Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Corrosion &
Advanced Surfaces
Oct 2015
Materials for
extreme conditions:
CORROSION
TECNALIA´s OFFER
What is corrosion?
What is corrosion?
ENVIRONMENTAL CONDITIONS
Development and optimization of
corrosion protection methods
Fulfill the environmental strengths
and reduction of the costs Splash zone
Early detection of corrosion
mechanisms Sub-merged zone
Sensor Techniques & Remote
monitoring Inside the tower
Diagnostics
01. Research & Development
Corrosion of painting
systems for metallic
structures: specification
and in situ control
Corrosion
evaluation
under
impressed
current
Behaviour of the
polymeric part of Corrosion of
the underwater galvanized/painted systems for
cables at high metallic structures:
pressure and specification, in situ control
temperature and corrosion monitorization
01. Research & Development
Labs equipped with testing facilities allowing Materials Testing & Failure Analisys
a large number of corrosion tests in
Material testing and characterization (i.e.
atmosphere, immersion or under mechanical chemical composition determination,
solicitation to be performed according to microstructure, mechanical properties:
standardized or specific demands. tensile test, fatigue,…).
Surface properties, i.e.: surface
roughness, coating adherence, wettability,
hardness, …).
Corrosion analysis, forecasting,
assessment, control and monitoring.
Wear and friction characterization.
Paints and paints characterization.
Natural marine
exposure site #2 for
material degradation
testing:
Marine Corrosion and
Protection
02. Testing & Analysis: Outdoor
Helgoland Island
02. Testing & Analysis: Outdoor
Bilbao, Spain
03. Corrosion Monitoring
ENVIRONMENTAL CONDITIONS
Atmospheric zone
gas environment, is extremely aggressive:
ELECTRICAL RESISTANCE
Fig1: investigation of a
plane tail with PT*
(Marc Genest et al.)
Fig2: Principle of
PT
(D. Wu et al.) 3
DIN 50018, ASTM G87-02: Sulfur dioxide corrosion testing in a saturated atmosphere, Standard Practice for Conducting
Moist SO 2 Tests ASTM G34-01
ASTM G66-99(2005) e1: Standard Test Method for Exfoliation Corrosion Susceptibility in 2XXX and 7XXX Series Aluminum
Alloys, Standard Test Method for Visual Assessment of Exfoliation Corrosion Susceptibility of 5XXX Series Aluminum Alloys
ASTM G110-92 (2003)e1, ASTM G67-04, Standard practice for evaluating intergranular corrosion resistance of heat
treatable aluminum alloys, Standard Test Method for Determining the Susceptibility to Intergranular Corrosion of 5XXX Series
Aluminum Alloys by Mass Loss
ASTM G31.72(2004): Standard Practice for Laboratory Immersion Corrosion Testing of Metals
ASTM G61-86(2003) e1: Standard Test Method for Conducting Cyclic Potentiodynamic Polarization Measurements for
Localized Corrosion Susceptibility of Iron-, Nickel-, or Cobalt-Based Alloys.
ASTM G59-97 (2003), ASTM G102-89 (2004)e1: Standard Test Method for Conducting Potentiodynamic Polarization
Resistance Measurements
ASTM B117-09, ASTM G75-09 A1, UNE-EN ISO 9227 (2007): Standard Practice for Operating Salt Spray (Fog) Apparatus
NACE TM0177 2005 A and C: Laboratory Testing of Metals for Resistance to Sulfide Stress Cracking and Stress Corrosion
Cracking in H2S Environments.
ASTM G36-94(2006): Standard Practice for Evaluating Stress-Corrosion-Cracking Resistance of Metals and Alloys in a Boiling
Magnesium Chloride Solution
ASTM G48-03 A, B, C, E: Standard Test Methods for Pitting and Crevice Corrosion Resistance of Stainless Steels and Related
Alloys by Use of Ferric Chloride Solution
ASTM G28-02(2008), ASTM A 262-02a (2008) B, C, E, F, ASTM A763-93 (2004), UNE-En ISO 3651-2. 1999: Standard Test
Methods for Detecting Susceptibility to Intergranular Corrosion in Wrought, Nickel-Rich, Chromium-Bearing Alloys
NACE TM 0284- 2003: Evaluation of Pipeline and Pressure Vessel Steels for Resistance to Hydrogen-Induced Cracking
ASTM A 262-02ª (2008) A: Standard Practices for Detecting Susceptibility to Intergranular Attack in Austenitic Stainless
Steels
06. Associations & Standards; DIN, ASTM, NACE,…), ACCREDITATIONS (ENAC, NADCAP)
ASTM D3359-09 A,B, UNE-EN ISO 2409 2007: Standard Test Methods for Measuring Adhesion by Tape Test, Paints
and varnishes - Cross-cut test ASTMD4541-09 B, UNE-EN ISO 11507 2007 A, ASTM D523-08: Standard Test Method
for Pull-Off Strength of Coatings Using Portable Adhesion Testers, Standard Test Method for Specular Gloss
UNE 48269:1995, ASTM D3363-05: Standard Test Method for Film Hardness by Pencil Test
UNE-EN ISO 1522 2007: Paints and varnishes - Pendulum damping test
ASTM D2794-93 (2004), UNE-EN ISO 6272-1 2004: Standard Test Method for Resistance of Organic Coatings to the
Effects of Rapid Deformation (Impact)
UNE-EN ISO 2808: 2007, 6A, 7C, 7D, Internal procedure 53-O-034: PAINTS AND VARNISHES - DETERMINATION OF
FILM THICKNESS
ASTM D2247-02, UNE-EN ISO 6270-2 2006: ASTM D2247-02: Standard Practice for Testing Water Resistance of
Coatings in 100% Relative Humidity, Paints and varnishes - Determination of resistance to humidity - Part 2:
Procedure for exposing test specimens in condensation-water atmospheres.
ISO 3231_1993, ASTM G87-02: Determination of resistance to humid atmospheres containing sulfur dioxide,
Standard Practice for Conducting Moist SO2 Tests
ASTM D5222-93a (2008) A, UNE-EN ISO 6860 2007: Standard Specification for High Fire-Point Mineral Electrical
Insulating Oils, Paints and varnishes - Bend test
UNE-EN ISO 1520 2007: Paints and varnishes - Cupping test
ADVANCED
SURFACES
Advanced surfaces
Corrosion protection/
Self-healing Sol-gel
Hydrophilic/
Coatings Hydrophobic
Diffusion barrier
Abrasion/ wear/
scratch resistant
Aesthetic/
Decorative Chromium coatings with tailored
surface finishing & aesthetic Nano-cromium deposited layer
Dense and porous coatings
Single layer and multilayer Ionic liquids allow electroplating metal and alloys
Different substrates: metals and metallic impossible to deposit using aqueous technology:
alloys, polymers, glass Al, Ti, Si...
Better quality than with aqueous technology
Reduced environmental impact
Advanced Surfaces: wet technologies
MICRO-NANOPRINTING:
Metallic (single
Based on NIL processes
metals and we develop and adapt the
alloys) coatings texture to injection
for different moulding or to
applications. thermoforming to obtain
large areas.
Possibility to INSERTS and MOULD
deposit metallic Surface Modification:
coatings onto inserts and solutions for
conductive and your moulds on different
non-conductive materials: rigid (metallic
substrate and glass) and
substrates.
flexible(silicones, acetates,
polyimides, etc..)
INJECTION MOULDING
Electroless plating and THERMOFORMING
system with nanostructured
inserts.
Advanced Surfaces
Characterisation
Visual appearance Coatings on magnesium
Scanning electron microscope (SEM) Alloys:
High-Humidity Test (ASTM
A380/ASTM97) Corrosion protection and
Copper sulfate Test (ASTM A380) aesthetic applications
Ferroxyl Test (ASTM A380)
Salt Spray Test (B117/ASTM967)
Pen surface tension TEST
Sessil drop test (contact angle)
Advanced Surfaces: Functionalization and protection
Functionalization
Hydrophobic and hydrophilic
surfaces, surface conditioning for
metal polymer bonding, surface
energy of various polymers can be
improved by plasma treatment for
improved wetting with water based
varnish.
As-received
Selective Corrosion
Protection of Electronic by
plasma treatment
Deposit thin, transparent and
insulating plasma-polymer anti-
aging coatings and to selectively
after plasma treating protect electronic units and
especially printed circuit boards.
Advanced Surfaces: Wear
CrAlN nanocrystalline
multiphase coatings
Advanced Surfaces: Wear, surface hardness, fatigue of steels, cast irons, and titanium alloys
Novel Plasma Nitriding of Low Novel Plasma Nitriding of Novel Plasma Nitriding of
allow steel Tool steel Stainless Steel
Friction coefficient
Active Screen Plasma Nitriding Active Screen Plasma Nitriding Active Screen Plasma Nitriding
on St-52 provide hardened on H13 provide hardened on 316L complex geometries
surfaces (>5 µm thickness), wear surfaces (>50 µm thickness), provide hardened surfaces with
resistance and low friction wear resistance and low friction high corrosion resistance in salt
coefficients. coefficients. spray test.
Advanced Surfaces: Tribology
Dry machining.
High speed
machining
Science of lubrication,
friction and wear
Sand and liquid particle
erosion of blades
Gearbox performance
Bearing
Oil/grease lubrication
systems
Dry lubricants
Coatings for space
applications at the ISS
Support
CrN coating on 316L
stainless steel
Advanced Surfaces: Electrical applications
Coloured coatings
Antireflection coatings
High reflection coatings
Metallic mirrors, high and
partially reflective coatings
Absorbers coatings based on
cermet materials
Filters coatings
Light interference in thin coating
Advanced Surfaces: Biomedical
Orthopaedic and
dental applications
TECNALIA has contributed with their developments to the creation of 3
companies related to ADVANCED SURFACES & COATINGS
1) AEROSTAR COATINGS
Company that manufactures HFPD thermal spraying equipment (own
technology) and develops industrial applications.