Cls Jeead-17-18 Xi Che Target-2 Set-2 Chapter-7

Chapter 7
Equilibrium
Solutions
SECTION - A
Objective Type Questions (One option is correct)
1. In which of the following does the reaction go almost to completion?
(1) A + B C; K = 104 (2) X+Y Z; K = 10–3
(3) P + Q R; K=1 (4) M+N O + P; K = 10–1

Sol. Answer (1)
K = 104 maximum
Greater the value of ‘K’ indicates reaction is moving towards completion.
2. At constant pressure, the addition of argon in Haber's process

(1) Reduces the formation of ammonia from N2 and H2
(2) Increases the formation of ammonia from N2 and H2
(3) Does not affect the equilibrium of the reaction in which ammonia is formed from N2 and H2
(4) Reduces the dissociation of ammonia
Sol. Answer (1)

N2 (g)  3H2
2NH3 (g)
On addition of inert gas (Ar), reaction starts moving in the backward direction.
3. Consider the general hypothetical reaction
A(s) 2B(g) + 3C(g)

If the concentration of C at equilibrium is doubled, then after the equilibrium is re-established, the concentration
of B will be
(1) Twice of its original value (2) Half of its original value
1
(3) 2 2 times of original value (4) times the original value
2 2
Sol. Answer (4)

2B(g)  3C(g)
A(s)
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152 Equilibrium Solution of Assignment (Set-2)
4. Pure NH3 is placed in a vessel at a temperature where its dissociation is appreciable. At equilibrium
(1) Kp does not change significantly with pressure
(2) Concentration of N2 does not change with pressure
(3) Concentration of NH3 does not change with pressure
(4) Kp changes with pressure but  does not change
Sol. Answer (1)
The value of equilibrium constant (Kp or Kc), only changes with temperature.
5. Which of the following relation holds true for an equilibrium reaction, if its reaction quotient
(Q) = 1?
(1) G = 0 (2) Gº = 0 (3) G > Gº (4) G = Gº
Sol. Answer (4)
G = G° + 2.303 RT log Qc
if Qc = 1
 G = G°
6. For the equilibrium
CO + H2O CO2 + H2.
The relation between Kp and Kc at 25ºC and at 100ºC are
(1) Kp = Kc, Kp = Kc (2) Kp = Kc(RT)–1, Kp = Kc
(3) Kp = Kc(RT), Kp = Kc (RT) (4) Kp = Kc(RT), Kp = Kc

Sol. Answer (4)

CO(g)  H2O(g)
CO2 (g)  H2 (g)
ng = 0
∵ Kp = Kc(RT)n
Kp = Kc
7. What is the vapour density of mixture of PCl5 at 250ºC when it has dissociated to the extent of 80%?
(1) 58 (2) 41.7 (3) 52.25 (4) 83.6
Sol. Answer (1)

PCl3 (g)  Cl2 (g)
PCl5 (g)
Dd ⎡∵ n  2 ⎤
 ⎢  0.8 ⎥
d(n  1) ⎣ ⎦
104.25  d
 0.8 
d(2  1)
 d = 58
Solution of Assignment (Set-2) Equilibrium 153
8. The equilibrium constant (Kp) for the reaction,
2SO2(g)+O2(g) 2SO3(g) at 1000 K is 3.5 atm–1
What would be the partial pressure of oxygen gas, if the equilibrium is found to have equal moles of SO2 and
SO3?
(1) 0.35 atm (2) 3.5 atm (3) 2.85 atm (4) 0.285 atm
Sol. Answer (4)

2SO2 (g)  O2 (g)
2SO3 (g)
Kp = 3.5
(PSO3 )2
Kp  ⎡∵ PSO  PSO ⎤
(PSO2 )2 (PO 2 ) ⎣ 3 2⎦
 1
3.5 
PO2
PO2  0.285
9. For the equilibrium H2O(s) H2O(l)

which of the following statements is true?
(1) The pressure changes do not effect the equilibrium

(2) More of ice melts, if pressure on the system is increased
(3) More of liquid freezes, if pressure on the system is increased

(4) Less of ice melts, if pressure on the system is increased
Sol. Answer (2)

H2O(s)
H2O(l)
Reaction will proceed in forward direction on increase in pressure.
10. Conjugate acid of PO4–3 is

(1) H3PO4 (2) H3PO4– (3) HPO4–2 (4) HPO3–
Sol. Answer (3)
PO43   H  HPO42
11. The dissociation constant of monobasic acids A, B and C are 10–4, 10–6 and 10–10 respectively. The
concentration of each monobasic acid is 0.1 M. Which of the following has been arranged in increasing order
of pH?
(1) C < B < A (2) A<B<C (3) B<C<A (4) B<A<C
Sol. Answer (2)

 –
H A
HA
[M ][H ]
Ka 
[HA]
Smaller the value of Ka, more will be pH.
12. Among the following, which causes the greatest change in pH on addition to 50 ml of 0.2 M oxalic acid
solution?
(1) Addition of 25 ml of 0.02 M oxalic acid
(2) Addition of 25 ml of 1 M NaOH solution
(3) Addition of 2 ml of 0.02 M NH4OH solution
(4) Addition of 50 ml of 0.2 M acetic acid solution
Sol. Answer (2)
NV (Resulting) = N1V1 – N2V2
25  1  50  0.2  2
 N
75
= 0.067 N of OH–
Hence, maximum change of pH.
13. What will be the H+ concentration in a solution prepared by mixing 50.0 ml of 0.20 M NaCl, 25 ml of 0.10 M
NaOH and 25.0 ml of 0.30 M HCl?
(1) 0.5 M (2) 0.05 M (3) 0.02 M (4) 0.10 M
Sol. Answer (2)

HCl  NaOH
NaCl  H2O
M1 = 0.3, M2 = 0.1 M
V1 = 25, V2 = 25 ml
 MV = 7.5 – 2.5
5
M
100
M = 0.05 = [H+]
14. To 250.0 ml of M/50 H 2SO 4, 4.0 g of solid NaOH is added and the resulting solution is diluted to
1.0 L. The pH of the resulting solution is
(1) 12.0 (2) 11.25 (3) 11.95 (4) 12.95
Sol. Answer (4)

H2SO4  NaOH
Na2SO4  H2O
meq. of resulting solution = meq. of NaOH – meq. of H2SO4
NV = 100 – 10
90
 Nr =
1000
 [OH–] = 9  10–2
pOH = – log [OH–] = 2 – log 9
= 2 – 0.95 = 1.04
pH = 14 – 1.04 = 12.95
15. One mole of N2O4(g) at 300 K is kept in a closed container under one atmosphere. It is heated to 600 K when
20% by mass of N2O4(g) decomposes to NO2(g). The resultant pressure is
(1) 1.2 atm (2) 2.4 atm (3) 2.0 atm (4) 1.0 atm
Sol. Answer (2)
p1 p
 2 …(i)
n1T1 n2 T2

N2O4 (g)
2Na2 (g)
t 0 1 0
At equilibrium 1 –  2
 Total = (1 + ) [∵  = 0.2]
 Total moles (n2) = (1 + 0.2) = 1.2
and n1 = 1
 By equation (i)
1 p2

1 300 1.2  600
p2 = 2.4 atm
1
16. For the equilibrium SO3(g) SO2(g) + O 2 (g), the molar mass at equilibrium was observed to be 60, then the
2
degree of dissociation of SO3 would be
(1) 0.33 (2) 0.66 (3) 0.25 (4) 0.50
Sol. Answer (2)

1
SO2 (g) 
SO3 (g) O2 (g)
2
M.mSO3 = 60 (observed at equilibrium)
Dd ⎡ 80 60 ⎤
 ⎢∵
D  40,
d  30 ⎥
d(n  1) ⎣ 2 2 ⎦
40  30
 
30(1.5  1)
10

30  0.5
 = 0.66
17. When a solution of benzoic acid was titrated with NaOH, the pH of the solution when half of the acid neutralized
was 4.2. Dissociation constant of the acid is
(1) 6.31 × 10–5 (2) 3.2 × 10–5 (3) 8.7 × 10–8 (4) 6.42 × 10–4
Sol. Answer (1)

C6H5COOH  NaOH
C6H5COONA  H2O
[Acid] = [Salt] at equilibrium
[Salt]

pH pK a  log
[Acid]
4.2 = – log Ka + 0
Ka = 6.31 × 10–5
18. If an aqueous solution at 25ºC, has twice as many OH– as pure water, its pOH will be
(1) 6.7 (2) 7.3 (3) 7 (4) 6.98
Sol. Answer (1)
[OH–] = 2 × 10–7
 pOH = – log [OH–] = – log 2 × 10–7
 pOH = 7 – log 2.0 = 7 – 0.3010
 pOH = 6.7
19. Solubility of AgCl in water, 0.01 M CaCl2, 0.01 M NaCl and 0.05 M AgNO3 are S1, S2, S3 and S4 respectively,
then,
(1) S1 < S2 < S3 < S4 (2) S1 > S3 > S2 > S4
(3) S1 > S2 = S3 > S4 (4) S1 > S3 > S4 > S2
Sol. Answer (2)

Water and AgCl don’t have common ion, therefore solubility will be maximum. But the concentration of AgNO3
is 0.05 which is maximum therefore solubility will be least.
20. pH of Ba(OH)2 solution is 12. Its solubility product is

(1) 10–6 M3 (2) 4 × 10–6 M3 (3) 5 × 10–7 M3 (4) 5 × 10–6 M3
Sol. Answer (3)
[H+] = 10–12 M
[OH–] = 10–2 M = 2 S [ S = 5 × 10–3]

2 
Ba  2OH
Ba(OH)2
S 2S
 KSP = 4 S 3
 KSP = 4 × (5 × 10–3)3
 KSP = 500 × 10–9 = 5 × 10–7 M3
21. Solubility product constants (Ksp) of salts of types MX, MX 2 and M3X at temperature 'T' are 4.0 × 10 –8,
3.2 × 10–14 and 2.7 × 10–15, respectively. Solubilities (mol dm–3) of the salts at temperature 'T' are in the order
[IIT-JEE 2008]
(1) MX > MX2 > M3X (2) M3X > MX2 > MX
(3) MX2 > M3X > MX (4) MX > M3X > MX2
Sol. Answer (4)
(MX) S2 = 4.0 × 10–8
S = 2.0 × 10–4
(MX2) 4S3 = 3.2 × 10–14
S3 = 0.8 × 10–14
S3 = 8 × 10–15
S = 2 × 10–5
(M3X) 27S4 = 2.7 × 10–15
S = 1 × 10–4
 Order is
MX > M3X > MX2
22. The Ksp of Ag2CrO4 is 1.1 × 10–12 at 298 K. The solubility (in mol/L) of Ag2CrO4 in a 0.1 M AgNO3 solution is
[JEE(Advanced)-2013]
(1) 1.1 × 10–11 (2) 1.1 × 10–10 (3) 1.1 × 10–12 (4) 1.1 × 10–9
Sol. Answer (2)
–2
The solubility of Ag2CrO4 = ⎡⎣CrO4 ⎤⎦
K sp 1.1 10 –12
 ⎡CrO 4–2
⎣
⎤
⎦ 2 2
 1.1 10 –10 mol L1
⎡ Ag ⎤ (0.1)
⎣ ⎦
SECTION - B
Objective Type Questions (More than one options are correct)
1. The following reaction attains equilibrium at high temperature
N2(g) + 2H2O (g) + heat 2NO (g) + 2H2 (g)
The concentration of NO(g) is affected by
(1) Increasing the nitrogen concentration (2) Decreasing the hydrogen concentration
(3) Compressing the reaction mixture (4) Addition of catalyst
Sol. Answer (1, 2, 3)

N2 (g)  2H2O(g)  heat
2NO(g)  2H2 (g)
According to Le-chatelier’s principle in above equation
On in increase in concentration of N2, reaction will be forward and more NO will be formed and on decreasing
concentration of H2, reaction will move in forward direction.
2. For the reaction PCl5 (g) PCl3 (g) + Cl2 (g), the forward reaction at constant temperature is favoured by
(1) Introducing an inert gas at constant volume (2) Introducing Cl2(g) at constant volume
(3) Increasing the volume of the container (4) Introducing PCl5 at constant volume
Sol. Answer (3, 4)
On increase in volume at constant temperature, pressure decreases and on decreases in pressure, reaction
always shifts in the direction where more number of moles are present.
In the following reaction

PCl3 (g)  Cl2 (g)
PCl5 (g)
On increase in volume, reaction will proceed in forward direction.
And on increase in concentration of PCl5, reaction will proceeds in forward direction.
3. If concentration of two acids are same, their relative strengths can be compared by
1 K1 [H  ]1 K1
(1)  (2) (3) (4)
2 K2 [H  ] 2 K2

 
H  A1
HA1
K a1 C12
K a1
1  …(i)
C

 
H  A2
HA 2
K a2
2  …(ii)
C
1 K a1

2 Ka 2
4. Which of the following solutions will have no effect on pH on dilution?
(1) 0.1 M NH4OH + 0.1 M NH4Cl (2) 0.5 M H2CO3 + 0.5 M NaHCO3
(3) 1 M CH3COONH4 (4) 0.1 M CH3COONa

1, 2, 3 are the buffer solution.
5. Which of the following is correct about the equilibrium?
(1) Catalyst has no effect on equilibrium state
(2) Keq changes with temperature
(3) Value of Keq changes by increasing concentration of equilibrium
(4) G = 0
The value of equilibrium constant only changes with temperature and at equilibrium G = 0
6. Which of the following statements are correct?
(1) The pH of 1.0 × 10–8 M solution of HCl is 8
(2) The conjugate base of H2PO4– is HPO4–2
(3) Auto-protolysis constant of water increases with temperature
(4) When a solution of weak monoprotic acid is titrated against a strong base, then, at half neutralization point
⎛ 1⎞
pH  ⎜ ⎟pK a
⎝2⎠
Sol. Answer (2, 3)
H2PO4 — H  HPO24
Acid Conjugate base
In water, on increase in temperature it produces more H+ ions.
7. Equal volumes of following solutions are mixed. In which case the pH of resulting solution will be average value
of pH of two solutions?
(1) pH = 2 (HCl) and pH = 12 (NaOH)
(2) pH = 2 (HCl) and pH = 4 (HCl)
(3) pH = 2 (HCN) and pH = 12 (NaOH)
(Ka of HCN = 10–10)
(4) pH = 5 (CH3COOH) and pH = 9 (NH3) (aq)
(Ka CH3COOH = Kb NH4OH)
Sol. Answer (1, 4)
pH = 7
Because it will form NaCl, which is a salt of strong acid and strong base
4  It is the salt of weak acid and weak base.
⎛1 1 ⎞
pH 
7  ⎜ pK a  pKb ⎟
⎝2 2 ⎠
Ka = Kb
 pH = 7
3
8. A weak base (BOH) with Kb = 10–5 is titrated with a strong acid HCl, at th of the equivalence point, pH of the
4
solution is
(1) 5 + log3 (2) 5 – log3 (3) 9 – log 3 (4) 8.523
Sol. Answer (3, 4)

BOH  HCl
BCl  H2O
[Salt] 33
pOH = pKb  log  5  log
[Base] 4 1
pOH = 5 + log 2.25
= 5 + 0.35
pH = 14 – 5.35
= 8.5
9. 0.1 molar CH3COOH is titrated with 0.1 molar NaOH solution. What would be the difference in pH between
1 3
and stages of neutralization of acid?
4 4
1
(1) 2 log (2) 2 log 3 (3) 0.9542 (4) 0.3010
4
Sol. Answer (2, 3)
⎛ 1/ 4 ⎞

pH1 pK a  log ⎜ ⎟
⎝3/ 4⎠
⎛3/ 4⎞

pH2 pK a  log ⎜ ⎟
⎝ 1/ 4 ⎠
 pH2 – pH1 = 2log3 = 0.9542
10. Which of the following solution will have pH close to 7?
M M
(1) 100 ml of HCl  100 ml of NaOH (2) 1 M solution of CH3COONH4 (Ka = Kb)
10 10
M M M M
(3) 100 ml of H2 SO 4  100 ml of NaOH (4) 100 ml of HCl  100 ml of Ca(OH) 2
10 10 10 10
Sol. Answer (1, 2)
Option (1) has equal millimoles and solution is the mixture of strong acid and strong base. Therefore, pH =
7, while in option 2, Ka = Kb and it is the salt of weak acid and weak base.
2 2
11. 2.5 mL of M weak monoacidic base (Kb = 1 × 10–12 at 25°C) is titrated with M HCl in water at 25°C. The
5 15
concentration of H+ at equivalence point is (Kw = 1 × 10–14 at 25°C) [IIT-JEE 2008]
(1) 3.7 × 10–13 M (2) 3.2 × 10–7 M (3) 3.2 × 10–2 M (4) 2.7 × 10–2 M
Sol. Answer (4)
At equivalence point
Volume of HCl used is 7.5 mL
Total volume = 10 mL
2
2.5 
Concentration of salt = 5  M
10 10
1014
Kh of salt =  102
1012
Here degree of hydrolysis is not negligible.
B  H2O


H  BOH
0.1(1 ) 0.1 0.1
10–2 = 10–2 2 = 10–1 (1 – )

0.1 – 0.1 – 2 = 0
On solving,
 = 0.27

[H ] 2.7  102 M
12. Aqueous solutions of HNO3, KOH, CH3COOH, and CH3COONa of identical concentrations are provided. The pair(s)
of solutions which form a buffer upon mixing is(are) [IIT-JEE 2010]
(1) HNO3 and CH3COOH (2) KOH and CH3COONa
(3) HNO3 and CH3COONa (4) CH3COOH and CH3COONa

Sol. Answer (3, 4)
Solution of weak acid and its salt with strong base behave like buffer. So, CH3COOH and CH3COONa mixture
form buffer. This can also form when HNO3 as limiting reagent react with CH3COONa.
CH3 COONa  HNO3  CH3 COOH  NaNO3
(Excess) (Limiting)
13. The thermal dissociation equilibrium of CaCO3(s) is studied under different conditions [JEE(Advanced)-2013]

CaO(s)  CO2 (g)
CaCO3 (s)
For this equilibrium, the correct statement(s) is(are)
(1) H is dependent on T
(2) K is independent of the initial amount of CaCO3
(3) K is dependent on the pressure of CO2 at a given T
(4) H is independent of catalyst, if any


CaO(s)  CO2 (g)
CaCO3 (s)
K  PCO2
K is only dependent on temperature and it is independent of the amount of reactant or product.

H is dependent on temperature according to Kirchoff’s equation but independent of addition of catalyst.
SECTION - C
Linked Comprehension Type Questions
Comprehension-I
Degree of dissociation : ()
 are the number of moles which are dissociating from 1 mole of given reactants and gas density measurements
can be used to determine the degree of dissociation. Let us take a general case where one molecule of a substance
A splits up into n molecules of A(g) on heating i.e.,
An(g) nA(g)
t=0 a 0
x
t = teq a–x nx  ⇒ x  a
a
a – a na
Total number of Moles = a – a + na
= [1 + (n – 1)] a
Observed molecular weight or molar mass of the mixture.
MA n
Mmixture  ; M A n  Molar mass of A n
[1  (n  1)]
1. A sample of mixture A(g), B(g) and C(g) under equilibrium has a mean molecular weight (observed) of 80.
The equilibrium is
A(g) B(g) + C(g)
(Mol. wt.= 100) (Mol. wt.= 60) (Mol. wt.= 40)
Find the degree of dissociation  for A(g).
(1) 0.25 (2) 0.5 (3) 0.75 (4) 0.8
Sol. Answer (1)

MA
Mmixture 
[1  (n  1)]
 MA = 100, n=2
Mmixture  80
(Observed)
100
 80 
[1  (2  1)]
100
1  
80
2
 = 0.25
8
2. If the total mass of the mixture in question (1) is 300 gm, then moles of C(g) present are
1 4 3 1
(1) (2) (3) (4)
4 3 4 2
Sol. Answer (3)
A(g)

B(g)  C(g)

t0 a 0 0
 0 a  a
t eq a a
Mass of ‘A’ (w1) = a (1–) × 100 [M.m = 100]
Mass of ‘B’ (w2) = a × 60 [M.m = 60]
Mass of ‘C’ (w3) = 2 × 40 [ M.m = 40]
∵ w1 + w2 + w3 = 300
a{100 – 100 + 60 + 40} = 300
100a = 300
a=3
 No. of moles of ‘C’ = a = 3  0.25 [ = 0.25]
3
= mole
4
Comprehension-II
Pure water is neutral in nature [H+] = [OH–]. When this condition is disturbed by changing the concentration of H+
or OH–, the neutral solution changes to acidic {[H+] > [OH–]} or basic {[H+] < [OH–]}. This change occurs during
salt hydrolysis. pH of salt solution can be calculated using the following relation
(i) Salt of weak acid and strong base
1
pH = [pKw + pKa + logC]
2
(ii) Salt of weak base and strong acid
1
pH = [pKw – pKb – logC]
2
(iii) For Salt of weak base and strong acid
1
pH = [pKw + pKa – pKb]
2
The pH of buffer can be calculated using the following formula
[Salt]
pH = pKa + log
[Acid]
[Salt]
pOH = pKb + log
[Base]
Answer the following questions when
pKa = 4.7447
pKb = 4.7447
pKw = 14
Choose the correct answer :
1. When 50 ml of 0.1 M NH4OH is added to 50 ml of 0.05 M HCl solution, the pH is nearly

(1) 1.60 (2) 12.40 (3) 4.75 (4) 9.25
Sol. Answer (4)
NH4OH + HCl  NH4Cl + H2O
(W.B) (S.A)
M1 = 0.1 M M2 = 0.05 M
V1 = 50 ml V2 = 50 ml
m.moles of NH4OH = 0.1 × 50
= 5 (Base)
m.moles of HCl = 2.5
 millimoles of NH4Cl = 2.5  (Salt)
[Salt]
  pKb  log
pOH
[Base]
2.5
 pK b  log
pOH
2.5
pOH  pKb
pOH = 4.7447
pH = 9.25
2. When 50 ml of 0.1 M NaOH is added to 50 ml of 0.1 M CH3COOH solution, the pH will be

(1) 4.7447 (2) 9.2553 (3) 8.7218 (4) 1.6020
Sol. Answer (3)
NaOH +

CH3COONa  H2O
CH3COOH
V1 = 50 ml V2 = 50 ml
M1 = 0.1 M M2 = 0.1 M
∵ millimoles of acid = millimoles of base

 pH will be calculated by the hydrolysis of salt (weak acid and strong base)
1 1
 pH 
7  pK a  logC
2 2
1 1 ⎡ 5 ⎤
pH  7   4.7447  log5  102 ⎢C  100 ⎥
2 2 ⎣ ⎦
pH 
7  2.37  0.65 [log5 = 0.6990]
= 8.72
3. 1 mole of CH3COOH is dissolved in water to form 1 litre aqueous solution. The pH of resulting solution will
be
(1) 9.2253 (2) 2.3723 (3) 14 (4) 7
Sol. Answer (2)
1
[CH3COOH] = = 1 mole/L
1
1 1 1
pH = (pK a 
– logC) (4.7447  log1.0)  4.7447
2 2 2
pH = 2.3723
Comprehension - III
pH is the negative logarithm of H+.
pH = – log[H+]
HCl  H+ + Cl–

H  OH
H2O
KW = [H+] [OH–]
KW depend on the temperature. With rise in temperature KW increases.
At 298 K, pH of pure water = 7
1. At 373 K, pH of the pure water is

(1) 7 (2) >7 (3) <7 (4) Cannot be stated
Sol. Answer (3)
KW = 10–13 at 373 K
2. The concentration of H+ in 10–1 M HCl given by
Kw
(1) 10–1 + 10–8 (2) 10 1  (3) 10–1 (4) 10–1 – 10–7
10 1
Sol. Answer (3)
3. The pH at first equivalence of H3PO4 vs NaOH titration at 298 K will be
3 8

(for H3PO4, K a 
10 , Ka 
10 , Ka 10 11 )
1 2 3
(1) 7 (2) >7
(3) < 7 (4) Depend on the concentration of titrant
Sol. Answer (3)
pH is less than 7.
Comprehension - IV
When 100 mL of 1.0 M HCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a
temperature increase of 5.7 °C was measured for the beaker and its contents (Expt. 1). Because the enthalpy of
neutralization of a strong acid with a strong base is a constant (–57.0 kJ mol–1), this experiment could be used to
measure the calorimeter constant. In a second experiment (Expt. 2), 100 mL of 2.0 M acetic acid (Ka = 2.0 × 10–5)
was mixed with 100 mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise of 5.6 °C was
measured. (Consider heat capacity of all solutions as 4.2 J g–1 K–1 and density of all solutions as 1.0 g mL–1)
[JEE(Advanced)-2015]
1. Enthalpy of dissociation (in kJ mol–1) of acetic acid obtained from the Expt.2 is
(1) 1.0 (2) 10.0 (3) 24.5 (4) 51.4

Sol. Answer (1)
Exp-I
Energy released = 5.7 kJ
Heat absorber by temperature rise = 200 × 4.2 × 5.7 = 2 × 42 × 57 = 4.788 kJ
Calorimetric constant = 5.7 – 4.788 = 0.912 J
Exp-II
Q = 200 × 4.2 × 5.6 = 4.704 kJ
Net energy = 4.704 + 0.912 = 5.616 kJ
Per mole of neutralization energy released = 56.16 kJ
Dissociation energy = 57 – 56.16 = 0.84 kJ  1kJ
2. The pH of the solution after Expt. 2 is
(1) 2.8 (2) 4.7 (3) 5.0 (4) 7.0
Sol. Answer (2)

Buffer is formed
⎡CH3COO  ⎤
pH pK a  log ⎣
 ⎦
⎡⎣CH3COOH⎤⎦
As per given question concentration of CH3COO– and CH3COOH is equal.
pH = pKa
= –log2 + 5
= 4.7
Comprehension - V
Thermal decomposition of gaseous X2 to gaseous X at 298 K takes place according to the following equation:

X2(g)
2X(g)
The standard reaction Gibbs energy, rG°, of this reaction is positive. At the start of the reaction, there is one mole
of X2 and no X. As thereaction proceeds, the number of moles of X formed is given by . Thus, equilibrium is the
number of moles of X formed at equilibrium. The reaction is carried out at a constant total pressure of 2 bar. Consider
the gases to behave ideally. (Given : R = 0.083 L bar K–1 mol–1) [JEE(Advanced)-2016]
1. The equilibrium constant Kp for this reaction at 298 K, in terms of equilibrium, is
8β2equilibrium 8β2equilibrium 4β2equilibrium 4β2equilibrium

(1) (2) 4 − β2equilibrium (3) 2 − β equilibrium (4) 4 − β2equilibrium
2 − βequilibrium
Sol. Answer (2)

X2(g)

2X(g)
Initial mole: 1 0
⎛ βeqbm ⎞
moles at equilibrium : ⎜⎝1 − ⎟ eqbm
2 ⎠
βeqbm
1− βeqbm
2 ×P P
Partial pressure : ⎛ βeqbm ⎞ ⎛ βeqbm ⎞
⎜⎝1 + ⎟ ⎜⎝1 + ⎟
2 ⎠ 2 ⎠
(Px )2 β2eqbmP
 Kp = =
Px2 ⎛ β2eqbm ⎞
1−
⎝⎜ 4 ⎠
⎟
4β2eqbm × P
 Kp =
(4 − β 2
eqbm )
Since P = 2 bar
8β2eqbm
So, K p =
(4 − β 2
eqbm )
2. The INCORRECT statement among the following, for this reaction, is
(1) Decrease in the total pressure will result in formation of more moles of gaseous X
(2) At the start of the reaction, dissociation of gaseous X2 takes place spontaneously
(3) equilibrium = 0.7
(4) KC < 1
Sol. Answer (3)
Since, G°, is positive
It means Kp < 1.
Kp = –2.303 RT log Kp.
So, eqbm = 0.7
8 × (0.7)2
Kp = >1 Hence eqbm  0.7
4 − (0.7)2
SECTION - D
Assertion-Reason Type Questions
1. STATEMENT-1 : For a given reaction at fixed temperatures, equilibrium constants Kp and Kc are related as
Kp = Kc(RT)n.
and
STATEMENT-2 : n = No. of moles of products — No. of moles of reactants.
Sol. Answer (3)
n = No. of moles of gaseous products – no. of moles of gaseous reactants
and Kp = Kc (RT)n
2. STATEMENT-1 : Equilibrium constant does not depend upon concentration of various reactants, presence of
catalyst, direction from which equilibrium is reached.
and
STATEMENT-2 : Equilibrium constant is only dependent upon the temperature.
Sol. Answer (2)
K Ho ⎡ 1 1⎤
log 2
 ⎢  ⎥
K1 2.303R ⎣ T1 T2 ⎦
Equilibrium constant is the ratio of conc. Of products and reactants. Hence, it does not depend upon factors
such as concentration, catalyst etc. It only depends upon temperature.
3. STATEMENT-1 : The pKa of weak acid becomes equal to pH of the solution at the mid point of its titration.
and
STATEMENT-2 : The molar concentration of proton aceptor and proton donor becomes equal at mid point of
a weak acid.
Sol. Answer (1)
[Salt]

pH pK a  log
[Acid]
At mid point
[Salt] = [Acid]
 pH = pKa
4. STATEMENT-1 : When a small amount of strong acid is added to a buffer solution, its pH value does not
change significantly.
and
STATEMENT-2 : Buffer action of the buffer solution resist the change in pH when small amount of acid is added to it.
Sol. Answer (1)
pH does not change with small amount of acid in buffer solution.
5. STATEMENT-1 : pH of water decreases with increase in temperature.

and
STATEMENT-2 : Kw of water decreases with increase in temperature.
Sol. Answer (3)

With increase in temperature, [H+] increases
 pH decreases. And Kw increases with increase in temperature.
6. STATEMENT-1 : It is difficult to distinguish between the strengths of the strong acids like HCl, HNO3, HClO4
etc. in dilute aqueous solution.
and
STATEMENT-2 : In dilute aqueous solution, all strong acids donate a proton to water and are essentially 100%
ionised to produce a solution containing H3O+ ions plus the anions of strong acid.
Sol. Answer (1)
For strong acids in aqueous solution
  100%
Ka 
 It is difficult to determine Ka value of acid.
7. STATEMENT-1 : Solubility of BaSO4 in 0.1 M Na2SO4 is 10–9 M hence its Ksp is 10–18.
and
STATEMENT-2 : In aqueous solution, solubility product of BaSO4 = S2. (Where S is solubility of BaSO4).
Sol. Answer (4)

2 2
Ba  SO4
BaSO4
S (S  0.1)
S = 10–9
 Ksp = [Ba2+] [SO42–]
= 10–9 × (0.1 + 10–9)
Ksp = 10–9 × 0.1 [0.1  109 ~ 0.1]
Ksp = 10–10
And Ksp(BaSO4) = S2 (in aqueous solution)
8.

CaO(s)  CO2 (g) , for given equilibrium Kp = pCO2.
STATEMENT-1 : CaCO3 (s)
and
STATEMENT-2 : If we add CaCO3, equilibrium will shift in forward direction.
Sol. Answer (3)
Solid have no effect.
9.

STATEMENT-1 : For H2 O(l)
H2 O(g) , vapour pressure is P atm then Kp is equal to vapour pressure.
and
STATEMENT-2 : Kp can be changed by adding more H2O vapour from out side.
Sol. Answer (3)
Kp is independent from pressure.

AB(g)  B(g) , Kp is always greater than Kc.
10. STATEMENT-1 : For a hypothetical equilibrium, AB2 (g)
and
ng
STATEMENT-2 : Relation of Kp and Kc will be K p  K c (RT) .
Sol. Answer (4)
At different temperature relation may be varied.
11. STATEMENT-1 : Buffer capacity is maximum when concentration of salt is equal concentration of acid.
and
[salt]
STATEMENT-2 : pH of the buffer is given by 
pH pK a  log .
[acid]
Sol. Answer (2)
12. STATEMENT-1 : HCl is a strong acid and true electrolyte.

and
STATEMENT-2 : Liquid HCl is bad conductor of electricity.
Sol. Answer (4)
HCl = Potential electrolyte
13. STATEMENT-1 : For every chemical reaction at equilibrium, standard Gibbs energy of reaction is zero.
and
STATEMENT-2 : At constant temperature and pressure, chemical reactions are spontaneous in the direction of
decreasing Gibbs energy. [IIT-JEE 2008]
Sol. Answer (4)
G = G° + RT ln Q
at equilibrium
G = 0
Q = Keq
 G° = –RT ln Keq
SECTION - E
Matrix-Match Type Questions
1. Match Column-I with Column-II.

Column-I Column-II
(A) N2 (g) + 3H2 (g) 2NH3 (g) (p) ng > 0
(B) PCl5 (g) PCl3 (g) + Cl2 (g) (q) Kp < Kc
(C) 2SO3(g) 2SO2(g) + O2(g) (r) Kp not defined
(D) CH3COOC2H5 (l) + H2O (l) (s) Kp > Kc

CH3COOH (l) + C2H5OH (l)
(assume temperature = 25°C)
Sol. Answer A(q), B(p, s), C(p, s), D(r)

(A) N2 (g)  3H2 (g)
2NH3 (g)
n = 2 – 4 = – 2
 Kp = Kc (RT)n = Kc (RT)–2
Kc
Kp 
RT
 Kc > Kp

PCl3 (g)  Cl2 (g)
(B) PCL5 (g)
n = 2 – 1 = 1
n > 0
 Kp > Kc

2SO2 (g)  O2 (g)
(C) 2SO3 (g)
n = 1
 n > 0
 Kp > Kc
(D) Kp is only defined for gaseous systems.
2. Match Column I with Column II
Column-I Column-II
(A) 25 ml of 0.1 M NaOH + 50 ml of (p) Basic buffer

0.1 M CH3COOH
(B) 25 ml of 0.1 M NaOH + 25 ml of 0.1 M HCl (q) Acidic buffer
(C) 25 ml of 0.1 M HCl + 50 ml of 0.1 M NH4OH (r) pH > 7
(D) 25 ml of 0.1 M NH4OH + 25 ml of (s) pH = 7

0.1 M CH3COOH
Given (Ka = Kb)

Sol. Answer A(q), B(s), C(p, r), D(s)
(A) Solution of weak acid and strong base.
(B) It will form salt of strong acid and strong base.
 pH = 7
(C) It is the solution weak base and strong acid.
 It will be basic buffer and pH > 7.
(D) ∵ Ka = Kb
 pH = 7 = pOH
3. Match the following
Column I Column II
(A) NaH2PO4 + Na2HPO4 (p) Buffer system
M M
(B) 100 ml Aniline  100 ml H2SO4 (q) pH < 7
10 5
M M
(C) 100 ml CH3 COOH  100 ml NaOH (r) pH changes on dilution
10 10
M M
(D) 100 ml H2C2O4  100 ml KOH (s) Salt hydrolysis occurs
10 5
(t) pH > 7
Sol. Answer A(p, q, s), B(q, r, s), C(r, s, t), D(r, s, t)
Mixture of salt of weak acid with strong base and weak acid form buffer. NaH2PO4 and Na2HPO4 form an acidic
buffer.
pH of buffer does not change with dilution, while pH of other acid or base change with dilution.
SECTION - F
Integer Answer Type Questions
1. Equal volumes of solution with pH = 6 and pH = 8 are mixed. What will be the pH of resulting mixture?
Sol. Answer (7)
pH = 6,  [H+] = 10–6
pH = 8,  [OH–] = 10–6
Hence complete neutralization and neutral solution is formed, so pH = 7.
2. In Homogeneous gaseous equilibrium, M  g  3N  g 4P  g . Initial concentration of M is equal to that of N.

If equilibrium concentrations of M and P are equal then what will be the value of KC?
Sol. Answer (8)
M(g)  3N(g)

4P(g)

Initially a a
ax a  3x 4x
Given 
a  x 4x 
or a 5x or x a
5
4
P4
 4x 

Hence: Kc   8
MN3
 a  x  a  3x 3
3. Ka for a monobasic organic acid is 2 × 10–5. What is pH of 0.2 M aqueous solution of its salt formed with KOH?
Sol. Answer (9)
HA + KOH  KA + H2O
Salt of WA + SB
pK a  logc
pH 
7 
9
2
4. For equilibrium NH4 COONH2  s 2NH3  g  CO2  g , equilibrium pressure is 3 atm. What will be the value
of Kp?
Sol. Answer (4)
NH4 COONH2  s  2NH3  g   CO  g
Kp = p(NH3)2 . (pCO2)
2 1
pNH3   3  2 atm. pCO2   3  1 atm.
3 3
Now K
p
 2 2 
1 4 atm
5. Find the pH of a buffer solution having equal volumes of 0.2 M NH4OH and 0.2 M NH4Cl
(Kb for base = 1.0 × 10–5).
Sol. Answer (9)
For basic buffer,
⎡ conj. acid  ⎤⎦
pK b  log ⎣
0.2
pOH  
5  log
Base 0.2
Hence pH = 14 – pOH = 14 – 5 = 9
6. The dissociation constant of a substituted benzoic acid at 25°C is 1.0 × 10–4. The pH of a 0.01 M solution of
its sodium salt is [IIT-JEE 2009]
Sol. Answer (8)
pK a 4 2
pH = 7   log C = 7   
8
2 2 2
7. Amongst the following, the total number of compounds whose aqueous solution turns red litmus paper blue is
[IIT-JEE-2010]
KCN K2SO4 (NH4)2C2O4 NaCl Zn(NO3)2
FeCl3 K2CO3 NH4NO3 LiCN
Sol. Answer (3)
In basic medium, red litmus paper turn blue.
(1) CN  H2O

HCN  OH
 (2) CO32  H2 O


HCO3  OH

(3) CN  H2O

HCN  OH

8. In 1 L saturated solution of AgCl [KSP(AgCl) = 1.6 × 10–10], 0.1 mol of CuCl [KSP(CuCl) = 1.0 × 10–6] is added.
The resultant concentration of Ag+ in the solution is 1.6 × 10–x. The value of "x" is. [IIT-JEE 2011]
Sol. Answer (7)
 Ag  Cl
AgCl 
x xy
K sp1 = 1.6 × 10–10 = x(x + y) …(i)
 Cu  Cl
CuCl 
y yx
K sp2 
1 10 –6 
y(x  y) ...(ii)
From equation (i) and (ii),
K sp1 x
1.6  10 –4  ...(iii)
K sp2 y
 x = 1.6 × 10–4 y
 K sp1 1.6  10 –10 1.6  10 –4 y(1.6  10 –4 y  y)
 10–6 = y2(1.6 × 10–4 + 1)

 y = 10–3  x = 1.6 × 10–7
 [Ag+] = x = 1.6 × 10–7
9. MX2 dissociates into M2+ and X– ions in an aqueous solution, with a degree of dissociation () of 0.5. The ratio
of the observed depression of freezing point of the aqueous solution to the value of the depression of freezing
point in the absence of ionic dissociation is [JEE(Advanced)-2014]
Sol. Answer (2)
 = 0.5
2
MX2

M
 2X
(1   )  2
1      2
i
1
i = 1 + 2
i = 1 + 2 × 0.5 = 2
SECTION - G
Multiple True-False Type Questions
1. STATEMENT-1 : pH of water at 25°C is less than the pH at 4°C.
STATEMENT-2 : Water is more acidic at 25°C than at 4°C.
STATEMENT-3 : Water is neutral at all temperatures
(1) T F T (2) F F T (3) F T T (4) T T F
Sol. Answer (1)
Kw  temperature
pH scale varies with Kw and hence with temperature.
2. STATEMENT-1 : Autoprotolysis constant of water increases with the increase in temperature.

STATEMENT-2 : When a solution of a weak monobasic acid is titrated with a strong base, at half neutralization
point pH = pKa + 1.
STATEMENT-3 :The pH of 10–8 M HCl is 8.
(1) F F T (2) T F F (3) F T T (4) T T T
Sol. Answer (2)
3. STATEMENT-1 : Net reaction can occur only if a system is in equilibrium.

STATEMENT-2 : All reaction tends to be in a state of equilibrium.
STATEMENT-3 : At equilibrium, G is zero.
(1) T T F (2) FTT (3) TT T (4) FT F
Sol. Answer (3)
Fact
4. STATEMENT-1 : Catalyst change the activation energy.

STATEMENT-2 : Catalyst can change equilibrium.
STATEMENT-3 : Kp is temperature dependent.
(1) T F T (2) FTT (3) F FT (4) T T T
Sol. Answer (1)
Catalyst can change the activation energy but cannot change equilibrium constant.
SECTION - H
Aakash Challengers Questions
1. The exact concentration of H+ ion in 10–3 molar HCl aq. solution at 298 K is
Kw Kw
(1) 10–3 + 10–7 (2) 103  (3) 103  (4) 10–3
[H ] [OH ]
Sol. Answer (2)
H+ comes from acid and water.
2. In ammonia formation process, due to increase in pressure, equilibrium will shift in

(1) Forward direction (2) Backward direction
(3) No effect (4) May be forward or in backward direction
Sol. Answer (1)
3. 4 mole of N2O4 is taken in container of unit volume at any temperature. After some time, equilibrium is attained
and vapour density of mixture is 34.5. The value of G will be
(1) Zero (2) 9.2 kcal
(3) 50 kcal (4) Data is insufficient to calculate
Sol. Answer (1)
G  RT lnK
[NO2 ]2
K
[N2 O 4 ]
Here K = 1
4. Which of the following pH curve represent the titration of weak acid and strong base (dotted line show
equivalence point)?
pH pH
pH pH
7
7 7 7
(1) 2) (3) (4)

Volume of Volume of
NaOH added NaOH added Volume of
Volume of
NaOH added NaOH added
Sol. Answer (2)
At equivalence point, pH will be more than 7 due to salt hydrolysis.
5. Which of the following equilibrium will shift in forward direction on increasing pressure?

(1) S(solid)
S(Liquid) (2)

H2O(Ice)
H2O(l)

(3) Ga(s)
Ga(liquid) (4) Both (2) & (3)
Sol. Answer (4)

Due to rise in pressure equilibrium will shift to that direction in which volume is less.
6.

The equilibrium constant of given reaction will be HCO3  H2 O
H2 CO3  OH
Kw Kw Kw
(1) K (2) K a1 (3) K a2 (4) K w K a1
a1
Sol. Answer (1)

These equilibrium constant values are given

H  HCO3
H2 CO3 K a1

HCO3
CO32  H K a2

H  OH
H2O Kw
On subtracting (2) from (1)
H2O
+
H + OH
–
Kw (1)
– H2CO3 –
HCO3 + H
+
K a1 (2)
–
HCO3 + H2O H2CO3 + OH–
Kw
 Required equilibrium constant is
K a1
7. Ammonium hydrogen sulphide dissociated according to the equation:

NH4HS(s) NH3(g) + H2S(g)
If observed pressure of the mixture is 1.12 atm at 106ºC, what is the equilibrium constant Kp of the reaction?

NH3 (g)  H2S(g)
Sol. NH4HS(s)
P P
2P = 1.12
P = 0.56 atm
Kp = P2 = 0.562 = 0.3136 atm2
8. The density of an equilibrium mixture of N2O4 and NO2 at 1 atm and 348 K is 1.84 g/dm3. Calculate the
equilibrium constant Kp of the reaction.
N2O4(g) 2NO2(g)

Sol. N2O4
2NO2
1 0
1  2
n  1 
P.M. 1 Mmix
d   1.84
RT 0.0821 348
 Mmix = 52.57
Now, (1 + ) × 52.57 = 92 (From law of conservation of mass)
 1 +  = 1.75
  = 0.75
⎛ 1  ⎞
PN
2O4 ⎜ 1  
⎟  1 0.143 atm
⎝ ⎠
⎛ 2 ⎞
P
NO2 ⎜ 1  
⎟  1 0.857 atm
⎝ ⎠
2
PNO 0.8572
2

Kp   5.14 atm
PN2O4 0.143
9. 15 g sample of BaO2 is heated to 794ºC in a closed evacuated vessel of 5 litre capacity. How many g of
peroxide are converted to BaO(s)?
2BaO2(s) 2BaO(s) + O2(g), Kp = 0.5 atm

2BaO(s)  O2 (g)
Sol. 2BaO2 Kp = 0.5 atm
PO2  0.5 atm
PV 0.5  5

n   0.0285 mole
RT 0.0821 1067
nBaO2 reacted = 0.0285 × 2 = 0.057
WBaO2 reacted = 0.057 × (137 + 32) = 9.633 g
10. Calculate the pH at equivalence point of the titration between 0.1 M CH3COOH (25 ml) with 0.05 M NaOH.
Ka for CH3COOH = 1.8 × 10–5.
Sol. M eq. of CH3COONa formed = 0.1 × 25 [CH3 COOH  NaOH  CH3 COONa  H2O]
0.125 0.0550 0.125
0.1 25
Concentration = = 0.033 M
75
1 1
pH 
7  pK a  logC (for salt of W.A + SB)
2 2
1 1
= 7  4.74  log0.033 = 8.63
2 2
11. Calculate change in pH of 1 L buffer solution containing 0.10 Mole each of NH3 and NH4Cl upon addition of
(i) 0.02 mole of dissolved gaseous HCl.
(ii) 0.02 mole of dissolved NaOH. (Assuming volume to be constant). Kb(NH3) = 1.8 × 10–5
Sol. (i) NH3 + HCl  NH4Cl
0.1 0.02 0.02
–0.02
Net NH4Cl = 0.1 + 0.02 = 0.12
Net NH3 = 0.08
[salt] 0.12

pH log  log  0.1761
[base] 0.08
(ii) Same as above, pH = 0.1761
12. Two solid compounds A and B dissociate into gaseous products at 20ºC as
(i) A (s) A (g) + H2S (g)
(ii) B (s) B (g) + H2S (g)

At 20ºC, pressure over excess solid A is 50 mm and that over excess solid B is 68 mm of Hg. Find
(a) The dissociation constant of A and B.
(b) Relative number of moles of A and B in the vapour phase over a mixture of solid A and B at 20ºC.
(c) Show that the total pressure of gas over the solid mixture would be 84.4 mm of Hg.

Sol. (a) A(s)

A '(g)  H2S(g) and B(s)
B'(g)  H2S(g)
50 = PA’ + PH2S and 68 = PB'  PH2S
∵ PA'  PH2S  KpA  (25)2 & KpB  (34)2 = 625 mm2 = 1156 mm2
(b) Kp
A
x(x  y) and Kp
B
y(x  y)
KpA x x 625 n'A

     0.5407
K pB y , y 1156 n'
B
x and y = 14.81 and 27.38 mm
(c) PT = P’A + P’B + P'H2S = x + y + (x + y) = 84.38 mm
13. The solubility product of Ca(OH)2 at 25ºC is 4.42 × 10–5 mole3 litre–3. A 500 ml of saturated solution of Ca(OH)2
is mixed with equal volume of 0.4 M NaOH solution. How much Ca(OH)2 in milligrams is precipitated?
Sol. K sp (Ca(OH)2 ) = 4.42 × 10–5 mol3l–3
For a saturated solution, 4s3 = 4.42 × 10–5
s = 2.23 × 10–2 = 0.0223 M = [Ca+2]
[OH–] = 2s = 0.0446 M
500  0.0446  500  0.4 

Now,  [OH  ]new 0.2223
1000
[Ca2 ][OH ]new
 4.42  10 5
2
[Ca2+]remaining= 8.94 × 10–4
500
[Ca2+]original = 0.0223   111.5  104
1000
 pptd = 111.5 × 10–4 – 8.94 × 10–4 = 102.46 × 10–4
MW [Ca(OH)2] = 74
wt. in mg = 102.46 × 10–4 × 74 × 103 = 758.2 mg
14. The pH of blood stream is maintained by a proper balance of H2CO3 and NaHCO3 concentrations. What volume
of 5 M NaHCO3 solution, should be mixed with 10 ml sample of blood, which is 2 M in H2CO3 in order to
maintain a pH of 7.4? Ka for H2CO3 in blood is = 7.8 × 10–7.

 
H  HCO3
Sol. H2CO3
[H ][HCO3  ]
ka 
[H2CO3 ]
[HCO3 ]

pH pk a  log
[H2CO3 ]
⎛ 5V ⎞
7.4 
7  log7.8  log ⎜ ⎟
⎝ 20 ⎠
 V = 78.37 mL
15. The solubility product of BaSO4 and BaCrO4 at 25ºC are 1 × 10–10 and 2.4 × 10–10 respectively. Calculate the
simultaneous solubilities of BaSO4 and BaCrO4.
Sol. Solubility of BaSO4 = x
Solubility of BaCrO4 = y
(x + y).x = 10–10
(x + y).y = 2.4 × 10–10
 y = 2.4 x
 (x + 2.4x) .x = 10–10
3.4x2 = 10–10
 x = 5.42 × 10–6 M
y = 1.3 × 10–5 M


Cls Jeead-17-18 Xi Che Target-2 Set-2 Chapter-7

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Cls Jeead-17-18 Xi Che Target-2 Set-2 Chapter-7

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Chapter 7

(1) A + B C; K = 104 (2) X+Y Z; K = 10–3

(3) P + Q R; K=1 (4) M+N O + P; K = 10–1

2. At constant pressure, the addition of argon in Haber's process

3. Consider the general hypothetical reaction

A(s) 2B(g) + 3C(g)

6. For the equilibrium

CO + H2O CO2 + H2.

The relation between Kp and Kc at 25ºC and at 100ºC are

(1) Kp = Kc, Kp = Kc (2) Kp = Kc(RT)–1, Kp = Kc

(3) Kp = Kc(RT), Kp = Kc (RT) (4) Kp = Kc(RT), Kp = Kc

2SO2(g)+O2(g) 2SO3(g) at 1000 K is 3.5 atm–1

9. For the equilibrium H2O(s) H2O(l)

(1) The pressure changes do not effect the equilibrium

(3) More of liquid freezes, if pressure on the system is increased

10. Conjugate acid of PO4–3 is

Smaller the value of Ka, more will be pH.

Sol. Answer (2)

20. pH of Ba(OH)2 solution is 12. Its solubility product is

1. The following reaction attains equilibrium at high temperature

N2(g) + 2H2O (g) + heat 2NO (g) + 2H2 (g)

The concentration of NO(g) is affected by

(3) Compressing the reaction mixture (4) Addition of catalyst

Sol. Answer (1, 2, 3)

Sol. Answer (3, 4)

In the following reaction

Sol. Answer (1, 3, 4)

4. Which of the following solutions will have no effect on pH on dilution?

(3) 1 M CH3COONH4 (4) 0.1 M CH3COONa

5. Which of the following is correct about the equilibrium?

(1) Catalyst has no effect on equilibrium state

(2) Keq changes with temperature

(3) Value of Keq changes by increasing concentration of equilibrium

6. Which of the following statements are correct?

(1) The pH of 1.0 × 10–8 M solution of HCl is 8

(2) The conjugate base of H2PO4– is HPO4–2

(3) Auto-protolysis constant of water increases with temperature

In water, on increase in temperature it produces more H+ ions.

10. Which of the following solution will have pH close to 7?

10–2 = 10–2 2 = 10–1 (1 – )

(1) HNO3 and CH3COOH (2) KOH and CH3COONa

(3) HNO3 and CH3COONa (4) CH3COOH and CH3COONa

For this equilibrium, the correct statement(s) is(are)

(2) K is independent of the initial amount of CaCO3

(3) K is dependent on the pressure of CO2 at a given T

(4) H is independent of catalyst, if any

K is only dependent on temperature and it is independent of the amount of reactant or product.

Sol. Answer (1)

(i) Salt of weak acid and strong base

(ii) Salt of weak base and strong acid

Choose the correct answer :

1. When 50 ml of 0.1 M NH4OH is added to 50 ml of 0.05 M HCl solution, the pH is nearly

2. When 50 ml of 0.1 M NaOH is added to 50 ml of 0.1 M CH3COOH solution, the pH will be

∵ millimoles of acid = millimoles of base

1. At 373 K, pH of the pure water is

2. The concentration of H+ in 10–1 M HCl given by

(1) 7 (2) >7

(3) < 7 (4) Depend on the concentration of titrant

Sol. Answer (3)

(1) 1.0 (2) 10.0 (3) 24.5 (4) 51.4

Dissociation energy = 57 – 56.16 = 0.84 kJ  1kJ

2. The pH of the solution after Expt. 2 is

(1) 2.8 (2) 4.7 (3) 5.0 (4) 7.0