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Positive Bias Temperature Instability Degradation of Buried InGaAs Channel nMOSFETs with
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Total Ionizing Dose Radiation Effects in the P-Type Polycrystalline Silicon Thin Film Transistors
Yuan Liu, Kai Liu, Rong-Sheng Chen et al.
Insulated gate and surface passivation structures for GaN-based power transistors
Zenji Yatabe, Joel T Asubar and Tamotsu Hashizume
Reliability study on positive bias temperature instability in SiC MOSFETs by fast drain current
measurement
Takuma Okunishi, Kenichi Hisada, Hisashi Toyoda et al.
1
Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics,
Chinese Academy of Sciences, Beijing 100029
2
High-Frequency High-Voltage Device and Integrated Circuits R&D Center, Institute of Microelectronics,
Chinese Academy of Sciences, Beijing 100029
3
Guangxi Experiment Center of Information Science, Guilin University of Electronic Technology, Guilin 541004
4
Microsystem and Terahertz Research Center, China Academy of Engineering Physics, Chengdu 610200
Continuous Si complementary metal-oxide- MOSFET has been proved by Franco et al., showing
semiconductor (CMOS) scaling and performance im- poor reliability when compared with Si-MOSFET, in
provements meet a great challenge. To maintain line with GeO𝑥 /high-𝑘 nMOS.[7] For surface channel
Moore’s law, great efforts have been devoted to al- InGaAs MOSFETs, the positive bias temperature in-
ternative channel materials beyond Si, such as ger- stability (PBTI) relaxation behavior does not obey the
manium, and InGaAs.[1−3] One promising solution single-log(t) trend, suggesting multiple defect types
is to integrate InGaAs channels for NMOS and Ge in Al2 O3 /InGaAs stacks.[7] Moreover, surface channel
channels for PMOS for CMOS applications. Recently, InGaAs MOSFETs under positive bias temperature
Ge thin films with high quality have been successfully instability (PBTI) stress and recovery have been sys-
integrated on lattice matched GaAs substrates,[4] and tematically investigated by Li et al.,[8] and they have
high performance Ge PMOS using HfO2 /Al2 O3 /GeO𝑥 revealed that there are high densities of fast interface
gate stack has been reported.[3] However, compared traps and slow oxide border traps near the interface
with Ge channel devices, InGaAs channel metal-oxide- between InGaAs and Al2 O3 . The border traps are
semiconductor field-effect transistors (MOSFETs) still more fragile under stress, and therefore the stress
need further study. The main obstacle for InGaAs mainly induces border traps.
MOSFETs is the lack of high-quality thermodynami- Compared with surface channel InGaAs MOS-
cally stable gate dielectrics. Recently, surface chan- FETs, InGaAs channel MOSFETs with a barrier layer
nel InGaAs MOSFETs with atomic layer deposited are obtained and have renewed attention for n-type de-
(ALD) Al2 O3 ,[2] HfO2 ,[5] ZrO2 [6] have demonstrated vices because a barrier layer helps to move the InGaAs
improved interface passivation and stability, while channel away from the high-𝑘 oxide interface, the-
the effective channel mobility is still relatively low refore higher electron mobility can be achieved.[9,10]
compared with that of the bulk InGaAs due to the Moreover, by selecting the barrier layer material, it
high defect density between the InGaAs channel and is able to obtain a high quality gate stack with low
the high-𝑘 gate dielectric, which may cause a se- interface trap density 𝐷it and border traps. For ex-
vere reliability problem. The surface channel InGaAs ample, our previous research has demonstrated very
* Supported by the National Science and Technology Major Project of China under Grant No 2011ZX02708-003, the National
Natural Science Foundation of China under Grant No 61504165, and the Opening Project of Key Laboratory of Microelectronics
Devices and Integrated Technology of Institute of Microelectronics of Chinese Academy of Sciences.
** Corresponding author. Email: liuhonggang@ime.ac.cn
057301-1
CHIN. PHYS. LETT. Vol. 34, No. 5 (2017) 057301
low 𝐷it in the level of 2 × 1011 cm−2 eV−1 and very HP 4284 LCR and Keysight B1500A meters, as
small accumulation capacitance frequency dispersion well as Lakeshore probe station, were used for the
in an Al2 O3 /InP stack by carefully tuning the ther- capacitance-voltage (𝐶 –𝑉 ) and current-voltage (𝐼 –𝑉 )
mal treatment and pre-dielectric surface passivation measurements, at room temperature. In the 𝐶 –𝑉 me-
process.[11] Although high performance is expected in asurements, split 𝐶 –𝑉 curves were measured by con-
buried channel InGaAs MOSFETs, its reliability rese- necting the source and drain for low terminal, the gate
arch is still in the infant stage, few reports have been for high terminal, and grounding the substrate. In
published for the buried channel case. Therefore, to the 𝐼d –𝑉g measurements, 𝑉d is set to 50 mV, while the
understand the reliability of buried channel InGaAs source and the substrate are grounded. During the
NMOSFETs, in this work, we investigate the degra- PBTI stress phase, the gate stress voltage is set as
dation under PBTI stress and recovery behavior by 𝑉g = 1–5 V, while 𝑉s = 𝑉d = 𝑉b = 0 V. During the
experiments and physical interpretations. recovery phase, all the electrodes are grounded. For
the fresh transistors used in this work, the threshold
(b)
(a)
NiGeAu
Ni/Au Gate
NiGeAu voltage 𝑉th is in the range of +0.3–+0.4 V. The sub-
DEc=2.9 eV
InGaAs(10nm) InGaAs(10nm)
EV
Ec threshold swing (𝑆 -factor) is around 145 mV/decade.
GaAs(50nm) Al2O3(8nm) GaAs(50nm) DEc=0.4 eV
AlGaAs
All the above measurements were performed at room
In0.49Ga0.51P Barrier layer (5nm)
i-In0.4Ga0.6As Channel (7nm)
AuNi
temperature (300 K).
DEc=0.7 eV EF
Si-planar doping
Al0.26Ga0.74As (300 nm) 160 (a) Surface channel (b) Buried channel
InGaAs Near interface Al2O3/InGaP/InGaAs
Al2O3/InGaAs
SI-GaAs (100) substrate traps 140
Al2O3 InGaP
Capacitance (pF)
120
Fig. 1. (a) Cross-sectional schematic structure of the pla- 1 kHz
100
nar buried channel In0.4 Ga0.6 As n-MOSFET with 5 nm
In0.49 Ga0.51 P barrier layer and 8-nm-Al2 O3 dielectric, 80 1 kHz
-0.5 0.0 0.5 1.0 1.5 2.0 0.0 0.5 1.0 1.5 2.0
ture was grown on a semi-insulating GaAs substrate
(V) (V)
by metal-organic chemical vapor deposition (MO- gs gs
CVD) and consisted of a 300 nm Al0.26 Ga0.74 As buf- Fig. 2.Split 𝐶 –𝑉 characteristics of (a) surface channel
fer layer (with Si planar doping at 3 nm below the In- InGaAs nMOSFETs and (b) buried channel InGaAs MOS-
FETs with the In0.49 Ga0.51 P barrier layer.
GaAs channel), a 7 nm In0.4 Ga0.6 As strained quantum
well channel layer, a 5 nm In0.49 Ga0.51 P barrier layer, Figures 2 illustrates the multi-frequency split 𝐶 –
and an n+ contact layer including a 50 nm GaAs cap 𝑉 curves at room temperature for the surface chan-
layer and a 10 nm In0.54 Ga0.46 As cap layer. The sheet nel InGaAs MOSFET and the buried channel InGaAs
resistance was 100 Ω/sq, and the room-temperature MOSFET with an InGaP barrier layer. For the sur-
Hall mobility was larger than 8000 cm2 /(V·s). The face channel case, huge capacitance frequency disper-
n+ contact layer was selectively removed by phosp- sion is observed, especially in the on-state region. The
hate acid solution (H3 PO4 :H2 O2 :H2 O=3:1:50). The origin of the capacitance frequency dispersion in the
In0.49 Ga0.51 P barrier layer was removed by hydro- on-state region is ascribed to the large amount of ox-
chloric acid solution (HCl:H3 PO4 =1:4). After a re- ide border traps. Compared with the surface channel
cess, the wafers were pretreated by diluted hydrochlo- MOSFET, the buried channel one shows much im-
ric acid solution and ammonia-based solution. Then, proved 𝐶 –𝑉 characteristics with significantly less fre-
8 nm Al2 O3 was deposited by ALD as the gate dielec- quency dispersion near 𝑉th and at on-state, indicating
tric. The Ni/Au gate metal, Ni/Ge/Au/Ge/Ni/Au that the insertion of an InGaP barrier layer is effective
source, and drain Ohmic contacts were then depo- in reducing the interface and border traps. Note that
sited by e-beam evaporation, respectively, after se- quantitative evaluation of the 𝐷it profile is impossi-
lectively etching Al2 O3 using a buffered oxide etch bly present, because it is difficult to accurately sub-
(BOE). Finally, a rapid thermal annealing (RTA) pro- tract the coupling capacitance from the substrate and
cess at 270∘C for 3 min in an N2 ambient was carried source/drain sides from the structure in Fig. 1(a).
out. The sheet resistance and the contact resistance According to the investigation by Li et al.,[8] the
of the source and drain regions were determined to be reductions of interface and border traps are benefi-
only 100 Ω/sq and 0.1 Ω·mm, respectively. Figure 1(b) cial to device reliability. Therefore, dc 𝐼d –𝑉g measu-
shows the energy band diagram for In0.4 Ga0.6 As chan- rements were performed under PBTI stress. Figure
nel MOSFETs with an In0.49 Ga0.51 P barrier layer. 3 shows the dc 𝐼d –𝑉g curves measured for the fresh
057301-2
CHIN. PHYS. LETT. Vol. 34, No. 5 (2017) 057301
device before stress (initial state, I lines), after 500 s the 𝑆 -factor is found to degrade from 145 mV/dec to
PBTI stress (S lines), and with additional 500 s reco- 184 mV/dec after +5 V stress for 10 s and shows a po-
very (R lines). Comparing S lines with I lines, the 𝑉g sitive ∆𝑉g , implying the degradation of interface with
shift ∆𝑉g at constant current 𝐼d is positive in both interface net acceptor trap generation. Since stress
the sub-threshold region and at high 𝐼d in the on- induced donor traps may also exist, the stress indu-
current region, indicating that net negative charge is ced acceptor traps are dominant when compared with
created after the PBTI stress. Compared with S lines, donor traps, and we are not able to distinguish the
R lines demonstrate a negative shift at high 𝐼d in the donor traps from acceptor traps at present, thus we
on-current region, indicating that recovery happens. use the ‘net’ acceptor trap here. This is different from
Compared with I lines, R lines demonstrate a positive the results of surface channel InGaAs MOSFETs. Mo-
shift, indicating that the stress induced traps are not reover, in Fig. 4(b), the 𝐼d –𝑉g curves at on-state shift
fully recoverable. Moreover, the results in Fig. 3 show positively, indicating that the oxide traps are gradu-
a permanent degradation in 𝑆 factor, suggesting that ally filled by electron injection in terms of forming
the stress induced interfacial traps are dominated by negative charge.
permanent traps. Therefore, on the basis of the re-
sults in Fig. 3, it is possible for us to conclude that 10
-4 (a)
1.0
(b)
permanent and recoverable traps coexist. 10
-5 145 mV/dec
Fresh
0.8
1 V, 10 s
-6
A)
10 2 V, 10 s
-4
10 I 3 V, 10 s
0.6
(A)
-7
R 10 4 V, 10 s
-4
2.0 184 mV/dec
-5 5 V, 10 s
(10
10 S -8
10
d
Fresh 0.4
-9
d
10
-6
1.5 10 1 V, 10 s
Fresh
A)
-10
2 V, 10 s
(A)
Stress I 10 3 V, 10 s 0.2
-7
-4
10 Recovery -11 4 V, 10 s
10
(10
1.0 5 V, 10 s
d
-8 0.0
10 -0.4 0.0 0.4 0.8 -0.8-0.4 0.0 0.4 0.8
d
R (V) (V)
-9 g g
10 0.5
10
-10 S Fig. 4. The 𝐼d –𝑉g curves for the fresh InGaAs n-
MOSFET, after 10 s PBTI stress (𝑉g = 1–5 V), 𝑉d =
0.0
-0.4 0.0 0.4 0.8 -0.4 0.0 0.4 0.8 50 mV. Comparing S lines with I lines, the 𝑉g shift Δ𝑉g
g
(V) g
(V) at constant current 𝐼d is positive (a) in the sub-threshold
region and (b) at high 𝐼d in the on-current region.
Fig. 3. The 𝐼d –𝑉g curves for the fresh buried channel In-
GaAs n-MOSFET (denoted by I lines), after 500 s PBTI 1.2
stress (𝑉g = 5.0 V) (denoted by S lines), and then af- 10
-4 (a) (b)
(10
0.6
current region. 10
-7
d
cording to the simulation results by Varghese et al.,[12] Fig. 5. The 𝐼d –𝑉g curves for the fresh InGaAs n-
donor traps at the interface induce negative 𝑉g shift of MOSFET, after 10–500 s PBTI stress (𝑉g = 5 V), 𝑉d =
the 𝐼 –𝑉 curves, and larger shift with lower 𝐼d current 50 mV (a) in the sub-threshold region, and (b) at high 𝐼d
level. Acceptor traps at the interface induce positive in the on-current region. The degradation of interface is
attributed to the interface net acceptor trap generation.
shift of the 𝐼 –𝑉 curves, larger shift with higher 𝐼d
current level. Concerning the different trends in the Figure 5 shows the 𝐼d –𝑉g curves for the fresh In-
sub-threshold region, we infer that the InGaP/Al2 O3 GaAs nMOSFETs, and the ones after 10–500 s PBTI
may contain less donor traps than the InGaAs/Al2 O3 stress (𝑉g = 5 V). In the sub-threshold region, the 𝑆
interface, which is reasonably consistent with the split factor degrades and becomes saturated even after 10 s
𝐶 –𝑉 characteristics in Fig. 2. stress. However, in the on-current region, degradation
To further understand the PBTI degradation in occurs gradually until 500 s stressing, indicating that
the sub-threshold region, PBTI stress in the range of the 𝑆 factor and on-current (transconductance 𝐺m or
𝑉g = 1–5 V is applied for 10 s to the buried channel high-field mobility) degradation come from different
InGaAs nMOSFETs, as shown in Fig. 4. In Fig. 4(a), sources. To further probe the traps behavior, NBTI
057301-3
CHIN. PHYS. LETT. Vol. 34, No. 5 (2017) 057301
-6 3
10
bias 𝑉g , as shown in Fig. 7. Compared with the density
(A)
-5
-7
10
of border traps in the surface channel InGaAs case,
(10
-8 2 Fresh
10
d
-3 V, 300 s
-9 permanent acceptor traps with similar magnitude in
d
10 R 1200 s
Fresh
10
-10
-3 V, 300 s
1 the order of 1 × 1012 cm−2 have been obtained in our
10
-11 R 1200 s
buried channel device while the density and type of
0
-0.4 0.0 0.4 0.8 -0.4 0.0 0.4 0.8 recoverable traps are quite different. In buried chan-
g
(V) g
(V) nel InGaAs MOSFETs, recoverable traps induced by
Fig. 6. The 𝐼d –𝑉g curves for the fresh InGaAs n-
PBTI stress are mainly acceptor traps and with the
MOSFET, after 300 s NBTI stress (𝑉g = −3 V), and re- maximal density level below 4 × 1011 cm−2 , while the
covery curve 𝑉d = 50 mV (a) in the sub-threshold region, recoverable traps induced by PBTI stress for the sur-
and (b) at high 𝐼d in the on-current region. face channel case are dominated by donor traps with
By using the similar method proposed by Li et al., the maximal density level of 1.5 × 1011 cm−2 .
the distribution of stress induced border traps could
be estimated from ∆𝑉g among the I lines, S lines and 28
R lines under the assumptions of (1) during PBTI Total net acceptor traps
)
24
-2
20
induced donor traps and acceptor traps in the devi- D AP
OX
11
16
ces. (2) At the end of 500 s recovery, the stress indu-
(10
12
ced donor traps fully recover while the acceptor traps D D
ox
AR DR
8 OX-
are partially recoverable and partially permanent. (3)
OX
D
nor traps and acceptor traps in the devices. The ex- -0.4 0.0 0.4 0.8
traction procedure is as follows: in the PBTI test, ∆𝑉g g
(V)
057301-4
CHIN. PHYS. LETT. Vol. 34, No. 5 (2017) 057301
but also affected by the stress induced acceptor traps. traps are negligible for the buried channel case.
(2) Albeit PBTI stress does not change the 𝑆 -factor
in Si-nMOSFETs because of the electron-trap-free na-
ture in high-𝑘 /SiO2 /Si stack, and PBTI stress indu- References
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057301-5