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G. Borellini
Exampls:
Sample/Temp.: 0°C 20°C 25°C 30°C 40°C 50°C
Example : pH 3,27 at 22 ºC
Potential in mV
Temperature
dependency of the
Nernst equation
pH
RxT
NERNST equation: E = ------------ x 2,30
nxF
-59.16 mV at 25°C
E = Potential difference
R = Gas constant -74.04 mV at 100°C
F = Faraday constant
T = Absolute temperature
n = charge number of the measured ion = 1
mV
0
bad
7 14 pH
59.16 mV at 25°C
good
Isothermal Point is
best at 0 mV
Example :
0.001 mol/l HCl = pH 3,00
Temperature of calibration : 25º C
Temperatura of measure : 60º C
If we don’t made automatic or manual temperature compensation at
60°C on the pHmeter the error is: 0,47 pH
Important:
When the electrode jumps from different
temperature, please wait before to read a
final value.
Theory is necessary !
Experience is essential
Good luck with your pH measurement
And greatings from Italy…..