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Years 9-10
Compounds
&
Reactions
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Revision Ionic
of Compounds Polyatomic
Basics Ions
Covalent Bonding
&
Covalent Compounds
Chemical
Reactions
Chemical
Equations
Some Reaction
Patterns Decomposition
Acids Combustion
&
Bases
Corrosion
Acids
&
Carbonates Indicators
Acids Precipitation
&
Metals Neutralisation
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Make your own “Mind-Map” TITLE PAGE.
Cut out the boxes. Sort them into an appropriate lay-out on a page of your
workbook, then glue them down. Add connecting arrows and colour in.
Polyatomic
of
Reactions Compounds
Ions
Basics
Simple Ionic
Some Reaction Chemical Compounds.
Patterns Names &
Equations Formulas
Corrosion
Combustion
Acids Acids Acids Neutralisation
& & & Decomposition
Bases Carbonates Metals Indicators
Combustion
Acids Acids Acids Neutralisation
& & & Decomposition
Bases Carbonates Metals Indicators
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Careers in Science
The World Needs Scientists Even if you don’t want to be a
The world needs scientists now and for professional scientist as such, there are
the next 20-30 years as never before. many popular, well-paid careers which
We face enormous challenges to are Science-based.
provide energy alternatives, while
reversing the trend of global warming. Health & Sports Sciences
Medicine, Physiotherapy, (and many other
Chemical and “therapy” occupations) Nursing and Sports
biological Science all demand a good
scientists will understanding of Science. Some tertiary
be needed to institutions give enrolment preference
help us switch to school-leavers who have studied
to renewable Chemistry and/or Physics at HSC level.
resources to
make fuels Engineering is traditionally Physics-
and plastics based, with some specialities needing
and much Chemistry as well.
more.
Even in careers in the mass media, such
Environmental scientists will be needed as Journalism, there are opportunities
to study and report on the state of rivers for those with a scientific education. So
and forests and the environmental many news stories, TV reports, etc,
impacts of major developments and cover scientific issues that people with
building projects. such knowledge are in demand.
Years 9-10 Topic 16 Compounds & Reactions 5 Usage & copying is permitted according to the
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Elements Compounds
It is essential for you to
understand the differences!
Elements
Pure Substance.
Only one type of atom present. Compounds
Each has a unique set of properties. Pure Substance.
Only one type of particle present.
Listed on the Periodic Table, with its
own symbol and Atomic Number. Each has a unique set of properties.
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Na Cl
Ions Cl-
electron (Atoms with an
Na+ ion
atom transfer atom electrical charge)
ion
17+
11+ 17+ 11+
Ionic Compounds
When atoms become ions they stick together and form a new substance.
This is a chemical compound, with different properties to the original elements.
Ionic compounds form crystals, made of billions of ions stuck together.
The diagram represents part of a crystal
of salt. Salt is the ionic compound Na+ Cl- Na+ Cl- Na+
Examples:
Compound of sodium + chlorine = “sodium chloride”
Compound of barium + oxygen = “barium oxide”
Compound of sulfur + aluminium = “aluminium sulfide”
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More on Valency
In a previous topic you were introduced to the idea of “valency”.
Valency is the “combining ratio” of an element which determines
the ratio with which it will combine with others.
Worksheet 1
Simple Ionic Compounds Student Name.............................................
(Revision) 2. A student attempted to write some
1. Write the name and formula for a chemical formulas. He got the symbols
compound made up of: correct, but everything else is wrong.
Write the correct formula & name.
a) potassium and iodine.
a) aluminium oxygenide, AlO2
.............................................. ................
b) barium and fluorine. .............................................. ................
b) sulfurium calcide, Ca2S1
.............................................. ................
c) magnesium and sulfur .............................................. ................
c) bromium hydrogide, H1Br1
.............................................. ................
d) chlorine and aluminium .............................................. ................
d) zinc sulfurious, Zn2S2
.............................................. ................
e) oxygen and silver .............................................. ................
e) sodoxide, ONa
.............................................. ................
.............................................. ................
Memorise these. All others can be deduced from the Periodic Table.
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Worksheet 2
Tutorial Worksheet Student Name.............................................
Compounds of Names
Multiple-Valency Metals As usual, name the metal first.
Formulas
For metals with more than one possible
Work out the formula exactly as usual. valency, you must write the valency
number (but not the charge sign) in
Metal symbols first, non-metal second. Roman numerals, in brackets after the
metal’s name.
You must figure out the smallest ratio of
ions which will give the same amount of These Roman numerals are shown in
+ve and -ve electrical charge. the name only, never in the formula.
Examples
Copper ions can be Cu+ or Cu2+. 2-
Cu+ O Cu+
Cu2+ O2-
Combined with oxygen, there are
2 possible compounds: Cu2O CuO
copper (I) oxide copper (II) oxide
c) d) e)
CuBr
f) g) h)
iron (III) fluoride
i) j)
Fe2+ F-
k) l) m)
PbS
n) o) p)
PbS2
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Worksheet 3
Tutorial Worksheet Student Name.............................................
Compounds of
Formulas
Polyatomic Ions As usual, you must figure out the
Use the Table of Data Next Page smallest ratio of ions which will give
Names Dead easy! the same amount of +ve and -ve
electrical charge.
As usual, metal (or +ve ion name) first.
Treat the polyatomic ion exactly as if it
Names of polyatomic ions do not was a simple ion.
change.
If more than one polyatomic ion is
If multiple-valency metals are involved, needed in the formula, its symbols
the rules for their names still apply. must be bracketed.
example: the compound of Fe3+ ion and e.g. Mg(NO3)2 NOT MgNO3 2
the hydroxide ion (OH-) is
This could be mis-understood to mean
iron (III) hydroxide, Fe(OH)3 32 atoms of oxygen, when what is meant
is that there are TWO nitrate (NO3-) ions.
c) d) e)
AgOH
f) g) h)
iron (II) sulfate
i) j)
Ba2+ CO3 2-
k) l) m)
Al(NO3)3
n) o)
NH4 + Cl-
p) q) r) ammonium sulfate
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Polyatomic Ion
Ammonium NH4 1+
Memorise these. All others can be deduced from the Periodic Table.
Worksheet 4
Ionic Allsorts Student Name.............................................
Some atoms achieve full outer orbits by sharing electrons with each other.
Diatomic Molecules Covalent Compounds
(di = 2. “diatomic” = 2 atoms)
Many of the elements which are gases at Many atoms can bond together to form
room temperature are not made up of “molecules” by sharing a pair of
single atoms, but of pairs of atoms electrons.
joined together. Cl2
H2 F2 Mostly it is the non-metal elements
N2 O2 (which all need to gain electrons) which
Diatomic Gas form these covalent, sharing bonds.
Elements
(Metal atoms need to lose electrons, so
they form ions and go in for ionic
bonding.)
The Inert Gases always
exist as single atoms
because they do not form Non-metals can gain electrons by either:
chemical bonds.
How does this happen? • forming -ve ions & ionic bonds,
or • sharing electrons covalently.
Imagine 2 chlorine atoms:
Each has
Water
7 electrons
in outer Our most familiar compound is covalent.
+ orbit. + inner
One oxygen H atom Oxygen orbits
(inner orbits atom not
not shown) atom shares shown
a pair of + +
If they get electrons with
very close each of 2 hydrogen H atom
together, atoms. +
shared pairs
they can + + of electrons
Similarly, H2, N2, O2, F2 (as well as Br2 & More important covalent
I2) form diatomic molecules by sharing compounds next page...
electrons in a “covalent bond”.
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Symbol Equation: O2 + H2 H 2O
(Remember that oxygen &
hydrogen are diatomic molecules... O2 and H2)
This symbol equation is NOT fully correct, because it does not show the
same number of atoms before and after the reaction.
To be fully correct, a symbol equation must be “balanced”.
The chemicals you start with are The chemicals you end up with
called “Reactants” are called “Products”
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Worksheet 5
Balancing Equations Student Name.............................................
Balance each of the following chemical equations.
Remember you must NOT change any formulas.
Balance an equation by writing numbers in front of a formula ONLY.
10. H 2O + Na H2 + NaOH
13. P4 + O2 P2O5
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Decomposition Reactions
Decomposition means to break down into simpler parts.
Decomposition Decomposition of
of a Compound Carbonates
“Carbonates” are ionic compounds
into its Elements containing the carbonate ion, CO3-2
combined with a metal ion.
You may see this reaction demonstrated:
Water When heated, carbonate compounds
decompose into simpler chemicals:
Hydrogen
gas, H2
example:
Oxygen gas,
O2 calcium calcium + carbon
carbonate oxide dioxide
The water
molecules CaCO3 CaO + CO2
have
decomposed. Gas released is
bubbled
The through
compound limewater.
has been
broken up
into its
Electricity elements.
Compound
supply
to be
decomposed
Word Equation
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Worksheet 6
Decomposition Student Name.............................................
Word Equations 5. Write a word equation for the
1. If you pass electricity into molten salt decomposition of magnesium carbonate
(sodium chloride) it decomposes into its into magnesium oxide and carbon dioxide.
elements. Write a word equation for this.
Worksheet 7
Decomposition Student Name.............................................
Word & Symbol Equations
Write a symbol equation for each 5.
reaction in Worksheet 6, then balance.
7.
3. (iodine is I2)
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Combustion Reactions
“Combustion” simply means burning.
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Worksheet 8
Combustion Student Name.............................................
Word Equations 4. combustion of methane to form
carbon dioxide and water.
Write a word equation for:
Worksheet 9
Combustion Student Name.............................................
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Precipitation Reactions
Many of the ionic compounds are soluble in water. They dissolve to form clear
solutions... they may be coloured, but are “see-through”.
If you mix together 2 different ionic solutions, often nothing happens... they just
mix together. Sometimes, however, a reaction occurs...
An Insoluble Precipitate Predicting a Precipitate
You might try this (or something similar) How can you predict when a reaction
in the laboratory: will occur, or when nothing will happen?
However, the combination of Ag+ and Cl- Na2S + CuSO4 CuS + Na2SO4
ions is not soluble in water.
(copper(II) sulfide is insoluble)
These ions instantly joined into a solid
crystal lattice and tiny solid particles
appeared, suspended in the water. This potassium + silver silver + potassium
solid will slowly fall down (“precipitate”) hydroxide nitrate hydroxide nitrate
to the bottom. The other ions remain in
solution as a new, dissolved compound. KOH + AgNO3 AgOH + KNO3
(silver hydroxide is insoluble)
Equations
sodium + silver silver + sodium
chloride nitrate chloride nitrate sodium + lead(II) lead(II) + sodium
carbonate nitrate carbonate nitrate
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Worksheet 10
Precipitation Student Name.............................................
Word Equations
1. Solutions of potassium carbonate and zinc chloride were mixed. A precipitate of
zinc carbonate formed because it is not soluble. Write a word equation for this.
2. When solutions of sodium iodide and lead (II) nitrate were mixed, a bright yellow
precipitate of insoluble lead (II) iodide formed. Write a word equation for the reaction.
3. When a solution of iron (III) chloride was added to sodium hydroxide solution, a
precipitate formed. What is the name of the most likely precipitate?
Answer with a word equation, showing which substance precipitated.
4. Barium sulfate is not soluble in water, but barium nitrate is soluble. What would
happen if a barium nitrate solution was mixed with copper (II) sulfate solution?
Answer by writing a word equation.
Worksheet 11
Student Name.............................................
Precipitation Write an equation in words, then in
Word & Symbol Equations symbols and balance.
1. Solutions of sodium carbonate and lead (II) nitrate were mixed. A precipitate of
lead carbonate formed because it is not soluble. Another compound remained in
solution.
3. Solid copper (II) sulfide formed when solutions of copper (II) sulfate and sodium
sulfide were mixed.
4. When sodium hydroxide and silver nitrate solutions were mixed a solid precipitate
formed. You should be able to guess what it was and write an equation.
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Corrosion
The most familiar example of corrosion is the rusting of iron or steel.
More generally, corrosion means a chemical reaction to a metal
which weakens it and eats it away.
Whether it reacts with oxygen, or something else, the point is that the metal is not
the metal element any more. It reacts to form a compound which is ugly & weak.
The metal loses its shininess and its strength... this is corrosion.
Acid-Base Indicators
Indicators are useful for identifying acids or bases.
An indicator chemical is coloured and it changes colour quite noticeably
depending on whether it is in contact with an acid or a base.
Some
Common in Pure water
Indicators in Acid (neutral) in Alkali
This indicator
cannot tell base or
Methyl Orange water apart, but can
identify an acid.
Orange Orange
Red “Acid Indicator”
This indicator
cannot tell acid or
Phenophthalein water apart, but can
identify a base.
clear Pink
clear “Base Indicator”
Universal Indicator
As its name suggests, this
indicator can identify acids,
alakalis and solutions which Blue
Red Green
are neither. (Neutral)
Neutralisation
Neutralisation is the reaction which occurs if an acid is mixed with a base.
Each destroys the other so that (if you have just the right quantities) the products
are neutral water and another dissolved ionic compound.
Example Reactions
The key to understanding neutralisation
Hydrochloric + potassium water + potassium
Every acid Every These acid hydroxide chloride
contains alkali react to
contains form
HCl + KOH H2O + KCl
H+ + OH- H 2O
Sulfuric + sodium water + sodium
acid hydroxide sulfate
The hydrogen ions (in every acid) react
with the hydroxide ions (in every alkali) H2SO4 + 2NaOH H2O + Na2SO4
to form water, which is neutral.
Water is always formed. The other product is called “a salt”.
Hydrochloric acid always produces “chloride salts”, sulfuric always gives
“sulfate salts” and nitric acid always makes “nitrate salts”.
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Worksheet 12
Corrosion Reactions Student Name.............................................
1. Write a word equation to describe: 2. Write a symbol equation (and balance)
for each reaction described in Q1 at left.
a) the surface corrosion of aluminium.
(When exposed to air, a layer of a)
aluminium oxide forms.)
c) the tarnishing of copper to copper (I) c) (use the symbol “S” for elemental sulfur)
sulfide in the presence of sulfur.
Worksheet 13
Student Name.............................................
Neutralisation
1. Write a word equation for the 2. Write a symbol equation (and
neutralisation reaction between: balance) for each reaction described in
Q1 at left.
a) hydrochloric acid and potassium
hydroxide. a)
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H2SO4 + Zn H2 + ZnSO4
Acid solution
In general terms:
Acid + Metal Hydrogen + a “salt”
Observed Changes
Temperature rises.
Bubbles form, because a gas is produced. You will find that not all metals will react
Magnesium is “eaten away” and disappears. and some react faster than others.
When acids react with carbonates they always produce CO2 gas
and water and a “salt” compound.
Examples:
copper(II) + sulfuric carbon + water + copper(II)
carbonate acid dioxide sulfate
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Worksheet 14
Acids & Metals Student Name.............................................
1. Write a word equation for the reaction 2. Write a symbol equation (and balance)
between: for each reaction described in Q1 at left.
Worksheet 15
Student Name.............................................
Acids & Carbonates
2. Write a symbol equation (and
1. Write a word equation for the reaction balance) for each reaction described in
between: Q1 at left.
d)
d) iron (III) carbonate and nitric acid.
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Topic Test 1
Compounds & Reactions Student Name............................................. Score = /30
List Items Not all will be used. d) the reaction of sulfuric acid on the
Some may be used more than once.
A. oxygen D. corrosion metal calcium.
B. neutralisation E. positive
C. combustion F. chloride
2. (4 marks)
What is the difference between ionic 5. (4 marks)
chemical bonding and covalent chemical a) The familiar substance “salt” is
bonding? described as being an “ionic crystal
lattice”. What does this mean? Use a
simple, labelled diagram to explain.
b) NaCl
c) H2SO4
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Topic Test 2
Student Name............................................. Score = /27
Compounds & Reactions
3. (3 marks)
Balance the following equations
a) Al + Br2 AlBr3
4. (14 marks)
For each of the following reactions:
i) write a word equation (2 marks) ii) write a symbol equation & balance it. (5 marks)
i)
ii)
i)
ii)
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Worksheet 7 Worksheet 11
1. 2NaCl 2Na + Cl2 1. Na2CO3 + Pb(NO3)2 PbCO3 + 2NaNO3
2. 8MgS 8Mg + S8
3. 2AgI 2Ag + I2 2. K2SO4 + Ba(OH)2 BaSO4 + 2KOH
4. CaF2 Ca + F2
3. CuSO4 + Na2S CuS + Na2SO4
5. MgCO3 CO2 + MgO
6. CuCO3 CO2 + CuO
4. NaOH + AgNO3 AgOH + NaNO3
7. K2CO3 CO2 + K2O
e)
2. sodium + lead (II) lead (II) + sodium
hydrochloric + magnesium water + magnesium
iodide nitrate iodide nitrate
acid hydroxide chloride
3. iron (III) + sodium iron (III) + sodium
chloride hydroxide hydroxide chloride
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H O
e)
magnesium + sulfuric carbon+water+magnesium b) Water is made up of separate
molecules. Each one has
H
carbonate acid dioxide sulfate
2 hydrogen atoms and 1 oxygen
atom. They are bonded together
by sharing pairs of electrons. H O
H
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Topic Test 2
1.
2.
a) barium sulfate
b) methane a) Ca(NO3)2 b) FeBr3
c) iron (II) hydroxide
d) ammonium nitrate c) Cu(OH)2 d) (NH4)2SO4
e) aluminium carbonate
e) NH3
3.
a) 2Al + 3Br2 2AlBr3
4.
a) i) pentane + oxygen carbon dioxide + water
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