Class Test -1

Chapter 1: Alcohol Phenol & Ethers

Q. 1: Multiple choice questions (7 marks)

1. In phenol carbon atom attached to -OH group undergoes ________.?

(A) sp3 hybridisation (B) sp hybridization (C) sp2 hybridisation (D) no hybridisation.
2. Which among the following reducing agents is NOT used to reduce acetaldehyde to ethyl
alcohol?
(A) Na-Hg and water (B) Zn-Hg and conc. HCl (C) H2-Raney Ni (D) LiAlH4/H+
3. Bakelite is the polymer of _______.
(A) Benzaldehyde and phenol (B) Acetaldehyde and phenol
(C) Formaldehyde and phenol (D) Formaldehyde and benzyl alcohol
4. Chloro ethane reacts with X to form diethyl ether. What is X
(A)NaOH (B)H2SO4 (C )C2H5ONa (D)Na2S2O3
5. In Williamson's synthesis
A)an alcohol is heated with conc. H2SO4 at 140°C B)an alkyl halide is treated with sodium
C)an alkyl halide is treated with sodium alkoxide D)None of the above
6. Methyl phenyl ether can be obtained by reacting
A)phenolate ions and methyl iodide B)methoxide ions and bromobenzene
C)methanol and phenol D)bromobenzene and methyl bromide
7. Which of the following is Lucas reagent?
(A) ZnCl2/con HCl (B) Br2/CCl4 (C) Ammoniacal silver nitrate (D) Cold Alkaline KMnO4
Q. 2: Solve the followings (Any 6) (12 marks)
1. What are alcohols? How they are classified?
2. Name the reagents used to convert phenol into 1. picric acid 2. 2,4,6-tribromophenol 3. benzene.
3. What is the action of following reagents on phenol.
i. Bromine in CS2 at low temp. ii. Dil. HNO3 at RT.
4. How diethyl ether prepared by continuous eherification process?
5. Give uses of phenol and diethyl ether.
6.how will you prepare 2-methyl butane-1-ol from an alkene.
7. how will you prepare methoxyethane from alkyl halide?
8. write structures of 1. 1-Ethylcyclohexanol 2. Hex-3-en-2-ol

Q. 3: solve the followings (Any 3) (9 marks)

1. Explain Kolbe and Riemer-Tiemann reaction.
2. Explain bromination, nitration, friedel craft alkylation and acylation of anisole.
3. Explain: I) Phenol is more acidic than ethanol.
4. How propane-1-ol prepared from Propanal & Propanoic acid..
5. How phenol is prepared from Clorobenzene, Isopropyl benzene & Aniline.

Q. 4. Solve the following. (7 mark)

1. crown ether
2. CH3-CH2-CH2-O-CH3 + HBr gives?
3. Williamson & Wurtz Synthesis
4. Give uses of alcohol.