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Abstract
This paper presents simulation studies conducted on a GAX absorption–compression (hybrid) cycle using ammonia–water as working
fluid for air conditioning applications. The degassing range of the cycle has been optimized for maximum COP. The effect of absorber
pressure on the heat duties of the cycle has also been studied. It is found that the maximum COP occurs at an optimum degassing range
of about 0.4 kg of ammonia per kg of strong solution. Comparison of hybrid and conventional GAX cycle was conducted, and it was
found that the hybrid GAX cycle has an average of 30% higher value of COP than the conventional GAX cycle. A reasonable agreement
is observed between the results and performance parameter trends obtained from the present study and the published results available in
the literature.
Ó 2007 Elsevier Ltd. All rights reserved.
0196-8904/$ - see front matter Ó 2007 Elsevier Ltd. All rights reserved.
doi:10.1016/j.enconman.2007.03.013
A. Ramesh Kumar, M. Udayakumar / Energy Conversion and Management 48 (2007) 2604–2610 2605
Nomenclature
and 1.86 for heating together with an energy integration of technique. They showed that by knowing the closeness of
16.9 kW was obtained for a 10.6 kW cooling capacity. Gar- the state points of the heat recovery processes, an economic
imella et al. [5] studied the performance of a GAX heat design trade off of cycle components could be achieved.
pump for both cooling and heating modes using the Scharfe et al. [9] analyzed the advantages and limitations
OSU-ABSIM simulation program. It was shown that for of the GAX cycle. An equation for the heat of desorption
a given capacity, the gas input based COP can be maxi- was derived, and it showed that at any temperature inter-
mized based on the UA variation of heat exchanging com- val, the heat demand in the desorber is higher than the heat
ponents of the cycle. Also, it was demonstrated that the supplied by the absorber. It was observed that the exergy
choice of desorber bypass fraction primarily depends on losses were high due to the high temperature range of the
the design requirements of the adiabatic analyzer, rather heat exchange process. Kang et al. [10] developed an
than being based on the potential heat duty matching advanced GAX cycle for utilization of waste heat, which
between the GAX absorber and desorber. A performance was called the waste heat GAX (WGAX) cycle. They
simulation considering both the cooling and heating modes reported that the generator outlet could be reduced to
as functions of the operating parameters using ABSIM was 172 °C with a higher COP of the WGAX cycle than that
investigated on a Phillips configuration GAX heat pump of the standard GAX (SGAX) cycle. They presented that
by Grossman et al. [6]. They identified the effect on COP the corrosion problem in the standard GAX cycle at higher
of the heat rejection temperature and equilibrium devia- Tg than 200 °C could be solved by adopting the WGAX
tions. Three control schemes were attempted to maintain cycle. Sabir et al. [11] studied the GAX-resorption refriger-
a fixed COP. With the assistance of a Lorentz type plot, ation cycle model. They showed that the COP of the
they arrived at the optimum flow rate of coolant in the GAX-resorption cycle is higher than that of the simple
GAX heat transfer loop. absorption and resorption cycle. Although the cost analysis
Kang et al. [7] established a theoretical model for the was not reported, it is understood from the discussion that
rectifier in the GAX absorption heat pump. Three different the simple GAX cycle is less expensive and gives a better
rectifier configurations were considered for study in this COP than the GAX-Resorption cycle. Kang and Kashiw-
work. Their investigations revealed that a minimum tem- agi [12] developed a GAX cycle for panel heating, which
perature difference between the interface and bulk regions was called the PGAX cycle. They studied the effects of
and a high heat transfer coefficient in the vapour region UA ratio and coolant split ratio on COP in the PGAX
reduces the size of the rectifier. Hanna et al. [8] analyzed and PSE cycles and concluded that there is an optimum
the GAX cycle processes by introducing the pinch point UA ratio that gives the highest COP in the PGAX cycle
2606 A. Ramesh Kumar, M. Udayakumar / Energy Conversion and Management 48 (2007) 2604–2610
for a given split ratio. For a 17.5 TR capacity, this paper urated vapour (11) passes to the compressor (12) through
provides the optimum UA values of the absorbers for the the condensate pre-cooler. The compressor is placed
split ratio of 0.87. Kang et al. [13] developed four different between the evaporator and the absorber. The compressor
advanced Hybrid GAX cycles. By controlling the pressure increases the absorber pressure (15) higher than the evapo-
of the heat exchanging components, the study showed that rator pressure. In the absorber, the refrigerant vapour is
a higher COP, very low evaporator temperature with rea- absorbed by the weak solution coming from the generator
sonable COP, corrosion minimization at higher generator (3) through an expansion valve (4) and forms the strong
temperatures and an increase of hot water outlet tempera- solution (1). The term ‘‘strong solution’’ represents a solu-
ture can be achieved. tion that is strong with refrigerant (NH3), while ‘‘weak
The above literature review reveals that although many solution’’ represents a solution that is weak with refriger-
works have been conducted to analyze the performance of ant. The strong solution (1) pumped to the generator pres-
the basic GAX cycle, few attempts have been made to mod- sure (2) is introduced into the high temperature part of the
ify it. Also, the cost and economic analysis of the GAX absorber, where it receives heat from the absorber, and the
cycle are rarely reported. Furthermore, the degassing range refrigerant in it is boiled off in the generator. The remaining
(difference between the masses of the strong and weak solu- solution (3) flows back to the absorber and, thus, completes
tions), which has the dominant role in the performance of the cycle. The generator and absorber temperature ranges
the GAX cycle is not well documented. This particular partially overlap. This overlapped heat is internally trans-
issue prompted the present work in which a hybrid GAX ferred from the absorber to the generator. The dotted line
compression–absorption cycle is introduced, and the effect (Qgax in Fig. 1) represents the heat exchange between the
on the COP is investigated in terms of degassing range. absorber and generator.
Fig. 1 illustrates the main components of the GAX com- Simulation was performed to evaluate the hybrid GAX
pression–absorption refrigeration cycle. The saturated cooling cycle with the assumptions enumerated below:
solution is assumed to leave the absorber (1) and the gen-
erator (3), and saturated ammonia liquid is assumed to 1. Condenser pressure is the equilibrium pressure corre-
leave the condenser (8). Saturated vapour is assumed to sponding to the refrigerant concentration and the
leave the evaporator (11). The condensate pre-cooler sub- condenser temperature.
cools the refrigerant that leaves the condenser (8) by pre- 2. The condition of the refrigerant at the exit of the
heating the vapour entering the compressor (12). The evaporator is saturated vapour, and the evaporator
high pressure cooled liquid refrigerant (8) from the conden- pressure is the saturated pressure at evaporator
sate pre-cooler enters the evaporator (10) through an temperature.
expansion valve that reduces the pressure of the refrigerant 3. The refrigerant pressure at the outlet of the recipro-
to the evaporator pressure. The liquid refrigerant (10) cating compressor is the absorber pressure.
vaporizes in the evaporator by absorbing heat from the 4. The approach temperature at either end of the GAX
room being conditioned, and the resulting low pressure sat- heat exchanger is assumed to 0 K.
Qc Qr Qg
5 14V
7
Condenser Rectifier GAXD Generator
6 14L
3
8 12
Qgax Expansion
17 2 valve
RHX Pump
P 4
R 9 1
E 13V
S GAXA
S Expansion 11
Absorber
U valve 15
13L
R
E 10 Qa
Compr-
Evaporator essor
Qe CW
TEMPERATURE
5. The efficiency of the solution pump is 0.5. The circulation ratio of the system can be derived as
6. The effectiveness of the heat exchanger (RHX) is 0.8. f ¼ ðrc wscÞ=ðssc wscÞ ð11Þ
7. The temperature of evaporator is assumed as 5 °C.
8. The condenser temperature varies between 45 °C and The degassing range is defined as
30 °C in steps of 5 °C. n ¼ ssc wsc ð12Þ
9. The generator temperature varies between 110 °C and
170 °C in steps of 10 °C. The strong and weak solutions can be determined as
10. The flow through all the components of the cycle is ms ¼ f mr ð13Þ
under steady state. mw ¼ ms mr ð14Þ
11. Pressure drops within the cycle can be neglected
except through the expansion valve. The energy balance for the solution heat exchanger is as
12. The result of the analysis is ignored whenever the follows
mass flow rate of refrigerant becomes zero or an T 9 ¼ T 8 ðe mcf C cf ðT 8 T 11 Þ=ðmhf C hf ÞÞ ð15Þ
unrealistic value in any of the state points of the
cycle. T 12 ¼ T 11 þ e ðT 8 T 11 Þ ð16Þ
The pump power is deduced as
A computer program to determine the thermodynamic
properties of the saturated ammonia–water solutions has W p ¼ ðP c P a Þ ðvc mr Þ=gp ð17Þ
been developed based on the correlations of Patek and h17 ¼ h1 þ ðW p =mr Þ ð18Þ
Klomfar [14]. The relation between the saturation pressure,
Energy balances for the condenser yield
solution temperature and ammonia concentration of the
ammonia–water mixture can also be obtained [15]. The Qc ¼ m7 ðh7 h8 Þ ð19Þ
input parameters to the simulation program are the con- The compression of refrigerant vapour is assumed a poly-
centration of the refrigerant leaving the rectifier, degassing tropic process. So the compression work can then be calcu-
ratio, temperatures of condenser, evaporator and genera- lated as
tor, compressor parameters, efficiency of the pump and
the effectiveness of the heat exchanger. For a given degas- CW ¼ mr ðP e vr nÞ=ðgv ðn 1ÞÞ
sing range and absorber pressure, the simulation program ðn1Þ=n
½ðP a =P e Þ 1 ð20Þ
is capable of determining the rate of heat that has to be
added or rejected from each component of the cycle as well The volumetric efficiency can be expressed as
as the COP at different generator temperatures. In the fol- 1=n
gv ¼ 1 þ k kðP a =P e Þ ð21Þ
lowing section, equations based on the mass, energy and
concentration balance of each component of the cycle is The coefficient of performance of cycle is (COP)
presented. For the desorber, the mass and energy balances COP ¼ Qe =ðQg þ W p þ CWÞ ð22Þ
yield:
m2 þ m6 ¼ m5 þ m3 ð1Þ 4. Validation of the model
m2 h2 þ m6 h6 þ Qgt ¼ m5 h5 þ m3 h3 ð2Þ
To validate the simulation model, the results and the
For the GAX desorber, the mass and energy balances yield:
parameter profiles are compared with the simulation work
m2 þ m6 þ m14V ¼ m5 þ m14L ð3Þ presented in the literature [13]. From Fig. 5, it can be seen
m2 h2 þ m6 h6 þ m14V h14V þ Qrq ¼ m5 h5 þ m14L h14L ð4Þ that at constant desorber and evaporator pressures (1790.3
and 516.87 kPa, respectively), the generator heat supply
For the absorber, the mass and energy balances yield: shows a fast decreasing trend, and the compressor work
m1 ¼ m15 þ m4 ð5Þ shows a gradually increasing trend with absorber pressure
m1 h1 þ m2 h2 þ Qat ¼ m15 h15 þ m4 h4 þ m17 h17 ð6Þ and, hence, cause an increase in the value of COP with
increasing absorber pressure. Kang et al. [13] showed that
For the GAX absorber, the mass and energy balances yield at constant desorber and evaporator pressures (1900 and
m13L ¼ m13V þ m4 ð7Þ 460 kPa, respectively), the cooling COP of the hybrid
GAX system increases with increasing absorber pressure.
m13L h13L þ Qav ¼ m13V h13V þ m4 h4 ð8Þ Thus, it is proved that the simulated COP profiles in this
The mass flow rate of refrigerant is calculated as work match well with the COP profiles obtained from the
OSU-ABSIM simulation work. Though the previous work
mr ¼ ðV p gv Þ=vr ð9Þ claims that the COP increase that could be achieved is 24%
higher than the standard GAX cycle, the present study pre-
The evaporator heat load is calculated as
dicts it as about 30% higher than the standard GAX cycle.
Qe ¼ mr ðh11 h10 Þ ð10Þ This difference is mainly due to the number of idealized
2608 A. Ramesh Kumar, M. Udayakumar / Energy Conversion and Management 48 (2007) 2604–2610
COP
value as 1.08. The heat duties of the components are also 1.3
1.0 Tg = 130 oC
The coefficient of performance is the ratio between the
cooling capacity of the refrigeration system to the heat load 0.2 0.3 0.4 0.5 0.6
added to the generator and power supplied to the pump DEGASING RANGE
and compressor. The mathematical expression is given by Fig. 3. Variation of COP with various generator temperatures.
Eq. (22). Fig. 2 shows the COP variation as a function of
the degasing range for various generator temperatures. 4.5 o o
Tc = 40 C Te = 5 C Pa = 916.87 kPa
The pressures of the desorber, evaporator and absorber
are kept constant as 1555.18 kPa, 516.87 kPa and 4.0
Tg = 170 oC
716.87 kPa, respectively. The degassing range at which
Tg = 160 oC
the COP attains maximum value for each generator tem- 3.5
CIRCULATION RATIO
Tg = 150 oC
perature is denoted as the optimum degassing range.
3.0
Fig. 3 represents the COP variation at higher absorber Tg = 140 oC
pressure (916.87 kPa) keeping all the other parameters con- Tg = 130 oC
2.5
stant. It can be deduced from Figs. 2 and 3 that increasing
the absorber pressure increases the COP for each degassing
2.0 Tg = 120 oC
range, and the higher COP value occurs in the lower degas-
sing range. Along the studied range of absorber pressure Tg = 110 oC
1.5
and evaporator temperature, the optimum degassing range
varies in the amount of ±0.05 about the mean value of 0.4. 1.0
This result is most significant in the context of designing 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65
and running the system. DEGASING RANGE
The circulation ratio is defined as the mass flow rate of Fig. 4. Variation of circulation ratio with various generator temperatures.
the strong solution required to be circulated in the solution
loop in order to circulate a unit mass flow rate in the refrig- Eq. (11). The degassing range affects the value of circulation
erant loop. The mathematical expression is given in ratio. As shown in Fig. 4, at the minimum value of degas-
sing range, the circulation ratio starts with a large value. At
a generator temperature of 110 °C, 0.03826 kg/s of strong
1.50
Tc = 40 oC Te = 5 oC Pa = 716.87 kPa solution is circulated in order to evolve 0.01175 kg/s of
1.45
refrigerant vapour. With rising degassing range, the con-
1.40 Tg = 170 oC
centration of the strong solution increases and the circula-
1.35 Tg = 160 oC
Tg = 150 oC
tion ratio decreases. When Tg increases, the weak solution
1.30
1.25
Tg = 140 oC concentration decreases. At constant degassing range, this
1.20
leads to a decrease in the strong solution concentration.
Further, it increases the absorber temperature. In order
COP
1.15
1.10 to maintain the refrigerant flow rate constant, the mass
1.05 flow rate of the strong solution is to be increased. However,
1.00 Tg = 110 oC the circulation ratio increases with the strong solution flow
Tg = 120 oC
0.95 rate for a constant refrigerant flow rate.
0.90 Tg = 130 oC Increasing the absorber pressure at constant degassing
0.85 range increases the absorber temperature. This increases
0.80 the temperature glide in the absorber and desorber heat
0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65
exchangers, resulting in the rise of heat availability in the
DEGASING RANGE
absorber and the heat required in the desorber as shown
Fig. 2. Variation of COP with various generator temperatures. in Fig. 5.
A. Ramesh Kumar, M. Udayakumar / Energy Conversion and Management 48 (2007) 2604–2610 2609
12
15
mass flow rate at state point 14v results in the increases 1.0
of heat required in the desorber. The rate of the incre- 0.9
ment of heat availability is higher than the rate of the incre- Hybrid GAX, Pa = 916.87 kPa
0.8
ment of heat requirement, causing the COP of the hybrid Conventional GAX, Pa = 516.87 kPa
cycle to be high. Although the compression work required 0.7
Table 1
Variation of mass flow rate at state point 13v with degassing range (Tg = 150 °C, Tc = 40 °C, Te = 5 °C, Pa = 916.87 kPa)
n 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55
m13V 0.0054 0.00603 0.00605 0.00603 0.00586 0.00554 0.0052 0.00458
2610 A. Ramesh Kumar, M. Udayakumar / Energy Conversion and Management 48 (2007) 2604–2610
15
14
ranges in the hybrid cycle, and it can operate success-
13 fully utilizing low temperature energy sources.
12
11 Acknowledgements
10
9 The author thanks K.E. Herold, R. Radermacher and
8
S.A. Klein, the authors of the book ’Absorption Chillers
7
and Heat Pumps’ (CRC Press) for their kindness in supply-
6
0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 ing published papers and program relating to GAX
DEGASING RANGE absorption technology.
Fig. 8. Variation of heat duty with various degassing ranges.
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