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CHAPTER 1
Surface Phenomena:
Chapter Objectives
• Explain the surface tension and capillarity
phenomena
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Surface 3
tension
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Surface Tension,
an effect within the surface layer of a
liquid that causes that layer to behave as an
elastic sheet
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Definition of Interface
• INTERFACE is the boundary between two or more phases (solid,
liquid or gas) exist together
• Interfacial tension: the force per unit length existing at the
interface between two phases (immiscible with each other)
• When one phase is gas, the term “surface tension” is more
commonly used.
Gas
Surface tension
Liq 1
Interface
Liq 2 Interfacial tension
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Types of interface
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𝑑𝑦𝑛𝑒 𝑁 𝑁. 𝑚 𝐽
1 𝑚
=1 𝑚
=1 𝑚2
=1 𝑚2
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Example
• The surface tension at 20 °C for several alcohols is
γ (CH3O) = 22.61 dyne·cm-1, and γ (C2H5OH) = 2.275 X 10-2 N.m-1
and γ (n-C3H7OH) = 23.78 mJ.m-2
Which of these alcohols has the greatest surface tension ?
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Capillarity
Also known as capillary action
It is a result of surface or interfacial tension
The ability of a liquid to flow in narrow spaces without the
assistance of, and in opposition to, external forces like
gravity
Capillarity manifests in many ways in the everyday world.
Paper towels absorb through capillarity. When burning a
candle, the melted wax rises up the wick due to capillarity. In
biology, though blood is pumped throughout the body, it is
this process which distributes blood in the smallest blood
vessels which are called, appropriately, capillaries.
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At equilibrium:
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• Example:
• A sample of chloroform rose to a height of 3.67
cm at 20°C in a capillary tube having an inside
radius of 0.01 cm. What is the surface tension of
chloroform at this temperature? The density of
chloroform is 1.476 g/cm3.
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Problem 2
Compare the heights to which water and carbon tetrachloride
will rise as a result of capillary action in a tube with an internal
diameter of 0.1 mm. At 20C the surface tensions of water and
carbon tetrachloride, respectively, are 0.0727 and 0.0268 Nm-1,
and their densities are 0.998 and 1.595 g L-1.
(Gravity acceleration : 9.8 m/s 2 )
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V
Guggenheim-Katayama Equation:
n
T
= o 1 -
Tc
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Coefficient of Spreading
SBA is defined as the coefficient of spreading of liquid B on the
surface of A. It is defined as the difference between the work of
adhesion (work of needed to separate one liquid from another)
and work of cohesion (work needed to pull a column of pure
liquid apart).
If SBA is positive then liquid B will spread on the surface of A
(oil on water)
If SBA is negative then liquid B will remain as a drop on the
surface of A.
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Group Assignment
• Write an 10-15 pages article on application of surface
phenomena in various applications. Your article should
consist:
• Background/history of the application/device
• Explanation on how the surface phenomena applied in the
application
• Illustration in molecular level
• Recent technology/news about the application
• Advantage/Importance of the application
• Reference (were you got all the information)
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• Date of submission and presentation : on week 5 & 6.
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