DL11CBKSMC12606

LAST YEARS AIEEE EXAMS QUESTIONS

1. Which of the following concentration factor is affected by change in temperature ? [AIEEE 2002]
(1*) Molarity (2) Molality (3) Mole fraction (4) Weight fraction
Sol. Molarity depends on volume (volume changes with changes in temperature)

2. Number of atoms in 560g of Fe (atomic mass 56g mol–1) is : [AIEEE 2002]

(1) Twice that of 70g N (2) Half that of 20g H (3*) Both (1) and (2) (4) None of these
Sol. 560g of Fe
560g
No. of moles = = 10 mole
56g
70 g of N
14g = 1 mole atom of N
70g = 5 moles of N
20g H = 20 moles of H-atoms.

3. In an organic compound of molar mass 108 g mol–1 C,H and N atoms are present in 9 : 1 : 3.5 by weight.
Molecular formula can be : [AIEEE 2002]
(1*) C6H8N2 (2) C7H10N (3) C5H6N3 (4) C4H18N3
Sol. Molar mass = 108 gm/mole

Element Wt. Ratio Wt. ratio/Atomic mass Simple Ratio Simple Integer ratio
9x 3x

C 9x 12 4 3 3
H 1x x 4 4
3.5 x x

N 3.5 x 14 4 1 1

 C3H4N
Empirical mass = 12 × 3 + 4 + 14 = 54
108
n 2
54
 Molecular Formula = C6H8N2

4. What volume of hydrogen gas at 273 K and 1 atm pressure will be consumed in obtaining 21.6 gm of
elemental boron (atomic mass = 10.8) from the reduction of boron trichloride by hydrogen- [AIEEE 2003]
(1) 44.8 lit. (2) 22.4 lit. (3) 89.6 lit. (4*) 67.2 lit.
Sol. 2BCl3 + 3H2  2B + 6HCl
21 .6
moles of B = =2
10 .8
So moles of H2 = 3
Now vol at STP = 3 × 22.4 = 67.2 lt.

5. 6.02 × 1020 molecules of urea are present in 100 ml of its solution. The concentration of urea solution is -
[AIEEE 2004]
(1) 0.001 M (2*) 0.01 M (3) 0.02 M (4) 0.1 M
Moles of solute 6.02  1120 / 6.02  10 23
Sol. Molarity = Vlt = = 0.01 M
100 / 1000

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6. If we consider that 1/6, in place of 1/12, mass of carbon atom is taken to be the relative atomic mass unit, the
mass of one mole of a substance will [AIEEE 2005]
(1) decrease twice (2) increase two fold
(3*) remain unchanged (4) be a function of the molecular mass of the substance
Sol. The mass of one mole of a substance willremain unchanged.

7. Two solution of a substance (non electrolyte) are mixed in the following manner. 480 ml of 1.5M first solution
+ 250 ml of 1.2M second solution.
What is the molarity of the final mixture ? [AIEEE 2005]
(1) 2.70M (2*) 1.344M
(3) 1.50M (4) 1.20M
M1V1  M2 V2
Sol. Final molarity =
V1  V2

1.5  480  1.2  520

= = 1.344M
480  520

8. Density of a 2.05M solution of acetic acid in water is 1.02 g/ml. The molality of the solution is : [AIEEE-2006]
(1) 1.14 mol kg–1 (2) 3.28 mol kg–1 (3*) 2.28 mol kg–1 (4) 0.44 mol kg–1
M
Sol. molality (m) = 1000 d  MM × 1000
1
M = Molarity
M1 = Molecular mass of solute
d = density
2.05
= (1000  1.02) – (2.05  60)  1000

= 2.28 mol kg–1

9. How many moles of magnesium phosphate, Mg3(PO4)2 will contain 0.25 mole of oxygen atoms ?
[AIEEE-2006]
(1) 0.02 (2*) 3.125 × 10–2 (3) 1.25 × 10–2 (4) 2.5 × 10–2
Sol. 8 moles of O-atom are contained by 1 mole Mg3(PO4)2.
1
Hence, 0.25 moles of O-atom = × 0.25 = 3.125 × 10–2 mole Mg3(PO4)2.
8

10. The density (in g mL–1) of a 3.60 M sulphuric acid solution that is 29% (H2SO4 molar mass = 98 g mol–1) by
mass will be [AIEEE-2007, 3/120]
(1*) 1.22 (2) 1.45 (3) 1.64 (4) 1.88
Sol. 3.6 M solution means 3.6 mole of H2SO4 is present in 1000 ml of solution
 Mass of 3.6 moles of H2SO4 is = 3.6 × 98 g = 352.8 g
 Mass of H2SO4 in 1000 ml of solution = 352.8 g
Given, 29g of H2 SO4 is present in 100 g of solution
100
 352.8 g of H2SO4 is present in × 352.8 = 1216 g of solution
29

Mass 1216
Now density = = = 1.216 g/mL = 1.22 g/mL
Volume 1000
11. In the reaction [AIEEE-2007, 3/120]
2AI(s) + 6HCl(aq)  2Al3+(aq) + 6Cl–(aq) + 3H2 (g)
(1) 6L HCl(aq) is consumed for every 3L H2 produced.
(2) 33.6 L H2(g) is produced regardless temperature and pressure for every moles that reacts.
(3) 67.2 L H2(g) at STP is produced for every mole of Al that reacts .

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(4*) 11.2 L H2(g) at STP is produced for every mole of HCl(aq) consumed.
Sol. 2Al(s) + 6HCl(aq)  2Al3+(aq) + 6Cl¯(aq) + 3H2(g)
3 mole H2 from 6 mole HCl consumed.
 1 mole H2 from 2 mole HCl consumed.
1/2 mole(11.2 Lit) H2 from 1 mole HCl consumed.

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RESONANCE AIEEE_MOLE CONCEPT1 - 4