01

XI (F.Sc.) CHEMISTRY Ch # 5

07-12-2013 10 10 MINUTES

Q.No.1 Choose the best option. 10

(i) Quantum number value for 2p orbitals is
(a) n=2 & 1=1 (b) n=1 & 1=2 (c) n=1 & 1=0 (d) n=2 & 1=0
(ii) When 6d orbital is complete, the entering electron goes into
(a) 7f (b) 7s (c) 7p (d) 7d
(iii) For d-sub-shell the azimuthal quantum number is
(a) 2 (b) 3 (c) 4 (d) 5
(iv) The electronic configuration of H is -

(a) IS2 (b) IS-1 (c) 2S-1 (d) 2S-2

(v) The mass of hydrogen atom is ________ gms.
(a) 1.6 x 10-27 (b) 1.6 x 10-26 (c) 1.6x10-25 (d) 1.6x10-24
(vi) Splitting of spectral lines when atoms are subjected to strong electric fields is called
(a) zeeman effect (b) stark effect (c) photoelectric effect (d) compton effect
(vii) Cathode rays produced greenish fluorescence on
(a) tin (b) alumina (c) silica (d) glass wall
(viii) In ground state of an atom, the electron is present.
(a) in the nuclecus (b) in second shell
(c) nearest the nucleus (d) farthest from the nucleus
(ix) Alpha rays consist of
(a) photon (b) neutrons (c) hydrogen nuclei (d) helium nucleus
(x) Plank equation is
(a) E=mc (b) E=mc2 (c) E=hv2 (d) E=hv

30 50 MINUTES
Q.No.2 Give short answers to the following questions. 10x2=20
(i) Why e/m value of cathode rays is just equal to that of electron?
(ii) Total energy of the bounded electron is also negative. Explain?
(iii) H and He+ are monoelectronic system but size of He+ is much smaller than H why?
(iv) Distribute the electrons is the orbital of Cu29 and Cr24?
(v) What are X-rays and what is their origin?
(vi) What is difference between continuous and line spectroum?
(vii) What is Paulis exclusion principle?
(viii) Differentiate between Orbit and Orbital?
(ix) Describe the defect of Rurtherfords Model?
(x) What is Zeeman effect?
Q.No.3 (A) Explain the Milikans oil drop experiment for determining the charge of an
electron?
Q.No.4. Point out the defects of Bohrs model. How these defects are partially covered by
sdual nature of electrons and heisenbergs uncertainty principle?