MATERIAL SAFETY DATA SHEET CI S003/A

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SOLID SULPHUR
1. Identification :
Substance Identification : Sulphur, Milled Sulphur, Granular Sulphur, Sulphur
pastilles, crystals, prills and granules.

: CHEMICAL INITIATIVES (Pty) Limited, Private Bag

Company Address X137, Bryanston, Gauteng, 2021
:
Emergency Telephone Number (011) 608-3300 or Toll free: 0800-1144455
2. Composition and Ingredients :
Hazardous Components : Sulphur solid
S8
3. Hazards identification :
Highly flammable and combustible Solid. A nuisance dust. Crystalline sulphur deposits and dust are readily
ignitable. Forms explosive mixtures with charcoal and oxidizing agents. Thermal decomposition will evolve
with large quantities of sulphur dioxide.
In dry state can form electrostatic charge if stirred, transported pneumatically or poured.
Contact could cause burns to skin and eyes.
Fire could produce irritating or Sulphur dioxide (SO2) gas. Threshold Limit value (TLV) of 2ppm / Short term
exposure limit (STEL) = 5ppm
Run-off from fire-control or dilution water could cause pollution.
Eye contact: Irritation and redness.
Inhalation: sore throat, coughing.
3
No recommended dust exposure limit therefore considered a nuisance dust. ACGIH 10mg/m (total dust) or
3
5mg/m (as respirable dust)
4. First Aid :
Specific Immediate Treatment

Skin : Remove contaminated clothing, wash skin with soap

and water or shower.

Eyes : IMMEDIATELY wash eyes with running water until

irritation is gone. Take to doctor if necessary.

Ingestion : Rinse mouth with water and do not induce vomiting.

Obtain medical attention. Sulphur is not considered
highly toxic.

Inhalation (SO2 gas, smoke, dust or H2S) : Move to fresh air. Take to doctor.

5. Fire fighting :
Requirements for fire fighting

Extinguishing Medias : Water, water fog, Dry chemical powder fire

extinguisher, sand, water spray or foam.

Fires : Protect product and containers from ignition during

nearby fires if possible.
 MATERIAL SAFETY DATA SHEET
SOLID SULPHUR
Respiratory equipment
Unusual fire and explosion hazards
6. Accidental Release :
Precautions
Spill or Leak
Environmental
7. Handling and Storage :
Handling and storage
CI S003/A
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: Breathing Apparatus set
: Combustion product is sulphur dioxide, an irritating
toxic gas which smells like burning match heads.
Dust air mixtures are highly flammable / explosive.
Sulphur fires are deep blue at night, with very short
flames. Fire is invisible in the daylight except for smoke
and heat. Burning material turn deep red black.
: Avoid mixtures of air and sulphur dust, sparks or open
flames, mixtures of sulphur and oxidizing agents in
general, large accumulations of sulphur dust which
become airborne in an explosion or process disruption
caused by other materials. Examples of oxidizing
agents are perchlorates, nitrates, chlorates,
permanganates, peroxides, oxygen and etc.
Good house keeping is essential to minimize fire
danger.
: Restrict access to area.
Provide adequate protective equipment, ventilation and
have fire fighting equipment at hand.
Remove sources of heat, flame and ignition.
Avoid setting fire to spilled material.
Avoid creating dust and sparks with tools.
Small spills may be cleaned up with a shovel and
broom.
Large spills may be cleaned up with front end loaders.
Personnel to thoroughly wash all exposed skin areas to
prevent irritation from dust.
: Do not let spillages enter drains, sewers or water
courses. Any spillages into the water courses must be
reported to the local regulatory body, of that area.
: Handle only with well grounded non-sparking
equipment.
Dry sulphur materials may generate static electricity
and sparking.
Avoid handling sulphur at high velocity in air.
Control dust formation.
Avoid contact with eyes and dust suspections.
Only use in well ventilated areas.
Do not use near sparking equipment or open flames.
Do not allow large amounts of waste to accumulate.
Do not store near oxidizing materials or near hot
equipment.
In the presence of moisture over long periods of time,
 MATERIAL SAFETY DATA SHEET CI S003/A
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SOLID SULPHUR
sulphur will convert to sulphuric acid which is corrosive
to metals, attacks paper, concrete, wood. Store in dry
place

8. Exposure and Personal Protection :

Occupational Exposure Limits : No Exposure Limits Established

Personnel Protective Equipment : Respiratory protection: dust mask suitable for use of
irritating dust.
Fire: Breathing apparatus shall be worn.
Indoor use areas should have sufficient local exhaust to
remove dust as it is release into the air.
Eye protection must be used.
Clothing: Long sleeves, long pants and gloves assist to
keep sulphur off the skin of sensitive persons prone to
irritation or dermatitis.
Fire fighting tools should be readily available.
Safety shower or eye wash fountain or bottle to be
available.
9. Physical and Chemical Properties :
Appearance : Yellow crystals or yellow powder.
Odour : Odourless when pure, with hydrocarbon impurities,
odour of rotten eggs.
0
Boiling Point : 444.6 C
0
Melting Point : 119 C
Relative Density (g/ml) : Solid : 2,07 at 20°C
Liquid : 1,79 at 138°C
Vapour Pressure : 0,133 kPa at 183,8°C
Flash Point : Liquid, pure : 188°C
Liquid, impure : as low as 168°C
Auto ignition Temperature : Dust in air : 190°C
Undispersed : 220°C
Non-corrosive when dry.
In presence of moisture will attack steel rapidly.
Flammable and explosive in finely divided form
Explosive Concentration by Mass in : Minimum : 35 g/cubic meter
Air Maximum : 1 400 g/cubic meter
10. Stability and Reactivity :
Conditions to Avoid : Dust and any source of ignition (Heat)
Reacts violently with strong oxidants with risks of fire
and explosion.
Incompatible Materials : Sulphur forms sulfides with most metals, including iron
and reacts with metals in the Sodium and Magnesium
groups on the periodic table.
11. Toxicology :
Inhalation Dust can cause irritation to the respiratory tract
Eye contact Dust may cause irritation
Ingestion Dust is unlikely to be hazardous if swallowed
 MATERIAL SAFETY DATA SHEET CI S003/A
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SOLID SULPHUR
Skin Dust may cause irritation
Long term exposure No known hazards are associated with the use of this
material
12. Ecology :
Users shall comply with the local, provincial and national environmental legislation.

13. Disposal :
Disposal Method Product : Chemical residues generally count as special waste. It
is recommend that you contact the authorities in charge
or approved waste disposal companies which will
advise you on how to dispose of special waste.
Recover, reclaim and recycle if practical.

Disposal Method Packaging : Disposal in accordance with local legal provisions

14. Transport :
Un No. : 1350
Hazchem Code : 2[Z]
ERG No. : 133
EAC : 32
IMDG – Shipping Name : Sulphur
IMDG Code : 4060
IMDG – Packaging Group : III
Marine Pollutant : Yes
Class : Class : 4.1 Flammable Solid Group : III
Subsidiary Risks : Not dangerous when transported in quantities of <400
kg or when formed in specific shapes.
Tremcard Number : 115A/41G03

15. Regulations :
EEC Hazard Classification : 4.1
Risk Phases : Highly flammable. Explosive when mixed with oxidizing
substances.
Safety Phases : Keep container tightly closed. In case of fire, use water
spray, dry chemical powder or regular foam.
16. Other :
 MATERIAL SAFETY DATA SHEET CI S003/A
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SOLID SULPHUR
DISCLAIMER:
Chemical Initiatives (PTY) Ltd provides the information contained herein in good faith but makes no
representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a proper-trained person using this product. Individuals
receiving the information must exercise their independent judgement in determining its appropriateness for a
particular purpose. Chemical Initiatives (PTY) Ltd makes no representations or warranties, either
express or implied, including without limitation any warranties of merchantability, fitness for a
particular purpose with respect of the information set forth herein or the product to which the
information refers. Accordingly, Chemical Initiatives (PTY) Ltd will not be responsible for damages
resulting from use of or reliance upon this information.