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CHEMISTRY TEST -2

Full mark – 70

Time – 2 hr

 

Each question carrying one mark (Q. No .1-4)

 

1

How many number of Hydrogen bonds formed by a water molecule .

2

Write the electronic configuration of the elements with atomic numbers : 24

3

How are bond order and bond length related each other

 

4

Round off each of the following lengths to retain two significant digits:

(a) 2.68 m (b) 2.62 m (c) 2.65 m

 
 

Each question carrying two mark(Q. No.5-14)

 

5.

What designation are given to the orbitals having

 
 

n=2

l=1

n=4

l=3

6.

Explain why hydrogen forms diatomic molecule while helium remainsMonoatomic

7

How many moles of NaHCO3 are contained in 33.6grams NaHCO3?

8

Calculate the wave number and wavelength of the spectral line observed in hydrogen spectrum with n 1 = 2 and n2 = 3.

9

Ionic radius of Na ion is 0.95 A and the inter-nuclear distance between the ion-pairs in NaCl ionic crystal is equal to 2.76 A. Calculate the radius of Cl-ion.

10

Arrange C, N, 0 and F in the decreasing order of their IE2 values.

11

using lewis symbol , represent the transfer of electron from Magnesium to Fluorine to form the correct molecular formula

12

what is polar covalent bond , give two example by showing the partial ionic charge and shifting of polarity

13

Assuming that the following reaction between oxygen and hydrogen goes to completion, which one is limiting reagent if 10.0 grams of hydrogen are mixed with 64.0grams of oxygen?

10.0 grams of hydrogen are mixed with 64.0grams of oxygen? 14 Calculate the no. of σ

14

Calculate the no. of σ-bond and Lone pair of electron in the following molecule

 
   
 
 

Each question carrying three mark(Q.No.15-22)

15

Predict the structures and hybridization of the following. Indicate the direction of distortions from the regular structures. XeF4 , XeOF4

16

The Vividh Bharti Station of All India Radio, Delhi broadcasts on a frequency of 1368 kHz (kilo hertz). Calculate the wavelength and wave number of the electromagnetic radiation emitted by the transmitter.

17

Define the term paramagnetism . Which one is paramagnetic between N2 and N 2+ .

18

why ClF3 have T-shape while BF3 have Trigonal planner

19

Explain the intermolecular forces between two Non polar molecules

20

Calculate the volume occupied by 7g CO at 27°C and 750 mm Hg.

21

At 0°C, the density of a gaseous oxide at 2 bar is same as that of nitrogen at 5 bar. What is the molecular mass of the oxide?

22

Using ideal gas equation; show that at a given temperature density of a gas is proportional to gas pressure p.

 

Each question carrying four mark(Q. No.23-25)

23

What are the important characterstics of gases and what are its parameters

24

Explain how the H-bond takesplace ? Briefly explain how the density of ice becomes lower then water .

25

Derive the gas law for partial pressure . What is the effect of pressure when Z =1 on deviation of ideal gas .

 

Each question carrying five mark(Q. No.26 & 27)

26

What are assumptions of kinetic theory of gases and what are the major difference between Ideal gas and real gas

27

Write short notes

a. Intermolecular H-bonding

b. Cause of real gas deviation from ideal gas

c. Hybridisation of C2H4