Chapter 2 21 2.2 23 2.4 2.5 2.6 2.7 2.8 2.9 2.10 211 2.12 2.13 2.14 2.15 2.16 2.17 0.2596 W/m K (a) 257.95 kcal/(h m? © iron C) (b) 52.832 Buvth f °F) (a) 10° Pas (b) 2.419 ALD Ibi 5.69 x 107 Ib/ft2s (ee hy 66.67 kg, 654 N 1.0197 kgf/cm?, 14.5038 psi 472.7 mm 15.3 m, 12.5 KI 18 W (a) 1286.305 N (b) 1.6378 bar (c) 0.5145 kJ. (d);196.2 J 30.6305 x 10° J _— 1.8829 x 104 8.0! . (i) 3.038 (ii) 10.94 Cp = 26.5386 + 4.24 x 10°F — 1.4295 x 1057? (a) Cp = 6.35 + LBL x 10°7 ~ 2.675 x 1077? (b) Cp = 6.825 + 1.665 x 10°7 - 2.675 x 10-77? (c) Cp = 9.495 x 10? + 0.271T - 4.0 x 10°57? ; (d) Cp = 6.795 + 0.93 x 10°37 — 8.256 x 1087 226.296 a) A = 18.2773, B= 3799.887, C ©) 6839.7966, C = -375.0628 (b) A = 14.331 28, B= 559 An we a Swers to Exercises560__ Answers to Exercises 2.18 (a) Cp = 96.55 + 0.1562T (b) Cp = 33. 24 + 0.03737 ¢ 2.19 5.6629 x 108 Witm?-K*) { 2.20 36.81 ke/s . i 3 ars where q is in Wie Dis in mand AT is in K 2.21 (b) q= 131 24.185 kmot (b) Ks = 4.795 x 10°, m}(min)(atm)> : 28 «107 LUmol)? me (min)(atmy™ * 2 3.602: atm L? 24moi)?, ** * 2.24 V(inch*) = 0.0610¢%% rR aE] 2.25 ap=7.5885| # DEF where AP is in Pa, pt is in Ib/(it s), H is in ft, p is in re Vis in fs and A, is in ft. Chapter 3 3.1 267.41 8 3.2 3 mol 3.3 266.45 kg 34728 3.5 58% C, 3.4% H and 38.6% Br eeie 3.6 9 kg-equivalents 3.7 57.026 3.8 31607 = 3:10 3.9 2 3.10 C)H,N 3.11 (a) 125,38 kg (b) 12.685 g 3.12 (a) 684.48 kg (b)'254.10-kg '2 PIE toh at 3.13 (a) 93.65 kg (b) 88.68 kg 3.14 (a) 146.58 g (b) BaCl,: 44.61 g, Na,SO,: 30.43 g (c) 25.04 gti Os EL 3.15 . 1292.76 kg bed La 3.16 0.41% ABODE «Tees wa Aron " BAT 43.74 kg, 22.28 m? at STP “3 3.18 (a) 17.64 m? (b) 164.21 kg 3.19 1053.2 kg, 895.2 kg Hy 3.20 0.8651 N “321 5-22 1.076 3.23 7.273 3.24 (a) 420 kg/m? (by 2.24 kmolh 3.25 18.91°Bé, 30°Tw 326 45°BE 3.27 29.1°BE , 29.3°API - 3.28 0.25 3.29 947 kg/m? 3.30 (a) 768.37 kg/m? —(b) 52.46 spay fs (©) gasoline = 24.66%, kerosene = 26.82%, gasoil = 28.30% and i nopentane = 20.22% “tly Ta ners to Eerie” 561 22 1, - 331 0.9263 3.32 131.53 kg. of Mg,, 1136.78 kg of, Na, 2132.67 i of Cl 333, 75.692 es 334 K 44.87%, S 18.4%, 0,,36.73% 338 47.23 i 3.36 Ferrous, 36.06%,,Fertic, 30.65%... 337 12.38% NaNO,, 87.62% water 3.38 567.04 kg 3.39 90.02% 3.40 0.4959, 0.33 341 55.23% 3.42 3.7203 x 105 kg 3.43 557.3 mol 3.44 24.57% SiO0,2CaO, 43.43% Si0,3CaO 3.45 95.58% (weight) ethanol 3.46 (a) 1.688% | (b) 3.48% 3.47 720 kg 3.48 1.0753 3.49 0.2860 ot 3.50 39.75%, 0.6596 3.51 (a) 622.5° (by 1.2971 (©), 1,213 ke 3.52 (a) 0.4751 (b) 42.77 . (c) 33.75, 3.53 (a) 40.78% A, 27.18% B, 32.04% C 3.54 16.66% " oe 3.58 30.73 3.56 Rs. 275.5. 562 Answers to Exe 3.57 3.58 3.59 3.60 3.61 3.62 3.63 3.64 3.65 3.66" 3.67 3.68 3.69 3.70 3.71 3.72 3.73 3.74 3.75 3.76 3.77 3.78 3.79 3.80 381 382 3.83 3.84 3.85 3.86 3.87 ises oe (a) 1.557 g-atom Ca, 3.133 g-atom C (b) CaC, (a) 33.27 kg (b) 36.96 kg (a) 3.09% |‘ (b) 0.0319 oth (a) 23.29% Oy,.76.71% Ny (b) 28.85 Chlorine 74.03%, Bromine 13.73%, Oxygen 12.24% 1.1% : min? 10.43 : - 1291 kg/m? 6 70.000 ppm: ve (a) 179.2 § (b) 0.046 * 2.78 mol/kg, 2.646 mol/L. (a) 12.94% - (b) 65.00%; (c) 5.773 mol/L *(d) 8.25 mol/kg solvent :‘ | * (a) 29.77% (b) 8.1467 moVL (€) 8.1467 g eq/L (4) 15.27% LICI, 84.73% water (@) 0.293 (b) 0.0727, 4.35 moVkg water (d) 8 geq/L? °° (a) 58.59% (b) 9.92 moVL_(c) 21.716 mol/kg water (a) KCI = 24%, water = 76% (b) 0.0709 (c) 5.15 moV/L’ (@) 4.24 4 moles (a) 0.0287 kg (b) 0.26602 mol/L (a) Nitrogen (b) 32.76% (c) 30% 94%, 94.5% “i (@) 90% (b) 100% (c) 75% 1 ts O.5E My + 0.5E . . : 443 8426 36, +4e, mes 5426, +24, vB ue 3-6-6 50.56, 43.43 kg of trisilicate and 24.57 kg of disilicate 10%, 94.4%, 5.44% wh (a) carbpn 240 kg, silica 865 kg (b) 188 kg (c) 1491 ke (a) 474.8 kg (b) 8.4% SO,, 10.11% O, and 81.49% N, (a) Ammonia, 17.97% | (b) 53.89 kg (a) 25.96 m? (b) 12.46 m? (c) 35.3 m> (d) 35.25% SO,, 23.53% SO, 41.18% O, (€) 56.47 (a) 29.5% (b) 14.71 kPa3.89 *.3.90 3.91 Chapter 4 41 42 43 44 45 46 47 48 49 4.10 4.11 4.12 413 414 415 4.16 3.88 (@) 0.4 (b) 0.343 bar Answers to Exercises 563 20% *y mb hen (@) 300 m?. (6) 994.29 m3 aps Set aL te " (c) N, = 29.32 mi = (@) 0.292 m3 (b) 40% 2 m?, Hy = 87.96 m>, NH, = $8.64 m?-. 1010.79 kg coe ae 91.67 moe ne : : an 7.688 m? . oe (@) 2.167 kg.(b):1.702 kg 0.3557 mivkg; 0.65% greater 12.67 bar 5.6686 x 105 Nim? 8 ot : 288.8 K wees . , (a) 0.7153 kg/m? (b) 2.8582 kg/m? . : 7.6098 104 kg . - 78.98 kg 0.355 kg 1.0195 x 10-3 m? 102°C 1.119 x 10-3 m3 (a) 3.0068 kmol (b) 0.3757 kmol, 0.125 (€) 0.7578 kg, 0.007 @) 6.25 me) 35.95 417 (a) 120 kPa (b) 1.3826 m?_ (c) 2 kg/m? oo 4.18 (a) 30.53 (b) CO, = 20.18, SO, = 1.05, CO = 1.83, 0; = 2.62, N, = 74.32 (c) 1.7213 kg/m? “(d) 1.0528 419 28.96, 1.1836 kg/m? . a , 2.01% hydrogen and 26.26% carbon dioxide - aa ® sees ® 108 mol. ethane, 1.2027 x 10° mol/L hydrogen, 7.2163 x 105 mol/L CO, (c) 241.82 keh . 421 (a) 250 bar, 750 bar (b) 8.5155 (c) 204.84 kg/m? 4.22 (a) 35.74 kPa (b) 11.59 mM . 4.23 3.2462 m? 5 > 428 (a) 20.14 kPa (b) 4.42 m3 (€), 2.196 mikg 4.25 Cy . 426 78%564. Answers to Exercises : 427. (a) 25.15. (b) 1.21 kg/m? * ved Reba NS +428 0.0252 kg " 4.29 ‘air; 4.313 x.105 N/m?, methyl alcohol: 1.951-x 10° Nim?,.and steam? 1.936 x 108 Nim? + 4.30 (a) 19.68 . (b) 22.36% CO,, 53.44% Cl, 17.8% Nz, 6.4% Hy? 4.31 -(a) 34.62 '(b) 38.82 432 20 4.33, 0.11, (a) 0.648% NH,, 99,352% air (b) 26.27 4.34 (a) CO, 2.12%, N, 5.39%, CH, 92.5% (b) 16.64° (c) 0.7424 kg/m? 4.35 30.25 4.36 (a) CO: $4.34, H,: 4.72, CH,: 0.36, CO,: 13.50, 3: (&) 17.93 (c) 0.8 yiteany, 3% ° 4.37 (a) 38.98 vert (b) Ethylene: 22.0%, Benzene: 49.05%, Oxygen: 1. Methane: 6.37%, Ethane: 19.27%, Nitrogen: 2.23%" © 1.7391 4.38 2.48 g, 7.528 4.39 (a) 121.6 m> (b) 24.7 kg 4.40 (a) 70.76 m? (b) 37.1 kg (c) 2.1% HCI, 97.9% Air 4.41 (a) 70.85 m> (b) 36.98 kg 4.42 (a) 92.02 m? (b) 1.082 kg 4.43 (a) 46.44 m3 (b) 34.22 m? (c) 87.72% 4.44 (a) 81.91 m? (b) 25.92 kg . 4.45 (a) 33.36 (b),30.28 _(c),20.73 kg (4) 60.28% vows 4.46 (a) 2.778 m/min” (b) 22.727 m/min” wee ° 4.47 (a) 91.43 m3 (b) 15.05 kg/h (c) 91.84% , 4.48 (a),37.41 kg. (b) 115.838 ke 449 03177 m? 4.50 (a) Ammonia, 17.97% (b) 53.89 kg 4.51 (a) 25.96 mi ) 12.46 m3, © 35.31.) . <7) 1) 56.51. 4.52 (a) 29.5% ‘we 14.71 kPa “453 (a) 70% (b) 0.6 bar bambi dated 2? 4.54 (a) 195.4 m? . (b) 36.036 kg Gedney 4.55 (a) 64.34% . (b) 15.074 m? os 8.605 > mm 4.56 404 te to his 4.57 (a) 4.98% CH,OH, 3.73% O,, 51.48% XN 19.9% HCHO, 19.9% H,O (b) 395.13 mm .36, N33? 26.72, a“Answers to Exer :4.58 20% 459 30% : 4.60 0.333 ethylene, 0.667 ethane 4 “a ° 11.08% CO, 83.35% N;, 5.57%. H,O _(b) 26.98 kg © 0.0836 bar a) 1142.58 m3 (by 4588.6 5 mh (c) 259.39 kg, 51.37% HNO, Chapter 5 5.1 380.1 K 8.2 601.3 K peas ‘ ea 5.3 (a) 68.30 bar. (b) 51.8 bar . 5.4 23.84 bar 5.5 93.8 kPa, 94.23 kPa by ideal gas equation 5.6 9.78 kg 5.7 1.48 kg 5.8 (a) 3.502 x 103 m°/mol, 0.936 (b) 3.5235 x 10° m*/mol,. 0942, 5.9 0.045 m?, 0.06751 m> $.10 0.3206 x 10 m?/mol 5.11 (a) V = 0.249 x 10° m?> (b) 0.23 x 10 m/mol t vee 5.12 (a) 3 x 10° mmol (b) 2.98 x 10 mi/mol Le 5.13 1.8 x 10+ m*/mol, a = 0.54985 N m‘/moP, b = 6.41 x 105 m/mol $.14 7.134 x 10° m/mol, 1.712 x 10° m*/mol $5.15 3.485 x 10% m*/mol, 0.8862 5.16 (a) 4.157 x 10-5 m/mol (b) 6.44 x 10° mmol - (¢) 5.3 x.10-5 m'/mot 5.17 76.76 bar $.18 551K $5.19 0.1255 m, 0.1357, m? using ideal gas equation 0 m*/mol 5.20 (a) 3.775 x 10-4 m/mol . (b) 3.827 x I 5.21 (a) 3.639 x 10% mmol (b) 3. 52 x 103 mmol (c) 3514 x 101 mifmol 5.22 (a) 2.036 x 10 m¥/mol (b) 1.433 x 10+ mmol (c) 1.4575 x 104 mmol 5.23 165.2 bar moot 5.24 V = 1.426 x 104 m’/mol 5.25 0.1136 m? * 5.26 371.8 K a 2.8635 x 104 m/mol miners eer “oer an cAmaga stew) 3.046 x 10 m¥%/mol (Dalton's law) (c) 2.847 x (a) 2962 x 104 m*/mol : 5.28 (a) 2.8776 kg/m? (b) 2 8769 k566 Answers to Exercises S66 AnswerstoBxerises Chapter 6 6.1 63.51 kPa and 118.04 kPa . 62 4.184 x 10? W/kg wk 6.3 2.34 kPa (293 K), 7.63 kPa (313 K), 13.04 kPa (323 K)O 20.87 kPa (333 K), 47.95 kPa’ (353 KY ‘ = 6.4 0.4653 bar 6.5 234.39 K 6.6 (a) 314.6 K (b) 28.06 kPa 6.7 15.33 kPa 68 6.7 kg 69 42 kPa, 0.5% 6.10 (a) 1.39 kg 6.11 1.32 kg 6.12 27.76 kPa, 0.18% 6.13 350.6 K, 30.55 kPa, 4.5%" 6.14 (a) A = 14.655, B = 2209.7, C= 43 (b) 2861 kPa 6.15 370K 6.16 (a) 181.97 kPa (b) 444.94 kI/kg 6.17 (a) 27.102 kPa, 1.66% (b) 379.5 K 6.18 27.46 kPa, 3.0% deviation Chapter 7 7.1 (a) 25.2% A ‘(b) 57.55 kPa’ 7.2 92.49% A 73 (a) 366.82 K (b) 20.85% n-hexane 7.4 (a) 39.06 kPa (0, 0), 66.99 kPa (0.2, 0.5335), 94.92 kPa (0.4, 0.7531), 108.88 kPa (0.5, 0.8206), 122.84 KPa (0.6, 0.8728), 150.77 kPa (08, 0.9482), 178.7 kPa (1, 0 (b) 108.9 kPa, 64 kPa 7.5 mole fraction of heptane x = 0.853, y = 0.893: 7.6 Between 350.9 K and 357.6 K 7.7 72.32% (Raoult’s law) 7.8 94.7 kPa and 77.2 kPa 19 54% TAO (a) 26.7% A, 26.7% B, 46.6% C (b) 11.47% A, 33.25% B, 58.3% C 711 x = 0.5008, y = 0.7344 ' 712 T= 3304 K, y = 0.5886; Answer: P = 57.63 kPa, y = 0.5908 713 f = 0.1982, x = 0.5608, y = 0.7344Answers to Exercises 567. 744. TK) 353.1, 358 363 368 373 378 383° 383.6" * x 10. 0.78 0.581 0.411" 0.258 0.130 '.0.017' 0 y 10-090 0.777 0.632 0.456 0.261 _0.039' » ‘0 7.15 7.47 kPa (benzene), 1.91 kPa (toluene); 76.8% (weight) benzene. : *°,:, a 736 Py = 8.53 and By = 2.24 kPa. Weight percent of benzene in vapour = 76.4% - 7.17 Exhibits positive deviation from Raoult’s law. If Raoult’s law is obeyed, vapour composition would be 0.413 mole fraction methanol ae 7.18 131.24 kPa, 46.2% A . pott 7A9 (a) 8.245 x 10? kPa, z Pt (b) 25.1% butane, 46.3% propane, 28.6% ethane, (c) 6.19 x 10? kPa, 35.17% butane, 64.83% propane 7.20 The liquid contains 67.42% (mol) nitrogen and the vapor contains 90. 34% (mol) nitrogen a 7.21 (a) 342 K (1, 1), 343 K (0.958, 0.983), 348 K (0.726, 0.875), 353 K 60. 527, 0.735), 358 K (0.360, 0.581), 363 K (0.210, 0.389), 368 K (0.094, 0.195) 372.4 K (0, 0) 7.22 (a) x and y are given in brackets’ against P in kPa: 33.79 (0, 0), 43.426 (0.2, 0.3775), 53.062 (0.4, 0. 6179), 62.698 (0.6, 0.7844), 72.334 (0.8, 0.9066), 81.79 (1, 1) (b) x and y are given in brackets against .T in K: 311.45 (1, 1), 315 (0.787, 0.902), 319 (0.581, 0.773), 323 (0.405, 6.623), 327 (0.254, 0.449), 331 (0.123, 0.250), 335.33 (0, 0) 722 (a) 352.8 K, 405.3 K, : (b) 352.8 (11), 363.2 (0.685, 0.914), 373.2 (0.446, 0.786),- 383.2 (0.266, 0.611), 393.2 (0.129, 0.378), 4053 ee (©) 369 K, 386.5 K ; SHS 7.24, (a) x and y are given in brackets against 'P in kPa: . 30.74 (0, 0), 57.58 (0.2, 0.573), 84.42 (0.4, 0.782), 111.26 (0.6, 0.89),-138.1 (0.8, 0.956), 164.94 (1, 1) eat (b) x and y are given in brackets against Tin K: 352.88 (1, 1), 360.0 (0.7658, 0.9474), 370.0 (0.5160, 0.8512), 380.0 (0. 3310, 0.7137). 390.0 (0.1900, 0.5273), 400.0 (0.0797, 0.2805), 408.9 (0, 0) les * 7.28 (a) 17.3% benzene (b) 57.5% benzene (c) 37.9%... -: 7.26 (a) 89.26 kPa (b) 59.5% benzene, 29.5% toluene and 11.0% wilene * (92.80, 85.26 7.27 (a) x = 0.5095, y = 0.8866. (b) 338.9 K, 75.7% pentane |.» ., 38 (©) 108.5. kPa, 83.4% pentane . 7.28 (a) 355.7 K- (b) 0.56 (¢) mole fraction of alcohol 0.16 7.29 64.86% A, 34.00% B, 1.14% C568 _Answersio 7.30. 9.0 kPa 731 0.1 101 x 104 kg oxygen per ke, water |: 732 3.074 x 104 m? , : 7.33 4.44104 bar“ et 734 H, = 0.23 bar “Hy = 0.217 bar ’ 735 5.0564 x:10- mot Ys +-7.36. 533 bar. bon A Saunt: tie 737 (a) 15.7 kPa (b) 391.4 K--(c) 374.1 K (6) 36.68 kPa 7.38 329.7 K, 356.9 K : 7.39 1310 kPa, liquid composition: 6. 8% ethane, 66.2% propane, 23.8% isobutene and the rest n-butane 2: , 7.40 (a) 330 K (b) 340.6 K . st us. ©) Mole %.in the, liquid and vapour given in brackets: Ethane (0.48, 0.09), Propane (36.3, 17.45), Isobutane (18.18, 18.74), n-Butane (44.98, 63. 3.35), Isopentane (0.13, 0.38), 500 mol each. 3. jo eee 4 7 Component ‘Mole % in liquid Mole % in vapour woos -., Methane bony 3:26 , 28.78 ” . “Ethane * * 16.30 SL, 29.68 ‘ Propane : 42.10 78 29,90 Isobutene 16.30 : “55.70 £ n-Butane vs 22.04» i 5.94 : 7.A2 (a) 930.3 kPa . . (b) 337.4 K, Composition of condensate: Ethane (1.8%), Propane (6.2%), Isobutane (17.3%); n-Butane (67.1%), Isopentane (7.50%) 330.2 K,° ‘Composition of the liquid and vapour: Ethane (3.22%, 16.81%), Propane (9.31%, 18.7%), Isobutane (19.55%, 18.46%), n-Butane (63.38%, 44.57%), Isopentane (4.54%, 1.46%) .; . , 7.A3" 2205 kPa; Methane: 41.91, Ethane: 20.25, Propane:'21.96, Isobutane: 8.57, n-Butane: 7.31706 kPa, Methane: 0.2, Ethane: 1.91, Propane: 16.14, Isobutane: 30.88, -Butane: 50.88 A HoGuP Mees tit tee F 4 7A4 861.4 kPa, 2446 kPa TAS 758 kPa 7A6 (a) 717 kPa (b) Propane: 63. 93%, n-Butane: 36.07% (c) Propane: 36.07%, n-Butane: 63.93% : (a) 356 K, 58.8% methanol, 24.1% ethanol, 8.4% propanol, '8.7% butanol, (b) 373 K, 8.8% methanol, 8.9% ethanol, 13.6% propanol, 68.6% butanol (a) 84.2 KPa (b) Ether = 51.26%, Water = 48, 74% (a) 347.97 K, Pure benzene (b) 342. 2K TAT 7AB C TADAnswers to Exercises 569 7-50 (@) 107.3 kPa) 66.449 7SU 342 K, 0.0975 kg ee ee 7-52 (a) 342 K. 0.7 ©) 0.0989 ke 7-53 (@) 372.3 K (b) 3% aniline : 7.54 (a) 306.5 K, 59.15% chioroben 755 (a) 346.5 K_ (b) 79.43% Chio 7.56 (a) 369.2 K (b) 4.78% aniline 7ST (a) 178.65 kPa (b) 361.14 K 7.58 Mole fractions of ethe Water-rich phase: 307(0.0123, 0.9295),.313(0.00914, 0.9277), 323(0. 0056, 0.8796), 333(0.0034, 0. son, 343(0.0018, 0.6945), 353(0.00098, 0.5334), 363(0.00037, 0.3092 7-59 (a) 327.2 K .(b) Pure water , (c) 316.7-K 7.60 (a) 369.2 K (b) 4.78% aniline 7.61 (a) 361.6 K, 21.9% toluene, 13.1% ethylbenzene, 65.0% water (b) 387.8 K, 26.8% toluene, 73.2% ethyl benzene 7.62 (a) 25 kPa (b) 12.5% A, 37.5% B, 50.0% C fhe vapour against temperature in K: 768 361 530028 35), 359450040). 357: 30d5) 354: 83(0. 50), 353.82(0.52), 352:40(0.548) ne ® 3a 37 pure toluene, last drop of vapour contains 44.36% toluene 7.65 (a) 388.8 K, pure component. I. (b) 365.5 K, pure component 2 7.66 16.7% A, 83.3% B ‘ 7.67 3.35 kg . 7.68 (a) 72.704 kg (b) 73.27% : - mo! 70 8 Liquid: 0062 a. 0737 @), 0.201 (©) Vapour: 0.409 (A), 0.591 (6) 7.70 2.842 kPa TV 372.47 K 7.72 (a) 885K (b) 7.8K zene (b) 341.1 K, 28.96% chlorobenzene roform (c) 76.29% Chloroform Fin the liquid and Vapour against temperature in K: hapter 8 / 5 ° ot) 16.6% (b) 29.2% * (€) 0.1991" (2) 0.4127 ° (e) 0.3914 kg/m? i 86 kPa. (b) 0.0351 . a 7 ° hse (b) H,O = 1.49%, CO, = 98.51% (c) 0.0369 (4) 0.0151, 83 @ (e) 0.0257 kg/m? 8.4. 25.71 kg“S70 _ Answers to Exercises 85 8.6 38.7 8.8 8.9. 8.10 8.11 8.12 8.13 8.14 8.15 8.16 8.17 8.1; 8.19 8.20 8.21 8.22 8.23 8.246 825 8.26 8.27 8.28 8.29 8.30 & 83) 8.32 8.33 8.34 8.35 Contains 0.946 x 10-? kg benzene per m? wt as 51.93 m? > 50.99 kg : 4kg 18.8% Ut 262.7 K beatin or 1623 kPa (2) 0.1429 (6) 0.3172 () 0.1667 (4) 0.4643. (c) 0.7988 (f) 2.2254 (8) 42.67 kg _(h) 20.87%. (i) 32.17% : 43.6% (a) 10.13 kPa: (by 0.2364" (c) 0.111" (d) 0.3096: (e)-70.44% (f) 73.41% “(g) 106.2 kg’ (@) 0.1526 (by 0.3163 (c) 13.90 kPa (d) 82.66% (e) 296 K (@) 3.6122 kPa (b) 49.65% (c) 0.023 (d) 47.79% (e) 340.2 K 7.35% het ; (a) 0.0537 () 82.42% (c) 81.48% (d) 327.45 K 315.4 K 19349 kI/m? : Y “ (@) 288.9 K (6) 0.0954 m? : (a) 285.75 K (b) 283.76 K 0.035 : (a) 0.2281, 0.0846 (b) Benzene 7.! 8% ™, 18.6% ww) (c) 49.37%, 45.08% . (@) 306.8 K (b) 420.9 kPa 344.22 kPa (a) 0.3467 kg (b) 41.73% 309.7 K, 0.0253 kg/kg dry air 0.0117 kg, 0.9857 m3 (a) 19.2%, 90.6% (b) 0.67% water, 2.2% water (c) 18.63%, 90.3% (d) 0.487 kg, 1.625 kg (e) 0.484 kg, 1.614 kg (@) 2.36% (b) 0.244 (c) 0.384 (d) 298.9 K (e) 236.6 13.25 kg ! (a) 0.1608 kg of acetone/kg dry of nitrogen, 0.2827 kg of acetone/kg ey nitrogen (b) 0.1219 kg (c) 12.7 kg (d) 104.75 m? 306.9 kPa . 6489.35 m°sh (a) 78.8% (b) 24.23 m/minAnswers to Exercises 57) 8.37 1.65 kgh 4 8.38 (a) 0.0191 km ir, 0. ‘bey a (b) 10276 be oe ay an 9.00494 kmol/mol dry air 839 2846 K “ 8.40 159.75 kPa . : B41 164.53 mh ee ve 8.42 322.9 K . . 8.43 20.5% . “ . 8.44 0.0258 kg of water per kg of dry air 8.45 0.0408 kg of water per kg of dry air 8.46 (a) 314.1 K (0) 0.224 kg of benzene per kg of dry air (c) 205.4 WI 8.48 (a) 299.3 K (b) 304 K 8.49 (a) 279K (b) 312.3 K 8.50 (a) 310K (b) 382.2 K (c) 3393.3 kg/h (4) 2851.9 mh 7 8.51 (a) 6.25% (b) 1.602 kPa (c) 0.16 kg water/kg dry air (d) 20.7 kPa (e) 7.73% (f) 287.7 K (g) 1.0238 ki/kg (bh) 300.7 K 8.53 (a) 0.04 (b) 0.0644 {c) 26.5% (d) 1.0036 m® (e) 310.2K (f) 158.05 kiikg 8.54 (a) 0.035 kg/kg (b) 0.0564kmol/kmol (c) 14% (d) 1.0345 mkg (e) 313 K(f) 186.2 Kihkg 8.55 55.81 m? 8.56 0.99875 mvkg, 153 ki/kg. 155 kIkg ir, 0.0564 kmol/kmol dry air, 30% . ost © $407 ena ‘o S107 K (@) Lo7L Linke. 0.979 mi/kg, 150.3 kikg 8.59 (a) 0.013 kge/kg of dry air, 0.0209 kmoVkmol dry air 1% (b) 326 K, 308 K, 0.028 ke/kg dry air, 28% 8.60 0.007 kg ' 8.61 (a) 299.5 K (b) 0.004 kg 8.62 (a) 298 K (b) 5.55 kg 8.63 © 0.04 ke/kg of dry air (b) 313 K {c) 310 K (d) 70% ° . «a (ec) 0.046 kekg of dry air, 318 K (D 0.598 kg 8.64 (a) 0.01 keskg dry air (b) 40% (€) 370 K (4) 68.6 KI 366 (399 “298 K (c) 31.82 kJ (d) 27.6 ky 8.66 333 K d . 8.67 ° 0.0322, sor, 283.2 K (b) 0.1206, 85%, 316.2 K (c) 6.07 kg 8.68 (a) 289 K (b) 0.01 kg/ke dry air (e) 0.004 kg 8.69 12056.6 kg/h : 8.70 6643 mh ; sae572 _ Answers to Exercises 371 8.72 8.73 8.74 8.75 . 8.76 8.77 8.78 8.79 8.80 8.81 8.82 Chapter9 et 91 92 93 94 95 96 9.7 98 99 9.10 9.41 9.12 9.13 9.14 9.15 9.16 9.17 9.18 9.19 9.20 9.21 (2) 44.9% (b) 189123 mim (2) 3604.6 mA (b) 3355.4 mm 4: @) 305 K (b) 0.2489 kg (c)} 8.76 mh 3.15 kg (2) 0.017 kg/kg dry air, 58%, 295 K (6) 6782.5 KI (c) 2.706 ke” (a) 310K (@) 312 K, 323 K ©) 48% (c) 90.07 m3 (2) 0.028 and 0.096 ke/kg dry air (b) 45.45 kg/h (c) 147895 kim (a) 0.0175, 44%; 0.02, 100%; 0.02, 0.9%, 0.038, 45% (by 2778 ke, ©) 2686 m? (a) 295.7 K, 300.7 K (b) 16.69 kg (c) 342.7 KK’ i (a) 313.) 15K, 318.65 K (b) 70% (c) 89.22 m>° ‘ @) 318.65 K (b) 70% {@) 311K () 2.43 kg (c) 9.11 kg we te 25 ke: 3457 kg | Urea 214.4 kg, Phosphoric acid 359 kg, KCI 411.5 kg O.8F - O.11P = 400; B - 0.675P = 0; 0.2F - 0.215P = 0; F = 573.3 kg, P = 533.3 kg, B = 360 kg 6250 5625 kg 33.33ke .-, Waste acid 419.18 k + Con. HNO, : ‘397: 26 kg. Con. H, 50. 183.56 kg 43.48 kg. Spent acid = 381.55 kg, Con. HNO, =179.83 kg, Con. 50, = 438.62 ke 0.0244 g/L hea 106.28 mol poe (a) 530.95 kg/h pat be : 0.3184 m* : Breton 40% 23:9 1; 10.64 19.19 > at : © fe 122105 (b) Rs. 75958 | 3.3322 x 104 kg/h 9.51 kg: Answers to Exercises 573 9.22 (a) 1.6349 x 103 m3: (by 853 kg bi ke ty " : 9.23 (a) 2000 kg, 1200 kg (b) 2000 kg/h (c) 800 kg/h 9.24 (a) 25% NaOH . (b) 60% NaOH, 2% NaCI, 38% H,O (©) 3500 kg 9.25 (a) NaCl 62.5%, Water 37.5% 9.26 (a) NaBr 2.68%, MgCl, 8.04% (b) NaCl 78.95%, NaBr 5.26%, MéCl, 15.79%. 9.27 (a) 35200 kg (b) 4800 kg (<) 10000 9.28 10.526 kg/100 kg of water 9.29 2997 K 9.30 (a) 17.5 kg (b) 18.61 kg cd 2 931 (a) 294.12 kg (b) 85.47 kg Bente : ' 9.32 (a) 251.26 kg () 103kg 0 < foe ue 9.33 (a) 1857 kg of water, 368 kg of crystals (b) 399 kg of crystals ‘ 9.34 700 kg, 94.7% so . 93S (0) 3.58 m? (b) $34 kg : Se 9.36 Na,SO, 5.2%, water 94.8% : 9.37 Na,SO,: Na,CO, = 1:2 a 9.38 $36.86 kg uo : . 9.39 (a) Na,SO, = 27.96%, H,O = 72.04% (b) 0.0147 kg - o 9.40 30.2 kg crystals vines ue Co . 9.4L 30% Ca (NO,)y4H,0, 70% CuSO, SHO ce 9.42 211 kg ” pa e 9.3 (a) 846 kg (b) 128.2 kg wo. : / : 9.44 (a) 6370 kg (b) 6630 kg pea Se 9AS 261.15 kg, 35 kg . so . 9.46 70.01 kg ; Se - 9.47 750.25 kg . 9.48 10.1% . . oo 9.49 (a) 47.42 kg (b) 25.91 kg | . : ‘ Lo 9.50 (a) 32.5 kg (b) 2.5 kg (c) 30.77% A, 23.08% B, 46.15% HO 951 (a) 7607.1 kg (b) 1085.7 kg. 952 (a) 4567.47 kg (b) 4732.53 kg 953 (a) 332.74 kg (b) 16.48 kg MgSO//100 kg of water 954 (a) 262.5 (b) 3863 kg (c) 3374.5 kg 955 (a) 607.95 kg (b) 130.85 ke 9.56 (a) 19.33 kg (b) 66.3% |S74 Answers to Exercises" STA Answersto Exercises 957 (a) 29.63 (b) 329.52 te @e 8487.14 ke (d) 102.86 kgs st 958 75% 9.59 93.1% Le 9.60 (a) 5.79% (b) 44.22% (c) 96.03% ne 9.61 (2) 588.24 kg ~ (b) 420.59 kg ¢ « 9.62 96.31% 9.63 96.91% a : . : 9.64 (a) 229.17 keh (b) 55% : .? 9.65 (a) 1.105 kg of water per kg of dry leather : (b) 1.05 kg of water per kg of dry leather (c) 95. 24% seas, : 9.66 (a) 42 kg ©) Pulp = 51.72%, Water = 48.28% Poet ee 9.67 150 kg Lethe bts . wae 9.68 0.4167 kg : . 9.69 (a) 12S kg, 102.04 kg (b) 97.22%, 2.55% me 9.70 6250 9.71 (a) 17.74 kgfh (b) 97.99 mm Soy : 9.72 (a) 313.15 K, 318.65 K (b) 70% © 89.22 m? : on 9.73 (a) 318.65 K (b) 70% . 4 9.74 (a) 311K (b) 2.43 kg © O11 ts 9.75 $279.5 kg of wet air oy Cra . 9.76 (a) 820 kg* (b) 105.26 kg (c) 4024. 16 ke cy 9.77 (a) 911.77 kg (b) 508 kg. . 9.78 (a) 37.1% acid, 62.9% water (b) 97.8 kg of raffinate, 149.2 kg of extract . (c) 47 kg 9.79 30 kg, 70 kg 9.80 (a) 68.23 kg, 131.77 kg (b) 74.13% 981 50.82 g (upper layer), 49.18 g (lower layer) 9.82 (a) 166.93 kg, 133.62 kg (b) 31.72 kg 9.83 (a) 97.49 kg (upper) 101.91 kg (lower) {b) 1: 1.006 {c) S, 59.17%, S_ 40.83% ” 9.84 82.05% 9.85 2.2383 x 107 kg 9.86 1.318 kg . See . . 6.11 ki . oss 23 137393 m? (b) N, = 10.97%, cH, = 89.03%" 18% 339 (a) 7.58 ke (b) 986 mol/min (c) 341% (4) 21.3 m/min bende ety991 9.92 9.93 9.94 9.95 9.96 9.97 9.98 9.99 9.100 9.101 9.102 9.103 9.104 9.105 9.106 9.107 9.108 9.109 9.110 9.111 9.112 9.113 ald 91S 9.116 9AIT 9.118 9.119 9.120 9.121 Answers to Exercises 575 () 74.89 kmolh (b) 1286.9 mim © 5.88% {@) 2916.37 kg (b) 75. 25%" (2) 961.67 kg “(b) 77.42% 0 () 157-73 kg (0) 1336.68 kg () 221.05 kg (4) 34.9 kg") 186.15 kg fs (2) 903.06 kmoth (b) Benzene: 0.554%, Toluene = 99.446% ‘ (2) 40 kg (b) 4.44 weight % alcohol "ht @) 37.5 kg (b) 0.6 ves : 462.48 kg ma ve : (a) Feed 44.02%, distillate 97.44%, residue 5.85% °° moe (©) Distillate 41.67 mol, residue 58.33 mol . (2) 615.84 kg (b) B = 3.2%, T = 64.32%, X = 32.48% . (@) 7895 mol; 49.6% propane, 50. 4% butane” 4) 35.9 mol a o 247.8 kg * Overhead: Ethylene 7.79%, Ethane AL 68%, Propylene 194 46%, ‘Propane 56. 07%, © Isobutane 5.0%; . Bottoms: Propane 0.8%, Isobutane 31.91%, n-Butane 47. 10%, m-Pentane 20. 19% (a) F = 40 kg/s, G = 60 kg/s, H = 20 keys“ Vee . . (b) Feed: B = 36.36%, C = 23.64%; D: B = 4.55%, C= 0.45%; F: B = 86.35%, C = 8.64% t (a) 92.33% (b) 240.9 mols O.1 55.56% fee ey # 0.8333 0.1837 0.875 (a) 0.3591 (b) 4.22 kg (c) 129.9 m? . (a) 375 kg (b) 10% (©) 0% oy (a) 100.000 kg/h . (b) 6.75% 5: oe ey 4 0.7093 kg/ke re {a) 26'56% (b) 6000 keh. (c) 1816.24 keh» a 1263.04 kg eh ot a ae (a) 23.44 kefh (a) 1.2. (b) 4651 - (6) 0.973 kg ee ; (a) 3571.43 kg (b) 58204 kg. (a) 0.2 * (b) 2.25 kg (a) 404.21 m? (b) 57.86 kg (c) 190.97 kg576 _Answees to Exercises a -122 (a) Benzene 2%, toluene 55.34%, xylene 42.67% 9: « (>) 2438.21 kg, 6768.62 kg (c) 96.92% (d) 975284 kg 9-123 (a) 7205.93 kgfh (b) 6195.52 kg/h (c) 93.66 kg/h (4) 6.05% 9.124 23295.37 kg; 10.83% NaCl, 84.88% H,O, 4.29% KCl 9.128 0.6132 ten : 9.126 (a) 6.97% (©) 4699 kph “O13m® . a 9127 (a) 926.32 kph (b) 74.42 kg (c) 37.21 kg : - 9.128 (a) 1:6 (b) 75.19 kg (c) 12.53 kg 9.129 (a) 2777.78 kg/h (b) 2109.88 kg/h (c) 17.400 kg/h (d) Mz 1932.1 kg/h pure NaCl; N: 667.90 kg/h, 89.83% KCI, 10.17% NaCl (€) 22109 kg/h, 10.85% NaCl, 2.71% KCI, 86.44% H,O 9.130 (a) 130.16 kg/h (b) 0.838 kg of dry airkg of dry air in the fresh air feed 9131 (a) 4.0953 kg/min (b) 52.21 kg/min (c) 45.44 m/min (d) 358.34 kg/min’ 9.132 (a) 24.53% (b) 5142.8 kg/h (c) 2007.06 kghh 9.133 (a) 315.8 kg/h (b) 105.26 kg/h (c) 894.74 kgm 9.134 (2) 0.9067 (b) 6.9% A, 12.3% B, 6.3% C, 74.5% D 9.135 (a) 0.9 (b) 30% A, 43.33% B, 2.22% C, 24.45% D (c) A = 13.33%, B = 10.00%. C = 5.00%, DaNG6T® 9.136 (a) 20% (b) 9.09% . i 9.137 20% cw 9.138 3.1 9.139 (a) 586.54 kgh (b) 413.46 kgh (c) 0.5551 te 9.140 0.6312 . . Chapter 10 10.1 49.1% 4 102 (a) 195.4 m? (b) 36.036 kg : meg 10.3 (2) 11.08% CO, 83.35% Nz 5.57% H,O (b) 26.98 kg (c} 0.0836 bar 10.4 0.3374 ethene, 0.6626 ethane 10.5 (a) 1.900 kmol (b) 13.78% CO, 4.59% CO, 4.25% O,, 77.38% N, inane: 0.21%, CO, © 3.32%, CO = 041%, HO = 56%, * 1O oda and Ni, = 76.08% ) Pirane: 0.22%, CO," 3.51%, CO = 0.44%, O, = 15.27% and N= s0sem 28% 12.34%, O, = 5.97%, H,0 =13.41%, N, = 68. . : oa wre «9. 97%, 1,0 = 15.03%, Ny = 75.0% (b) 0.553 kg (c) 28.09 hg ee god m (bd) $4.286 m? {c) 20.45% CO, 1.34% O, 78.21% Ny“1030 w co, neem eins . 10.10 (@) Co, %. O, = 6.45%, N. 1.88%, = ' (b) 2784.93 wt (32756 K? HAO = 15.065 (@) 6216 m’m (b) 10.96% CO,, (c) 17138 mm 10.12 (a) CO 1.71%, CO, 17.5%, 0, 2.19%, 10.13 (a) CO, 9.83%, CO 0.52%, 0, 6.57%, 10.14 25% 10.15 (a) 25.0% (b)C:H=1: 0.338 vn 10.16 (a) Methane = 50.0%, N, = = 50.0% (b) 7.73% - 10.17 (a) 33.33% (8 os 10.18 (a) 60.14% CH,, 39.86% cn, ) 39.94% 10.19 (a) 19.71% (b) 0.374 (c) 13.72 m? “ 10.20 (a) 12.19%° (b) 60.81% (c) 12.3304 mol (d) 1767.14 m? 10.21 (a) 405 (b) 3:1, C,H, (©) 18.72 mM” . , 10.22 (a) 1:7.5 (b) 22.69 kg (c) 0.812 kmol , “10.23 37.0% 10.24 (a) 2.67:1, CH, (b) 85:1 | (c) 77.81 m/min ~ 10.25 (a) 10% (b) CHig_(c) 5716.7 m? (4) 3812.8 kg/h 10.26 24.2% 10.27 79.36% 10.28 (a) 12.44% (b) 1:0.2778 (0) 15.66 md) 1.94 kg 10.29 26.57% 10.30 (a) 16.24% (b) 1216.7 m> 10.31 (a) 0.811 10.32 94.23% C, 5.77% H, : : 10.33 (a) 2237.76 kg (b) ‘co, = = 8.76%, 1,0 = 9:19%, Og = 6.68%, Nz = 75.37% 10.11 . and 23 ‘ 0.61% CO, 85.69% Nz and 2.74% 0, N, 78.6% (b) 17729 ke . . N, 83.0856 : (©) 28.76 “ 10.34 319.08 K Cte 1035 19.9% 3 . 10.36 (a) 251.61 kg (b) 1.056 OE eS To OR oe ws : 10.37 (a) 24.6% (b) 37.62 kmot Ee Be Sine Oe Ly 10.38 CO, = 11.33%, SO, = 0.33%, CO = 2.12%, Q, = 3.38%, HO = 6.49%, Ny = 76.35% 2 10.39 75.3% 10.40 (a) 2.188 kg (b) 4.6% (c) 14.26 kg - - 1% : 0.41 (a) 6.67 kg (b) 0.834" oat (a) 63.42% (b) 41-71 mm? (e) 13.54 wved edd a atS78 Answers to Exercises eee Anwers 10 Brees 1043 (a) 16.61% (bd) 11.41 kg (c) 16.4517 m3. .(d) 22.08% C, 77:5 92% inerts 10.44 (a) 1190.53 kg (6) 43.02 kmolh 4 () CO, 13.08%, CO 1.44%, H,0 6.60%, 0, 403%, so, 0.09%, M7 74376% her 10.45 50% ~ 10.46 (a) 8.92 kmol : (b) 47.29% (c) 381.93 m>- 6). 10.47 (a) 196.154 kmol (b) 170.57 kmol (c) 1.75% 1500: 10.48 (a) 1231.824 kg (b) 11.17% 10.49 (a) 3.72% (b) 40% | (€) 10.87 me 10.50 3.88%, 5.12% noe 1051 (a) 50.2% " (b) 1362.6 kg (c) 52.91 1 kg o 1085.06 m? 10.52 (a) 2.572 kg (b) 1458.6 kg (c) 1197.8 m? (d) 3.897%: + (©) Ci 73.8%, H: 5.129%, O: 9.771, S: 1.1, Ash: 10.2% 10.53 (a) 27.14% (b) CO, 7.71%, CO 1.94%, N, 83.37%, O, 6.92% (c) 14.256 kPa 10.54 6.34% SO,, 1.59% SO,, 10.10% O,, 81 97% N, 10.55 2.0276 kg. 10.56 2.7886 kg 10.57 (a) 80.789 kg, 2.24% FeS,, 34.11% Fe,Oy, 18.09% ZnO, 6.99% SO,, 18.57% inerts, (b) 7.73% . : 10.58 89.35% . : * ‘ . 10.59 17.02% 10.60 312.8 m° vest 10.61 (a) 347 m3 (b) 70.0% © 864.04 m . ! . 10.62 (a) 361.42 m>_ (b) 77.0% (or 69.5% or 4.6%) (©) 892.84 m? 10.63 76.8% 10.64 (a) 60% (b) 14.23 m> (c) 8.42 m? 10.65 0.2975 ’ 10.66 (a) 73.64 kg (b) 1.8501 kmol O,, 14.8371 ton Ny. 14511 kmot $0, (©) 40.5% (d) 3.07% 10.67 67.6% : ja9 (a 60 0, 721%, 80, 8.65%, 0, 10.90%, N, 73.24% si » oe © troas Pb ve) sd, 7.01%, 58, 0.22%, 3, 8.87%, Ny 83.91% (©) TST kg he He N 10.70 80.07% 37.08 ky (6) SO, = 9.45%, O, = 11.55%, Ny = 79.003 ° — 10.71 80, = 05%, SO, = 9.4%, O, = 7.39%, Ny = 82.71% a (a) 6.043 kg (b) 50, 9.13%, SO, 7.66%, Nz 73.01%, O, 10.20% (c) 117.24 kg (A) 87.84% 10.72Answers to Exercises 579 1074 (9 132 Ong eae 6) 182.77 ig ° 10.75 (a) 9.70% "MIS ke son ne (@) 0.32% 50,, 10.30% 0, go-3a% NO Kem oe “ 10.76 (a) 523.81 kg (b) 0.4334 Kg (©) 1765 kg bes 10.77 (a) CaCO, 60.31 10.78 Caco, 70% °° 10.79 (a) 65% CaCO,, 30% M; . $% i (6) 7.97 kot "te) 86.2 tte) este 10.80 (a) 40%? (b) Air/Fuel: 15.35:1 °c) 99.55 kg’ (4) 94.73 kg 10.81 (a) Phosphate:sand:charcoal = 1:0.663:0.288 (b) 6.04 kg . . : 10.82 (a) 3.36% (b) 49.886% ne . toa 10.83 (a) 114.15 kg (b) 718.44 kg (c) 72% noe coe . 10.84 51.58 kg : 10.85 (a) 185.08 kg te {b) CaSO, = 70.35%, H,SO, = 15.11%, HF = 1.03%, inetts = 13.51% 10.86 298.3 kg : ae Se Ee , 10.87 (a) 13.16% (b) 91.52% (c) 595.62 kg: Al,O, 16.05%, impurities 83.95% 10.88 (a) NO 2%, N, 78%, O, 20% (b) 0.7 kPa 0.68 kPa (c) 29.49 kg - foe 10.89 (a) 131.84 kg (b) Na,SO, 63.38%, H,SO, 34%, H,O 1.5%, HNO, 1.12% ~ (©) 107.91 kg (d) 72.35 kg, 3.42 kg . - 10.90 30%), ky wet 10.91 (a) 1244.27 m? (b) 300.04 kg / 10.92 (a) 1142.86 m? Le, . (b) 51.34 kmol; 1.19% NH,, 10.58% O,, 71.42% N;, 6.72% NO, 10.09% H,O {c) 49.79 kmol, 1.22% NH,, 7.79% O,, 73.65% N,, 0.69% NO, 6.24% NO,, 10.4% H,O (d) 205.15 kg, 63.32% 9 + 10,93 (a) 276 mol (b) 0.7567 ke - - tee : 10.94 2.8303 x 107 m¥day ~ ats .6 m> . (b) 297.24 m?_ (c) 117. 1095 8 aise Hea ee Oy, 18.3% Cly 64.55% Ny vo x 1.136 k, mo : w096 ° Hct = 18.78%, Cl, = 27.38%, O, = 6.18%, Ny = 40.70%, HO = 696% © a” %, MgCo, 35.13%, inens 456% (b) 9.12% {c) 43.93 kg (c) 324.53 K . ve Loo. : 10.97 (a) 2020.29 kg of CCI, 842.37 kg of S (b) 1660 kg of CC,, 644.42 kg ofS... 10.98 (a) CS,, 20.28% (b) 71.89% (c) S19Bkg ks Coe f . 44.477.92 kg 1417.26 kmol, 1079.76 kmol (b) 44477.92 kg. 1099 3 HCI w 40.98%, Ethylene = 16.54%, O, = 9.89%, Ny = 32.58%i $80 _Answers to Exercises (d) HCI = 4.1%, Ethylene = 2.36%, O, = 1.8%, Ny H,O = 9.11%, EDC = 50.05% se, 10.109 90.7%, 91.9% : : not 10.101 (a) 97.49% (b) 94.55% (c) 1123.4 kg (d) 1255.77 kg (c) HCt 603.07 kg, H,O 266.18 kg: - : 10.102 (a) 1:1.2313 : toe! at (b) HCI 20.69%, Cl, 15.09%, O, 7.95%, Ny 48.61%, H,O 7.67% 10.103 404 10.104 30300 kg/h 10.105 (a) 4.98% CH,OH, 3.73% O,, 51.48% N,, 19.9% HCHO, 19.9% H,O 32.58%, (b) 395.13 m 10.106 (a) 30.1% (b) 4.54:1 10.107 (a) 42.04 kg (b) 81.15 kg (c) 0.67 kg/h 10.108 50% . 10.109 (a) 5 mol (b) 50% (c) 86.5 mol (4) 72.57% 10.110 (a) 2710.71 kg (b) 2403.21 kg (c) 27.81:1 . 10.111 CH, 23.08%, H,O 64.23%, ether 0.13%, ethanol 2.31%, ines 10.26% - 10.112 Ethylene 50.72%, ethanol 2.4%, ether 0.13%, water 33.4%, inerts 13.35% 10.113 (a) 18.94 kg, 86.28 ke (b) monosuiphonate 7.58%, disulphonate 34.51%, H,SO, 51.34%, H,0 6.57% 10.214 (a) 3:11 : (b) Mass%: ethanol 29.22%, acetaldehyde 9.31%, H,O 3.81%, O, 10.83%, N, 46.82%; Mol®: ethanol 20.69%, acetaldehyde 6.90%, HjO 6.90%, O, 11.03%, Ny 54.48% 10.118 77.27% : . . 10,116 (a) 294.86 kg, 91.46% (b) 0.49 (c) 108.9 kmol 10.217 (a) 4 kmolh (>) 80% (c) 1 kmol/n 10.118 (a) 177.45 kg/h (b) 106.93 kg/h 10,119 (a) 1.66 kmol, 2.13 kmol (b) 314.86 kgf (c) 28.21% (4) 37.28 m? 10.120 (a) 3001.6 kg (b) 100.8 kg (0) 3203.2 kg kmol/h C,H: $, 200 kmolh C,H, S, 140 kmol/h C,H, 60 kmolh C,H,. ran emt fe oe tmotm Hy Ss ‘cb fink Hg S, 1b Loew GH CMe 10.122 (a) 300 (b) 1700 12214 ae 86 mol NH, 2. eae e sae koh to A, 190.6 kmoth to B (b) 404.04 kmolm 10.125 ° to jars, CH,OH 4.82%, CH, 0.69%, H,0 0.69%, 1, 62.53% (c) 28 mot10.126 (a) 0.0079 10.127 (a) 673.74 ©) CO 20.38%, H. 76) oN 7%, 10.128 (a) 1:5.71 ©) 244 » CH, 3.0% (©) 48.4 mot -() 97.0% trol (b) 6.667 mol *. Be a ) 32. mol: 10.129 (2) 860 kmol wen wou SO 72am. . 10.130 (a) $0.08 kmol_ (6) 5.87 kmol (©) 293 kel : 10.131 (a) 0.0157 (b) 0.2 mol Ar/3 mol N. H, ( 382 | 0 10.132 4 mol to 100 mol feed ee tenn ° pane mol (b) 42.71% Hy). 57.29% CH, (c) 127.17 mol ‘ ‘ . -79 kmol (b) 95.69% (c) 6.18 kmol Chapter 11 11.1. 17.845 m, 25 15 112 13.86 5 113 89.55 kg, 878.51 N . : 11.4 30.6305 x 105 5 . oo US 1.667 x 102 KI : 11.6 7.355 kJ, 61.29 W 1.7 (a) 14.715,0 (b) 0, 14.715 () 0.035 K 1S 168 W 119 123.46 oP ao, 11.10 (a) 4.164 x 10? N_ (b) 1.3254 x 10° N/m? (c) 2.082 x 10° J (d) 490.5 J 1141 17.15 ms . 11.12 (a) 13) 147.153 11.13 2.156 x 10° 5 11.14 20.39 m nas 31 11.16 1.146 x 10° ks x 103 ae 1839 KJ (b) 1839.4 kJ (c) 1655.46 1 (d) 38.36 m/s (e) 1839.6 AI 11.19 AU = 37.9 Ki/mol; Bf = 41 Ki/mot 11.20 U, = 0.9045 bike, U, = 282.11 kite. 1, © 320.5 Wg 11.25 584 x 1043 14.22 420.1 kJ, 2214 ha, 24039 hing 572 RF ) Q = 0, Ws = 588.34 kI/kg, AH = -588.34 ki/kg 11.102 1744 hp 11.103 35 kJ “11.104 (a) 402.64 mvs, (b) 5.751 x 10+ m? 11.105 344 K 11.106 (a) 46.88 Jkg (b) 50 ike 11.107 15.35 hp 11.108 2453 ki/kg 11.109 2.03 hp 11.110 1.72 K 11.111 30.523 kW 11.112 2.95 x 105 N/m?, 1481.3 W 11.113 4.316 kW, 86.22 kPa, 966 kPa 11.114 81.51 kW 11.115 $67 K : 11.116 (a) 6259 kg/h (b) 378 keh 11.117 0.86 hp 11.118 82.785 kPa 11.119 (a) 5725.2 kWh/day (b) 1.099 m 11.120 122 155 kg/h, 7759 kg/h Rene 11.121 3.174 x 108 Kh toca wt 11.122 35 kg : 11.123 (a) 9.4313 * % 105 kM. (b) 12.3470 x 108 ‘ih ray 11.124°(a) 2976.1 kg/h (b) 1.94 x 10° kJ 11.125 178354 kJ/h 11.126 214.030 kJ/h, 17.26 kg 41.127 1029025 kJ 41.128 3314.8 kJChapter 12 12.1 12.2 12.3 12.4 12.5 12.6 12.7 12.8 12.9 12.10 12.11 12.12 12.13, 12.14 12.15 12.16 12.17 12.18 12.19 12.20 12.21 12.22 12.23 12.24 12.25 12.26 12.27 12.28 12.29 12.30 12.31, 12.32 12.33 12.34 — 1207.43 kJ -194.9 kJ/mol —323.53 ki/kmol —81.46 kJ ~ 102.933 kJ/mol — 110.52 ki/mol 74.79 kJ - 110.52 kJ/mol (a) 240 kgfh (b) 95.71 kmol/h 49.819 x 103 kJ/m? and 45.224 x 10° kJ/m? at STP greater by — 142.216 kJ =114.408 kJ th —904.7 kJ/mol — 1654.27 kJ/mol —241.83 kI/mol —2204.14 kJ/mol 49.02 kJ/mol 1.16 kJ/mol 117.715 kJ/mol —110.52 kJ/mol -199.5 kJ/mol 5.608 x 10° ki/kg -177.0 kJ 286.46 kJ 5.7K — 183.950 kd 185.342 kJ/mol -42.62 kJ/mol 23178 kJ/kg methane 328299.8 kI/kmol CH, — 393.83 kJ/mol 155.509 kJ/mol 886.83 kJ/mol —224,5 kd Answers to Exercises S85586 © Answers 10 Exercises. 12.35 2.072 x 105. _ 12.36. 132.385 x 103 kIm "12.37 32525.5 ki/kmol acid 12.38 19 662.7 kJ "12.39 -377.45 k3/mol tans 12.40 617.88 kd . tyne piet 12.41. — 3283.43 kJ/mol 12.42 70.35 x 103 KI “12.43. 5641.26 kd 12.44 — 191.88 x 10? kI/kmol 5.12.45 28098 KI’, sine Pate 12.46 320.97 kJ 1512.47 @ 9.298 kg/h « (b) 297.04 mh (c) 548 865 kJ 12.48 1805449 kJ 12.49 1308 K > 12.50 2285.3 K 12.51 82% 12.52 387.1 K 12.53 854 K 12.54 1215 K . fe ; 12.55 1914.7 K 12.56 400 K 12.57 857 K 12.58 2237 K