Flowsheet

Sand Thickener
Clarifier Filter Waste
Mixer Flocculator

Sea
water

Waste Milk of
lime
Bowl
classifier
Water Wash
Natural Screen towers
Lime
gas Boiler Slacker Waste
Rejects
Soda towaste
ash Scrubber Waste Compressor
CO2
CO2
Turbo flocculator Turbo
carbonator Purifier
Sand Purifier
Fresh Mg(OH) 2
filter
water Tank Tank freshwater slurry
storage

Filter
Boiling Mg0 Basic
Purified Carbonation
tank tank Spray
carbon (Light) carbonates
dioxide drier Calciner
Waste

Purified Mg (OH) 2

Various finishing operations for oxides Mg(OH) 2 Various Heavy Milk of

and hydroxides, such as : paste Mg(OH) 2
Mg0 magnesia
powders
(1) Filtering (3) Calcining (1) (4) (2) (3) (4) (4)
(1) (2) (4)
(2) Drying (4) Packaging
PERHITUNGAN NERACA MASSA PEMBUATAN MAGNESIUM OKSIDA

Ca(OH)2 CO2

Sea Water Mg(OH)2 Mg(OH)2 MgCO3

THICKENER STORAGE CARBONATION
H2O
TANK
100.000 L

MgCl2 4,176 g/L Mg(OH)2

MgSO4 1,668 g/L CaCl2 MgCO3

CaSO4.2H2O CO2

Ca(OH)2 PASTE POWDER HEAVY Milk of Magnesia

H2O MgO H2O

MgO, CO2 MgCO3 DRYER

CALCINER

BASIC
CARBONATES

1. NERACA MASSA PADA THICKENER

Ca(OH)2

Sea water Mg(OH)2

100.000 L

MgCl2 4,176 gr/L

MgSO4 1,668 gr/L CaCl2

H2O CaSO4.2H2O
 Ca(OH)2

H2O

Basis 100.000 L air laut

MgCl2 dalam 100.000 L = 4,176 gr/L x 100000 L = 417600 gr : 1000 kg/gr = 417,6 kg

Mol MgCl2 = 417,6 kg : 95 kg/kmol = 4,396 kmol

MgSO4 dalam 100.000 L =1,668 gr/L x 100000 L = 166800 gr : 1000 kg/gr = 166,8 kg

Mol MgSO4 = 166,8 kg : 120 kg/kmol = 1,39 kmol

Air laut = 100000 L x 1 kg/100 L = 1000 kg

H2O dalam air laut = 1000 kg – (417,6 + 166,8) kg = 415,6 kg

Mol H2O = 415,6 kg : 18 kg/kmol =23,08 kmol

Reaksi 1

MgCl2 + Ca(OH)2 Mg(OH)2 + CaCl2

m 4,396 - - -

b 4,396 4,396 4,396 4,396

s - 4,396 4,396 4,396 kmol

BM - 74 58 111 kg/kmol

kg - 325,304 254,968 487,956 kg

Komponen Input (kg) Output (kg)

MgCl2 417,6
Ca(OH)2 325,304
Mg(OH)2 254,968
CaCl2 487,956
total 742,9 742,9
 Reaksi 2

MgSO4 + Ca(OH)2 + 2H2O Mg(OH)2 + CaSO4.2H2O

m 1,39 - 23,08 - -

b 1,39 1,39 2,78 1,39 1,39

s - 1,39 20,3 1,39 1,39 kmol

bm - 74 18 58 172 kg/kmol

kg - 102,86 365,4 80,62 239,08 kg

komponen Input (kg) Output (kg)

MgSO4 166,8
Ca(OH)2 102,8
H2O 415,5 365,4
Mg(OH)2 80,62
CaSO4.2H2O 239,08
total 685,2 685,1

2. NERACA MASSA PADA STORAGE

Mg(OH)2 Mg(OH) 2

Mg(OH)2

Paste Powder Heavy MgO Milk of Magnesia

Mg(OH)2 yang masuk kedalam storage = (254,968 + 80,62) kg = 335,588 kg

Mg(OH)2 yang akan diubah menjadi 4 produk = 200 kg

 Mg(OH)2 yang akan diolah pada carbonation tank = 335,588 kg – 200kg = 135,588 kg

Mol Mg(OH)2 = 135,588 kg : 58 kg/kmol = 2,337 kmol

3. NERACA MASSA PADA CARBONATION TANK

CO2

Mg(OH)2 MgCO3, H2O

135,588 kg MgCO3, CO2

Mg(OH)2 + CO2 MgCO3 + H2O

m 2,337 - - -

b 2,337 2,337 2,337 2,337

s - 2,337 2,337 2,337 kmol

BM - 44 84 18 kg/kmol

Kg - 102,828 196,308 42,066 kg

komponen Input (kg) Output (kg)

Mg(OH)2 135,5
CO2 102,8
MgCO3 196,3
H2O 42,06
total 238,4 238,37
 4. NERACA MASSA PADA DRYER

H2O MgCO3 196,308 kg, H2O 42,066 kg

MgCO3 196,308 kg (95%)

H2O 10,332 kg (5%)

Kemurnian MgCO3 95%

H2O pada MgCO3 : 5/95 x 196,308 kg = 10,332 kg

H2O yang menguap pada dryer = 42,066 kg – 10,332 kg = 31,733 kg

5. Neraca massa pada Calciner

MgO + CO1 MgCO3 196,308 kg

MgCo3 MgO + CO2

m: 2,337 - -

b: 2,337 2,337 2,337

s: - 2,337 2,337 kg

BM: - 40 44 kg/kmol

Kg: - 93,48 102,828 kg

Tabel Neraca Massa

Komponen Input (kg) Output (kg)

MgCO3 196,308
MgO 93,48
Co2 102,828
TOTAL 196,308 196,308