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Atomic No.: H=1, He=2, Li=3, Be=4, B=5, C=6, N=7, O=8, F=9, Na=11, Mg=12, Al = 13, Si = 14,
P = 15, S = 16, Cl = 17, Ar =18, K=19, Ca=20,Cr=24, Mn=25, Fe=26, Co=27, Ni=28, Cu=29, Zn=30,
As=33, Br = 35, Ag = 47, Si = 21, Sn = 50, Ti = 22,I = 53, Xe = 54, Ba = 56, Pb = 82, U = 92, V = 50.
Atomic masses: H =1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16, F=19, Na=23, Mg=24, Al=27,
Si=28, P=31, S=32, Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59, Ni=58.7, Cu=63.5,
Zn = 65.4, As = 75, Br = 80, Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137, Pb = 207, U = 238.
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Useful Data
PHYSICS
CHEMISTRY
Atomic No.: H=1, He=2, Li=3, Be=4, B=5, C=6, N=7, O=8, F=9, Na=11, Mg=12, Al = 13,
Si = 14, P = 15, S = 16, Cl = 17, Ar =18, K=19, Ca=20,Cr=24, Mn=25, Fe=26, Co=27,
Ni=28, Cu=29, Zn=30, As=33, Br = 35, Ag = 47, Si = 21, Sn = 50, Ti = 22,I = 53, Xe = 54,
Ba = 56, Pb = 82, U = 92, V = 50.
Atomic masses: H =1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16, F=19, Na=23,
Mg=24, Al=27, Si=28, P=31, S=32, Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn = 65.4, As = 75, Br = 80, Ag = 108, Sn = 118.7, I = 127, Xe = 131,
Ba = 137, Pb = 207, U = 238.
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Ph y s i c s
PART – A
Straight Objective Type
This part contains 30 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.
1. A uniform circular disc of radius r oscillates about a horizontal axis which lies in plane of
disc. Find the perpendicular distance of axis from centre for the time period to be maximum.
(A) r/2 (B) r/4 (C) 3r/4 (D) 3r/8
π
2. The equation of a standing wave is given as y = 0.02 sin + 50πt cos (10πx ) where x and
2
y are in metres and t is in seconds. Choose the incorrect statement:
(A) The wavelength of wave is 0.2m
(B) Displacement node occurs at x = 0.15m
(C) Displacement antinode occurs at x = 0.3m
(D) The speed of constituent waves is 0.2 m/s
4. A black body emits radiation at the rate P when its temperature is T. At this temperature the
wavelength at which radiation has maximum intensity is λo. If at another temperature T’, the
power radiated is P’ and wavelength at maximum intensity is λo/2 then:
(A) P’T’=32 PT (B) P’T’=16 PT (C) P’T’=8 PT (D) P’T’=4 PT
5. A source emits sound of frequency 1000 Hz in air. If this sound wave is incident on a water
surface, it gets partially reflected back and partially refracted (transmitted) in water.
Difference in wavelength transmitted and wavelength reflected will be (speed of sound in
air = 330 m/s, Bulk modulus of water = 2.25x109, ρwater = 1000 kg/m3):
(A) 0.8 m (B) 1.17 m (C) 1.8 m (D) 2.21 m
6. A ideal monoatomic gas initially occupies volume V and pressure P. Now the gas undergoes
a process in which pressure of the gas is proportional to its volume. It is found that the rms
speed of the gas molecule gets doubled after the process. Heat supplied to the gas in the
above said process is:
(A) 4PV (B) 6PV (C) 8 PV (D) 10 PV
Space For Rough Work
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8. A small body of super dense material, whose mass is twice the mass of the earth but whose
size is very small compared to the size of the earth, starts from rest at a height H<<R above
the earth’s surface, and reaches the earth’s surface in time t. Then t is equal to:
[g = acceleration due to gravity near earth surface]
2H H 2H 4H
(A) (B) (C) (D)
g g 3g 3g
9. A system consists three particles, each of mass M lying on the corners of an equilateral
triangle of side 2ℓ. If the length of each side of the triangle is decreased to ℓ, without the gain
in kinetic energy of the particles, the work done by an external agent is given by:
3GM2 3GM 3GM2
(A) − (B) − (C) (D) None of these
2ℓ 2ℓ ℓ
10. A vessel contains a mixture of one mole of oxygen and two moles of nitrogen at 300 K. Then
the ratio of average rotational kinetic energies per O2 molecule to per N2 molecule is:
(A) 1 (B) 7 (C) 7/8 (D) 8/7
11. Three masses 700gm, 500gm and 400gm are suspended at the end of a
massless spring as shown, when 700 gm is removed system oscillates with a
period 3sec. What will be its period when 500gm is also removed?
(A) 1 sec
(B) 2 sec 700 gm
(C) 3 sec
500 gm
12
(D) sec 400 gm
5
12. An open pipe of length 47cm has fundamental frequency 340 Hz. What is the diameter of
the tube if velocity of sound in air is 340 m/sec?
(A) 2 cm (B) 5 cm (C) 8 cm (D) 10 cm
Space For Rough Work
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(D) P0 V0
V
V0 2V0 3V0
14. A body of mass m is situated in a potential field Ux = U0 (1 − cosαx) when U0 and α are
constants. The time period of small oscillations of the mass is:
m m 2m 3m
(A) π (B) 2π (C) 2π (D) 2π
uo α 2
uo α 2
uo α 2
uo α 2
(A) (B)
B B
ρ ρ
U U
A C
(C) (D)
B C B A
ρ ρ
(A) ∆U1 > ∆U2 > ∆U3 (B) ∆U1 < ∆U2 < ∆U3 3
(C) ∆U2 < ∆U1 < ∆U3 (D) ∆U2 > ∆U1 > ∆U3 V0 2V0
V
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18. Two particles P and Q describe SHM of same amplitude ‘A’ and angular frequency ω, along
the same straight line. The maximum distance between the two particles is 2 A. The initial
phase difference between the particles is:
π π 2π
(A) (B) (C) (D) π
4 2 3
19. The velocity of waves in a string fixed at both ends is 2 m/s. The string forms standing waves
with nodes 5.0 cm apart. The frequency of vibration of the string (In Hz) is:
(A) 40 (B) 30 (C) 20 (D) 10
20. A closed gas cylinder is divided into two parts by a piston held tight. The pressure and
volume of gas in two parts respectively are (P, 5V) and (10P, V). If now the piston is left free
and the system undergoes isothermal process, then the volume of the gas in two parts
respectively are:
(A) 2V, 4V (B) 3V, 3V (C) 5V, V (D) 4V, 2V
21. In a room where temperature is 30oC a body cools from 61oC to 59oC is 4 minutes. The time
taken by the body to cool from 51oC to 49oC will be:
(A) 4 minutes (B) 6 minutes (C) 5 minutes (D) 8 minutes
22. One train is approaching an observer at rest and another train is receding from him with
same velocity 4 m/s. Both the trains blow whistles of same frequency of 243 Hz. The beat
frequency (In Hz) as heard by the observer is (speed of sound in air = 320 m/s):
(A) 10 (B) 6 (C) 4 (D) 1
23. A vehicle is moving on a circular path of radius R with constant speed gR. A simple
pendulum of length λ hangs from the ceiling of the vehicle. The time period of oscillations of
the pendulum in a vertical plane containing centre of circular path is:
ℓ ℓ 2ℓ
(A) 2π (B) 2π (C) 2π (D) none of these
g 2g g
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24. A standing wave having three antinodes and four nodes is formed between two atoms
having a distance of 2A° between them. The wavelength of the standing wave is:
(A) 1.33A° (B) 6 A° (C) 1.4 A° (D) 8 A°
25. If a tunnel is dug along the diameter of the earth and a body is dropped into it, them the time
taken by it to cross the tunnel once is (R = radius of earth)
R R g g
(A) 2π (B) π (C) 2π (D) π
g g R R
26. Two rods of length l1 and l2 are made of materials whose coefficients of linear expansion
are α1 and α 2 . If the difference between two lengths is independent of temperature then:
l1 α l1 α α12 α2
(A) = 1 (B) = 2 (B) l22 α1 = l12 α 2 (D) = 2
l2 α2 l2 α1 l1 l2
27. An ideal gas has molar heat capacity Cv at constant volume. The gas undergo the process
T = T0 (1 – αV) where α, T0 is constant and V is volume. Then molar heat capacity of the gas is:
R R
(A) Cv + (1 − αV) (B) Cv − (1 − αV)
αV αV
R R
(C) Cv − (1 + αV) (D) Cv + (1 + αV)
2αV 2αV
29. If the intensity of sound is doubled, by how many decibels (in dB) does the sound level
increase?
(A) 2 (B) 3 (C) 4 (D) 6
30. The fractional change in the value of free-fall acceleration ‘g’ for a particle when it is lifted
from the surface to an elevation h (h<<R) is:
(A) h/R (B) −(2h/R) (C) 2h/R (D) none of these
Space For Rough Work
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Chemistry
PART – B
Straight Objective Type
This part contains 30 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONLY ONE is correct.
1. Which of the following dienes is expected to have least value of enthalpy of hydrogenation?
H2C
CH2 CH2
(A) H2C CH2 (B) (C)) H2C (D) H2C C CH2
CH3
2. 2+
O 2N C C CH3 Hg
dil.H2SO4
→ P, P is :
CH3
O O
CH3 O
O CH3
3. What will the correct product (A) and (B) respectively of the following reaction?
R
H2 ( 1 eq.)
Ni (200°-300°)
→A
Br2 (1 eq)
(B)
R R R H
H R
R H
H H
R H R R
(A) Br
(B) Br
(C) Br (D) Br
, Br
, , ,
Br Br Br
4. Which of the following will be the correct product (P) of the reaction?
H3C CH2
NBS
→P ?
Br
Br H 3C CH2 Br
(A) H3 C (B) (C) (D) CH2
Br H 3C CH2
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CH3 CH2
(A) H3C (B) H3C O CH3 (C) O CH3 (D) H3C
CH3
NO2
CH3 NO2
(I) (II) (III) (IV)
(A) III > IV > I > II (B) I > IV > III > II
(C) II > I > III > IV (D) IV > III > I > II
10.
+
H2N CH3
NO2
→(A). (A)(major product) is
CH3
CH3
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11. Number of meso forms and optically active forms possible in the following structure is:
CH3 (CHOH)2 CO2H
(A) 2, 0 (B) 0, 4 (C) 0, 2 (D) 0, 0
H N
(A) (B) (C) N (D)
H 3C CH3
(A) (B) (C) (D)
H3 C CH3
CH3
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17. Rank the hydrogen atoms (Ha, Hb, Hc) in the following molecule according to their acidic
strength
Ha O O
H2C
CH3
Hb H Hc
H
(A) a > b > c (B) b > a > c (C) b > c > a (D) c > b > a
H
H shows:
18. The structure
H3C
COOH
(A) geometrical isomerism (B) optical isomerism
(C) geometrical & optical isomerism (D) tautomerism
(C) (D)
Cl CH3 Cl CH3
CH3 CH3
Cl Cl
OH +
H
H3C
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B , H3C
(D)
H3C CH3
3
Cu Cl
25. CH2=CH−C≡CH + HCl
2 2 → ' X ' . ‘X’ is
major
H2C H3C H3C CH2
Cl
(A) CH2 (B) CH (C) (D)
CH
Cl Cl Cl Cl
26. A hydrocarbon of formula C6H10 absorbs only one molecule of H2 upon catalytic
hydrogenation. Upon ozonolysis, the hydrocarbon yields a compound of the following
structure,
O
H
H
O
The hydrocarbon is:
(A) cyclohexane (B) cyclohexyne (C) cyclohexene (D) cyclobutane
Space For Rough Work
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27. An organic compound decolourises Br2 in CCl4 and can be reduced catalytically. Also, it
gives a precipitate with ammonical cuprous chloride. The compound will be:
CH3
|
(A) CH3−CH=CH−CH3 (B) CH3CH2C≡CH (C) CH3−C≡C−CH3 (D) CH3 − C = CH2
28. CH3 CH
3
HBr
→ Major product :
CH2
CH3 CH3
CH3 CH Br CH CH3
3 3
(A) (B) (C) Br (D) Br
Br CH3 CH3
CH3
NBS
CCl 4
→
Br CH3
Br CH3
CH3 Br
(A) (B) (C) (D)
Br
30. H3C
CH2
HOCl
→ major product
H3C
H3C
H3C H 3C H3C
OH
(A) H3C (B) Cl (C) Cl (D) OH
Cl H3C H 3C H3C
OH H H
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Mathematics
PART – C
Straight Objective Type
This part contains 30 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.
1. Total number of integers n such that 2 ≤ n ≤ 2000 and H.C.F. of n and 36 is one, is equal to:
(A) 666 (B) 667 (C) 665 (D) none of these
2. ‘n’ is selected from the set {1,2,3,….,100} and the number 2n + 3n + 5n is formed. Total
number of ways of selecting n so that the formed number is divisible by 4, is equal to:
(A) 50 (B) 49 (C) 48 (D) none of these
3. In a plane there are 37 straight lines, of which 13 pass through the point A and 11 pass
through the point B. Besides, no three lines pass through one point, no line passes through
both points A and B, and no two are parallel. Then the number of intersection points the
lines have is equal to:
(A) 535 (B) 601 (C) 728 (D) 963
4. Seven different lecturers are to deliver lectures in seven periods of a class on a particular
day. A, B and C are three of the lectures. The number of ways in which a routine for the
day can be made such that A delivers his lecture before B and B before C, is :
(A) 210 (B) 420 (C) 840 (D) none of these
n
2r + 2 ⋅ n Cr
5. ∑r = 0 (r + 1)(r + 2)
is equal to:
7. The sum 10
C3 + 11C3 + 12 C3 + ..... + 20
C3 is equal to
(A) 21
C4 (B) 21
C4 + C4
10
(C) 21
C17 − 10 C6 (D) none of these
8. The number of terms free from radical sign in the expansion of (1+31/3+71/7)10 is
(A) 1 (B) 6 (C) 11 (D) none of these
Space For Rough Work
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1 1 1 2a
9. If x=2+5i (where i2=−1) and 2 + + = , then the value of (x3−5x2+33x−19) is
1!9! 3!7! 5!5! b!
equal to:
(A) a (B) b (C) a−b (D) a+b
10. If |z−25i| ≤ 15, then |maximum arg (z) − minimum arg(z) equals:
π
(A) 2 cos−1(3/5) (B) 2 cos−1(4/5) (C) + cos−1(3 / 5) (D) sin−1(3/5)−cos−1(3/5)
2
1+ z
12. If |z| = 1, then equals:
1+ z
(A) z (B) z (C) z −1 (D) none of these
13. If |z−i|≤2 and z1 = 5 + 3i, (where i = −1) , then the maximum value of |iz+z1| is:
(A) 2 + 31 (B) 7 (C) 31 − 2 (D) 31 + 2
n
−1 2r −1
14. ∑ tan 2r −1
is equal to
r =1 1+ 2
π π
(A) tan−1(2n ) (B) tan−1(2n ) − (C) tan−1(2n+1 ) (D) tan−1(2n+1 ) −
4 4
π
15. If cot−1x+cot−1y+cot−1z= , then x+y+z is also equal to:
2
1 1 1
(A) + + (B) xyz (C) xy+yz+zx (D) none of these
x y z
π 1
16. The value of cos + cos−1 − is equal to:
6 2
3 3 1 1
(A) (B) − (C) (D) −
2 2 2 2
Space For Rough Work
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2x
17. Range of tan−1 2
is:
1+ x
π π π π π π π π
(A) − , (B) − , (C) − , (D) ,
4 4 2 2 2 4 4 2
18. The number of values of x in the interval [0, 5π] satisfying the equation
3 cos 2x − 10 cos x + 7 = 0 is
(A) 5 (B) 6 (C) 8 (D) 10
π π 1
19. The sum of all the solution of the equation cos x ⋅ cos + x ⋅ cos − x = , x ∈ [0,6π] is:
3 3 4
110 π
(A) 15π (B) 30π (C) (D) none of these
3
π
21. If in triangle ABC, ∠A = , then the value of r+2R is equal to:
2
1 1 1 1
(A) (a + b − c) (B) (b + c − a) (C) (a + c − b) (D) (a + b + c)
2 2 2 2
r 1 A B C
22. If in triangle ABC, = , then the value of tan tan + tan is equal to:
r1 2 2 2 2
1
(A) 2 (B) (C) 1 (D) none of these
2
A B
24. In a ∆ABC, tan and tan satisfy 6x2−5x+1=0. Then:
2 2
2 2
(A) a + b > c 2
(B) a2 − b2 = c2 (C) a2 + b2 = c2 (D) none of these
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26. The arithmetic mean of a set of observation is X . If each observation is divided by α and
then is increased by 10, then the mean of the new series is
X X + 10 X + 10α
(A) (B) (C) (D) αX + 10
α α α
27. Standard Deviation of a data is 7, when each observation is decreased by 7 then standard
deviation of new data is
(A) 0 (B) 14 (C) 7 (D) 49
28. The elevation of a tower at a station A due north of it is α and at a station B due west of A
is β. Then the height of the tower is
AB sin α.sin β AB sin α.sin β AB cos α.sin β AB cos α.cos β
(A) (B) (C) (D)
sin α − sin β
2 2
sin α + sin β
2 2
sin α + sin β
2 2
sin2 α + sin2 β
29. Two ships are sailing in the sea on the two sides of a lighthouse. The angle of elevation of
the top of the lighthouse is observed from the ships are 30º and 45º respectively. If the
lighthouse is 100 m high, the distance between the two ships is:
(A) 173 m (B) 200 m (C) 273 m (D) 300 m
30. The number of ways of arranging n boys (B1, B2, ….Bn) and n girls (G1, G2,…..Gn) around a
circle such that boys and girls should sit alternatively and B1 and G1 are not together is
(A) (n−1)!(n−2)! (B) (n−1)!(n−2)!(n2+n+2)
(C) (n−1)!(n−2)!(n2+2) (D) (n−1)!(n−2)!(n2−3n+2)
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2. D P112211
2π
K= ⇒ λ = 0.2
λ
2n + 1 π
For node 10πx = ⇒ n = 1, x = 0.15 m
2 2
For antinode 10 πx = nπ
For n = 3, x = 0.3 m
3. C P111102
1
U = Fx
2
4. A P112333
P = σAT 4 , T ' = 2T, P'=σA(2T)4
5. B P112218
330 1500
λa = m ⇒ λω = m
1000 1000
6. B P111209
Pf = 2P, Vf = 2V, C = 2R, ∆Q = n2R∆T
7. C P111220
V V W1 T1
As B = D ⇒ =
VA VC W2 T2
8. C P110902
1 2 1 2
at + gt = H
2 2
9. A P110908
1 1
∆U = − 3GM2 −
rf ri
10. A P111215
2
KERot = kT = kT
2
11. B P111105
m 0.9 0.4 T 0.4 2
T = 2π ⇒ 3 = 2π ⇒ T = 2π ⇒ = = ⇒ T = 2 sec
k k k 3 0.9 3
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12. B P112222
Antinodes are formed at a distance 0.6r from the end of the tube, where r is radius of the
tube.
47 + 2 × .6r = λ/2
λ = v/n = 100 cm
47 + .6D = 100/2
D = 5 cm
13. C P111220
WAB = −P0 V0
WCD = +4P0 V0
WABCD = +3P0 V0
14. B P111105
−dU −d
We know that F = = (U0 − U0 cos αx )
dx dx
Or F = − U0 α sinαx ≈ − U0 α × αx
[∵ For small oscillations angular displacement is small so sinαx ≈ αx]
∴ F = − U0α2x . . . (i)
As F α x and − ve sign shows that the force F is directed towards the equilibrium position, so
if the body is left free, it will execute S.H.M.
Comparing (i) with equation, F = − ky . . . (ii)
Spring factor, k = U0α2
Inertia factor = mass of body = m
inertia factor m
As time period, T = 2π = 2π
spring factor U0 α2
15. A P111220
ρRT
U = nCvT, P =
M
In process CA, T is constant, ∴ U is constant.
U 3nM 3R
= ∵ Cv =
P 2ρ 2
Uρ = constant if P is constant
∴ Process AB will be hyperbola in U-ρ graph.
In process BC, V is constant. ∴ ρ is constant.
16. A P111220
Isothermal → ∆U2 = 0
PVC
Isobaric → ∆U1 = nCV ( 2T0 − T0 ) = nCV T0 = 0 0 V
R
Adiabatic → ∆U3 = - ∆W = negative
17. B P112225 ℓ O
Let first pulse be released at t = 0.
a v0
ℓ
Time when first pulse reaches O = t1 = u=0
v − vo
Time when second pulse reaches O =
1
ℓ + v o T − aT 2
t2 = T + 2
v − vo
vT aT 2
T′ = t2 – t1 = −
v − v o 2(v − v o )
2f 2 (v − v o )
∴ f′ =
2fv − a
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18. B P111107
Let, y1 = A sin ωt and y2 = A sin (ωt + φ)
y2 – y1 = A 2 = A sin(ωt + φ) – A sin ωt
ωt + φ + ωt ωt + φ − ωt
or 2 A = 2A cos .sin
2 2
φ φ
= 2A cos (ωt + ) sin
2 2
φ
For maximum value, cos (ωt + ) = 1
2
φ φ 1
∴ 2A sin = 2 A or sin =
2 2 2
φ π π
i.e. = or, φ = .
2 4 2
19. C P112211
λ v 2
v = 2 m/s = 5cm ⇒ λ = 10cm ⇒ f = = = f = 20 Hz
2 λ 0.1
20. A P111210
V1 1
P ' V1 = P × 5V ⇒ = & V1 + V2 = 6V
V2 2
P ' V2 = 10P × V
∴ V1 = 2V
V2 = 4V
21. B P111226
Rate of cooling α difference in temperature
dT
− α ∆θ
dt
dT
= − K∆θ
dt
dT = − K∆θ.dt
In First Case For second case
dT = 61−59=2 dT = 2
∆θ = 60 − 30 = 30 ∆θ = 50 − 30 = 20
dt = 4 minutes dT 2
∴ ∴ dt = = = 6 min.
K∆θ 1
60 x 20
dT 2 1
K =− = − = −
∆θdt 30 x 4 60
22. B P112225
320 320 320 320
fb = f2 − f1 = 243 − 243 = 243 − = 6
320 − 4 324 316 324
fb = 6
23. B P111105
mv 2
Centrifugal force FC = = mg.
R
Net force opposite to tension in equilibrium = m2 g2 + m2 g2 = 2 mg
ℓ
geff = g 2 ; T = 2π
g 2
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24. A P112213 A A A
3λ/2 = 2A°
λ = (4/3)A° = 1.33 A° N N N N
25. B P110905
R
Time period of SHM along tunnel = T = 2π
g
T
Required time =
2
26. B P111203
If change in length is ∆l
Then ∆I1 = L01 α1∆T
∆I2 = L02 α2∆T
difference in length is l2 − l1 = (L 02 + ∆l2 ) − (L 01 + ∆l1 )
=(L02 − L01) + (∆I2 − ∆I1)
L02 − L01 is independent of temperature for I2 − I1 to be independent of temperature.
∆I2 − ∆I1 must be equal to zero
i.e. L1 α1∆T = L2 α2∆T
i.e. L1 α1 = L2 α2
L1 α 2
i.e. = .
L2 α1
27. B P111207
Q = ∆U + W
P dV R
C = Cv + ⇒ C = CV − (1 − αV)
n dT αV
28. D P111105
3
k1 = k ; k 2 = 3k
2
1 9k 9
keff = k1 + k2 = = k
2π 2m 2
29. B P111301
I I
We know that β = 10 log10 ; According to the problems βA = 10log10
I0 I0
2I
βB − β A = 10log = 10 × 0.3010 = 3 dB
I
30. B P110905
GM
g= 2 . . . .(i)
R
dg −2GM
= putting dR = h we obtain
dR R3
dg −2GM 1
⇒ = . . . . (ii)
h R2 R
From (i) and (ii)
dg h
⇒ = −2 ⇒ Change is –ve. That means g decreases.
g R
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PART – B : CHEMISTRY
1. B C111707
2. C C114714
Mechanism is through carbocation stability so ketone will be formed on methyl side.
3. D C111707
4. B C111703
NBS brominates at allylic position or, allylic hydrogen.
5. B C111707
CH2
→
HBr
→
C 2H5ONa
H3C Peroxide anti M.K . addition H3C Br SN 2 H3C OC2H5
6. B C111302
Basicity is proportional to conjugate acid stability.
7. D C111301
8. A C111401
9. D C111302
Acidic strength is proportional to stability of conjugate base.
10. B C114714
11. B C111403
12. B C111301
Cyclooctatetraene existing tub shape.
13. A C111403
14. A C111403
15. C C111401
Hydrogen bond between OH & F
16. C C111302
In (C), –NMe2 group is thrown out of the plane of the aromatic ring, i.e. lone pair of electrons
on N atom are not involved in conjugation and hence most basic.
17. D C111302
Acidic strength is proportional to stability of conjugate base.
18. B C111403
19. B C111403
Enantiomers are non super imposible mirror image.
20. C C111722
Two moles for dehalogenation & one for deprotonation
21. B C111707
CH+2 CH3 CH3
22. D C111707
Due to anti addition
23. C C111707
24. C C111302
CH≡C−H + NH2 → CH≡C− + NH3
CH≡C−H + CH3− → CH≡C− + CH4
CH≡CH + Na in liq. NH3 → CH2=CH2
25. A C111707
26. C C111707
27. B C C111713
The given alkyl should be terminal.
28. C C111707
29. D CC111704
NBS brominates allylic or benzylic position.
30. B C111707
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PART – C: MATHEMATICS
1. A M111212
2. B M111216
3. A M111212
4. C M111215
5. D M111212
6. A M111212
7. C M110410
8. B M110410
9. B M110410
10. B M110303
11. A M110832
12. A M110301
13. B M110302
14. B M112501
15. B M112501
16. B M112501
17. A M112504
18. C M112208
19. B M112208
20. A M112210
21. D M113549
22. B M113549
23. C M113542
24. C M113542
25. C M113544
26. C M112301
Let x1, x2, ….., xn be n observations, then
1
X = ∑ x1
2
27. C M112304
Deviation does not changes by changing a data
28. A M111432
29. C M111432
30. D M111209
(n−1)!n!−(n−2)!(−1)! 2n−2C1 = (n−1)!(−2)! {n(n−1)−(2n−2)}
= (n−1)!(n−2)!(n2−3n+2)
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