The liquid from the
vations the reaction rate is slow in comparison to the second flash is totally refluxed to the first flash (‘liquid
mass transfer rate of oxygen. recycle’). The temperature of the second flash was varied
for each experiment in such a way that the differences
between experimental and model values for the gas and
MODELLING OF THE EXPERIMENTAL REACTOR liquid mole flows of all components were minimized. The
calculations to determine the temperatures of the second
A model was constructed to determine the kinetic par- flash were performed with a simulated combined feed of
ameters under conditions of mass transfer limitations the liquid discharge and vapour flows. For experiments per-
while taking into account partial condensation of the formed with the correct tracing, the temperature of
vapour phase. To include a description of the partial con- the second flash was fixed at the temperature of the first
densation between the reactor and the condenser the
model comprised two flash calculations for the reactor
Figure 3. Observed conversion rates for oxygen as function of the oxygen Figure 4. Schematic drawing of model. The symbols in this scheme are
concentration in the liquid at saturation. utilized in the overview of model equations.
Trans IChemE, Part A, Chemical Engineering Research and Design, 2005, 83(A2): 187–195
MODELLING TOLUENE OXIDATION 191
Condensate Balc 3.24 . 1025 5.61 . 1026 35.5% 8.74 . 1025 127.5%
Bald 9.29 . 1024 1.69 . 1024 21.7% 1.38 . 1023 61.3%
BzA 4.45 . 1024 1.87 . 1024 34.2% 1.34 . 1024 37.3%
H2O 1.26 . 101 2.23 . 1021 11.0% 2.57 . 1021 12.6%
Tol 1.61 . 102 2.72 . 100 11.0% 3.34 . 101 36.1%
Liquid discharge Balc 6.92 . 1023 5.61 . 1026 2.4% 8.74 . 1025 9.4%
Bald 1.53 . 1021 1.69 . 1024 3.0% 1.38 . 1023 8.7%
BzA 5.09 . 100 1.87 . 1024 0.5% 1.34 . 1024 0.4%
Tol 4.84 . 102 2.72 . 100 11.0% 3.34 . 101 38.5%
flash. The temperatures of the second flash were 5 to 158C first-order rate constant is kfo ¼ 295 + 14 s21, the Hatta
lower than the reactor temperature depending on the number is w ¼ 0.92+0.05 and the enhancement factor is
composition of the condensate flow. The liquid recycle E ¼ 1.36+0.03.
amounts to 10 – 20% (mole flow basis) compared to the
vapour flow feeding the second flash. The statistical results
of the calculations are given in Table 2. The kinetic DISCUSSION
parameters in Figure 1 were estimated by a least squares
minimization procedure. In the estimation procedure (and From Table 1 it appears that the input process parameters
in the subsequent model calculations) the temperatures in are controlled with acceptable accuracy of approximately
the second flash were fixed at the values calculated earlier. 1%. The response variables differ in accuracy in the
The most suitable variables as experimental data points and range of 1.5% for toluene in the liquid discharge flow to
the optimal weighting were identified after some trial and 20% for benzoic acid in the condensate flow. Benzoic
error. Best results were obtained with the toluene conver- acid concentrations in the condensate flow are difficult
sion, selectivities for benzyl alcohol, benzaldehyde and to analyse because at room temperature the condensate sep-
benzoic acid and the oxygen off-gas concentration. The arates into a water and an organic phase. The low accuracy
weights of the experimental values for a particular variable for the oxygen measurement is a combination of the
were set as reciprocals of the average values, except for analytical measurement and the length of the sample pipe
oxygen which was given a lower value (10% of the recipro- from the off-gas vessel to the instrument. The simulation
cal average). The results are given in Table 3. In Table 4 of the partial condensation in the piping to the condenser
the sums of the squared residuals of model prediction vessel is successfully performed by modelling the reactor
and experimental values (SSR) are shown. The model part with an additional flash calculation (Figure 4) and
results for the data applied in the estimation procedure this is illustrated when the results in Table 2 are compared.
are shown in the parity plots in Figures 5 –8. Comparison The differences between model predictions and experimen-
between experimental values and model calculations for tal observations are clearly reduced with respect to the situ-
the oxygen concentration in the off-gas are shown in ation where there is no liquid recycle. When compared
Figure 9. The residuals for benzyl alcohol, benzaldehyde to the indication of experimental errors in Table 1, the
and benzoic acid selectivity are shown in Figures 10 model describing the partial condensation has a scatter in
and 11. Residual values are given as the difference in the model predictions that is much closer to the
selectivity between experiment and model relative to the
observed experimental value. The calculated pseudo
Trans IChemE, Part A, Chemical Engineering Research and Design, 2005, 83(A2): 187–195
192 HOORN et al.
Figure 6. Comparison between experimental values and model Figure 9. Comparison between experimental values and model calcu-
calculations for the selectivity of benzyl alcohol. lations for the oxygen concentration in the off-gas.
Trans IChemE, Part A, Chemical Engineering Research and Design, 2005, 83(A2): 187–195
MODELLING TOLUENE OXIDATION 193
CONCLUSIONS
Experiments performed in a reactor that was operated
under industrial conditions have been successfully applied
in the estimation of kinetic parameters in a model with
inclusion of the description of mass transfer phenomena.
Analyses of the mass transfer characteristics reveal that
toluene oxidation under industrial conditions is a slow reac-
tion with respect to mass transfer.
Trans IChemE, Part A, Chemical Engineering Research and Design, 2005, 83(A2): 187–195
194 HOORN et al.
xO2,sat oxygen mole fraction in liquid at saturation, mol/mol Scott, E.J.Y., Chester, A.W., 1972, Kinetics of the cobalt-
y mole fraction in vapour, mol/mol catalyzed autoxidation of toluene in acetic acid. J Phys Chem, 76:
z mole fraction in vapour, mol/mol 1520–1524.
Shridhar, T., Potter, O.E., 1980, Interfacial areas in gas-liquid stirred
Greek symbols vessels. Chem Eng Sci, 35: 683–695.
1 gas volume per unit volume dispersion, m3/m3 Suresh, A.K., Sridhar, T., Potter, O.E., 1988, Autocatalytic oxidation
x conversion, mol/mol of cyclohexane—mass transfer and chemical reaction. AIChE J, 34:
f fugacity coefficient 81–93.
fV volumetric flow, m3/s Westerterp, K.R., van Swaaij, W.P.M., Beenackers, A.A.C.M., 1984,
w Hatta number Chemical reactor design and operation, 371–377. (John Wiley &
rmol,L liquid molar density, kmol/m3 Sons, New York, USA).
s selectivity, mol/mol Wilke, C.R., Chang, P., 1955, Correlation of diffusion coefficients in dilute
tL residence time, s solutions. AIChE J, 1: 264–270.
Sub/superscripts (see also Figure 4 for descriptions) The manuscript was received 2 June 2004 and accepted for publication
i any component after revision 13 December 2004.
BALC benzyl alcohol
BALD benzaldehyde
BzA benzoic acid
H2O water
N2 nitrogen APPENDIX
O2 oxygen
TOL toluene Overall pseudo first-order rate constant for oxygen
F feed flow to Flash 1
G gas vapour flow from Flash 2 3 1
L liquid discharge flow from Flash 1 k fo ¼ k12 cTOL þ ðk3 cBALD þ k4 cBALC Þ
V vapour flow from Flash 1 to Flash 2 2 2
R liquid recycle flow from Flash 2 to Flash 1
Definition of Hatta number and mass transfer equations
Abbreviations pffiffiffiffiffiffiffiffiffiffiffiffiffi
ACM Aspen Custom Modeler kfo D
SSO Sum of Squared Observations w¼
SSR Sum of Squared Residuals
kL
FGL ¼ J VR a
REFERENCES pffiffiffiffiffiffiffiffiffiffiffiffiffiffi cO2,sat (cO2 )=(1 þ w2 )
E ¼ 1 þ w2
Bateman, L., 1951, Olefin oxidation. Quart Revs (London), 8: 147–167. cO2,sat cO2
Bhattacharya, D., Guha, D.K., Roy, A.N., 1973, Liquid phase air oxidation
of toluene to benzoic acid. II. Kinetics and mechanism. Chem Age India, J ¼ kL cO2,sat cO2 E
24: 87–90.
Borgaonkar, H.V., Raverkar, S.R., Chandalia, S.B., 1984, Liquid phase Reaction rate expressions (according to Figure 1)
oxidation of toluene to benzaldehyde by air. Ind Eng Chem Prod Res
Dev, 23: 455–458.
Cao, G., Servida, A., Pisu, M., Morbidelli, M., 1994, Kinetics of p-xylene R1 ¼ k12 cTOL cO2
liquid-phase catalytic oxidation. AIChE J, 40: 1156–1166. R2 ¼ k12 cTOL cO2
Helfferich, F.G., 2001, Kinetics of homogeneous multistep reactions, in
Compton, R.G. and Hancock, G. (eds). Comprehensive Chemical R3 ¼ k3 cBALD cO2
Kinetics, vol. 38, 283–286 (Elsevier, Amsterdam, The Netherlands).
Hikita, H., Asai, S., 1964, Gas absorption with (m,n)-th order irreversible R4 ¼ k4 cBALC cO2
chemical reaction. Int Chem Eng, 4: 332 –340. RBALC ¼ R2 R4
Keading, W.W., Lindblom, R.O., Temple, R.G., Mahon, H.I., 1965,
Oxidation of toluene and other alkylated aromatic hydrocarbons to ben- RBALD ¼ R1 R3 þ R4
zoic acids and phenols. Ind Eng Chem Process Des Dev, 4: 97–101.
Kondratiev, V.N, 1969, The theory of kinetics, in Bamford, C.H. and RBzA ¼ R3
Tipper, C.F.H. (eds). Comprehensive Chemical Kinetics, vol. 2, RH2O ¼ R1 þ R4
165– 173 (Elsevier, Amsterdam, The Netherlands).
Lozar, J., Falgayrac, G., Savall, A., 2001, Kinetics of the electrochemically 1
assisted autoxidation of toluene in acetic acid. Ind Eng Chem Res, 40: RO2 ¼ R1 (R2 þ R3 þ R4 )
6055–6062. 2
Morimoto, T., Ogata, Y., 1967, Kinetics of the autoxidation of toluene RTOL ¼ R1 R2
catalyzed by cobaltic acetate. J Chem Soc (B), 62– 66.
Mulkay, P., Rouchaud, J., 1967, Solvatation des catalyseurs d’oxydation
en phase liquide homogène. Bull Soc Chim Fr, 12: 4653– 4657. Definition for toluene conversion
Pohorecki, R., Baldyga, J., Moniuk, W., Podgórska, W., Zdrójkowski, A.,
Wierzchowski, P.T., 2001, Kinetic model of cyclohexane oxidation.
Chem Eng Sci, 56: 1285–1291.
FF,TOL FL,TOL þ FG,TOL
x¼
Quiroga, O.D., Gottifredi, J.C., Capretto de Castillo, M.E., 1980, Liquid FF,TOL
phase catalytic toluene oxidation, formulation of a kinetic model.
Lat Am J Chem Eng Appl Chem, 10: 77 –88.
Russell, G.A., 1957, Deuterium-isotope effects in the autoxidation of
Definition for benzoic acid, benzaldehyde and benzyl
aralkyl hydrocarbons. Mechanism of the interaction of peroxy radicals. alcohol selectivity
J Am. Chem Soc, 79: 3871–3877.
van’t Riet, K., 1979, Review of measuring methods and results in nonvis- FL,i þ FG,i
cous gas-liquid mass transfer in stirred vessels. Ind Eng Chem Process si ¼ P P
Des Dev, 18: 357 –364. j FL,j þ j FG,j
Trans IChemE, Part A, Chemical Engineering Research and Design, 2005, 83(A2): 187–195
MODELLING TOLUENE OXIDATION 195
Definition for off-gas oxygen concentration Mass balances for all components except oxygen for
Flash 1 and Flash 2 (see Figure 4)
FG,O2
cO2,out ¼
FG,N2 þ FG,O2 fL,i xi ¼ fV,i zi
fG,i yi ¼ fR,i wi
Mole fractions and concentrations for all components
FF,i þ FR,i þ V Ri ¼ FL,i þ FV,i
ci ¼ rmol,L xi FV,i ¼ FG,i þ FR,i
FL,i
xi ¼ P Mass balances for oxygen
i FL,i
FG,i fL,O2 xO2,sat ¼ fV,O2 zO2
yi ¼ P
i FG,i fG,O2 yO2 ¼ fR,O2 wO2
FVAP,i FF,O2 ¼ FGL,O2 þ FV,O2
zi ¼ P
i FVAP,i FGL,O2 þ FR,O2 þ VR RO2 ¼ FL,O2
FREC,i FV,O2 ¼ FG,O2 þ FR,O2
wi ¼ P
i FREC,i
Trans IChemE, Part A, Chemical Engineering Research and Design, 2005, 83(A2): 187–195