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Permeability Hysteresis
J. COLONNA GAZ DE FRANCE
!=. B!?!WWD I GEOPETROLE
GAZ DE FRANCE
J. L. MILLET
I PARIS, FRANCE
I
ym, /’?7a
P~ ~ = pa + pwgb on the lower end of the core Pc=pg-pw=pg2 -pa... . . . ...(5)
(in]ection of the gas) . . . . . . (2)
Injection and output pressures of the gas, (relative pressure in the gas on the input face).
respectively, Drainage and imbibition are obtained by causing
pressures pg ~ and pgz to vary simultaneously by
Pgl and p
g2
= Pg, -pwgb . . . . . ...(s)
constant increments or decrements.
For each value of P=, time is allowed for reaching
are controlled by pressure regulators,
apparent flow equilibrium; gas flow measurement so
When the gas flow is stabilized, the total pressure
obtained for a pressure drop Ap = pwgb permits an
drop causing flow will be equal, in all experiments
easy calculation of gas permeability, kg; the
performed; to: . .
w-ettirig-@se ~ii~’~it b=irt~ ~ CICSed ChCIUIC, the
Ap=pWgh . . . . . . . . . . . . ..(4) gas saturation is related to the volume of wetting
phase expelled from the sample and accumulating
This pressure drop being linear in the gas flow, in a graduated reservoir in the circuit. Although the
the capillary pressure (under dynamic conditions wetting phase is low volatility silicone oil (pw = 4
for gas) cp), corrections are necessary to take into account
Nitrogen Injection
\r r-l%
1
0
!!-
0
--:
perm&ble
partitions Gas flow
I’ieasuremcnt
\
\ Lei?e! reding m
graduated buret
( salumhon measurement )
o-
Constant flow pump ‘~’
Pressure Regulators
FEBRuARY, 1972
evaporation when the gas (nirrogen) flow is high. value higher than all the values previously reached
These corrections are easily obtained by calculating during the same run, the fi.cst drainage curve DO is
the difference between the weight lost by the obtained again. In other words, the previous history
sample and the weight of silicone oil accumulated of the sample is thus erased. The same feature will
in the graduated reservoir. be observed in all later runs.
The sample is saturated initially by the wetting A third run (reference points a to 8) provides the
phase and, during the first drainage operation, we hysteresis loop corresponding to the particular case
call Pd the displacement pres sue at which gas in which the imbibition is performed starting from
saturation first appesm and P~ the threshold the wetting-phase irreducible saturation Sw,.
pressure thar causes the first flow of gas through Two similar hysteresis loops–denoted “complete”
the sample. because their imbibition cycle 10 has been conducted
During a drainage cycle, the injection pressure down to the residual gas saturation — have been
p ~ is first set at the selected value by correctly studied for the Hassi R’Mel sandstone (Runs’4 and
positioning the plunger in the first Mariotte vessel 5, Fig. 3). Results from the two samples are
(Fig. I). Simultaneously, the plunger in the second unquestionably coherent. They axe also in
Mariotte vessel placed in the output circuit is accordance with results obtained by several other
moved an equivalent amount. In this case, the authors.
setring of the output pressure p 2 is performed only Morrow and Harris 3 have studied hysteresis
when the accumulation of recuperated gas between phenomena on unconsolidated layers of glass beads;
sample and regulator is sufficient for bubble-to- the experimental apparatus was derived from
bubble contact. (During an imbibition cycle the conventional desorption techniques. Similar studies
output pressure is first reduced, then progressively had been performed previously by Poulovassilis
the injection pressure. ) using a consolidated bed made from a sintered
Thus, as long as the gas flow is not established aggregare of glass beads. q More recently, Evrenos
throughout the sample, the output gas pressure is and Comers) 6 have observed simultaneously the
nfir 0s.
..”. .=.* M..
=m~U rhe -.. --. -., =-------
...s c-apillarv nressure cannot be constant evo!l~ri~n of capillary pressures and relative
along the sample. Besides, even if the capillary permeabilities for wetting and nonwetting phases
pressure were constant, there would remain a during hysteresis cycles between limiting
displacement capiIlary pressure at which gas would saturations S and S,w, using more or less
expel the wetting phase from the largest pores consolidated C%i3brian sandstones (Fig. 4).
accessible from the sample’s end, without causing The similarity of the results obtained by such
continuous gas flow because these large pores different experimental methods on artificial
communicate with each other through smaller consolidated and unconsolidated porous media and
openings. on various natural media seems to indicate that the
general evolution of capillary pressures during
EXPERIMENTAL RESULTS alternating cycles of drainage and imbibition is
CAPILLARY PRESSURE-SATURATION
nmr
Afium. -mnwcpo
L.“,. .3 . . .
h
p0?051ty ?9, a z
The second run (reference points 1 to 13 in Run n“ 1 ( o—c )
chronological order) was performed afrer total 33 Run . . 2 ( 1—13 1
experiment shows the unique character of the first WETTlffi PHASE SATURATION (“/.)
drainage curve — each time we set a capillary rF~G. PVPT 1P PA DTT ~APV DPUQ.Q1l RU
2 — L x Qu.ti b-. .- . .. . . ., —w., ..-, ~c)~~.~.s
pressure (or a nonwetring-phase saturation) at a
CORE.
L
1
Q
Lrngth 8,7 cm
VOSGES 5AND5TONE
5ect oon J9,6 Cti e
Length 17, 5 cm
Smt I+mn 1140 m Q
Secllon 19,6 cmz
Porosity W,m a
G BOSe Perm 1260 m D
Run n“4 ( a-l
Pwoslty 19,50 z
Runn” S( l-4
R“n”l (o—e)
0
E R. n.2 (1—13 I
\
Ru .“3 I<_& )
*
.
i
z
<
w
I
E
n.
0
) 6
0
01
0 m 40 60 m
log)
WETTING PHASE SATURATION
al 40
FIG. 3 — CYCLIC CAPILLARY PRESSURE, HASSI wETTING PHASE 5ATURATION ( ~o )
R’MEL CORE. ----- .- ------ . . .. .. . . .. An..”” .-..
FIG, 5 — CYCLIC FJLKMEA131L1 1 I , VU>L15D bUKU.
Poros ,t y . 248%
mm
HAS51 R MEL SANDSTONE
Bose P?rmiotxl$ty. 1235 mD
t
Ill
A 1st Irnb, bnt!c.n
$4 ~ 5ectto. . 19,6 cm2
n 2nd Dro, nrqe \\
Base h.m.l 140 mD
3
n.
v 2 nd Imbtbmon
12 x 3 .d D.o, noqe n
%rlslty f9, @ z
a00 - //
-..
9 7 .,+ lmh, b,tm” E R.” .04 (a—f)
\
4 R.. n05 (1—4)
.
1-
:
z
< bm
U
x
E
u
a
m
ul
6
u
[
\
.i ,
WATER SATURATION 1~]
WATER SATURATION (z)
FE BRLIARY. 1972 31
results to seek a formalized representation of the penetrate and then to flow through the channels
evolution of the relationships. belonging to the network (opening pressure).
If we consider the capillary pressure at which
INTERPRETATION OF water could start to repenetrate each of these
EXPERIMENTAL RESULTS networks to prevent the passage of gas (stoppage
pressure), this pressure is not necessarily equal to
FORMALIZED REPRESENTATION OF OBSERVED the “Yb
---”;mu nr.=c.nre
... ..e y.--..--..., ~u~ COU!CJ in pincip!e be in
PHENOMENA ORIGIN OF HYSTERESIS PHENOMENA
certain networks as low as the threshold pressure
When capillary pressure in a porous medium is proper (Ps). In fact, this pressure is governed by
increased during drainage, the gas penetrates the smallest diameter of the “forced access path”
progressively into pores having smaller and smaller in the network already occupied by gas. Fig. 7
diameter. In each pressure increment there is shows how, if repenetration of water may take place
activated a new family of networks consisting of in Networks 1, 2 and 4 as soon as the capillary
interconnected paths whose varying diameters are pressure drops below the opening pressure, the
equal or larger than the one that it is now possible capillary pressure in Networks 3 and 5 will need to
to penetrate. drop much lower before gas circulation is interrupted.
All the new networks thus activated have only Hysteresis phenomena observed in two-phase
one common feature — the value of the capillary displacements are essentially due to the existence
pressure necessary to allow the gas f~st to of these differences between opening and stoppage
we F/inq
phase
123656
(3) Imbtbltlon
Pc - Pq
FIG. 7 — EVOLUTION OF FLUID DISTRIBUTION IN POROUS MEDIUM FOR DRAINAGE AND IMBIBITION.
Ak
-F
Ac
Pc
J
PCn
dk
— VS P= OBTAINED DURING FIRST DRAINAGE.
‘lG” 8 – ‘lAGRAM ‘F A Pc
FEBRUARY, 1972 99
-% A PC
Pc. Pc F’cn Pc
..........);--- -. r 1
during a subsequent drainage, to reach threshold
pressure to obtain a gas permeability.
*
El
kg( I%f) ~kg(pc2
L
........ .-----
:%( PCJ );
J
Experimental results show an additional
hysteresis phenomenon between first drainage DO
and drainages D1 following totaI imbibition (Fig.
12). During such a drainage DI the presence in the II
displaced ‘water of gas not yet untrapped allows
onIY a partiaI reconstitution of the networks
~cciv=~ed during drainage DO. This effect decreases
I
progressively until total disappearance occurs when
the maximum capillary pressure PM obtained during //
drainage DO is reached.
This qualitative remark, together with the
schematic representation described above, wilI be
used for the extrapolation
acquired data and the introduction
of experimentally
of the concept
,
into a mathematical model (see Appendix).
m -MUA DTT
rEm,.,nzuuu. TTV
. s - PADTT
*.,. .-- .1 .AwV
.. .
PRESSURE RELATIONSHIP
Fig. 11 shows the general shape of the trajectories FIG. 1 I — ORGANIZATION OF THE TRAJECTY3RIES
of the point representing the kg-Pc function, based OF THE POINT REPRESENTING THE RELATIONSHIP
on the above mentioned hypotheses. The theoretical (kg - P= ).
------
---
water would start re-invading each one of the pressure and water permeability-capillary pressure,
networks, this pressure will be equal or inferior to and of the Do, l., D1 curves for the capillary
........
ilk \
El %(% ) +s(%!
...... ......
[%-(-G \ s
.-2 ‘A
02
‘A
AS.-~wf=m &:&;
------ %
- --- ‘1
k W&me.
/“’
. / .<
._l!p_+~l
I \&h
II b
\
% v
------ %2-------- 1 ,\ F
‘t
.. .
.-—
0
~FRRT*nv ,0,9
. . . . . . . . . .A ..- 95
pressure-gas saturation relationship. Pg = pressure of gas
Our solutions are somewhat different from the /Jw = pressure of the wetting phase
intermediate scanning curves and the incomplete
p= = atmospheric pressure
trajectories covered by those curves that have been
Pc = capillary pressure
reported.3-5 The ‘[envelope curves” appear merely
as a particular illustration of the reproducibility of Pd = displacement pressure
any hysteresis loop. PM = maximum capillary pressure
Additional experiments are needed to check P~ = threshold pressure
completely the validity of these solutions. Such
s gf = residual gas saturation
experiments would be quite delicate because of the
high degree of precision required on all operations
sWr = residual wetting phase saturation
since the duration and the repetitive nature of these A = difference
operations would lead to a cumulation of small Ap = pressure drop (difference of pressure)
errors that would not be compatible with the pw = wetting phase density
accuracy expected on the results. pw = wetting phase viscosity
We are pleased with the agreement between the
qualitative laws described and the experiments ACKNOWLEDGMENTS
already performed. This has led us to believe that
our procedure gives a satisfactory answer, on the The authors express their thanks to Andr4
technico-economic level, to the problem of the Houpeurt, scientific adviser to Geopetrole, for the
evolution of the hydrodynamic characteristics of a valuable advice provided during the course of this
rock that has been submitted to a given history of investigation and to Henri Dasse of Geopetrole for
fluid displacements. his many useful suggestions. Appreciation is
As a further development of this work, we plan to extended to the management of Gaz de France
reactivate certain preliminary studies already (Etudes et Techniques Nouvelles) and to the
conducted with the very simplified model mentioned,l management of Geopetrole for permission to present
introducing a summary representation of the results this paper.
obtained here. The purpose of these studies would
be to evaluate the sensitivity of the reservoirs to REFERENCES
the variation of certain parameters outlined in this CcNew Orientations in the Use of the
1. Colonna, J.:
paper. Because of the large amount of computer Relative Permeability Concept, ” Review, IFP (April,
time required for a compiete mathematical simulat- 1969) Voi. XXIV, tU.
ion, the use of a mathematical model is contemplated 2. Rapoport, L. A. and Leas, W. J.: “Relative Pe~ea-
only as a function of the results given by the bility to Liquid in Liquid-Gas Systems;’ Trans., AIME
preliminary sensitivity studies. (1951) Vol. 192, 83-98.
3. Morrow, Norman R. and Harris, Colin C.: “Capillary
NOMENCLATURE Equilibrium in Porous Materials, ” Sot. Pet. Erzg. J.
(March, 1965) 15-24.
DO, D1,,.. = drainage 4. Poulovasailia, A.: clHysteresis Of Pore water, an
Application of the Concept of Independent Domain s,”
g = acceleration of gravity
Soil Science (June, 1962) Vol. 93, 405.
b = length (of sample)
5. Evrenos, A. I. and Comer, A. G.: “Numerical Simula-
1.,11,... = imbibition tion of Hysteretic Flow in Porous Media, ” Paper SPE
kg .= effective permeability to gas 2693 presented at 44th Annual SPE Fall Meeting, held
in Denver, CO1O. (Sept. 28-Ott. 1).
kw = effective permeability to wetting phase
6. Evrenos, A. I. and Comer, A. G.: “Sensitivity Studies
,.# P..
“’ “-=
e.w.
..a.=.
+-. R-l
. . .
.+;. . .,=
. . . .
P~_.=.~hil
- . . . . ---------
itv and
----
C!anilkfitV in
--r . ..- . . . .
APPENDIX *
Pcti to Pcn+l.
Each line is written with terms, the sum of which
corresponds to total variation A’An of the same
property when P= decreases from pcn+l to pen. Fig.
17 shows how elements of such a matrix can be
obtained in a simple way from curves.
In a practical way, experimental data used for
A
I
Pe
h 7
R/
AII, II.3 _
An, n.2 —
‘ AII,II
7
/
Do
II
I T
0 + ● 3
FEBRUARY, 1972 w
the determination of specifical matrix may be Drainage increases until irreducible water saturation
obtained by: (1) water saturation, (2) water permea- is reached followed by re-imbibition until capillary
bility, and (3) gas permeability measurements. ptessure is reduced to zero.
The following steps were undertaken during the The good agreement between this schematic
experiments. The first, partial drainage with representation and the results obtained by most
re-imbibition is performed until capillary pressure authors allows a sufficiently accurate formalization
is reduced to zero. Eventually second partial of intermediate scanning curves. In such a way, the
drainage is achieved to an upper level of capillary number of experimental imbibition following partial
pressure as was formerly obtained, and re-imbibition drainage can be reduced in most cases to one or
occurs until capillary pressure is reduced to zero. two.
***