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Article history: In this paper, thermal energy analysis of three zones of a lime production process, which are preheater,
Received 22 September 2015 rotary kiln and cooler, is performed. In order to perform a proper quantitative estimation, the system was
Accepted 7 February 2016 modeled using energy balance equations including coupled heat transfer and chemical reaction mecha-
Available online 17 February 2016
nisms. A mathematical model was developed, and consequently, the thermal and chemical behavior of
limestone was investigated. The model was verified using empirical data. After model confirmation,
Keywords: the variation of Specific Fuel Consumption (SFC) versus production rate was predicted and the optimum
Rotary kiln
condition was determined. Subsequently, fuel consumption was calculated regarding to altered residence
Lime production process
Mathematical modeling
time inside each zone of lime production process, for a constant output. Results indicate that increasing
Thermal efficiency the residence time inside each zone of lime production process, will enhance thermal efficiency and saves
Residence time fuel consumption. Relative enhancement will be the same for different sizes of limestone. It was found
Fuel saving that a 10-min increase in material residence time inside the preheater or rotary kiln can reduce fuel con-
sumption by around two percent. Whereas, a 5-min increase in material residence time inside the cooler
would be enough to obtain a similar result. Finally, the ratio of air-to-fuel and production rate are chan-
ged in such a way that the same product is achieved. The model predicts that lowering excess air from
15% to 10% leads to a 2.5% reduction of Specific Fuel Consumption (SFC).
Ó 2016 Elsevier Ltd. All rights reserved.
1. Introduction a dry type cement rotary kiln using empirical data. They analyzed
all three parts (rotary kiln, preheater and cooler) [24]. Mujumdar
Determining the more important parameters and their impact et al. presented the integrated model for cement rotary kiln, cal-
on energy efficiency can play a key role in thermal management ciner, cooler and preheater, and developed a simulation software
and fuel consumption reduction of any heating process. Nowadays, titled RoCKS [25]. However, they did not make any comparisons
mathematical modeling is a widespread method for studying the with experimental data. Söğüt et al. performed an exergy analysis
thermal behavior of industrial furnaces, and finding ways to reduce on the cement production line [26]. In most recent work, Liu et al.
their energy consumption. Examples of related works with this presented the energy flow model for the cement clinker manufac-
approach could be found in Refs. [1–11]. turing process [27].
A rotary kiln is a type of industrial furnace with applications in In this paper, a specific integrated model is developed for the
steel, cement, incineration and chemical industries. It is also the lime production unit at Mobarakeh Steel Complex (MSC), Iran.
prevalent type of kiln in the lime production process. Numerous For this process, the heat transfer and calcination reaction phe-
investigations have focused on the mathematical modeling of this nomena have been simulated using 1D thermochemical equations
type kiln; however, most of them have only modeled the rotary in rotary kiln, preheater and cooler. Integrated modeling helps us
kiln section regardless of its up- and down-stream sections to consider the effects of upstream and downstream sections in
[12–23]. However, the effects of the cooler and preheater, which the thermal efficiency of the process. Comparing calculated values
have been employed in more modern installations, have seldom from model and experimental measurements proves the suitable
been studied [23–26]. Engin and Ari investigated energy audit in accuracy of the model. In the results section, first, the effect of
limestone feed rate on SFC is studied. Next, the effects of material
residence time inside preheater, rotary kiln and cooler on fuel con-
⇑ Corresponding author at: Isfahan University of Technology, Isfahan
sumption are investigated. Finally, the effect of air-to-fuel ratio on
84156-83111, Iran.
E-mail address: h.shahin@me.iut.ac.ir (H. Shahin).
http://dx.doi.org/10.1016/j.enconman.2016.02.017
0196-8904/Ó 2016 Elsevier Ltd. All rights reserved.
H. Shahin et al. / Energy Conversion and Management 114 (2016) 110–121 111
Nomenclature
Material inlet
Preheater
Rotary kiln
Primary air
& Fuel
Secondary
air
Cooler
specific energy consumption of the lime production process is radiative modes, and after reaching calcination temperature, it will
estimated. be decomposed to lime (CaO) and carbon di-oxide (CO2). The ther-
mal energy produced by a natural gas burner is mainly consumed
in the calcination reaction. Reaching the outlet of the rotary kiln,
2. Process description the material is discharged into the cooler where lime is cooled
and the secondary air is preheated.
As shown in Fig. 1, the MSC lime production process consists of
three zones, preheater, rotary kiln and cooler. Table 1
Limestone (CaCO3) is charged into the preheater and heated Operating condition.
with the counter current combustion products. Then, preheated
Limestone feed rate (ton/h) 34
materials enter the rotary kiln. Rotation of the cylindrical kiln Final calcination (%) 95
and its inclination forces the materials to move slowly with homo- Secondary air flow rate (Nm3/h) 20,000
geneous temperature to the kiln outlet. A gas burner resides at the Primary air flow rate (Nm3/h) 4000
end of the rotary kiln. Limestone absorbs heat by convective and Fuel (NG) flow rate (Nm3/h) 2340
Fuel heat value (kJ/Nm3) 36,000
Preheater capacity (ton) 70
Kiln inclination (%) 2.5
Kiln rotational speed (rpm) 1.5
Inner kiln diameter (m) 3.1
Outer kiln diameter (m) 3.75
Kiln length (m) 38
Cooler capacity (ton) 11.7
Calcination temperature (°C) 750
Specific Fuel Consumption (SFC) (Nm3/h) 68.82
Particle size (mm) 30
Table 2
Model validation.
Fig. 3. Heat transfer mechanisms in the rotary kiln (Q1 = heat from flame to
exposed bed, Q2 = heat from flame to exposed wall, Q3 = heat from exposed wall to
exposed bed, Q4 = heat from freeboard gas to exposed bed, Q5 = heat from exposed
gas to exposed wall, Q6 = heat from covered wall to covered bed, Q7 = heat loss to
surroundings). Fig. 4. The rotary kiln solution algorithm in each element.
H. Shahin et al. / Energy Conversion and Management 114 (2016) 110–121 113
Fig. 6. The pie diagram of the energy balance for the control volume.
114 H. Shahin et al. / Energy Conversion and Management 114 (2016) 110–121
4
hg;b ¼ ðeg eb Þrð T g ðT Þ Þ=ðT g T Þ
4
ð4Þ
Part of the heat which is radiated to inner wall is conducted in
axial and radial directions. The radial conduction heat transfer is
calculated by Eq. (5) [30].
dQ l ¼ ðT w;out T w;in Þ lnðDout =Din Þ=ð2pkeff dxÞ ð5Þ
The other part of heat is transferred to bed with radiation, and
contact heat transfer. The radiation and contact heat transfer coef-
ficient from the inner wall to bed are calculated by Eqs. (6) and (7)
Fig. 7. Axial (a) temperature profile of gas and material and (b) calcination respectively [29,31].
percentage in rotary kiln.
hw;b;rad ¼ ew ð1 eg Þeb ððT w Þ4 ðT b Þ4 Þ=ðT w T b Þ ð6Þ
h i1=2
wall by radiation and convection. In an industrial furnace the con- hw;b;cnt ¼ 1:13 keq qeq C eq =t ð7Þ
vection heat transfer could be neglected in comparison with the
radiation heat transfer if its temperature is high enough [28]. Fur- The radial conduction heat in wall of rotary kiln is transferred to
thermore, due to bed reaction, the CO2 is produced, and is added to ambient with radiation, and free convection heat transfer. The
combustion gas with bed temperature and absorbs heat from com- radiation and free convection heat transfer coefficients are calcu-
bustion gas. Therefore, the energy balance for combustion gas can lated by Eqs. (8) and (9) respectively [32].
be written as Eq. (1) [29]. By solving this ordinary differential
equation the axial variation of combustion gas temperature along hw;a;radi ¼ eShell r T 2w þ T 2a ðT w þ T a Þ ð8Þ
the kiln length is calculated.
F f Q N jf expðjf xÞdx ¼ F f Gg qg cg dT g þ dAx hrad;g ðT g T Þ hw;a;cnv ¼ Nuka =Din
8 ," 9
_ CO2 cCO2 ðT g T b Þ
m ð1Þ < 169 #278 =2
1 0:559
¼ 0:6 þ 0:387 Ra6D 1þ k =D ð9Þ
Here, T is given by, : Pr ; a in
T ¼ vT b þ ð1 vÞT w ð2Þ
H. Shahin et al. / Energy Conversion and Management 114 (2016) 110–121 115
In bed, the received heat increases the material temperature has the various shape and particle size. The volume-based particle
and calcination. When the temperature of material become above size is used in Eq. (12) which is defined as the radius of the sphere
the calcination temperature, reaction is occurred. Consequently, that has the same volume as a given particle.
CO2 gases are produced and blend to combustion gas. Reaction
heat is expressed as Eq. (10) [33] R ¼ ð3v K CaO =ðHCaCO3 qCaCO3 ÞÞ ðT T c Þ=r 2p ð12Þ
Fig. 9. Effect of material feed rate on (a) exhaust gas temperature and (b) outlet
material temperature. Fig. 10. Effect of rotary kiln residence time on (a) fuel flow rate and (b) efficiency.
116 H. Shahin et al. / Energy Conversion and Management 114 (2016) 110–121
where
.
dA ¼ A=Nelement ¼ N particle 4 p r 2p Nelement ð16Þ
and
qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
U ¼ ðNu kÞ=ð2r p Þ ¼ f a 2 þ Nu2lam þ Nu2turb K=ð2r p Þ ð17Þ
. 2
Nuturb ¼ 0:037Re0:8
w Pr 1 þ 2:443Re0:1
w Pr3 1 ð19Þ
Fig. 13. Effect of preheater residence time on (a) preheater exhausted gas
temperature and (b) outlet material temperature. Fig. 14. Effect of preheater residence time on (a) preheater heat recovery and (b)
calcination.
After providing this computer code, the process was simulated 4. Results
under normal operating conditions (see Table 1). To assess the
accuracy of the model, temperatures of outlet material from pre- 4.1. Temperature and calcination profiles
heater, rotary kiln and cooler were measured. Additionally, calcina-
tion of the final product was measured. The results from the model To better study thermal behavior of material through the length
are compared with actual operational data and as can be seen in of the rotary kiln, first, temperature variations and calcination are
Table 2, they are in reasonable agreement. predicted and illustrated in Fig. 7. According to this figure, the
Using the model, the energy balance in the lime production pro- sharp peak of gas temperature in the flame region will result in
cess was also evaluated and related results are depicted in Fig. 6. As more heat absorption in material. After passing the flame region,
shown in this figure, near 70% of fuel burning energy is consumed heat storage in material converted to chemical energy, therefore,
by calcination. Exhaust gases have the major portion of heat loss in a considerable reduction of temperature is observed.
118 H. Shahin et al. / Energy Conversion and Management 114 (2016) 110–121
Fig. 17. Effect of cooler residence time on (a) calcination and (b) outlet material
temperature.
Finally, the effect of excess air is investigated. Excess air is A mathematical model was developed to simulate the MSC lime
defined as the amount of air above the stoichiometric requirement production process, and its results were compared with experi-
for complete combustion [38]. For constant flow rate of fuel and mental data. The following conclusions can be drawn from our
primary air, the flow rate of secondary air is changed to achieve study:
5%, 10%, 15% and 20% excess air. Then, the feed rate of limestone
is adjusted in model to keep the calcination of product unchanged. For each size of limestone, a certain production rate can be
As expected, the lower excess air leads to lower SFC. According to determined with minimum SFC.
Fig. 18, reduction of excess air from 15% to 10% can improve SFC by A 10-min increase in residence time inside the preheater and
2.5%. The higher rate of secondary air leads to more heat recovery rotary kiln will reduce fuel consumption for about 2%.
from the lime product. On the other hand, the temperature and Longer residence time inside the preheater will recover more
flow rate of exhaust gas become larger, hence heat loss is intensi- energy from outlet gases and will use this energy to increase
fied (Fig. 19). Ultimately, this will result in an increased SFC. temperature and calcination percentage of preheated material.
Increasing residence time inside the cooler is more effective
than other zones of the lime production process. For instance,
a 5-min increase in residence time inside the cooler has the
same effect as a 10-min increase in residence time inside the
preheater or rotary kiln: 3% fuel saving.
As expected, excess air can reduce thermal efficiency of the lime
(i.e. its lowering from 15% to 10% will reduce the SFC by 2.5%).
Acknowledgement
References
[1] Kremer H, May F, Wirtz S. The influence of furnace design on the NO formation
in high temperature processes. Energy Convers Manage 2001;42:1937–52.
[2] Tiwari MK, Mukhopadhyay A, Sanyal D. Process modeling for control of a batch
heat treatment furnace with low NOx radiant tube burner. Energy Convers
Manage 2005;46:2093–113.
[3] Sardeshpande V, Gaitonde U, Banerjee R. Model based energy benchmarking
for glass furnace. Energy Convers Manage 2007;48:2718–38.
[4] Chandok J, Kar I, Tuli S. Estimation of furnace exit gas temperature (FEGT)
using optimized radial basis and back-propagation neural networks. Energy
Convers Manage 2008;49:1989–98.
[5] Saboonchi A, Hassanpour S, Abbasi S. New heating schedule in hydrogen
annealing furnace based on process simulation for less energy consumption.
Energy Convers Manage 2008;49:3211–6.
[6] Casanova-Peláez P, Cruz-Peragón F, Palomar-Carnicero J, Dorado R, López-
García R. RBF–ARX model of an industrial furnace for drying olive pomace.
Energy Convers Manage 2012;64:106–12.
[7] Gürtürk M, Oztop HF, Hepbaslı A. Energy and exergy assessments of a perlite
expansion furnace in a plaster plant. Energy Convers Manage 2013;75:488–97.
[8] Gürtürk M, Oztop HF, Hepbasli A. Energy management and environmental
aspects of a high capacity perlite furnace through exergetic analysis. Energy
Convers Manage 2014;82:188–201.
[9] Acevedo L, Usón S, Uche J. Exergy transfer analysis of an aluminum holding
furnace. Energy Convers Manage 2015;89:484–96.
[10] Duan W, Yu Q, Wang K, Qin Q, Hou L, Yao X, et al. ASPEN plus simulation of
coal integrated gasification combined blast furnace slag waste heat recovery
system. Energy Convers Manage 2015;100:30–6.
[11] Swanepoel JA, Mathews EH, Vosloo J, Liebenberg L. Integrated energy
optimisation for the cement industry: a case study perspective. Energy
Convers Manage 2014;78:765–75.
[12] Gorog J, Brimacombe J, Adams T. Radiative heat transfer in rotary kilns. Metall
Trans B 1981;12:55–70.
[13] Barr P, Brimacombe J, Watkinson A. A heat-transfer model for the rotary kiln:
Part II. Development of the cross-section model. Metall Trans B
1989;20:403–19.
[14] Silcox GD, Perching DW. The effects of rotary kiln operating conditions and
design on burden heating rates as determined by a mathematical model of
rotary kiln heat transfer. J Air Waste Manag Assoc 1990;40:337–44.
[15] Bui R, Simard G, Charette A, Kocaefe Y, Perron J. Mathematical modeling of the
rotary coke calcining kiln. Can J Chem Eng 1995;73:534–45.
[16] Boateng A, Barr P. A thermal model for the rotary kiln including heat transfer
within the bed. Int J Heat Mass Transf 1996;39:2131–47.
[17] Mastorakos E, Massias A, Tsakiroglou C, Goussis D, Burganos V, Payatakes A.
Fig. 19. Effect of excess air on (a) exhaust gas temperature and (b) outlet material CFD predictions for cement kilns including flame modelling, heat transfer and
temperature. clinker chemistry. Appl Math Model 1999;23:55–76.
H. Shahin et al. / Energy Conversion and Management 114 (2016) 110–121 121
[18] Yang L, Farouk B. Modeling of solid particle flow and heat transfer in rotary [28] Emadi A, Saboonchi A, Taheri M, Hassanpour S. Heating characteristics of billet
kiln calciners. J Air Waste Manag Assoc 1997;47:1189–96. in a walking hearth type reheating furnace. Appl Therm Eng 2014;63:396–405.
[19] Li SQ, Ma LB, Wan W, Yao Q. A mathematical model of heat transfer in a rotary [29] Kunii D, Chisaki T. Rotary reactor engineering. Elsevier; 2007.
kiln thermo-reactor. Chem Eng Technol 2005;28:1480–9. [30] Bergman TL, Incropera FP, Lavine AS. Fundamentals of heat and mass
[20] Georgallis M, Nowak P, Salcudean M, Gartshore I. Modelling the rotary lime transfer. John Wiley & Sons; 2011.
kiln. Can J Chem Eng 2005;83:212–23. [31] Kunii D, Levenspiel O. Fluidization engineering. Elsevier; 2013.
[21] Mintus F, Hamel S, Krumm W. Wet process rotary cement kilns: modeling and [32] Gesellschaft V, Chemieingenieurwesen V-GVU. VDI heat atlas. Springer Science
simulation. Clean Technol Environ Policy 2006;8:112–22. & Business Media; 2010.
[22] Mujumdar K, Ranade V. Simulation of rotary cement kilns using a one- [33] Georgallis M, Nowak P, Salcudean M, Gartshore I. Mathematical modelling of
dimensional model. Chem Eng Res Des 2006;84:165–77. lime kilns. Pulp Pap Can Ont 2002;103:44–7.
[23] Sadighi S, Shirvani M, Ahmad A. Rotary cement kiln coating estimator: [34] Kemp IC. Comparison of particles motion correlations for cascading rotary
integrated modelling of kiln with shell temperature measurement. Can J Chem dryers. In: Proceedings of the 14th International Drying Symposium (IDS), São
Eng 2011;89:116–25. Paulo, Brazil, B2004. p. 790–7.
[24] Engin T, Ari V. Energy auditing and recovery for dry type cement rotary kiln [35] Sai P, Surender G, Damodaran A, Suresh V, Philip Z, Sankaran K. Residence time
systems––a case study. Energy Convers Manage 2005;46:551–62. distribution and material flow studies in a rotary kiln. Metall Trans B
[25] Mujumdar KS, Ganesh K, Kulkarni SB, Ranade VV. Rotary Cement Kiln 1990;21:1005–11.
Simulator (RoCKS): integrated modeling of pre-heater, calciner, kiln and [36] Liu XY, Specht E. Mean residence time and hold-up of solids in rotary kilns.
clinker cooler. Chem Eng Sci 2007;62:2590–607. Chem Eng Sci 2006;61:5176–81.
[26] Söğüt Z, Oktay Z, Karakoç H. Mathematical modeling of heat recovery from a [37] Antony SJ, Hoyle W, Ding Y. Granular materials: fundamentals and
rotary kiln. Appl Therm Eng 2010;30:817–25. applications. Royal Society of Chemistry; 2004.
[27] Liu Z, Wang Z, Yuan M, Yu H. Thermal efficiency modelling of the cement [38] Sarofim AF. The John zink combustion handbook. Chem Eng 2001;108:10.
clinker manufacturing process. J Energy Inst 2015;88:76–86.