REVISION DATE: 02-12-2005

SAFETY DATA SHEET

TRETOLITE* DMO86000
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND
COMPANY/UNDERTAKING
PRODUCT NAME TRETOLITE* DMO86000
PRODUCT NO. DMO86000
APPLICATION Demulsifier
SUPPLIER Baker Petrolite
Kirkby Bank Road,
Knowsley Industrial Park
Liverpool. L33 7SY. UK
Tel +44(0)1515462855
Fax +44(0)1515473590
EMERGENCY TELEPHONE Baker Petrolite:- + 44 (0) 151 546 2855
CHEMTREC International:- +1 703 527 3887
. * TRETOLITE is a trademark of Baker Hughes Incorporated.

2 COMPOSITION/INFORMATION ON INGREDIENTS
Name EC No. CAS-No. Content Classification

1,2,4-TRIMETHYLBENZENE 202-436-9 95-63-6 5-10% R10 Xn;R20 Xi;R36/37/38 N;R51/53

ALIPHATIC ALCOHOLS 203-234-3 104-76-7 1-5% Xi;R36/38.
ALKYL (C3-4) BENZENES 265-199-0 64742-95-6 1-5% Xn;R65. N;R51/53.
ALKYL (C3-5) BENZENES 265-198-5 64742-94-5 30-60% Xn;R65. Xi;R37/38. N;R51/53.
ALKYLBENZENE SULPHONIC ACID 271-528-9 68584-22-5 1-5% Xn;R22. C;R34.
MESITYLENE 203-604-4 108-67-8 < 1% R10 Xi;R37 N;R51/53
NAPHTHALENE 202-049-5 91-20-3 1-5% Carc. Cat. 3;R40 Xn;R22 N;R50/53
XYLENE 215-535-7 1330-20-7 < 1% R10 Xn;R20/21 Xi;R38

The Full Text for all R-Phrases are Displayed in Section 16

3 HAZARDS IDENTIFICATION
Flammable. Irritating to respiratory system and skin. Limited evidence of a carcinogenic effect. Toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic environment.
CLASSIFICATION Carc 3;R40. Xi;R37/38. N;R51/53. R10.

4 FIRST-AID MEASURES
INHALATION
Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any
discomfort continues. If respiratory problems, artificial respiration/oxygen.
INGESTION
DO NOT induce vomiting. Get medical attention immediately. Drink plenty of water.
SKIN CONTACT
Wash the skin immediately with soap and water. Get medical attention promptly if symptoms occur after washing.
EYE CONTACT
Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical
attention promptly if symptoms occur after washing.

5 FIRE-FIGHTING MEASURES

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TRETOLITE* DMO86000
EXTINGUISHING MEDIA
Fire can be extinguished using: Water spray, fog or mist. Alcohol resistant foam. Dry chemicals, sand, dolomite etc.
SPECIAL FIRE FIGHTING PROCEDURES
Use supplied air respirator if product is involved in a fire. Cool containers exposed to flames with water until well after the
fire is out.
SPECIFIC HAZARDS
Vapours/gases/fumes of: Carbon dioxide (CO2). Carbon monoxide (CO).

6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Do not discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable
adsorbent material.
SPILL CLEAN UP METHODS
Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb in vermiculite, dry sand or
earth and place into containers.

7 HANDLING AND STORAGE

USAGE PRECAUTIONS
Keep away from heat, sparks and open flame. Ventilate well, avoid breathing vapours. Use approved respirator if air
contamination is above accepted level. Avoid spilling, skin and eye contact.
STORAGE PRECAUTIONS
The drums should be stored, with their seals intact, in conditions that avoid extremes of temperatures. Under these
conditions the shelf life of the product should be approximately two years. If the product is to be stored in bulk containers,
please contact Baker Petrolite for advice on materials of construction of the containers.
STORAGE CLASS
Flammable liquid storage. Environmentally hazardous storage.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Name Std LT - ppm LT - mg/m3 ST - ppm ST - mg/m3

XYLENE WEL 50 ppm(Sk) 220 mg/m3(Sk) 100 ppm(Sk) 441 mg/m3(Sk)

1,2,4-TRIMETHYLBENZENE WEL 25 ppm No std.

NAPHTHALENE WEL 10 ppm 53 mg/m3 15 ppm 80 mg/m3

INGREDIENT COMMENTS
WEL = Workplace Exposure Limits
PROTECTIVE EQUIPMENT

PROCESS CONDITIONS
Use engineering controls to reduce air contamination to permissible exposure level.
ENGINEERING MEASURES
Explosion-proof general and local exhaust ventilation.
RESPIRATORY EQUIPMENT
Use chemical cartridge protection with appropriate cartridge. Chemical respirator with organic vapour cartridge.
HAND PROTECTION
Use protective gloves made of: Neoprene, nitrile, polyethylene or PVC.
EYE PROTECTION
Wear approved chemical safety goggles where eye exposure is reasonably probable.

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TRETOLITE* DMO86000
OTHER PROTECTION
Wear appropriate clothing to prevent repeated or prolonged skin contact.
HYGIENE MEASURES
Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly with soap & water if
skin becomes contaminated. Promptly remove any clothing that becomes contaminated.

9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE Liquid
COLOUR Brown
ODOUR Characteristic
SOLUBILITY Immiscible with water Soluble in Aromatic solvents
MELTING POINT (°C) <- 30 RELATIVE DENSITY 0.910 - 0.990 @ 16 °c
VISCOSITY 10 - 70 cSt @ 38 °c FLASH POINT (°C) Min. 50 PM Closed cup.

10 STABILITY AND REACTIVITY

STABILITY
No particular stability concerns.
CONDITIONS TO AVOID
Avoid contact with strong oxidisers. Avoid heat, flames and other sources of ignition.
HAZARDOUS POLYMERISATION
Will not polymerise.
MATERIALS TO AVOID
Strong oxidising substances.
HAZARDOUS DECOMPOSITION PRODUCTS
Vapours/gases/fumes of: Carbon dioxide (CO2). Carbon monoxide (CO).

11 TOXICOLOGICAL INFORMATION
INHALATION
Vapours may irritate throat and respiratory system and cause headache, dizziness and dullness.
INGESTION
Irritating. May be absorbed in the body and cause dizziness, nausea and vomiting.
SKIN CONTACT
Irritating to skin. Prolonged contact may cause redness, irritation and dry skin.
EYE CONTACT
Irritating and may cause redness and pain.

12 ECOLOGICAL INFORMATION
ECOTOXICITY
The product contains substances which are toxic to aquatic organisms and which may cause long term adverse effects in
the aquatic environment.

13 DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Absorb in vermiculite or dry sand, dispose in licensed special waste. Dispose of waste and residues in accordance with
local authority requirements.
WASTE CLASS
The definitive European Waste code for this product will depend upon the final use that is made of this material. If the
material, as originally delivered is to be disposed of please contact Baker Petrolite HSE Q&RA dept for assistance
assigning the correct EU Waste Code.

14 TRANSPORT INFORMATION

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TRETOLITE* DMO86000

UK ROAD CLASS 3
PROPER SHIPPING NAME FLAMMABLE LIQUID, N.O.S. (contains aromatic naphtha)
UN NO. ROAD 1993 UK ROAD PACK GR. III
ADR CLASS NO. 3 ADR CLASS Class 3: Flammable liquids.
HAZARD NO. (ADR) 30 Flammable liquid 30
(flash-point between 23°C
and 61°C, inclusive) or
flammable liquid or solid in
the molten state with a
flash-point above 61°C,
heated to a temperature
equal to or above its
flash-point, or self heating
liquid.
ADR LABEL NO. 3 HAZCHEM CODE 3Y
RID CLASS NO. 3 UN NO. SEA 1993
IMDG CLASS 3 IMDG PACK GR. III
MARINE POLLUTANT UN NO. AIR 1993

AIR CLASS 3 AIR PACK GR. III

15 REGULATORY INFORMATION
LABELLING

Harmful Dangerous for the

environment
CONTAINS NAPHTHALENE
RISK PHRASES
R10 Flammable.
R37/38 Irritating to respiratory system and skin.
R40 Limited evidence of a carcinogenic effect.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
SAFETY PHRASES
S24 Avoid contact with skin.
S36/37 Wear suitable protective clothing and gloves.
S51 Use only in well-ventilated areas.
S57 Use appropriate containment to avoid environmental contamination.
S60 This material and its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions/safety data
sheets.

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TRETOLITE* DMO86000
UK REGULATORY REFERENCES
Chemicals (Hazard Information & Packaging) Regulations. The Control of Substances Hazardous to Health Regulations.
EU DIRECTIVES
Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EEC.

16 OTHER INFORMATION
GENERAL INFORMATION
The information and recommendations contained herein are believed to be accurate and reliable as of the date issued.
However, we do not warrant their accuracy or reliability. We only warrant you, but to no other persons, that the product
referenced herein shall conform to our quality assurance specifications for the product on the date of shipment to you .WE
EXPRESSLY DISCLAIM ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, INCLUDING THE IMPLIED WARRANTIES
OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Any technical advice, information or
recommendation, given to you is given gratis without warranty whatsoever as to the advice, information or
recommendation given or the results obtained. You shall assume all risks and shall be solely responsible for the results
obtained from the storage, handling or use of the product whether alone or in combination with other substances. UNDER
NO CIRCUMSTANCES SHALL WE BE LIABLE FOR ANY ECONOMIC CONSEQUENTIAL (INCLUDING LOST PROFIT OR
SAVINGS) OR INCIDENTAL DAMAGES EVEN IF WE ARE INFORMED OF THEIR POSSIBILITY, EXEMPLARY OR
PUNITIVE DAMAGES, REGARDLESS OF THE FORM OF ACTION WHETHER IN CONTACT OR TORT INCLUDING OUR
SOLE OR JOINT NEGLIGENCE AND STRICT LIABILITY.
REVISION COMMENTS
NOTE: Lines within the margin indicate significant changes from the previous revision.
REVISION DATE 02-12-2005
RISK PHRASES IN FULL
R10 Flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R22 Harmful if swallowed.
R34 Causes burns.
R36/37/38 Irritating to eyes, respiratory system and skin.
R36/38 Irritating to eyes and skin.
R37 Irritating to respiratory system.
R37/38 Irritating to respiratory system and skin.
R38 Irritating to skin.
R40 Limited evidence of a carcinogenic effect.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.

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