PROBLEMA 1 Flujos molares Entalpias molares parciale

Mezclado ṅ2(Kmol/min) 0.625 ĥ1(KJ/Kmol)

Compuestos ṅ1(Kmol/min) 0.375 ĥ2(Kj/Kmol)
A B
T(K) 308.15 T(K) 308.15 Flujos másicos Dilución infinita
Pm 1 Pm 1 ṁ1(Kg/min) 0.375 ĥ (KJ/Kmol)
1
∞

Flujo molar 1 Flujo molar 2 ṁ2(Kg/min) 0.625 ĥ2∞(Kj/Kmol)

XA1 1 XB2 0.8
XB1 0 XA2 0.2 Balance de energía
Entalpia de mezclado h1(KJ/Kmol) 0
A0 3101.7 h2(KJ/Kmol) 519.52896
A1 -131.8 hM(KJ/Kmol) 775.425
A2 184.1
∆hlv(KJ/Kg) 2256.1 Calor absorbido(KJ/min)
Flujo molar total
450.7194
ṅM(Kmol/min) 1
XAM 0.5
XBM 0.5 Agua necesaria(Kg/min)

0.1997781127
Entalpias molares parciales

ĥ1(KJ/Kmol) 742.475
ĥ2(Kj/Kmol) 808.375

Dilución infinita
ĥ (KJ/Kmol)
1
∞
3417.6
ĥ2∞(Kj/Kmol) 3154
 PROBLEMA 2
MEZCLADO
Datos de cada componente
V (m3) T (°C) P (bar) Tc (K) Tr Pc (bar) Pr Zc Vc (m3/mol)
Butano (1) 2 425.1 0.0588097 37.96 0.0790306 0.274 255
25 3
Pentano (2) 4 469.7 0.0532255 33.7 0.0890208 0.27 313

Datos de la mezcla
Yi T (°K) P (bar)
Butano 0.67
323 20
Pentano 0.33

Sʳ(T,P)/R = Ln(Zmix - Bmix) + θmix/√8Bmix Ln ( Zmix+ (1+ √2) Bmix / Zmix+ (1- √2) Bmix )

Г1 0.1080241 Г2 0.109365 A12 1.6284473

α1 2.2778623 α2 2.4774988 Amix 1.5547276
A1 1.3996448 A2 1.8946525 Bmix 0.1129891
B1 0.1045504 B2 0.1301222 Ωmix -1.555011

Metodo de Cardano

�3𝑚𝑖𝑥+𝑝�𝑚𝑖𝑥2+qZmix+r=0

p -0.887011 Q -0.342729 Q3 -0.040258 A -0.670762

q 1.2904497 R 0.0841969 R2 0.0070891 B 0.5109544
r -0.161458

SR/R CpGImix 1.06E-03

ΔS 3.15E-01
 w CpGI/R R (bar*m3/mol*K)
0.2 11.928
8.31E-05
0.252 14.371

Zmix 0.1358622
 PROBLEMA 3
Modelos de actividad
T(K) Antoine
333.15 a b c
T(°C) Metanol 16.5785 3638.27 239.5
60 Agua 16.3872 3885.7 230.17
Psat(Kpa) Y1 Y2 γ1 γ2
Metanol 83.9891 P(Kpa) X1 X2 0.5714 0.4286 1.582707 1.010648
Agua 20.00704 39.223 0.1686 0.8314 0.6268 0.3732 1.480315 1.023617
42.984 0.2167 0.7833 0.6943 0.3057 1.32885 1.072317
48.852 0.3039 0.6961 0.7345 0.2655 1.254023 1.1085
52.784 0.3681 0.6319 0.7742 0.2258 1.170613 1.154316
56.652 0.4461 0.5539 0.8085 0.1915 1.104413 1.229421
60.6 0.5282 0.4718 0.8383 0.1617 1.056896 1.307527
64 0.6044 0.3956 0.8733 0.1267 1.037638 1.345416
67.9 0.6804 0.3196 0.8922 0.1078 1.027872 1.377941
70.2 0.7255 0.2745 0.9141 0.0859 1.021035 1.395383
72.8 0.776 0.224
X1 vs GE/RTX1X2
0.7
0.6 f(x) = - 0.1603867615x + 0.6679656483
R² = 0.7452360442
0.5
GE/RTX1X2

0.4 X1 vs GE/RTX1X2
0.3 Linear (X1 vs GE/RTX1X2)

0.2
0.1
0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
X1
 Ln(γ1) Ln(γ2) GE/RT GE/RTX1X2 X1X2/GE/RT Modelo a b
0.459137 0.010592 0.086217 0.615068 1.625836 Margules 0.668 -0.16
0.392255 0.023342 0.103286 0.608489 1.643416 Van Laar 1.469 0.478
0.284314 0.069822 0.135006 0.638191 1.56693
0.226356 0.103007 0.148412 0.638051 1.567273
0.157527 0.143508 0.149762 0.606092 1.649914
0.099314 0.206543 0.149904 0.601531 1.662424
0.055336 0.268138 0.13952 0.583521 1.713733
0.036947 0.296703 0.119965 0.551677 1.812655
0.027491 0.32059 0.107946 0.542037 1.844894
0.020816 0.333169 0.090783 0.522272 1.91471

X1 vs X1X2/GE/RT
2.5

2
f(x) = 0.478829963x + 1.4694830101
X1X2/GE7RT

1.5 R² = 0.7470357167
/RTX1X2 X1 vs X1X2/GE/RT
1 vs GE/RTX1X2) Linear (X1 vs X1X2/GE/RT)
1

0.5

0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
X1
 A B R2
0.588 -0.08 0.745
0.680735 0.513611 0.747
 Modelos de actividad
2.5

1.5
X1 vs Ln(Y1)
X1 vs Ln(Y2)
X1 vs GE/RT
X1 vs GE/RTX1X2
X1 vs X1X2/GE/RT
1

0.5

0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

X1
 PROBLEMA 4 Zi Tc(K) Pc(Bar) P2s(Bar) w
FLASH N-butano 0.45 425.1 37.47 47.0 0.200
Alimentación N-pentano 0.55 469.7 33.60 81.0 0.252
P(atm) 1
Z1=X1 0.45
Z2=X2 0.55
T(K) 287.07569
Psat Datos Balances Flash A
N-butano 1.6842948 P(atm) 1 VB1(Kmol) 17.647059 P(atm) 1
N-pentano 0.4401224 Z(Kmol) 200 LA1 182.35294 X1 0.411290323
Pf (atm) N1A(Kmol) 75 X1A 0.4112903 X2 0.588709677
0.9999999476 Y1B 0.85 X2A 0.5887097 T(K) 288.4582362
Psat
N-butano 1.765203733
N-pentano 0.465404206
PflashA

0.9999991727

ENTALPÍAS
Flash A Flash B
HIV-A(J/mol) 127.19381 HIIV-A(J/mol) -412.680742
HIV-B(J/mol) 179.73039 HIIV-B(J/mol) -583.135831
HIL-A(J/mol) -23214.49 HIIL-A(J/mol) -23905.3495
HIL-B(J/mol) -27587.25 HIIL-B(J/mol) -28634.1577
 A1 A2 A3 CpL CpV R (J/molK)
5.741624 2292.436 -27.8623 100 92.000 8.314
5.853654 2555.604 -36.2529 150 130.000

Flash B Balances
P(atm) 1 X1B 0.589707
Y1A 0.726011213 X2B 0.410293
Y2A 0.273988787 VB(Kmol) 17.647059
T(K) 282.5900345 VA(Kmol) 33.699657
YIB 0.85 LB(Kmol) 16.052598
Y2B 0.15
Psat
N-butano 1.441393884
N-pentano 0.365592373
P flashB

1.000000021

S
Alimentación
H2L-Z (J/Mol) -23376.81
H1L-Z (J/Mol) -27833.15
Calor intercambiado
Intercambiador A 1317118
Intercambiador B -451639.9
 PROBLEMA 5
FLASH 2 Composiciones Y Tc(K) Pc(Bar)
Variables del problema Y1 0.3560258 Acetona 508.2 47.01
Alimentación Y2 0.6439736 Metanol 512.6 80.97
P (bar) 5 ∑Y 0.9999994
Z1 =X1 0.3
Z2 = X2 0.7 Antoine A B C Psat
T F(K) 379.45 Acetona 6.244412 2975.953 -34.5228 4.3364614
Tambor Metanol 7.513334 3593.389 -35.2249 4.3423481
P(bar) 2
ψ 0.5 Coeficiente Actividad K1 1.1867527
A 0.64 Lnɣ1 0.3136 K2 0.9199622
Ln(Ps/Pc) A1 - A2/T(K)+A3 ɣ1 1.3683422901
Lnɣ2 0.0576
ɣ2 1.0592911945

Toperacion(K) 350.48464

Componentes Psat ɣ1 Ki Metodo RR

Acetona 1.96612 1.3683423 1.3451626 0.0883084

Metanol 1.6640045 1.0592912 0.8813327 -0.088307
1.712E-06

Tc(K) Pc(Bar) w A1 A2

Acetona 508.2 47.01 0.307 6.244412 2975.953

Metanol 512.6 80.97 0.564 7.513334 3593.389
 w
0.307
0.564

RR - Xi RR - Yi

0.2558458 0.3441542
0.7441533 0.6558467
0.9999991 1.0000009

A3 Cp/R R (J/molK) A(J/mol) 10304.8781

-34.5228 8.96 8.314 B(J/mol) 23808.94051

-35.2249 5.549 C(J/mol) 17633.27603

Q (J/mol K) -16480.5426