SOLUCION DEL EJERICICO DE FIXED BED CATALYTIC REACTOR

(ADIABATICO)
ALUMNA: MALDONADO YUPANQUI KAREN THALIA
ESCUELA: AMBIENTAL

1° 2°
Etapa Etapa
Refrigerante 50
ton/dia

SOLUCION:
 Balance de Energía
𝑑𝑇 −∆𝐻 𝐹𝐴𝑜
=
𝑑𝑥𝐴 𝐹𝑡 𝐶𝑝

𝑑𝑇
= 250.7 − 0.0203𝑇
𝑑𝑥
𝑇 𝑥
∫ 𝑑𝑇 = ∫ (250.7 − 0.0203𝑇)𝑑𝑥
𝑇0 𝑥𝑜

𝑇 − 𝑇𝑜 = (250.7 − 0.0203𝑇)(𝑥 − 𝑥𝑜)

𝑻𝒐 + 𝟐𝟓𝟎. 𝟕(𝒙 − 𝒙𝒐)
𝑻=
𝟏 + 𝟎. 𝟎𝟐𝟎𝟑(𝒙 − 𝒙𝒐)
  Balance de Materia

𝑑𝑇 𝐹𝐴𝑜
=
𝑑𝑥𝐴 𝜌𝐴𝑐 (−𝜏𝑝)

DATOS:
Ac= 26267.777 cm2
𝑘1𝑝𝑆𝑂2 𝑝𝑂2 − 𝑘2𝑝𝑆𝑂3 (𝑝𝑂2 )0.5
𝜏𝑝 = 1
(𝑝𝑆𝑂2 )2
Reemplazando:
𝑑𝑧 3.4332 ∗ 10^(−4)
=
𝑑𝑥 𝜏𝑝

𝒅𝒛 𝟑. 𝟒𝟑𝟑𝟐 ∗ 𝟏𝟎^(−𝟒)
=
𝒅𝒙 𝟑𝟏𝟎𝟎𝟎 𝟖(𝟏 − 𝒙) 𝟏𝟑 − 𝟒𝒙 𝟓𝟑𝟔𝟎𝟎 𝟖𝒙 𝟏𝟑 − 𝟒𝒙 𝟎.𝟓
𝟏𝟕𝟒𝟓𝟓𝟓 ∗ 𝒆−𝟏.𝟗𝟖𝟕𝑻 ∗( )∗( ) − 𝟕. 𝟓𝟎𝟗 ∗ 𝟏𝟎𝟗 ∗ 𝒆−𝟏.𝟗𝟖𝟕𝑻 ∗ ( )∗( )
𝟏𝟎𝟎 − 𝟒𝒙 𝟏𝟎𝟎 − 𝟒𝒙 𝟏𝟎𝟎 − 𝟒𝒙 𝟏𝟎𝟎 − 𝟒𝒙
𝟎.𝟓
𝟖(𝟏 − 𝒙)
( )
𝟏𝟎𝟎 − 𝟒𝒙

1° Para la primera etapa donde la temperatura inicial es 643 la conversión inicial

es 0 y la temperatura final es 833 la conversión a esta temperatura se puede
hallar, con el siguiente programa:

clc, clear all

%ALUMNA: MALDONADO YUPANQUI KAREN THALIA
disp('........................................')
disp(' DETERMINACION DE x PARA UNA TEMPRATURA T')
disp('........................................')
x0=0;
T0=643;
Tf=833;
fprintf(' x T(K) ')
for i=T0:10:Tf
x=((i-T0)/(250.7-0.0203*i))+x0;
fprintf('%10.0f %10.3f\n',i,x)
end

CORRIENDO PROGRAMA:

........................................
DETERMINACION DE x PARA UNA TEMPRATURA T
..........................................................................................
x T(K)
 653 0.042
663 0.084
673 0.127
683 0.169
693 0.211
703 0.254
713 0.296
723 0.339
733 0.382
743 0.424
753 0.467
763 0.510
773 0.553
783 0.596
793 0.639
803 0.683
813 0.726
823 0.769
833 0.813
Entonces para la temperatura de 833 se obtiene una conversión de 0.813, utilizando las dos
ecuaciones de balance de materia:

𝑑𝑧 3.4332 ∗ 10^(−4)
=
𝑑𝑥 𝜏𝑝

𝑑𝑧 3.4332 ∗ 10^(−4)
=
𝑑𝑥 31000 8(1 − 𝑥) 13 − 4𝑥 53600 8𝑥 13 − 4𝑥 0.5
174555 ∗ 𝑒 −1.987𝑇 ∗( )∗( ) − 7.509 ∗ 109 ∗ 𝑒 −1.987𝑇 ∗ ( )∗( )
100 − 4𝑥 100 − 4𝑥 100 − 4𝑥 100 − 4𝑥
0.5
8(1 − 𝑥)
(100 − 4𝑥 )

Se podrá determinar z1 , con el método de Runge Kutta

clc, clear all

%ALUMNA: MALDONADO YUPANQUI KAREN THALIA

syms x
T=(643+250.7*(x))/(1+0.0203*(x));
TK0=643;
x0=0;
xf=1;
z0=0;
n=10;
h=(xf-x0)/n;
i=0;
prof=z0;
con=x0;
temp=TK0;
disp('=========================================================')
disp(' DATOS PARA LA CONVERSION ')
disp('----------------------------------------------------------')
disp('=========================================================')
fprintf('i x T(K) z(cm) z(ft)\n')
disp('=========================================================')
fprintf('%2.0f %10.f %11.3f %10.3f %10.3f\n',i,x0,TK0,z0,z0)
for i=1:n;
x=x0;
Ta=eval(T);
k1=h*((3.4332*10^(-4))/(((174555*(exp(-31000/(1.987*Ta)))*(8*(1-
x)/(100-4*x))*((13-4*x)/(100-4*x)))-(7.509*10^(9)*(exp(-
53600/(1.987*Ta)))*(8*x)/(100-4*x))*(((13-4*x)/(100-
4*x))^(0.5)))/((8*(1-x))/(100-4*x))^(0.5)));
x=x0+h/2;
Tb=eval(T);
k2=h*((3.4332*10^(-4))/(((174555*(exp(-31000/(1.987*Tb)))*(8*(1-
x)/(100-4*x))*((13-4*x)/(100-4*x)))-(7.509*10^(9)*(exp(-
53600/(1.987*Tb)))*(8*x)/(100-4*x))*(((13-4*x)/(100-
4*x))^(0.5)))/((8*(1-x))/(100-4*x))^(0.5)));
x=x0+h/2;
Tc=eval(T);
k3=h*((3.4332*10^(-4))/(((174555*(exp(-31000/(1.987*Tc)))*(8*(1-
x)/(100-4*x))*((13-4*x)/(100-4*x)))-(7.509*10^(9)*(exp(-
53600/(1.987*Tc)))*(8*x)/(100-4*x))*(((13-4*x)/(100-
4*x))^(0.5)))/((8*(1-x))/(100-4*x))^(0.5)));
x=x0+h;
Td=eval(T);
k4=h*((3.4332*10^(-4))/(((174555*(exp(-31000/(1.987*Td)))*(8*(1-
x)/(100-4*x))*((13-4*x)/(100-4*x)))-(7.509*10^(9)*(exp(-
53600/(1.987*Td)))*(8*x)/(100-4*x))*(((13-4*x)/(100-
4*x))^(0.5)))/((8*(1-x))/(100-4*x))^(0.5)));
x=x0+h;
TK=eval(T);
z0=z0+(1/6)*(k1+2*k2+2*k3+k4);
zm=z0/30.40;
x0=x0+h;
prof=[prof,zm];
con=[con,x0];
temp=[temp,TK];
fprintf('%2.0f %10.2f %10.3f %10.3f %10.3f\n',i,x0,TK,z0,zm)
end

CORRIENDO PROGRAMA:
=========================================================
DATOS PARA LA CONVERSION
----------------------------------------------------------
=========================================================
i x T(K) z(cm) z(ft)
=========================================================
0 0 643.000 0.000 0.000
1 0.05 653.684 69.529 2.287
2 0.09 664.349 118.275 3.891
3 0.14 674.995 152.955 5.031
4 0.18 685.621 177.980 5.855
5 0.23 696.227 196.291 6.457
6 0.27 706.815 209.873 6.904
7 0.32 717.383 220.085 7.240
8 0.36 727.932 227.868 7.496
9 0.40 738.462 233.884 7.694
10 0.45 748.973 238.603 7.849
11 0.49 759.465 242.363 7.972
12 0.54 769.938 245.413 8.073
13 0.58 780.392 247.939 8.156
14 0.63 790.827 250.087 8.227
15 0.68 801.243 251.977 8.289
16 0.72 811.641 253.732 8.346
17 0.77 822.020 255.518 8.405
18 0.81 832.380 257.783 8.480

Z1=257.783 cm =8.480 ft
Para la segunda etapa se tendra los siguientes datos
x0=0.81
xf=0.99
clc, clear all
%ALUMNA: MALDONADO YUPANQUI KAREN THALIA
syms x
x0=0.81;
T=(643+250.7*(x-x0))/(1+0.0203*(x-x0));
TK0=643;
xf=0.99;
z0=0;
n=10;
h=(xf-x0)/n;
i=0;
prof=z0;
con=x0;
temp=TK0;
disp('=========================================================')
disp(' DATOS PARA LA CONVERSION ')
disp('--------------------------------------------------------')
disp('=========================================================')
fprintf('i x T(K) z(cm) z(ft)\n')
disp('=========================================================')
fprintf('%2.0f %10.f %11.3f %10.3f %10.3f\n',i,x0,TK0,z0,z0)
for i=1:n;
x=x0;
Ta=eval(T);
k1=h*((3.4332*10^(-4))/(((174555*(exp(-31000/(1.987*Ta)))*(8*(1-
x)/(100-4*x))*((13-4*x)/(100-4*x)))-(7.509*10^(9)*(exp(-
53600/(1.987*Ta)))*(8*x)/(100-4*x))*(((13-4*x)/(100-
4*x))^(0.5)))/((8*(1-x))/(100-4*x))^(0.5)));
x=x0+h/2;
Tb=eval(T);
k2=h*((3.4332*10^(-4))/(((174555*(exp(-31000/(1.987*Tb)))*(8*(1-
x)/(100-4*x))*((13-4*x)/(100-4*x)))-(7.509*10^(9)*(exp(-
53600/(1.987*Tb)))*(8*x)/(100-4*x))*(((13-4*x)/(100-
4*x))^(0.5)))/((8*(1-x))/(100-4*x))^(0.5)));
x=x0+h/2;
Tc=eval(T);
k3=h*((3.4332*10^(-4))/(((174555*(exp(-31000/(1.987*Tc)))*(8*(1-
x)/(100-4*x))*((13-4*x)/(100-4*x)))-(7.509*10^(9)*(exp(-
53600/(1.987*Tc)))*(8*x)/(100-4*x))*(((13-4*x)/(100-
4*x))^(0.5)))/((8*(1-x))/(100-4*x))^(0.5)));
x=x0+h;
Td=eval(T);
k4=h*((3.4332*10^(-4))/(((174555*(exp(-31000/(1.987*Td)))*(8*(1-
x)/(100-4*x))*((13-4*x)/(100-4*x)))-(7.509*10^(9)*(exp(-
53600/(1.987*Td)))*(8*x)/(100-4*x))*(((13-4*x)/(100-
4*x))^(0.5)))/((8*(1-x))/(100-4*x))^(0.5)));
x=x0+h;
TK=eval(T);
z0=z0+(1/6)*(k1+2*k2+2*k3+k4);
zm=z0/30.40;
x0=x0+h;
prof=[prof,zm];
con=[con,x0];
temp=[temp,TK];
fprintf('%2.0f %10.2f %10.3f %10.3f %10.3f\n',i,x0,TK,z0,zm)
end

=========================================================
DATOS PARA LA CONVERSION
--------------------------------------------------------
=========================================================
i x T(K) z(cm) z(ft)
=========================================================
0 0.81 643.000 0.000 0.000
1 0.83 647.276 92.880 3.055
2 0.85 651.549 177.202 5.829
3 0.86 655.819 254.503 8.372
4 0.88 660.086 326.221 10.731
5 0.90 664.349 393.791 12.954
6 0.92 668.610 458.813 15.093
7 0.94 672.867 523.386 17.217
8 0.95 677.121 591.063 19.443
9 0.97 681.373 670.915 22.070
10 0.99 685.621 900.676 29.627

Z2=900.676 cm = 29.627 ft

RESPUESTA: Z1=257.783 cm =8.480 ft y Z2=900.676 cm = 29.627 ft