PHYSICAL CHEMISTRY By: Shailendra Kumar

PHYSICAL CHEMISTRY
by: SHAILENDRA KR.
Meq. Approach
Classes at: -
SCIENCE TUTORIALS; Opp. Khuda Baksh Library, Ashok Rajpath, Patna
PIN POINT STUDY CIRCLE; House No. 5A/65, Opp. Mahual Kothi, Alpana Market, Patna

Topic: Chemical Equilibrium

01. 2 mole of PCl 5 were heated in a closed (a) 1.33 (b) 3.11
vessel of 2 litre capacity. At equilibrium 40% (c) 4.21 (d) 1.63
of PCl5 dissociated into PCl3 and Cl2. The
06. When 20 g of CaCO3 were put into 10 litre
value of equilibrium constant is:
flask and heated to 800°C, 35% of CaCO3
(a) 0.267 (b) 0.53 remained unreacted at equilibrium. Kp for
(c) 2.63 (d) 5.3 decomposition of CaCO3 is:
02. One mole of ethyl alcohol was treated with (a) 1.145 atm (b) 0.145 atm
one mole of acetic acid at 25°C. (c) 2.145 atm (d) 3.145 atm
2/3 of the acid changes into ester at
07. 1.1 mole of A are mixed with 2.2 mole of B
equilibrium. The equilibrium constant for the
and the mixture is then kept in one litre flask
reaction will be :
till the equilibrium is attained
(a) 1 (b) 2 A + 2B 2C + D. At the equilibrium, 0.2
(c) 3 (d) 4 mole of C are formed. The equilibrium
03. If in the reaction N2O4 2NO2, α is degree constant of the reaction is:
of dissociation of N2O4 then the number of (a) 0.001 (b) 0.002
molecules at equilibrium will be: (c) 0.003 (d) 0.004
(a) 3 (b) 1 08. In a chemical equilibrium, the rate constants
(c) (1–α)2 (d) (1+α) of the forward and backward reactions are
04. If CuSO4⋅5H2O CuSO4⋅3H2O(s) + 2H2O (v) respectively 3.2 × 10–4 and 1.2 × 10–5, the
K p =1.086 × 10 –4 atm 2 at 25°C. The equilibrium constant is:
efflorescent nature of CuSO4⋅5H2O can be (a) 0.37 (b) 26.7
noticed when vapour pressure of H2O in (c) 0.25 (d) 3.7
atmosphere is:
09. For the reaction, 2NO2 (g) 2NO(g) + O2 (g),
(a) > 7.92 mm (b) < 7.92 mm Kc = 1.8 × 10–6 at 185°C. At 185°C, the Kc for
> 7.92 mm
(c) < (d) None of these NO (g) + 1/2 O2 (g) NO2 (g) is :
05. Sulphide ions in alkaline solution react with (a) 0.9 × 106 (b) 7.5 × 102
solid sulphur to form polyvalent sulphide ions. (c) 1.95 × 10–3 (d) 1.93 × 103
The equilibrium constant for the formation of
10. 4 mole of A are mixed with 4 mole of B, when
S22– and S32– from S and S2– ions are 1.7 and
2 mole of C are formed at equilibrium,
5.3 respectively. Equilibrium constant for the
according to the reaction, A + B C + D.
formation of S32– from S22– and S is:
The equilibrium constant is:

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PHYSICAL CHEMISTRY By: Shailendra Kumar
(a) 4 (b) 1 [P 4O10] [P4O10]
(c) √2 (d) √4 (c) Kc = ––––––––– (d) Kc = –––––––––
5[P4] [O2] [P4] [O2]5
11. For the reaction, H2 (g) + I2(g) 2HI (g) at
720 K, the value of equilibrium constant is 17. Equilibrium is established in the reaction,
50, when equilibrium concentration of both A (aq.) + B (aq.) 2C (aq.)
H 2 and I 2 is 0.5 M.K p under the same
conditions will be: If equilibrium concentration are
[A] = 0.25, [B] = 0.4 and [C] = 0.5 mol dm–3.
(a) 0.02 (b) 0.2 The value of Kc is:
(c) 50 (d) 50RT (a) 0.25 (b) 0.4
12. At a given temperature, the Kc for the reaction, (c) 2.5 (d) 4.0
PCl5 (g) PCl3 (g) + Cl2 (g) is 2.4 × 10–3. At
the same temperature, The Kc for the reaction 18. At a certain temperature, 2HI H2 + I2 only
PCl3 (g) + Cl2 (g) PCl5 (g) is : 50% HI is dissociated at equilibrium. The
equilibrium constant is:
(a) 2.4 × 10–3 (b) – 2.4 × 10–3
(a) 1.0 (b) 3.0
(c) 4.2 × 102 (d) 4.8 × 10–2
(c) 0.5 (d) 0.25
13. On adding A to the reaction at equilibrium,
AB (s) A (g) + B (g), the new equilibrium 19. The reaction, A + 2B 2C + D was studied
concentration of A becomes double, the using an initial concentration of B which was
equilibrium concentration of B would become: 1.5 more that of A. But the equilibrium
concentration of A and C were found to be
(a) 1/2 of its original value equal. Then the Kc for the equilibrium is :
(b) 1/4 of its original value (a) 4 (b) 8
(c) 1/8 of its original value (c) 6 (d) 0.32
(d) Twice its original value 20. In a system : A (s) 2B (g) + 3C (g). If the
14. For a reaction, 2A + B C, where initial concentration of C at equilibrium is increased
concentration of A = 2M, B = 1M and by a factor 2, it will cause the equilibrium
C = 0, the concentration of B at equilibrium concentration of B to change to:
is 0.5 M. The value of equilibrium constant (a) two times of its original value
for the reaction is:
(b) one half of its original value
(a) 0.5 (b) 2.0
(c) 2√2 times of its original value
(c) 1.0 (d) 1.5
(d) 1/2√2 times of its original value
15. For a reaction N2 + 3H2 –––––→ 2NH3; ∆H =
–22 kcal. If energy of activation for this 21. The vapour density of undecomposed N2O4
reaction is 70 kcal, the energy of activation is 46. When heated, vapour density
for backward reaction is : decreases to 24.5 due to its dissociation to
NO2. The percent dissociation of N2O4 at the
(a) 70 kcal (b) 92 kcal final temperature is :
(c) 48 kcal (d) none of these (a) 87 (b) 60
16. The equilibrium constant for the reaction; (c) 40 (d) 70
P4 (s) + 5O2 (g) P4O10 (s) is : 22. For an equilibrium change involving gaseous
1 phase, the forward reaction is first order while
(a) Kc = –––––– (b) Kc = [O2]5 the reverse reaction is second order. The unit
[O2]5 of Kp for the forward equilibrium is :

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PHYSICAL CHEMISTRY By: Shailendra Kumar
(a) Atm (b) Atm2 29. In an aqueous solution of volume 500 mL,
(c) Atm –1
(d) Atm –2 when the reaction of 2Ag++Cu Cu2+ + 2Ag
reached equilibrium the [Cu2+] was x M.
23. The formation of phosgene is represented
When 500 mL of water is further added, at
as,
the equilibrium [Cu2+] will be:
CO + Cl2 COCl2
(a) 2x M
The reaction is carried out in 500 mL flask.
(b) x M
At equilibrium 0.3 mole of phosgene, 0.1 mole
of CO and 0.1 mole of Cl2 are present. The (c) Between x M and x/2 M
equilibrium constant of the reaction is: (d) Less than x/2 M
(a) 30 (b) 15 30. 40% of a mixture of 0.2 mole of N2 and 0.6
(c) 5 (d) 3 mole of H2 react to give NH3 according to the
equation, N2(g) + 3H2(g) 2NH3(g) at
24. ∆Gº for the reaction X + Y Z is
constant temperature and pressure. Then the
– 4.606 kcal. The equilibrium constant for the
ratio of the final volume to the initial volume
reaction at 227°C is:
of gases are:
(a) 100 (b) 10
(a) 4 : 5 (b) 5 : 4
(c) 2 (d) 0.01
(c) 7 : 10 (d) 8 : 5
25. The partial pressure of CH3OH(g), CO(g) and
31. At temperature T, a compound AB 2 (g)
H2(g) in equilibrium mixture for the reaction,
dissociates according to the reaction
CO(g) + 2H2(g) CH3OH(g) are 2.0, 1.0
2AB2(g) 2AB(g) + B2(g) with a degree of
and 0.1 atm respectively at 427ºC. The value
dissociation x, which is small compared with
of Kp for the decomposition of CH3OH to CO
unity. The expression for Kp, in terms of x
and H2 is :
and the total pressure P, is:
(a) 102 atm (b) 2 × 102 atm–1
(a) Px3 / 2 (b) Px2 / 3
(c) 50 atm2 (d) 5 × 10–3 atm2
(c) Px3 / 3 (d) Px2 / 2
26. The equilibrium constant of a reaction is 20.0.
32. Two systems PCl5(g) PCl3 (g) + Cl2(g)
At equilibrium, the rate constant of forward
and COCl 2 (g) CO(g) + Cl 2 (g) are
reaction is 10.0. The rate constant for
simultaneously in equilibrium in a vessel at
backward reaction is:
constant volume. If some CO is introduced
(a) 0.5 (b) 2.0 into the vessel then at the new equilibrium
(c) 10.0 (d) 200.0 the concentration of :
27. For the reaction, C(s) + CO2 (g) 2CO(g), (a) PCl5 is greater
the partial pressures of CO2 and CO are 2.0 (b) PCl3 remains unchanged
and 4.0 atm respectively at equilibrium. The
(c) PCl5 is less (d) Cl2 is greater
Kp for the reaction is:
33. Kc for the reaction:
(a) 0.5 (b) 4.0
[Ag(CN)2]– Ag+ + 2CN–, the equilibrium
(c) 8.0 (d) 32.0
constant at 25ºC is 4.0 × 10–19, then the silver
28. In the reaction, PCl3 PCl 3 + Cl 2, the ion concentration in a solution which was
amounts of PCl5, PCl3 and Cl2 at equilibrium originally 0.1 molar in KCN and 0.03 molar in
are 2 mole each and the total pressure is 3 AgNO3 is:
atm. The equilibrium constant Kp is :
(a) 7.5 × 1018 (b) 7.5 × 10–18
(a) 1.0 atm (b) 2.0 atm
(c) 7.5 × 1019 (d) 7.5 × 10–19
(c) 3.0 atm (d) 6.0 atm
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PHYSICAL CHEMISTRY By: Shailendra Kumar
34. For the reaction A + B 3C at 25ºC, a 3 litre is Kc = 4.9 × 10–2. The value of Kc for the
vessel contains 1, 2, 4 mole of A, B and C reaction
respectively. If Kc for the reaction is 10, the 2SO2(g) + O2(g) 2SO3(g)
reaction will proceed in:
will be
(a) Forward reaction
(a) 416 (b) 2.40 × 10–3
(b) Backward reaction
(c) 9.8 × 10–2 (d) 4.9 × 10–2
(c) In either direction
41. For an endothermic reaction where ∆H
(d) In equilibrium represent the enthalpy of the reaction in kJ/
35. The equilibrium constant K c for mol, the minimum value for energy of
A(g) B(g) is 1.1, Gas B will have molar activation will be:
concentration greater than 1 if: (a) Less than ∆H (b) Zero
(a) (A) = 0.91 (b) (B) > 0.91 (c) More than ∆H (d) Equal to ∆H
(c) (A) > 1 (d) At all these 42. Favourable conditions for manufacture of
36. Amount of PCl5 (in mole) need to be added ammonia by the reaction,
to one litre vessel at 250ºC in order to obtain N2 + 3H2 2NH3; ∆H = –21.9 kcal are:
a concentration of 0.1 mole of Cl2 for the given
change is: (a) Low temperature, low pressure and
catalyst
PCl5 PCl3 + Cl2; Kc = 0.0414 mol/litre
(b) Low temperature, high pressure and
(a) 0.3415 (b) 0.0341 catalyst
(c) 3.415 (d) 0.3145 (c) High temperature, low pressure and
37. For the reaction, CO (g) + Cl2(g) COCl2(g) catalyst
the value of Kp/Kc is equal to: (d) High temperature, high pressure and
(a) 1.0 (b) RT catalyst
(c) √RT (d) 1/RT 43. Predict the conditions for forward reaction
38. The equilibrium constant (Kc) for the reaction, on the basis of Le-Chatelier’s principle for:
N2 (g) + O2(g) 2NO(g) 2SO2(g) + O2(g) 2SO3(g) ∆H = –198 kJ
at room temperature T is 4 × 10–4. The value (a) Lowering the temperature and
of Kc for NO (g) 1/2 N2(g) + 1/2 O2 (g) at increasing pressure
the same T is: (b) Any value of temperature and
(a) 0.02 (b) 50 pressure
(c) 4 × 10–4 (d) 2.5 × 10–2 (c) Lowering of temperature as well as
39. A definite amount of solid NH4HS is placed in pressure
a flask already containing NH3 gas at certain (d) Increasing temperature as well as
temperature and 0.50 atm pressure. NH4HS pressure
decomposes to give NH3 and H2S and total 44. The reaction quotient (Q) at equilibrium is :
equilibrium pressure in flask is 0.84 atm. The (a) = 1 (b) = K
equilibrium constant for the reaction is:
(c) > K (d) < K
(a) 0.30 (b) 0.18
45. A chemical reaction A B is said to be at
(c) 0.17 (d) 0.11 equilibrium when:
40. The equilibrium constant for the reaction, (a) Complete conversion of A to B has
SO3(g) SO2(g) + 1/2 O2 (g) taken place
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PHYSICAL CHEMISTRY By: Shailendra Kumar
(b) Conversion of A to B is only 50% (c) Kc = Kp (d) Kc < Kp
complete 52. For the chemical reaction,
(c) Only 10% conversion of A to B has 3X (g) + Y (g) –––––→ X3Y (g); the amount of
taken place X3Y at equilibrium is affected by:
(d) The rate of transformation of A to B (a) Temperature and pressure
is just equal to the rate of
(b) Temperature only
transformation of B to A in the
system (c) Pressure only
46. For N2 + 3H2 2NH3; ∆H = –ve then: (d) Temperature, pressure and catalyst
(a) Kp = Kc (b) Kp = KcRT 53. Which oxide of nitrogen is the most stable?
(c) Kp = Kc(RT)–2 (d) Kp = Kc(RT)–1 (a) 2NO2 (g) N2 (g) + 2O2 (g);
47. On applying pressure to the equilibrium, K = 6.7 × 1016 mol litre–1
Ice water (b) 2NO (g) N2 (g) + O2 (g);
Which phenomenon will happen? K = 2.2 × 1030 mol litre–1
(a) More ice will be formed (c) 2N2O5 (g) 2N2 (g) + 5O2 (g);
(b) More water will be formed K = 1.2 × 1034 mol–5 litre–5
(c) Equilibrium will not be disturbed (d) 2N2O (g) 2N2 (g) + O2 (g);
(d) Water will evaporate K = 3.5 × 1033 mol litre–1
48. Oxidation of SO 2 by O 2 to SO 3 is an 54. A higher value for equilibrium constant, K
exothermic reaction. The yield of SO3 will be shows that:
maximum if: (a) The reaction has gone to near
(a) Temperature is increased and completion towards right
pressure is kept constant (b) The reaction has not yet started
(b) Temperature is reduced and (c) The reaction has gone to near
pressure is increased completion toward left
(c) Both temperature and pressure are (d) None of the above
increased 55. If K1 and K2 are equilibrium constants for
(d) Both temperature and pressure are reaction (I) and (II) respectively for,
reduced N2 + O2 2NO .........(I)
49. The equilibrium constant Br2 2Br at 500 K 1/2 N2 + 1/2 O2 NO .........(II)
and 700 K are 10–10 and 10–5 respectively.
The reaction is: Then:
(a) Endothermic (b) Exothermic (a) K2 = K1 (b) K2 = √K1
(c) Fast (d) Slow (c) K1 = 2K2 (d) K1 = 1/2 K2
50. Which equilibrium in gaseous phase would 56. If pressure is applied to the equilibrium of
be unaffected by an increase in pressure? solid liquid. The melting point of the solid:
(a) N2O4 2NO2 (b) N2 + O2 2NO (a) Will not change
(c) N2 + 3H2 2NH3 (b) May increase or decrease depending
upon its nature
(d) CO + 1/2 O2 CO2
(c) Will always increase
51. For the reaction H2 + I2 2HI:
(d) Will always decrease
(a) Kc = 2Kp (b) Kc > Kp
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PHYSICAL CHEMISTRY By: Shailendra Kumar
57. For the reaction equilibrium, (a) N2 (g) + O2 (g) 2NO (g)
2NOBr (g) 2NO (g) + Br2 (g), If PBr = P/9 (b) PCl5 (g) PCl3 (g) + Cl2 (g)
2
at equilibrium and P is total pressure. The
(c) N2 (g) + 3H2 (g) 2NH3 (g)
ratio Kp/P is equal to:
(d) SOCl2 (g) SO2 (g) + Cl2 (g)
(a) 1/9 (b) 1/81
63. In an equilibrium reaction, if ∆G° = 0 the
(c) 1/27 (d) 1/3
equilibrium constant, K should be equal to:
58. In lime kiln, the reversible reaction,
(a) 0 (b) 1
CaCO3 (s) CaO (s) + CO2 (g)
(c) 2 (d) 10
proceeds to completion because :
64. For a system in equilibrium, ∆G = 0 under
(a) of high temperature conditions of constant:
(b) CO2 escapes out (a) temperature and pressure
(c) CaO is removed (b) temperature and volume
(d) of low temperature (c) Energy and volume
59. When two reactants A and B are mixed to (d) Pressure and volume
give products C and D, the reaction quotient
65. Raising the temperature of a reversible
Q, at the initial stages of the reaction:
chemical reaction:
(a) Is zero
(a) Favours the forward rate only
(b) Decrease with time
(b) Favours the backward rate only
(c) Is independent of time
(c) Favours both the forward and
(d) Increases with time backward rates as the case may be
60. For the reaction, (d) Favours neither the forward not
CuSO4⋅5H2O(s) CuSO4⋅3H2O(s) + 2H2O(v) backward rates
Which one is correct representation? 66. For reaction PCL3(g) + Cl2(g) PCl5 (g),
(a) Kp = (pH O) 2
(b) Kc = [H2O] 2 the value of K c at 250ºC is
2
2
26 mol litre –1 . The value of K p at this
(c) Kp = Kc (RT) (d) All of these
temperature will be:
61. The equilibrium constant for the reactions
(a) 0.61 atm–1 (b) 0.57 atm–1
are: k 1 (c) 0.83 atm–1 (d) 0.46 atm–1
H3PO4 H+ + H2PO4–; K1
67. In which of the following cases, does the
k2 reaction go furthest to completion?
H2PO4– H+ + HPO42–; K2
(a) K = 103 (b) K = 10–2
k3 (c) K = 10 (d) K =1
HPO42– H+ + PO43–; K3
68. If K1 and K2 are the respective equilibrium
The equilibrium constant for constants for the two reactions,
N3PO4 3H+ + PO43– will be: XeF6(g) + H2O(g) XeOF4(g) + 2HF(g)
(a) K1/K2 K3 (b) K1 × K2 × K3 XeO4(g) + XeF6(g) XeOF4(g) + XeO3F2(g)
(c) K2/K1 K3 (d) K1 + K2 + K3 The equilibrium constant for the reaction,
62. In which of the following equilibrium, change XeO4(g) + 2HF(g) XeO3F2(g) + H2O(g) is:
in volume of the system does not alter the
(a) K1K 2 (b) K1/K22
number of moles?
(c) K2/K1 (d) K1/K2
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PHYSICAL CHEMISTRY By: Shailendra Kumar
69. If 1.0 mole of I2 is introduced into 1.0 litre flask 75. The equilibrium constant for the reactions,
at 1000 K, at equilibrium N 2 (g) + O 2 (g) 2NO(g),
(Kc = 10–6), which one is correct? NO(g) + 1/2 O2 (g) NO2 (g) are K1 and K2
(a) [I2 (g)] > [I (g))] (b) [I2 (g)] < [I (g)] respectively. Then the equilibrium constant
for the equilibrium
(c) [I2 (g)] = [I (g)] (d) [I2 (g)] = 1/2[I(g)] N2(g) + 2O2 (g) 2NO2 (g) is:
70. For the reactions, (a) K1 / K2 (b) K1K 2
A B; Kc =2 (c) K1K2 2
(d) K12K 2
B C; Kc = 4 76. Kp / Kc for the reaction,
C D; Kc = 6 CO(g) + 1/2 O2(g) CO2(g) is:
Kc for the reaction, A D is: (a) RT (b) 1/√RT
(a) (2 + 4 + 6) (b) (2 × 4)/6 (c) √RT (d) 1
(c) (4 × 6)/2 (d) 2 × 4 × 6 77. Consider the following equilibrium in a closed
71. For a reaction in equilibrium: container:
(a) There is no volume change N2O4 (g) 2NO2 (g)
(b) The reaction has stopped completely At a fixed temperature, the volume of the
(c) The rate of forward reaction is equal reaction container is halved. For this change,
to the rate of backward reaction which of the give statements holds true
(d) The forward reaction is faster than regarding the equilibrium constant (Kp) and
reverse reaction degree of dissociation (α)?

72. In a flask colourless N2O4 is in equilibrium (a) Neither Kp nor α change

with brown coloured NO2. At equilibrium, (b) Both Kp and α change
when the flask is heated at 100ºC the brown (c) Kp Changes, but α does not changes
colour deepens and on cooling it becomes (d) Kp does not changes, but α changes
less coloured. The change in enthalpy ∆H,
for the system is: 78. At constant temperature, the equilibrium
constant (Kp) for the decomposition reaction.
(a) Negative (b) Positive N2O4 2NO2 is expressed by,
(c) Zero (d) Undefined
73. Increase in temperature favours the forward (4x2 P)
Kp = ––––––––––
2
reaction in: (1 – x )
(a) 2SO2 (g) + O2 (g) 2SO3 (g)
Where P = pressure, x = extend of
(b) 2O3 (g) 3O2 (g) decomposition. Which of the following
(c) C(graphite) C (diamond) statement is true?
(d) H2 (g) + 1/2 O2 (g) H2O (g) (a) Kp increases with increase of P
74. An example of reversible reaction is: (b) Kp increases with increase of x
(a) AgNO3(aq) + HCl(aq) ––––→ AgCl(s) + HNO3(aq) (c) Kp increases with decrease of x
(b) 2Na + 2H2O ––––→ 2NaOH + H2 (d) Kp remains constant with change in P or x
(c) NaOH + CH3COOH ––––→ CH3COONa + H2O 79. In which of the following reaction increase in
(d) Pb(NO3)2 + 2NaI ––––→ PbI2 + 2NaNO3 pressure at constant temperature does not
affect the moles at equilibrium?

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PHYSICAL CHEMISTRY By: Shailendra Kumar
(a) 2NH3 (g) N2(g) + 3H2 (g) 85. Equilibrium constants K 1 and K 2 for the
(b) C (g) + 1/2 O2 (g) CO (g) following equilibria are related as:
(c) H2 (g) + 1/2 O2 (g) H2O (g) NO (g) + 1/2 O2 (g) NO2 (g); K1
(d) H2 (g) + I2(g) 2HI (g) 2NO2 (g) 2NO (g) + O2 (g); K2
80. For the reaction: 1 1
CO(g) + 1/2 O2(g) CO2 (g), Kp / Kc is: (a) K2 = ––––– (b) K2 = –––––
K12 K1
(a) RT (b) (RT)–1 K1
(c) (RT)–1/2 (d) (RT)1/2 (c) K2 = K12 (d) K2 = –––––
2
81. The exothermic formation of ClF 3 is 86. For the reaction,
represented by the equation: CH4 (g) + 2O2 (g) CO2 (g) + 2H2O(l),
Cl2 (g) + 3F2 (g) 2ClF3; ∆H = –329 kJ ∆rH = –170.8 kJ mol–1
Which of the following will increase the Which of the following statements is not true?
quantity of ClF3 in equilibrium mixture of Cl2, (a) Addition of CH 4 (g) or O 2 (g) at
F2 and ClF3? equilibrium will cause to the right
(a) Increasing the temperature (b) The reaction is exothermic
(b) Removing Cl2 (c) At equilibrium, the concentrations of
(c) Increasing the volume of container CO2(g) and H2O (l) are not equal
(d) Adding F2 (d) the equilibrium constant for the
82. For the reaction : reaction is give by
2NO2(g) 2NO(g) + O2 (g); Kc = 1.8 × 10–6 at [CO2]
–1 –1
Kp = –––––––––––
184ºC and R = 0.083 JK mol . When Kp [CH4] [ O2]
and Kc are compared at 184ºC. It is found 87. Phosphorus pentachloride dissociates as
that: follows, in a closed reaction vessel,
(a) Kp > Kc (b) Kp < Kc PCl5(g) PCl3 (g) + Cl2 (g)
(c) Kp = Kc < Kc
(d) Kp > If total pressure at equilibrium of the reaction
83. The graph relates In K eq vs (1/T) for a mixture is P and degree of dissociation of
reaction. The reaction must be: PCl5 is x, the partial pressure of PCl3 will be:
(a) exothermic InKeq
x 2x
(b) Endothermic (a) –––––– P (b) –––––– P
x+1 1–x
(c) ∆H is negligible
x x
(d) Highly spontaneous at (c) –––––– P (d) –––––– P
ordinary temperature
x–1 1–x
84. When two reactants A and 1/T
B are mixed to give products C and
D, the reaction quotient, Q at the initial stages
of reaction:
(a) is zero
(b) decreases with time
(c) independent of time
(d) increases with time
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PHYSICAL CHEMISTRY By: Shailendra Kumar
A n s w e r s

01. a 30. a 59. a

02. d 31. a 60. d
03. d 32. c 61. b
04. b 33. b 62. a
05. b 34. b 63. b
06. a 35. d 64. a
07. a 36. a 65. c
08. b 37. d 66. a
09. b 38. b 67. a
10. b 39. d 68. c
11. c 40. a 69. a
12. c 41. c 70. d
13. a 42. b 71. c
14. c 43. a 72. b
15. b 44. b 73. c
16. a 45. d 74. c
17. c 46. c 75. c
18. d 47. b 76. b
19. d 48. b 77. d
20. d 49. a 78. d
21. a 50. b 79. d
22. a 51. c 80. c
23. b 52. a 81. d
24. a 53. a 82. a
25. d 54. a 83. a
26. a 55. b 84. d
27. c 56. b 85. a
28. a 57. b 86. d
29. d 58. b 87. a

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