Competitive Adsorption of dyes (congo red, methylene blue, malachite green) on

Activated Carbon.

Penulis : Bibek Dash

Tahun : 2010
Nama Jurnal : Bachelor of Technology (Chemical Engineering)
Volume/ Nomor/ Halaman : -/ - / 1-29
Abstrak :
The objective of this work is the study of adsorption of dye solution which is
a mixture of three dyes (methylene blue, congo red & malachite green) using
commercial activated carbon.
Removal of these dyes from aqueous solution using commercial activated carbon has
been
investigated. Liquid phase adsorption experiments were conducted. Batch adsorption
studies are
carried out by observing the effect of experimental parameters, namely, pH, amount of
adsorbents,
contact time and temperature. Adsorption capacity of activated carbon is determined for
competitive adsorption of mixture of dyes. Optimum conditions for dye removal are
studied like
pH value, contact time required, amount of adsorbent, temp, etc.

Principles of Adsorption and Adsorpsion Process

Penulis : Douglas M. Ruthven

Tahun : 1984
Nama Jurnal : Physical Adsorption
Volume/ Nomor/ Halaman : -/ -/ 21-34
Abstrak :
 Physical Chemistry

Penulis : Gilbert W Castellan

Tahun : 1983
Nama Jurnal : Physical Chemistry
Volume/ Nomor/ Halaman : -/ - / 1-6
Abstrak :
The greatest stumbling block that can be erected in the path of learning
physical chemistry is the notion that memorizing equations is a sensible way to
proceed. Memory should be reserved for the fundamentals and important definitions.
Equations are meant to be understood, not to be memorized. In physics and chemistry
an equation is not a jumbled mass of symbols, but is a statement of a relation between
physical quantities. As you study keep a pencil and scratch paper handy. Play with
the final equation from a derivation.

Prediction of Presure-Viscosity Coeffisient of Mixtute

Penulis : Shiniciro Hayashi, Kazuo Masuhara, Sobahan Mia,

Shigeki Morita, and Nobuyoshi Ohno
Tahun : 2008
Nama Jurnal : Tribology online
Volume/ Nomor/ Halaman : 3/ 2/ 86-89
Abstrak :
The pressure-viscosity coefficient alpha is one of the most important property
for EHL condition, however its measurement has difficulty. Therefore authors
attempt to predict alpha for blend oils by using the relationship between pressure-
viscosity coefficient and logarithm of kinematic viscosity at atmosphericpressure,
which is used for single oil as ever.

METODE PENENTUAN KOEFISIEN KEKENTALAN ZAT CAIR

DENGAN MENGGUNAKAN REGRESI LINEAR HUKUM STOKES

Penulis : Anwar Budianto

Tahun : 2008
Nama Jurnal : SDM Teknologi Nuklir
Volume/ Nomor/ Halaman : 3/ 2/ 1-10
Abstrak :
Telah dilakukan uji yang bertujuan untuk mengetahui nilai viskositas air,
minyak goreng, olie serta untuk mengetahui pengaruh suhu terhadap nilai viskositas
masing-masing. Metode yang digunakan adalah metode bola jatuh. Penelitian
dilakukan ketika bola telah bergerak dengan kecepatan konstan (GLB), maka berlaku
W=FS + FA, dengan W=gaya berat bola, FS = gaya stokes, FA = gaya archimedes.
 PENGARUH SUHU POLIMERISASI L-ASAM LAKTAT MELALUI
METODE RING OPENING POLYMERIZATION (ROP) TERHADAP
KARAKTERISTIK POLYLACTIC ACID (PLA)

Penulis : Minhatul Ulya* dan Rudiana Agustini

Tahun : 2012
Nama Jurnal : Jurnal Kimia
Volume/ Nomor/ Halaman : 1/ 1/ 1-10
Abstrak :
Penelitian ini bertujuan untuk mengetahui pengaruh suhu polimerisasi
terhadap karakteristik PLA yang meliputi viskositas, massa molekul, dan titik leleh.
Viskositas PLA diukur menggunakan viskometer Ostwald sehingga didapatkan
viskositas intrinsik yang dapat dihubungkan melalui persamaan Mark-Houwink-
Sakurada untuk mendapatkan massa molekul PLA. Titik leleh PLA dianalisis dengan
Differensial Scanning Calorimetry (DSC). Hasil penelitian menunjukkan bahwa suhu
polimerisasi L-asam laktat melalui metode ring opening polymerization (ROP)
berpengaruh terhadap viskositas dan massa molekul PLA. Viskositas dan massa
molekul PLA meningkat seiring dengan suhu polimerisasi yang semakin besar hingga
mencapai suhu polimerisasi 140°C, kemudian terjadi penurunan pada suhu
polimerisasi 160°C. Titik leleh PLA pada suhu polimerisasi 100°C, 120°C, 140°C,
dan 160°C berturut-turut 157,82°C, 157,91°C, 164,41°C dan 161,97°C.

Acetylation of barnyardgrass starch with acetic anhydride under iodine catalysis

Penulis :Josiane Bartz, Jorge Tiago Goebel , Marcos Antônio

Giovanaz , Elessandra da Rosa Zavareze ,Manoel
Artigas Schirmer, Alvaro Renato Guerra Dias
Tahun : 2015
Nama Jurnal : Food Chemistry
Volume/ Nomor/ Halaman : 4/ 3/ 236-242
Abstrak :
Barnyardgrass (Echinochloa crus-galli) is an invasive plant that is difficult to
control and is found in abun dance as part of the waste of the paddy industry. In this
study, barnyardgrass starch was extracted and studied to obtain a novel starch with
potential food and non-food applications. We report some of the physicochemical,
functional and morphological properties as well as the effect of modifying this starch
with acetic anhydride by catalysis with 1, 5 or 10 mM of iodine. The extent of the
introduction of acetyl groups increased with increasing iodine levels as catalyst. The
shape of the granules remained unaltered, but there were low levels of surface
corrosion and the overall relative crystallinity decreased. The pasting temperature,
enthalpy and other gelatinisation temperatures were reduced by the modification.
There was an increase in the viscosity of the pastes, except for the peak viscosity,
which was strongly reduced in 10 mM iodine.
 PARAMETER KINETIKA REAKSI DEKOMPOSISI KATALITIK
METANA MENJADI KARBON NANOTUBE
DENGAN KATALIS Ni-Cu-Al

Penulis : Praswasti PDK Wulan, Widodo W Purwanto*,

Yuswan Muharam, Anindya Adiwardhana
Tahun : 2012
Nama Jurnal : Jurnal Teknik Kimia Indonesia
Volume/ Nomor/ Halaman : 11/ 1/ 34-40
Abstrak :
Pengembangan teknologi produksi karbon nanotube melalui konversi katalitik
hidrokarbon akan efisien dan efektif jika didasarkan pada pengetahuan mekanisme
nukleasi dan pertumbuhan karbon nanotube. Sebagian besar studi melakukan riset
yang difokuskan pada identifikasi produk utama reaksi dan estimasi energi aktivasi.
Data kinetika dan mekanisme pertumbuhan karbon nanotube tidak tersedia dengan
lengkap sehingga model kinetika proses selalu didasarkan pada data kinetika
eksperimen. Pada penelitian ini, dilakukan studi untuk memperoleh parameter
kinetika reaksi dekomposisi katalitik metana menggunakan katalis Ni-Cu-Al dengan
target komposisi 2:1:1 yang dipreparasi dengan metode kopresipitasi menggunakan
presipitan larutan natrium karbonat. Data kinetika eksperimen diambil pada rentang
temperatur 650-750 oC dan tekanan 1 atmosfer. Data kinetika diuji dengan model
kinetika mikro yang diturunkan dari mekanisme reaksi permukaan katalis. Model
kinetika yang paling sesuai dengan hasil percobaan adalah tahap adsorpsi yang
menunjukkan bahwa konsumsi intermediate (reaksi permukaan) lebih cepat dari
pembentukan intermediate (adsorpsi metana). Parameter kinetika yang diperoleh
berupa Energi aktivasi sebesar 40,6 kJ/mol dan faktor pre-eksponensial 8,625 x 106.

ISOTERM KESETIMBANGAN
ADSORPSI TIMBAL PADA ABU SEKAM PADI

Penulis : Bregas S T Sambodo

Tahun : 2012
Nama Jurnal : Jurnal Teknik Kimia Indonesia
Volume/ Nomor/ Halaman : 4/ 2/ 100-105
Abstrak :
One of methods to overcome lead pollution in water is adsorption process. Rice hull,
an abundance agriculture side product in Indonesia, would turn to ash and use as an
alternative adsorbent for lead adsorption. The objectives of this research were to
explore how much lead could be adsorbed on rice hull ash and to determine a suitable
adsorption isotherm model for this process. The batch sorption experiments were
carried out in the 1 liters stirred glass vessel containing 5 ppm Pb(NO3)2 solution.
The weights of adsorbent (rice hull ash) introduced into the vessel were 1 g, 5 g, 8 g
and 15 g. The temperatures of solution were 35oC, 45oC and 55oC. After reaching
equilibrium the solution was analyzed for the remaining Pb2+ by AAS.
 PENYISIHAN LOGAM BESI (Fe) PADA AIR SUMUR DENGAN
KARBON AKTIF DARI TEMPURUNG KEMIRI

Penulis : Nunik Prabarini dan DG Okayadnya

Tahun : 2012
Nama Jurnal : Jurnal Kimia Teknik Lingkungan
Volume/ Nomor/ Halaman : 5/ 2/ 33-42
Abstrak :
Arang aktif dapat dibuat dan tempurung kemiri yang ada saat ini masih berupa
limbah. Pengolahan tempurung kemiri sebagai arang aktif adalah salah satu cara
mudah untuk menambah nilai ekonomis. Arang aktif dibuat dengan proses
karbonisasi suhu tinggi didalam furnace. Arang hasil karbonisasi tersebut kemudian
diaktifkan dengan asam kuat, setelah itu dianalisis daya serap arang aktif terhadap
penyisihan Fe yang terkandung dalam air sumur.

Study Eksperimental Jarak Terhadap Koefisien Tekanan Silinder

Ganda Diposisikan Alined

Penulis : Ketut Astawa, Sukadana & Karnata.

Tahun : 2009
Nama Jurnal : Jurnal Ilmiah Teknik Mesin CakraM
Volume/ Nomor/ Halaman : 3/ 2/133-137
Abstrak :
Faktor-faktor yang mempengaruhi dari koefisien tekanan fluida adalah
kecepatan fluida, kerapatan fluida, viskositas fluida dan geometri dari permukaan
yang dilewati oleh fluida. Penelitian ini dilakukan dengan memvariasikan beberapa
faktor yang mempengaruhi nilai koefisien tekanan yaitu permukaan geometri
termasuk bentuk silinder dan variasi aliran . Tekanan yang diukur didasarkan pada
perubahan panjang kolom minyak (r, mm) pada manometer miring yang tersambung
ke tekanan yang terletak pada permukaan silinder. Data yang dikumpulkan
didasarkan pada variasi tiga jenis ruang tabung 1.2D, 1.7D, dan 2.2D, dan tiga jenis
variasi diameter silinder ada 2 ", 2.5" dan 3 ", dan aliran bebas dijaga tetap konstan 6
m / s. Hasil penelitian menunjukkan bahwa, semakin tinggi ruang tabung
mempengaruhi posisi dan nilai dari tekanan maksimum di bagian belakang silinder.
Nilai dan posisi dari titik pemisahan lebih pada arah belakang sejalan dengan
peningkatan aliran bebas. Penurunan tekanan terjadi pada bagian belakang pada aliran
bebas yang tinggi.
 MOLECULAR MODELING OF CATIONIC PORPHYRINS
AS LIGAD OF RADIOPHARMACEUTICAL KIT

Penulis : Ni Made Pitri Susanti1,2), Rahmana E. Kartasasmita2),

Amir Musadad2), and Daryono H. Tjahjono2)
Tahun : 2011
Nama Jurnal : Jurnal Kimia
Volume/ Nomor/ Halaman : 5/ 1/ 94-100
Abstrak :

Porfirin kationik dan interaksinya dengan DNA telah menjadi perhatian

penting dalam pengembangan fotosensitizer dalam teknik terapi fotodinamik pada
pengobatan kanker. Namun demikian, teknik terapi ini memiliki kekurangan dalam
mendokumentasikan secara fotografik fluoresensi yang teramati secara endoskopi[.
Penelitian ini bertujuan mengamati perubahan molekular senyawa porfirin kationik
yang dilabel dengan radionuklida pemancar radiasi gama (γ) dan partikel beta (β)
beserta afinitasnya terhadap DNA secara teoritik. Model molekul 5,10,15,20-tetrakis-
[3,4-bis(karboksimetilenoksi) imidazolium] porfirin (T3,4BCImP), 5,10,15,20-
tetrakis-[3,4-bis (karboksimetilenoksi) pirazolium] porfirin (T3,4BCPzP) serta
kompleks hasil pelabelan dengan radionuklida Tc dan Re pada gugus karboksinya
diopti masi dengan metode teori fungsi densitas (density functional theory/DFT),
sedangkan muatan atom dihitung menggunakan natural population analysis (NPA).
Energi orbital molekul juga dihitung menggunakan metode dan parameter yang sama.
Hasil penelitian menunjukkan bahwa molekul Tc-T3,4BCPzP memiliki
fotosensitifitas dan afinitas yang terbaik terhadap DNA dibandingkan molekul
lainnya. Gugus karboksilat pada substituen meso memungkinkan T3,4BCPzP dan
T3,4BCImP dapat di-label dengan radionuklida Tc dan Re sebagai kandidat kit
radiofarmasi.

Green Inhibitors for Corrosion Protection ofMetals and Alloys:

An Overview

Penulis : B. E. Amitha Rani and Bharathi Bai J. Basu

Tahun : 2011
Nama Jurnal : International Journal of Corrosion
Volume/ Nomor/ Halaman : 2012/ -/ 1-15
Abstrak :
Attribution License, which permits unrestricted use, distribution, and
reproduction in any medium, provided the original work is roperly cited.Corrosion
control of metals is of technical, economical, environmental, and aesthetical
importance. The use of inhibitors is one of the best options of protecting metals and
alloys against corrosion. The environmental toxicity of organic corrosion inhibitors
has prompted the search for green corrosion inhibitors as they are biodegradable.
 KOROSI LOGAM DI DALAM BEBERAPA MEDIA CAIR

Penulis : Bregas S T Sambodo

Tahun : 1999
Nama Jurnal : Jurnal Teknik Kimia Indonesia
Volume/ Nomor/ Halaman : 2/ 1/ 1-8
Abstrak :
A study of corrosion on iron and aluminium in some liquid solutions has been
done from thermodinamical and electrochemical point of view. The results show that
there are different kinds of corrosion on iron and aluminium.

Occupational Asthma: New Low-Molecular-Weight

Causal Agents, 2000–2010

Penulis : J. A. Pralong,1 A. Cartier,1 O. Vandenplas,2 andM.

Labrecque1
Tahun : 2012
Nama Jurnal : Jurnal Kimia Teknik Lingkungan
Volume/ Nomor/ Halaman : 2012/ -/ 1-10
Abstrak
Background.More than 400 agents have been documented as causing
occupational asthma (OA). The list of low-molecular-weight (LMW) agents that have
been identified as potential causes of OA is constantly expanding, emphasizing the
need to continually update our knowledg: by reviewing the literature. Objective. The
objective of this paper was to identify all new LMW agents causing occupational
asthma reported during the period 2000–2010. Methods. AMedline search was
performed using the keywords occupational asthma, new allergens, new causes, and
low-molecular-weight agents. Results. We found 39 publications describing 41
new LMW causal agents, which belonged to the following categories: drugs (n = 12),
wood dust (n = 11), chemicals (n = 8), metals (n = 4), biocides (n = 3), and
miscellaneous (n = 3). The diagnosis of OA was confirmed through SIC for 35 of 41
agents, peak expiratory flow monitoring for three (3) agents, and the clinical history
alone for three (3) agents. Immunological tests provided evidence supporting an IgE-
mediated mechanism for eight (8) (20%) of the newly described agents. Conclusion.
This paper highlights the importance of being alert to the occurrence of new
LMWsensitizers, which can elicit OA. The immunological mechanism is explained
by a type I hypersensitivity reaction in 20% of all newly described LMW agents.
 Copper Corrosion Inhibitors. A review

Penulis : M. M. Antonijevic* and M. B. Petrovic

Tahun : 2007
Nama Jurnal : Int. J. Electrochem
Volume/ Nomor/ Halaman : 2008/ 3/ 1-28
Abstrak :
The literature dealing with the electrochemical corrosion of copper and
possibility of its prevention using inhibitors is examined. Inorganic compounds are
investigated as well, but organic compounds and their derivatives in much greater
numbers. Researches are directed to influence of compounds structure, concentration,
method of application as well as media that inhibitor is used in on inhibition
efficiency. Moreover, action mechanisms are studied. The attempts to find models,
which can enable prediction of possibilities of newly synthesized compounds to act as
corrosion inhibitors, combining theory and practical investigations of substances with
similar structure are also significant.

Temperature Effects on the Rate of Reaction of Plasma

Albumin with Formaldehyde in Water Solution and
Ethanol-Water-Mixtures

Penulis : J.T. Ugye1, A. Uzairu, S.O. Idris and H.O. Kwanashie

Tahun : 2013
Nama Jurnal : Chemistry Journal
Volume/ Nomor/ Halaman : 3/ 5/ 128-132
Abstrak :
The effects of temperature on the rate of reaction of plasma albumin and
formaldehyde in water solution and in ethanol water mixtures (1-25%) were
investigated under seven temperatures from 20-45 oC. The effects of the temperature
variations on the reaction of plasma albumin with formaldehyde were then
established from a plot of ln(At-A∞) against time at each of the varied temperatures.
Also the Erying plots, logk2/T vs. 1/T as a function of different temperatures were
plotted and the thermodynamic parameters were calculated from the relation ln(k2 /
T) = - ΔH҂/RT + ΔS҂/ R + 23.8 while the activation energy was calculated by using
the expression Ea = ΔH҂ + RT and the plot of lnk against 1/T according to the
Arrhenius equation. The result of the temperature dependent study in water solution
showed a mean second order rate constant k2=, 2.47 (±0.1) mol-1s-1, while that in
ethanol-water-mixtures showed a mean value of (2.47 (±0.4). The rate constants of
the reaction in both media were observed to have decreased steadily with increase in
temperatures, it could then be asserted that the reaction was not favoured at high
temperatures in both media.
APLIKASI LabVIEW SEBAGAI PENGUKUR KADAR VITAMIN
C DALAM LARUTAN
MENGGUNAKAN METODE TITRASI IODIMETRI

Penulis : Anggi Pratama1, Darjat, ST, MT2, Iwan Setiawan, ST, MT2
Tahun : 2005
Nama Jurnal : jurnal kimia
Volume/ Nomor/ Halaman : 2/ 1/ 1-9
Abstrak :
Vitamin C atau L-asam askorbat merupakan senyawa bersifat asam dengan rumus
empiris C6H8O6 (berat molekul = 176,13). Vitamin C digunakan sebagai antioksidan
untuk pembentukan kolagen, penyerapan zat besi,serta membantu memelihara
pembuluh kapiler, tulang dan gigi. Kadar vitamin C dalam larutan dapat diukur
menggunakan titrasi redoks iodimetri, dengan menggunakan larutan indikator kanji
(starch) yaitu dengan menambahkan sedikit demi sedikit larutan iodin (I2) yang
diketahui molaritasnya sampai mencapai titikkeseimbangan yang ditandai dengan
perubahan warna larutan menjadi biru pekat.Modul LabVIEW dapat digunakan
sebagai pengukur kadar vitamin C dalam larutan terotomatisasi dengan komputer.
Input perubahan warna larutan dideteksi dengan sensor cahaya LDR. Pada kondisi
awal, sistem akan meggerakkan kran buret berisi larutan iodin dalam posisi membuka
hingga pada saat kondisi setimbang sistemakan menggerakkan kran buret dalam
posisi menutup. Output sistem juga menggerakkan motor DC yang dikopel dengan
pengaduk. Dengan diketahuinya molaritas dan volume larutan iodin yang
ditambahkan selama titrasi pada larutan bervitamin C, maka kadar vitamin C dalam
larutan dapat dicari nilainya. Sample yang diuji adalah minuman ringan dengan kadar
Vitamin C tertera pada kemasan. Dari hasil pengujian didapatkan rata-rata error
sebesar 1,224 mg untuk tiap pengujian.

Temperature impact assessment on struvite solubility product:

A thermodynamic modeling approach

Penulis : Mary Hanhouna, Ludovic Montastruca, Catherine

Azzaro-Pantela,Béatrice Biscansa, Michèle Frècheb,
Luc Pibouleaua
Tahun : 2005
Nama Jurnal : jurnal kimia
Volume/ Nomor/ Halaman : 2/ 1/ 1-24
Abstrak :
This work addresses the problem of phosphorus recovery from wastewater by
struvite precipitation,which is chemically known as magnesium ammonium
phosphate hexahydrate MgNH4PO4·6H2O. Thestruvite solubility product values that
are reported in the literature were found to vary significantly,from one solution.
 DEKOMPOSISI JERAMI SECARA TERMOKIMIA
DALAM AIR PANAS BERTEKANAN

Penulis : Arif Jumari1

Tahun : 2008
Nama Jurnal : jurnal kimia
Volume/ Nomor/ Halaman : 7/ 1/ 1-8
Abstrak :
Rice stalks can be one of the potential alternative energy resources by
converting itinto oil by thermochemical liquefaction in the hot compressed water.
This research was intended to find a temperature and a pressure which produce a
maximum yield of oil, and the contained substances in the oil. A 100 ml cylindrical
autoclave used in the experiment was loaded with 5 g dry powdered rice stalks, 2 g
catalyst (sodium carbonate) and 70 ml water. After having blown with Nitrogen, the
autoclave was heated in the tube furnace until the desired temperature, and then kept
at this temperature for 10 min. The liquid product was extracted with n-hexane and
the extract was distillated to obtain oil. The results showed that the maximum yield
was 29.8% at 280oC, 6.42 MPa. The oil mostly contained hydrocarbon compounds
from C-19 to lower. The main compound was n-octadecane by 6.16% weight.

Thermochemistry of Imidazolium-Based Ionic Liquids:

Experiment and First-Principles Calculations

Penulis : Sergey P. Verevkin a, Vladimir N. Emel’yanenko,

Dzmitry H. Zaitsau, Andreas Heintz Chris D. Muzny,
Michael Frenkel
Tahun : 2010
Nama Jurnal : Physical Chemistry
Volume/ Nomor/ Halaman : -/ -/ 1-6
Abstrak :
A for the definition of the symbols see reference 13, Th = 298.15 K; V(bomb) = 0.32
dm3; pi(gas) = 3.04 MPa; mi(H2O) = 1.00 g; b Masses obtained
from apparent masses. c ΔTc = Tf - Ti + ΔTcorr; (εcont)·(-ΔTc) = (εicont )·(Ti -
298.15 K) + (εfcont )·(298.15 K - Tf + ΔTcorr.). d ΔUcorr, the
correction to standard states, is the sum of items 81 to 85, 87 to 90, 93, and 94 in
reference 13. f ε = 14804.82 ± 0.9 J·K-1.
 PHYSICAL CHEMISTRY

Penulis : Atkins
Tahun : 2006
Nama Jurnal : Physical Chemistry
Volume/ Nomor/ Halaman : -/ -/ -
Abstrak :
The most striking change in presentation is the use of colour. We have made
everyeffort to use colour systematically and pedagogically, not gratuitously, seeing as
a medium for making the text more attractive but using it to convey concepts and data
more clearly. The text is still divided into three parts, but material has been moved
between chapters and the chapters have been reorganized. We have responded to the
shift in emphasis away from classical thermodynamics by combining several chapters
in Part 1 (Equilibrium), bearing in mind that some of the material will already have
been covered in earlier courses. We no longer make a distinction between ‘concepts’
and ‘machinery’, and as a result have provided a more compact presentation of
thermodynamics with less artificial divisions between the approaches. Similarly,
equilibrium electrochemistry now finds a home within the chapter on chemical
equilibrium, where space has been made by reducing the discussion of acids and
bases.

Determination of nanoparticle size distribution together with density or

molecular weight by 2D analytical ultracentrifugation

Penulis : Randy P. Carney1,2, Jin Young Kim1, Huifeng

Qian3, Rongchao Jin3, Hakim Mehenni4,5, Francesco
Stellacci1,2 & Osman M. Bakr4,5
Tahun : 2011
Article : DOI: 10.1038/ncomms1338
Abstrak :
Nanoparticles are finding many research and industrial applications, yet their
characterization remains a challenge. Their cores are often polydisperse and coated
by a stabilizing shell that varies in size and composition. No single technique can
characterize both the size distribution and the nature of the shell. Advances in
analytical ultracentrifugation allow for the extraction of the sedimentation (s) and
diffusion coefficients (D). Here we report an approach to transform the s and D
distributions of nanoparticles in solution into precise molecular weight (M), density
(ρP) and particle diameter (dp) distributions. M for mixtures of discrete nanocrystals
is found within 4% of the known quantities. The accuracy and the density information
we achieve on nanoparticles are unparalleled. A single experimental run is sufficient
for full nanoparticle characterization, without the need for standards or other auxiliary
measurements. We believe that our method is of general applicability and we discuss
its limitations.
Equilibrium and kinetics Studies of Adsorption of Heavy Metals ontoActivated
Carbon

Penulis : Abbas Hammed Sulaymon, Thamer Jasim

Mohammed, Jenan Al-Najar*
Tahun : 2012
Nama Jurnal : Canadian Journal on Chemical Engineering &
Technology
Volume/ Nomor/ Halaman : 3/ 4/ 1-7
Abstrak :

Heavy metal ions are toxic pollutants. The contamination of water by toxic
metals is a world-wide environmental problem. This paper studies the adsorption
isotherm of heavy metals named Pb(II), Cu(II), Cr(III) and Co(II) ions from aqueous
solution onto activated carbon. The results show that activated carbon can be used as
an adsorbent for the removal of heavy metals. The amount of metal ions adsorbed
increases with increasing the initial metal ions concentration. Six adsorption isotherm
models were used to analyze the experimental data. Radk- Prausnitz, Langmuir
isotherm, Redlich-Peterson and Sips isotherm models gave the best fit with the
correlation coefficient, R2, value ranging from 0.999 to 0.978 (Ave. 0.993). This is
followed by Freundlich isotherm (Ave. 0.971) and Temkin isotherm (Ave. 0.937).
The kinetics of these metal ions adsorbed onto activated carbon was analyzed using
pseudo-first order and pseudo-second order. Results were found to follow pseudo-
second order equation.

Economic Assessment of Low-Molecular-Weight Heparin (Enoxaparin) Versus

Unfractionated Heparin in Acute Coronary Syndrome Patients : Results From
the ESSENCE Randomized Trial

Penulis : Daniel B. Mark, Patricia A. Cowper, Scott D.

Berkowitz
Tahun : 1998
Article : doi: 10.1161/01.CIR.97.17.1702
Abstrak :

In the ESSENCE trial, subcutaneous low-molecular-weight heparin

(enoxaparin) reduced the 30-day incidence of death, myocardial infarction, and
recurrent angina relative to intravenous unfractionated heparin in 3171 patients with
acute coronary syndrome (unstable angina or non–Q-wave myocardial infarction). No
increase in major bleeding was seen.
 Chemical Reaction and Thermal Diffusion
Effects on Mass Transfer Flow through an Inclined Plate

Penulis : Farjana Akter1, Md. Manjiul Islam1, Ariful Islam1,

Md. Shakhaoath Khan2, Md. Saddam Hossain1
Tahun : 2016
Nama Jurnal :
Volume/ Nomor/ Halaman : 6/ -/ 62-74
Abstrak :
A numerical investigation of boundary layer mass transfer flow through an inclined
plate with the effect of chemical reaction and thermal diffusion is presented in this
study. The governing partial differential equations (PDE) are transformed to a system
of dimensionless non-similar coupled PDEs. The transformed, non-similar
conservations equations (momentum balance equation, energy balance equation and
concentration balance equation) are then solved using a numerical approach known as
explicit finite difference method (EFDM). Basically EFDM introduced for the
unsteadiness in the momentum, temperature, and concentration fluid fields is based
on the time dependent fluid velocity, temperature and concentration of the boundary
surface. During the course of discussion, it is found that the various parameters
related to the problem influence the calculated resultant expressions. The computed
numerical solution results for the velocity, temperature, and concentration distribution
with the effect of various important dimensionless parameters (Grashof number,
Modified Grashof number, Prandtl number, Schmidt number, Soret number, Dufour
number, chemical reaction parameter and inclination parameter) entering into the
problems are critically analyzed and discussed graphically. It can be seen that two
physical phenomena chemical reaction and thermal diffusion can greatly effect on the
boundary layer fluid flows through an inclined plate.

Solubility Product of Hexavalent Uranium Hydrous Oxide

Penulis : Kenso FUJIWARA1;_,y, Hajimu YAMANA2,

Toshiyuki FUJII2, Keizo KAWAMOTO2, Takayuki
SASAKI1 and Hirotake MORIYAMA1
Tahun : 2005
Nama Jurnal : Journal of NUCLEAR SCIENCE and
TECHNOLOGY
Volume/ Nomor/ Halaman : 42/ 3/ 289-294
Abstrak :
The solubility of U(VI) hydrous oxide was measured in the hydrogen ion
concentration (pHc) range from 4 to 6 at 25_1_C in a NaClO4 solution. The
experiment was carried out by oversaturation method at ionic strength I¼0:1, 0.5 and
1.0 and by undersaturation method at I¼1:0. The solid phase was found to be
composed of a mixture of UO3.2H2O and UO2(OH)2 by XRD. The concentration of
U(VI) was measured by inductively coupled plasma mass spectrometry (ICP-MS).
 FUNGSI GELOMBANG
Persamaan Schrödinger

Penulis : Anggi Pratama1, Darjat, ST, MT2, Iwan Setiawan,

ST, MT2
Tahun : 2005
Nama Jurnal : Jurnal Kimia Fisika
Volume/ Nomor/ Halaman : 1/ 3/ 1-7
Abstrak :
Fungsi gelombang Ψ, diperoleh dengan memecahkan persamaan Schrödinger.
Persamaan Schrödinger merupakan persamaan pokok dalam mekanika kuantum.
Untuk mendapatkan persamaan Schrödinger, kita mulai dari persamaan gelombang
paket yang telah diperoleh sebelumnya.

Analisis Fungsi Gelombang dan Spektrum Energi Potensial

Rosen Morse Menggunakan Metode Hipergeometri

Penulis : Suparmi
Tahun : 2012
Nama Jurnal : Jurnal Matematika dan Sains
Volume/ Nomor/ Halaman : 17/ 2/ 1-7
Abstrak :
Perilaku partikel atomik dapat dipahami dengan jelas bila energi dan fungsi
gelombang dari partikel tersebut diketahui. Spektrum energi dan fungsi gelombang
untuk partikel yang dipengaruhi oleh potensial Rosen Morse dianalisis menggunakan
metode hipergeometri. Persamaan Schrödinger untuk potensial Rosen Morse diubah
menjadi persamaan diferensial orde dua fungsi hipergeometri dengan substitusi
variabel dan parameter secara tepat. Spektrum energi diperoleh secara eksak dan
fungsi gelombang dinyatakan dalam bentuk polynomial hipergeometri. Grafik
potensial efektif dengan spektrum energi, fungsi gelombang tingkat dasar, tingkat
pertama dan kedua serta rapat probabilitasnya divisualisasikan dengan menggunakan
bahasa pemograman Delphi 7.0.
 Anomalously Strong Effect of the Ion Sign on the
Thermochemistry of Hydrogen Bonded Aqueous Clusters of
Identical Chemical Composition

Penulis : Alexey B. Nadykto

Tahun : 2009
Nama Jurnal : International Journal of Molecular Sciences
Volume/ Nomor/ Halaman : 10, 507-517
Abstrak :
The sign preference of hydrogen bonded aqueous ionic clusters Χ±(H2O)i (n
=1-5, Χ = F; Cl; Br) has been investigated using the Density Functional Theory and
abinitio MP2 method. The present study indicates the anomalously large difference in
formation free energies between cations and anions of identical chemical
composition. The effect of vibrational anharmonicity on stepwise Gibbs free energy
changes has been investigated, and possible uncertainties associated with the
harmonic treatment of vibrational spectra have been discussed.

CO2 Adsorption on Activated Carbon Honeycomb-Monoliths:

A Comparison of Langmuir and Tóth Models

Penulis : Diana P. Vargas

Tahun : 2012
Nama Jurnal : International Journal of Molecular Sciences
Volume/ Nomor/ Halaman : 13, 8388-8397
Abstrak :
Activated carbon honeycomb-monoliths with different textural properties were
prepared by chemical activation of African palm shells with H3PO4, ZnCl2 and CaCl2
aqueous solutions of various concentrations. The adsorbents obtained were
characterized by N2 adsorption at 77 K, and their carbon dioxide adsorption capacities
were measured at 273 K and 1 Bar in volumetric adsorption equipment. The
experimental adsorption isotherms were fitted to Langmuir and Tóth models, and a
better fit was observed to Tóth equation with a correlation coefficient of 0.999. The
maximum experimental values for adsorption capacity at the highest pressure (2.627–
5.756 mmol·g−1) are between the calculated data in the two models.
 Thermochemistry of Molecules in the
B/F/H/N System

Penulis : PATRI´CIA R. P. BARRETO

Tahun : 2004
Nama Jurnal : chemistry journal
Volume/ Nomor/ Halaman : -
Abstrak :
A self-consistent set of thermochemical data for 88 chemical species in
the B/F/H/N system is obtained from ab initio electronic structure calculation.
Calculations were performed for both stable and radical species. The quantities
calculated include the atomization energy (¥ D0), heat of formation (_Hf) at 0 K and
298.15 K, and bond dissociation energies (BDE) for all species. Good agreement is
found between the calculation data and experimental or theoretical reference data for
the quantities analyzed in this work for several species containing B, F, H, and N
atoms.We also present a compilation of experimental and theoretical atomization
energies (16experimental _ 26 theoretical data), heat of formation at 0 K (25
experimental _ 26theoretical data), heat of formation at 298 K (29 experimental _ 36
theoretical data), and bond dissociation energy for several species. Polynomial fits of
the predicted thermodynamic data (heat capacity, entropy, and enthalpy) over the
200–6000 K temperature range are also included, for the 88 species. The species
analyzed in this study are important in a kinetic mechanism for growth boron nitride
films in a Chemical Vapour Deposition (CVD) reactor. It is generally difficult to
optimize conditions in a CVD reactor because films properties depend on complex
interactions involving heat and mass transport, chemical kinetics, and
thermochemistry. Developing a reliable set of thermodynamic data is a necessary first
step for system optimization, since it provides important constraints on the possible
reaction mechanism. © 2005 Wiley Periodicals, Inc. Int J Quantum Chem 103: 659–
684, 2005
 Molecular theory of partial molar volume and its
applications to biomolecular systems

Penulis : T.Imai
Tahun : 2007
Nama Jurnal : Condensed Matter Physics
Volume/ Nomor/ Halaman : Vol. 10, No 3(51), pp. 343–361
Abstrak :
The partial molar volume (PMV) is a thermodynamic quantity which contains
important information about the solute-solvent interactions as well as the solute
structure in solution. Additionally, the PMV is the most essential quantity in the
analysis of the pressure effect on chemical reactions. This article reviews the recent
developments in molecular theories of the PMV, especially the reference interaction
site model (RISM) theory of molecular liquids and its three-dimensional
generalization version (3D-RISM), which are combined with the Kirkwood-Buff
solution theory to calculate the PMV. This article also introduces our recent
applications of the theory to some interesting issues concerning the PMV of
biomolecules. In addition, theoretical representations of the effects of intramolecular
fluctuation on the PMV, which are significant for biomacromolecules, are briefly
discussed.

ARANG AKTIF
(Pengenalan dan Proses Pembuatannya)

Penulis : MEILITA TRYANA SEMBIRING

Tahun : 2003
Nama Jurnal : jurnal kimia
Volume/ Nomor/ Halaman : -
Abstrak :
Arang merupakan suatu padatan berpori yang mengandung 85-95% karbon,
dihasilkan dari bahan-bahan yang mengandung karbon dengan pemanasan pada
suhu tinggi. Ketika pemanasan berlangsung, diusahakan agar tidak terjadi kebocoran
udara didalam ruangan pemanasan sehingga bahan yang mengandung karbon tersebut
hanya terkarbonisasi dan tidak teroksidasi.
 Generalized Perturbational Molecular
Orbital (PMO) Theory

Penulis : DONG-KYUN SEO

Tahun : 1999
Nama Jurnal : jurnal kimia
Volume/ Nomor/ Halaman : -
Abstrak :
The useful perturbation expressions for wave functions and energies
that are needed in perturbational molecular orbital _PMO. theory are rederived and
generalized in two aspects: First, degenerate systems now can be treated in a
systematic manner, as in the case of nondegenerate systems. Second, the new
expressions can cope with complex wave functions. Two examples of applications to
degenerate systems are given to show the qualitative and quantitative utility of the
new expressions.

EXPERIMENTAL DETERMINATION OF THE MOLECULAR WEIGHT

OF SOME BINARY MIXTURES AND PETROLEUM LIQUIDS.
Penulis : Isehunwa, SO
Tahun : 2007
Nama Jurnal : Canadian Journal of Pure and Applied Sciences
Volume/ Nomor/ Halaman : Vol. 7, No. 1, pp. 2271-2275
Abstrak :
Accurate molecular weights of pure compounds are available and can be readily
obtained in the literature. However, those of binary and multi-component mixtures
are not readily available and are usually obtained from pure components by applying
mixing rules, which may not be very accurate. The molecular weights of n-
Nonane+n-Tetradecane, n-Hexane+n-Nonane, n-Hexane+Toluene, Toluene+n-
Tetradecane and some petroleum liquids were experimentally determined using a
cryoscope. The results were compared with estimates from Kay’s mixing rule and the
observed deviations used to modify Kay’s equation in order to obtain an improved
mixing rule for the molecular weight of binary mixtures. A simple relation was also
established for predicting molecular weight of petroleum liquids from API gravity.
The average absolute deviation (AAD) of 0.04 and 0.40 for the molecular weight of
heavy and light petroleum liquids respectively represents an improvement over most
of the existing correlations.
 DESAIN SISTEM PROTEKSI KATODIK ANODA KORBAN PADA
JARINGAN PIPA PERTAMINA UPms V

Penulis : Iswahyudi
Tahun : 2007
Nama Jurnal : jurnal kimia
Volume/ Nomor/ Halaman : -
Abstrak :
Sistem proteksi katodik anoda korban adalah salah satu metode untuk
mencegah serangan korosi dengan mengkorosikan logam anoda pada sel galvani.
Logam yang diproteksi diatur agar berperan sebagai katoda dalam suatu sel korosi
dan pasangan yang ditempelkan adalah logam lain yang memiliki potensial elektrode
yang lebih negatif sehingga berperan sebagai anoda.
Proses perancangan sistem proteksi mengacu pada NACE standard RP169-
2002 “Control Of External Corrosion For Underground or submerged Metallic Piping
System”. Langkah yang paling pertama adalah mengukur resistivitas tanah dengan
metode Wenner kemudian dilanjutkan perancangan sesuai dengan ketentuan NACE
standard.

Tomographic imaging of molecular

Orbitals

Penulis : D. M. Villeneuve
Tahun : 2004
Nama Jurnal : nature
Volume/ Nomor/ Halaman : vol 432
Abstrak :
Single-electron wavefunctions, or orbitals, are the mathematical constructs used to
describe the multi-electron wavefunction of molecules. Because the highest-lying
orbitals are responsible for chemical properties, they are of particular interest. To
observe these orbitals change as bonds are formed and broken is to observe the
essence of chemistry. Yet single orbitals are difficult to observe experimentally, and
until now, this has been impossible on the timescale of chemical reactions. Here we
demonstrate that the full three-dimensional structure of a single orbital can be imaged
by a seemingly unlikely technique, using high harmonics generated from intense
femtosecond laser pulses focused on aligned molecules. Applying this approach to a
series of molecular alignments, we accomplish a tomographic reconstruction of the
highest occupied molecular orbital of N2. The method also allows us to follow the
attosecond dynamics of an electron wave packet.
 ADSORPSI METHYLEN BLUE DENGAN ABU DASAR PT.IPMOMI
PROBOLINGGO JAWA TIMUR DAN ZEOLIT BERKARBON

Penulis : Intan Permata Sari

Tahun : 2009
Nama Jurnal : Prosiding Skripsi Semester Gasal
Volume/ Nomor/ Halaman : -
Abstrak :

Penelitian ini mempelajari tentang kapasitas adsorpsi dari abu dasar dan zeolit
berkarbon. Uji adsorpsi dilakukan dengan cara penentuan waktu setimbang,
penentuan konsentrasi awal, dan pH optimum. Dari data hasil penelitian didapatkan
pada abu dasar memiliki waktu setimbang 720 menit sedangkan zeolit berkarbon 180
menit. Data hasil penentuan konsentrasi awal diketahui bahwa semakin menigkat
konsentrasi methylen blue maka semakin meningkat kapasitas adsorpsinya. pH
efektif untuk adsworpsi methylen blue pada pH2. Uji kinetik abu dasr dan zeolit
berkarbon mengikuti model orde dua semu, sedangkan uji isoterm mengikuti model
langmuir dan tempkin.