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Kode/sks : MAK3211/3
WEEK 2
Pseudo order reactions
Measurement of reaction rate
Dr.Muhdarina,M.Si
Lab.Riset Sains Material, Jurusan Kimia FMIPA UR
Email: muhdarina.m@lecturer.unri.ac.id
Pseudo order
We know:
R = k [C12H22O11]
However, since the solvent H2O participates in
the reaction, the rate law is:
R = k’ [C12H22O11]w [H2O] v
Pseudo order
Because H2O is always present in great excess,
its concentration remains nearly constant,
therefore [H2O] v is essentially constant and the
rate law is apparently
R = k [C12H22O11] where k = k’ [H2O] v
k [NO2-] = k'
A = log10 Io/I
A λ = ε λ cd
where ε λ is the absorption coefficient for the
molecule in question. ε λ depends on the
wavelength and the identity of the molecule,
λ is the wavelength, d is the path-length and c is
the concentration of the absorbing species.
Spectroscopic Techniques
• Special features of absorbance measurements;