No.1.b-i.

Mc Cabe-Thiele Stage Determining Method Data

Pressure = 101,325 kPa
Tb- Octane = 125,5 0C
Tb- Hexane = 68,74 0C
Antoine Constant
A B C
n-Hexane 13,8193 2696,04 224,317
n-Octane 13,9346 3123,13 209,635

No T (0C ) Psat-H Psat-O K-H K-O X-H Y-H

1 68,74 101,4522 15,1115 1,0013 0,1491 0,9985 0,9998
2 70 105,5276 15,8950 1,0415 0,1569 0,9531 0,9926
3 75 122,9765 19,3404 1,2137 0,1909 0,7911 0,9601
4 80 142,5917 23,3738 1,4073 0,2307 0,6539 0,9202
5 85 164,5465 28,0672 1,6239 0,2770 0,5368 0,8717
6 90 189,0185 33,4980 1,8655 0,3306 0,4361 0,8136
7 95 216,1892 39,7480 2,1336 0,3923 0,3490 0,7446
8 100 246,2438 46,9044 2,4302 0,4629 0,2730 0,6635
9 105 279,3702 55,0587 2,7572 0,5434 0,2063 0,5687
10 110 315,7585 64,3073 3,1163 0,6347 0,1472 0,4588
11 115 355,6011 74,7512 3,5095 0,7377 0,0946 0,3321
12 120 399,0912 86,4953 3,9387 0,8536 0,0474 0,1869
13 125 446,4232 99,6491 4,4059 0,9835 0,0048 0,0213
14 125,5 451,3752 101,0463 4,4547 0,9972 0,0008 0,0035

𝐵
ln 𝑃𝑠𝑎𝑡 = 𝐴 −
𝑇+𝐶
With Pressure in kPa and Temperature in Celcius
For n-Hexane :
2969,04
ln 𝑃𝑠𝑎𝑡 − 𝐻 = 13,8193 − 𝑃𝑠𝑎𝑡 − 𝐻 = 101,4522 𝑘𝑃𝑎
68,74 + 224,317
𝑃𝑠𝑎𝑡 101,4522 𝑘𝑃𝑎
𝐾 − 𝐻𝑒𝑥𝑎𝑛𝑒 = 𝐾 − 𝐻𝑒𝑥𝑎𝑛𝑒 = = 1,0013
𝑃𝑡𝑜𝑡𝑎𝑙 101,325 𝑘𝑃𝑎
For n-Octane :
3123,13
ln 𝑃𝑠𝑎𝑡 − 𝑂 = 13,9346 −
68,74 + 209,635
𝑃𝑠𝑎𝑡 − 𝑂 = 15,1115 𝑘𝑃𝑎
 15,1115 𝑘𝑃𝑎
𝐾 − 𝑂𝑐𝑡𝑎𝑛𝑒 = = 0,1491
101,325 𝑘𝑃𝑎
1 − 𝐾𝑜𝑐𝑡𝑎𝑛𝑒 1 − 0,1941
𝑋 − 𝐻𝑒𝑥𝑎𝑛𝑒 = = = 0,9985
𝐾ℎ𝑒𝑥𝑎𝑛𝑒 − 𝐾𝑜𝑐𝑡𝑎𝑛𝑒 1,0013 − 0,1941
𝑌 − 𝐻𝑒𝑥𝑎𝑛𝑒 = 𝐾ℎ𝑒𝑥𝑎𝑛𝑒 × 𝑋ℎ𝑒𝑥𝑎𝑛𝑒 = 1,0013 × 0,9985 = 0,9998