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Points
Phase
Diagrams
III:
Fe
–
Fe3C
Phase
Diagrams
Muddiest
Points:
•
What
is
the
difference
between
eutectoid,
hypoeutectoid,
and
hypereutectoid?
,-.,-(Phases
What Are Characteristics of Important /#0123-#4526728#
on Fe – Fe3C Diagram?
!""#
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Ferrite-‐(α)
Alpha
Iron:
BCC
Iron
/98:935;9<.#=>*#?#/#
with
inters//al
solid
solu/on
of
C
up
to
0.022
wt%
carbon
Carbide
(CemenBte)-‐
Iron
Carbide:
A
hard
and
"#$%&$'()*+%,&-'./*01%.*,*2(.34%*2'4()*51,2%*&''42*(.$'*$6'*)(7%8%.$*2'4()*51
bri@le
stoichiometric
(fixed
composi/on)
compound,
Fe3C.
It
has
an
orthorhombic
crystal
From
Wikimedia
Commons
structure.
Author:
#=Orci
;
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#
Fe-‐Fe3C
Phase
Diagram
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9-8?-72CE7-# Fe-‐Fe3C
Phase
Diagram
Eutectoid
ReacBon-‐
Steel
IK#LE3C-A5C-#
&"""#
γ
γ+
Fe3C
Temperature
°C
%""#
α
+
γ
727
°C
0.022
0.76
$""#
α
α
+
Fe3C
Fe3C
M#J#,-
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6.67
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Comp.
Hypereutectoid
Comp.
Composi/on-‐
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%
C
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&(G!F/# IJ#H#
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&'""#
Steel
Terminology
&
Phase
ProperBes
&&!+
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IK#LE3C-A5C-#
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General
Proper/es:
#M#J#I###
"*+$#
!" !$"()+,"
• Ferrite:
α
-‐
BCC
Fe
0.022
wt%
C
max.
DucBle.
!"#$"%&'(%")*+))
%""# "#"$"!"""
D'D"F,"
• Austenite:
γ
-‐
FCC
Fe
2.14%
C
max.
DucBle.
"*"''# %&%''" %&DE"
• CemenBte:
Fe3C
–
Stoichiometric.
Hard
and
bri`le
ceramic.
MK#,-775C-#
$""# "#" #"$"()+,"
()+,"
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8389)
SAE-‐AISI
Terminology:
YY
XXX
Carbon
Steel
ABC:)78)98:2;",:5C&" ABC)4)78)98:2;",:5C&"
• First
2
or
3
digits
give
steel
alloy
type
+,#$,-./,01)2'3)4)+) />8?>
• 10xx
is
plain
carbon
steel
(no
alloy
elements)
"#$%&$'()*+%,&-'./*01%.*,*2(.34%*2'4()
AISI
Carbon
Steel
ClassificaBon
Chart
• 41xx
is
a
common
alloy
steel
(Cr
0.5-‐0.95%;
Mo
0.12-‐0.30%)
• See
h`p://www.keytometals.com/page.aspx? ClassificaBon
%
Carbon
ID=CheckArBcle&site=kts&NM=333
for
more
informaBon
Low
Carbon
<0.30%
C
Medium
Carbon
0.30%-‐0.60%
• Second
2
or
3
digits
give
%C
content
x
100
High
Carbon
0.60%-‐1.00%
• YY80
has
0.80
wt%
C
Ultrahigh
Carbon
1.25%-‐
2.00%
• YY100
has
1.0
wt.%
C
ApplicaBons
for
Steel
Types
Low
Carbon
Steel:
Used
for
automobile
body
panels
*
and
low-‐strength
wires
*
Medium
Carbon
Steel:
Used
for
axles,
gears,
rails,
and
railway
wheels
#
High
Carbon
Steel:
Used
for
springs
and
high-‐
strength
wires
*
41XX
Alloy
Steels:
Used
for
components
in
fossil
fuel
and
nuclear
power
plants
See
h@p://www.keytometals.com/Ar/cles/Art62.htm
for
more
informa/on
*=
From
Clker.com
#=
Wikimedia
Commons,
author
Rkingsbury-‐
Background
removed
How Does Carbon Content Affect Mechanical Properties?
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nd
Tensile
Strength
(MPA)
Yield
a!"#$%&'(%&)#(*"$#&+,-#(.,/&01234&
#'!"
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%
ElongaBon
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#!!" (!"
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(!" &!"
&!""# !# &!""# !#
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*"+,-./01-."
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&(G!F/#
9-8?-72CE7-#F/##
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&&!+#F/#
IK#LE3C-A5C-# IK#LE3C-A5C-#
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I### ComposiBon
(wt%
C)
ComposiBon
(wt%
C)
"*+$#
Temperature
°C
Temperature
°C
%""# %""#
"*"''#
MK#,-775C-#
$""# $""#
M#J
!""# !""#
"# ComposiBon
(wt%
C)
&# "# ComposiBon
'# (wt%
C)
&# (#
/>8?>35@
As
wt%
C
:Yield
and
Tensile
Strength
and
%
ElongaBon
Muddiest
Points
Phase
Diagrams
III:
Fe
–
Fe3C
Phase
Diagrams
Muddiest
Points:
•
What
is
the
difference
between
eutectoid,
hypoeutectoid,
and
hypereutectoid?