Page 1/7

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 17.01.2013 Version number 14 Revision: 10.12.2012

* 1 Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier
· Trade name: OKS 1361
· 1.2 Relevant identified uses of the substance or mixture and uses advised against Foodstuff
· Application of the substance / the preparation Coating
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
OKS Spezialschmierstoffe GmbH
Ganghoferstr. 47
D-82216 Maisach
Tel. +49 8142 3051 500
Fax. +49 8142 3051 599
E-Mail: mcm@oks-germany.com
· Informing department: MCM departement
· 1.4 Emergency telephone number: (+49) 8142-3051 517

* 2 Hazards identification
· 2.1 Classification of the substance or mixture
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
F+; Extremely flammable
R12: Extremely flammable.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification
guideline for preparations of the EU" in the latest valid version.
· Classification system:
The classification is in line with current EC lists. It is expanded, however, by information from
technical literature and by information furnished by supplier companies.
· 2.2 Label elements
· Labelling according to EU guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on
Hazardous Materials (GefStoffV)
· Code letter and hazard designation of product:

F+ Extremely flammable

· Risk phrases:
12 Extremely flammable.
· Safety phrases:
2 Keep out of the reach of children.
9 Keep container in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
23 Do not breathe spray.
51 Use only in well-ventilated areas.
60 This material and its container must be disposed of as hazardous waste.
· Special labelling of certain preparations:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C.
Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material.
(Contd. on page 2)
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 Page 2/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.01.2013 Version number 14 Revision: 10.12.2012

Trade name: OKS 1361

(Contd. of page 1)
Buildup of explosive mixtures possible without sufficient ventilation.
· Classification in accordance with Directive 75/324/EEC: Extremely flammable
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

* 3 Composition/information on ingredients
· 3.2 Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with harmless additions.
· Dangerous components:
CAS: 106-97-8 butane, pure 50-75%
EINECS: 203-448-7 F+ R12
Flam. Gas 1, H220; Press. Gas, H280
CAS: 74-98-6 propane liquefied 25-50%
EINECS: 200-827-9 F+ R12
Flam. Gas 1, H220; Press. Gas, H280
· Additional information For the wording of the listed risk phrases refer to section 16.

* 4 First aid measures

· 4.1 Description of first aid measures
· General information Instantly remove any clothing soiled by the product.
· After inhalation
Supply fresh air; consult doctor in case of symptoms.
In case of unconsciousness bring patient into stable side position for transport.
· After skin contact Wash with water and soap and rinse thoroughly.
· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
· After swallowing Do not induce vomiting; instantly call for medical help.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· 5.1 Extinguishing media
· Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
· For safety reasons unsuitable extinguishing agents Water with a full water jet.
· 5.2 Special hazards arising from the substance or mixture
Can be released in case of fire
Carbon monoxide (CO) and carbon dioxide ( CO2 )
Can form explosive gas-air mixtures.
· 5.3 Advice for firefighters
· Protective equipment:
Wear self-contained breathing apparatus.
Do not inhale explosion gases or combustion gases.
Wear full protective suit.
(Contd. on page 3)
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 Page 3/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.01.2013 Version number 14 Revision: 10.12.2012

Trade name: OKS 1361

(Contd. of page 2)
· Additional information Cool endangered containers with water spray jet.

6 Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Keep away from ignition sources
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
· 6.2 Environmental precautions:
Do not allow to enter drainage system, surface or ground water.
Do not allow to enter the ground/soil.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 8 for information on personal protection equipment.

* 7 Handling and storage

· 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Keep away from heat and direct sunlight.
Use only in well ventilated areas.
· Information about protection against explosions and fires:
Fumes can combine with air to form an explosive mixture.
Keep ignition sources away - Do not smoke.
Do not spray on flames or red-hot objects.
Protect from heat.
Protect against electrostatic charges.
Beware: Container is pressurized. Keep away from direct sun exposure and temperatures over
50°C. Do not open by force or throw into fire even after use.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers:
Observe official regulations on storing packagings with pressurized containers.
Store in cool location.
· Information about storage in one common storage facility: Store away from oxidizing agents.
· Further information about storage conditions:
Store in a cool place. Heat will increase pressure and may lead to the container exploding.
· Storage class 2B
· 7.3 Specific end use(s) No further relevant information available.

* 8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.01.2013 Version number 14 Revision: 10.12.2012

Trade name: OKS 1361

(Contd. of page 3)

· 8.1 Control parameters

· Components with critical values that require monitoring at the workplace:
106-97-8 butane, pure
WEL Short-term value: 1810 mg/m³, 750 ppm
Long-term value: 1450 mg/m³, 600 ppm
Carc (if more than 0.1% of buta-1.3-diene)
· Additional information:
The currently valid safety information database was used to compile this data sheet.
· 8.2 Exposure controls
· Personal protective equipment
· General protective and hygienic measures
Do not eat, drink or smoke while working.
Wash hands during breaks and at the end of the work.
Do not inhale gases / fumes / aerosols.
Instantly remove any soiled and impregnated garments.
Avoid contact with the eyes and skin.
· Breathing equipment: Not necessary if room is well-ventilated.
· Protection of hands: Protective gloves.
· Material of gloves Nitrile rubber, NBR
· Penetration time of glove material
For the mixture of chemicals mentioned below the penetration time has to be at least 480 minutes
(Permeation according to EN 374 Part 3: Level 6).
· Eye protection: Tightly sealed safety glasses.

* 9 Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Aerosol
Colour: Colourless
· Smell: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Not applicable, as aerosol
Boiling point/Boiling range: Not applicable, as aerosol
· Flash point: Not applicable, as aerosol
· Inflammability (solid, gaseous) Not applicable.
· Ignition temperature: 365°C (DIN 51 794)
· Decomposition temperature: Not determined.
· Self-inflammability: Product is not self igniting.
· Danger of explosion: Not determined.
· Critical values for explosion:
Lower: 1.4 Vol %
Upper: 10.8 Vol %
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.01.2013 Version number 14 Revision: 10.12.2012

Trade name: OKS 1361

(Contd. of page 4)

· Vapor pressure: Not determined.

· Density at 20°C 0.63 g/cm³ (DIN 51 757)
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
dynamic: Not determined.
kinematic: Not determined.
· 9.2 Other information No further relevant information available.

10 Stability and reactivity

· 10.1 Reactivity
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions
Danger of bursting
Reacts with oxidizing agents
Forms explosive gases / fumes
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: Carbon monoxide and carbon dioxide

* 11 Toxicological information
· 11.1 Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
106-97-8 butane, pure
Inhalative LC50/4 h 658 mg/l (rat)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritant effect.
· Sensitization: No sensitizing effect known.

12 Ecological information
· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water.
(Contd. on page 6)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.01.2013 Version number 14 Revision: 10.12.2012

Trade name: OKS 1361

(Contd. of page 5)
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

13 Disposal considerations
· 13.1 Waste treatment methods
· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage
system.
· European waste catalogue
16 05 04* gases in pressure containers (including halons) containing dangerous substances
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

* 14 Transport information
· 14.1 UN-Number
· ADR, IMDG, IATA UN1950
· 14.2 UN proper shipping name
· ADR 1950 AEROSOLS
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· 14.3 Transport hazard class(es)
· ADR
· Class 2 5F Gases.
· Label 2.1
· IMDG, IATA
· Class 2.1
· Label 2.1
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards:
· Marine pollutant: nein
· 14.6 Special precautions for user Warning: Gases.
· Kemler Number: -
· EMS Number: F-D,S-U
· 14.7 Transport in bulk according to Annex II
of MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Tunnel restriction code D
GB
(Contd. on page 7)

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 17.01.2013 Version number 14 Revision: 10.12.2012

Trade name: OKS 1361

(Contd. of page 6)

* 15 Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
· VOC- Concentration 88.80 %
· Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This data is based on our present knowledge. However, it shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
R12 Extremely flammable.
· Department issuing data specification sheet: Technical departement
· * Data compared to the previous version altered.
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