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Table 2
Types of Flotation Processes
1. Plain gravity flotation
Example: API Oil-water separator
Wax water separator
2. Dissolved air flotation (DAF)
Example: Full flow pressurization system
Partial How pressurization system
Recycle flow pressurization system
Flow pattern: laminar flow. Fine air bubbles
Air Addition: 1% of liquid influent flow
3. Dispersed air flotation (or induced air flotation)
Example: Dcinking flotation
Foam separation
Gas stripping
Aeration/oxidaiion
Ore flotation
Flow pattern: Turbulent flow, large air bubbles
Air addition: 400% of liquid influent flow
4. Vaccum flotation
Example: Scum vacuum flotation
5. Electrolytic flotation (or clcctroflotation)
Example: Sacrificing electrode system
Non-sacrificing electrode system
Flow pattern: Laminar flow, fine bubbles
(ias production:
5. Electrolytic flotation (or clcctroflotation)
Example: Sacrificing electrode system
Non-sacrificing electrode system
Row pattern: Laminar flow, fine bubbles
(ias production:
Anode: 2H,<>----- > 4H* + (), + 4e~
Cathode: 4e + 4 H ,()----- ►2H, + 4<)H"
2 H ,0 ----- > 2H, + 0 2
6. Biological dotation
Example: Activated sludge thickening under denitrification condition
Row pattern: Laminar flow and fine bubbles
Gas production:
6NOj + 2CH,OH----- » 6N(). + 2 C O ,+ 4H20
6NO: + 3CH ,()H ---- » 3N, + 3CO, + 3 H ,0 + 60H
6NO, + 5CH3() H ----> 5C02 + 3N, + 7H,() + fi()H
Although many gases, such as carbon dioxide, nitrogen, hydrogen, oxygen, and
o/one, arc suitable, air is the cheapest and most readily available for bubble generation.
Based on the technique and the type o f gas used lor bubble generation, the adsorptive
bubble separation process can be classified mainly as dissolved air flotation, dispersed
air flotation, vacuum flotation, electrolytic flotation (i.c., clcctroflotation) and biological
flotation, as indicated in Table 2. If no gas is involved or used at all. the substances
(such as oil or wax) are separated from liquid by the density difference between the
target substance and the liquid, and the process is termed plain gravity flotation. The
most common plain gravity flotation is the oil-water separation process. The following
section briefly defines various adsorptive bubble separation processes.
Adsorptive Bubble Separation and Dispersed A ir Flotation 85
Table 3
Control Technology Summary for Flotation
Effluent concentration Removal efficiency (*&)
Pollutant Range Median Median
Classical pollutants (mg/L)
BOD (5-d) 140-1000 250 68
COD 18-3200 1200 66
TSS (fiber, sludge, floe) 18-740 82 88
Total phosphorus <0.05-12 0.66 98
Total phenols >0.001-23 0.66 12
Oil & grease 16-220 84 79
Toxic pollutants (pg/L)
Antimony ND-2300 20 76
Arsenic ND-18 <10 45
Xylene ND-1000 200 97
Cadmium BDL-<72 3 98
Chromium 2-620 200 52
Copper 5-960 180 75
Cyanide <10-2300 54 10
Lead ND-1000 70 98
Mercury BDL-2 75
Nickel ND-270 41 73
Silver BDL-66 19 45
Zinc ND-53000 2(X) 89
Bisi 2-chtylhcxyl) phthalatc 30-1100 100 72
Nickel ND-270 41 73
Silver BDL-66 19 45
Zinc ND-53000 2(X) 89
#/'s(2-chtyIhexyl) phthalutc 30-1100 100 72
Butylbcnzylphthalatc ND-42 >99
Carbon tetrachloride BDL-210 36 75
Chloroform ND-24 9 58
Dichlorobromomethane NA >99
Di-n-butyl phthalutc ND-300 20 97
Diethyl phthalate NA >99
Di-n-octyl phthalate ND 33 II 78
N-nitrosodiphcnylaminc NA 620 66
2.4-Dimethylphenol ND-28 14 >99
Pcntachlorophcnol 5-30 13 19
Phenol 9-2400 71 57
Dichlorobcnzene 18-260 140 76
Ethylbenzene ND-970 44 65
Toluene ND-2100 580 39
Naphthalene ND-840 96 77
Anthraccnc/phcnanthrcnc 0.2-600 10 81
NA = not available: BDI. = below detection line: NI) = not detected.
Soun e: US fiPA.
hubbies and the attached solid particles rise to the surface to form a scum blanket, which
can be removed by a continuous scooping or skimming mechanism, (irit and other
heavy solids that settle to the bottom are raked to a central sludge sump for removal.
Auxiliary equipment include an aeration tank for saturating the wastewater with air. vacuum
Adsorptive Bubble Separation and Dispersed A ir Flotation 87
pumps, and sludge pumps (1,2). In theory, vacuum notation is similar to dissolved air
flotation because both processes rely on pressure reduction for generation of fine bubbles.
The reactor designs of two processes, however, are significantly different. Vacuum flotation
has been gradually replaced by dissolved air flotation in various practical applications.