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2009 Society of Economic Geologists, Inc.

Economic Geology, v. 104, pp. 623633

Resources of Gold in Phanerozoic Epithermal Deposits


STEPHEN E. KESLER1, AND BRUCE H. WILKINSON2
1 Department of Geological Sciences, University of Michigan, Ann Arbor, Michigan 48109-1005
2 Department of Earth Sciences, Syracuse University, Syracuse, New York 13244-1070

Abstract
We have estimated Earths endowment of gold in Phanerozoic epithermal deposits using a tectonic-diffusion
model, which simulates the emplacement of deposits at a shallow crustal depth and their subsequent vertical
tectonic migration in the crust. The calculation was calibrated by least-squares comparison of a calculated
age-frequency distribution to the age-frequency distribution for 448 epithermal deposits of Phanerozoic age.
Results indicate that ~17 percent of the epithermal deposits that formed through Phanerozoic time remain in
the crust today whereas ~83 percent have been removed by erosion. Assuming a similar age distribution for all
1,181 epithermal deposits in our compilation indicates that ~307,000 deposits formed throughout Phanerozoic
time, that ~63,000 of these remain in the crust, and that ~244,000 have been eroded. Grade and tonnage data
of gold in 757 epithermal deposits in the compilation have an arithmetic average of 34.7 t and yield an estimate
of 2.2 106 t of gold for epithermal deposits remaining in the crust.
Using the model-based vertical distribution of deposits remaining in the crust, we estimate that epithermal
deposits in the upper kilometer of the United States contain 2.9 104 t of gold. Adjusting for areas of out-
cropping volcanic rocks in each continent increases our estimate to 4.0 104 t. These estimates are similar to
the 1.7 104 t gold resource estimated by the U.S. Geological Survey using completely different methods.
Several comparisons based on these results provide insights into the efficiency of processes that form epi-
thermal deposits and the outlook for sustainability. For instance, all of the epithermal deposits that formed
through Phanerozoic time represent only about 0.03 percent of the gold in the crust. Only about 0.007 percent
of crustal gold remains in epithermal deposits; the rest has been eroded and recycled. This is consistent with
comparisons based on the flux of gold in the Taupo Volcanic Zone, which indicate that epithermal deposits trap
only 0.1 to 0.2 percent of the gold that moves through convergent margin hydrothermal systems. Epithermal
gold deposits that remain in the crust can supply current production from them for 1,400 to 5,000 years,
depending on success of exploration and depth of mining. Finally, we are consuming gold from epithermal
deposits about 17,000 times faster than Earth is replenishing the supply.

Introduction Principles of the Tectonic-Diffusion Model


EPITHERMAL DEPOSITS are the most common and widely dis- The tectonic-diffusion model that is used here to estimate
tributed hydrothermal concentrations of gold near the sur- the number of epithermal gold deposits in the crust relies on
face of Earths crust. Despite their abundance, or perhaps be- the fact that age-frequency distributions for mineral deposits
cause of it, estimates of Earths epithermal gold endowment reflect the rates at which they formed and moved to the sur-
have been limited to extrapolations of information from the face. Age-frequency distributions for mineral deposits at con-
surface to depths of about a kilometer (U.S. Geological Sur- vergent margins are log-normal (skewed) in form and there is
vey, 1998; Frimmel, 2008). Here we estimate Earths epi- a direct relation between the mode (most common value) in
thermal gold endowment using the tectonic-diffusion model these distributions and the depth at which the deposits form
of Wilkinson and Kesler (2007), which is based on the age- (Kesler and Wilkinson, 2006). Deposits that form at great
frequency distribution of these deposits (Fig. 1). This ap- depth require more time to reach the surface than deposits
proach differs from previous efforts in providing an estimate that form at shallow levels, and their age frequency distribu-
of global resources to greater depths in Earths crust. tion defines an older modal age. Using preliminary compila-
Epithermal deposits contain various combinations of gold, tions of isotopic ages, Kesler and Wilkinson (2006) showed
silver, arsenic, antimony, mercury, tellurium, and selenium, as that epithermal deposits, which form largely in the upper
well as locally important amounts of copper, zinc, and lead kilometer of the crust, have a modal age of ~3 Ma, whereas
(Lindgren, 1933; Simmons et al., 2005). Although some epi- porphyry copper deposits, which originate at average depths
thermal deposits are mined exclusively or largely for silver, of ~2 km, have a modal age of ~12 Ma, and orogenic gold de-
mercury, antimony and arsenic, most are exploited for their posits that form largely at average depths closer to 10 km have
contained gold. Even where another recovered element, es- a modal age of ~160 Ma. This relation between depths of em-
pecially silver, is more abundant than gold on an atomic basis, placement and modal ages makes ore deposits an excellent in-
gold is usually more important economically because of its dicator of uplift and denudation (erosion) rates, and provides
higher value. In this estimate of Earths epithermal gold re- the basis for the tectonic-diffusion model.
sources, we have tried to include all epithermal deposits in The basic function of the tectonic-diffusion model is to pro-
which gold is either the main product or an economically im- duce a theoretical (computational) age-frequency distribution
portant by-product. that comes as close as possible to matching the actual (real-
Earth) age-frequency distribution for a specific group or type
Corresponding author: e-mail, skesler@umich.edu of deposits (Wilkinson and Kesler, 2007). For the estimate of
Submitted: August 19, 2008
0361-0128/09/3829/623-11 623 Accepted: June 1, 2009
624 KESLER AND WILKINSON

computational surface, for different ratios of uplift, stasis, and


A subsidence. At each iteration of the model calculation, the
25
age-frequency distribution of deposits at the model surface is
Bin Size = 1 Ma compared to the age-frequency distribution for known de-
20
posits by conventional least-squares methods until a best-fit is
Deposits

n = 349
obtained. This provides a quantitative calibration for the cal-
15
culation, and results in estimates of the numbers of deposits
in the subsurface and at the surface, as well as those that have
10
been eroded. These numbers can be multiplied by an appro-
priate average metal content for the deposit type of interest
5
to obtain an estimate of total metal endowment contained in
these deposits. Kesler and Wilkinson (2008) used this ap-
60 50 40 30 20 10
proach and the porphyry copper deposit database of Singer et
al. (2005) to estimate Earths deposit-hosted endowment of
Age (my)
copper.
The depth at which the model deposits are emplaced in the
50 B calculation is estimated from geologic and fluid inclusion data
on actual deposits, as discussed below. The constant rate of
Bin Size = 0.1 deposit emplacement in the model calculation is intended to
40
Deposits

n = 448 approximate a long-term average global rate of mineraliza-


30 tion, but does not require that real-Earth rates of mineraliza-
tion are constant. It simply provides a base against which the
20 history of real-Earth mineralization can be compared. Devia-
tions from this average represent greater and lesser intensi-
10 ties of mineralization or preservation.
Geologic Characteristics of Epithermal Deposits
-1 0 1 2 3 Epithermal deposits form at temperatures of less than
log Age (my) about 300C in mainly subaerial hydrothermal systems that
occupy fractures and other permeable zones at depths of less
FIG. 1. Ages of epithermal gold-bearing deposits. A. Age-frequency dis- than about 1.5 km (Simmons et al., 2005). They are usually as-
tribution plotted on an arithmetic scale. Open bars show the actual age- sociated with volcanic or shallow intrusive rocks, largely in
frequency distribution for all deposits of Cenozoic age. Shaded bars are the
age-frequency distribution that would result if ore formation proceeded at a convergent margin settings, although they are also found in
Phanerozoic average rate. B. Age-frequency distribution (open bars) plotted rift and back-arc settings and less commonly in areas with lit-
on a log scale showing the approximate log-normal distribution of all deposit tle or no magmatism (Sillitoe, 1993; Cooke and Simmons,
ages. Shaded bars are the normal age-frequency distribution to the log data 2000; Hedenquist et al., 2000; Simmons et al., 2005). Geo-
(mean = 1.25, standard deviation = 0.71).
logic environments of this type are widespread in the modern
Earth and similar environments were probably present dur-
ing much of geologic history, making epithermal deposits
epithermal gold resources, we have compiled a global data- common and widespread.
base that is discussed below and that yields an age-frequency Information on epithermal deposits that is needed for the
distribution (Fig. 1) very similar to that from our preliminary tectonic-diffusion estimate includes their: (1) average depth
compilation (Kesler and Wilkinson, 2006). The important of formation, (2) average gold content, and (3) age-frequency
point to resource estimates is that in generating the theoreti- distribution. Although epithermal deposits have been divided
cal age-frequency distribution, the model calculation deter- into two and sometimes three different groups (Simmons et
mines the number and vertical distribution of deposits in the al., 2005), these groups are not sufficiently different (in terms
crust. The calculation does this by emplacing deposits at a of the three parameters used for the model calculation) to
fixed rate and crustal depth, and then allowing each one to merit separate treatment. Accordingly, epithermal gold de-
move randomly (tectonic diffusion) upward (uplift and ero- posits are considered as a single group for the purposes of this
sion), downward (subsidence and burial) or sideways (stasis) preliminary resource estimate.
during each interval of model time (Fig. 2). In the calculation, Information used in the estimate was obtained from sum-
some migration paths bring deposits upward to a position mary papers (Hedenquist et al., 1990; Sillitoe, 1993; Cooke
above the Earths surface, where they are eroded (Fig. 2A, and Simmons, 2000; Hedenquist et al., 2000; Simmons et al.,
B). Many other deposits undergo amounts of subsidence that 2005), supplemented by global compilations of Mosier et al.
equal or exceed rates of uplift and therefore remain in the (1986), Gosselin and Dub (2005) and unpublished data from
subsurface, never reaching the computational surface; these the U.S. Geological Survey (D.A. Singer, writ. commun., May
constitute Earths crustal endowment of ore deposits (Fig. 2008). Additional information came from regional surveys for
2C). the circum-Pacific (Hedenquist et al., 1990), southwest Pa-
As the calculation proceeds, the model determines the cific (White, 1995; Garwin et al., 2005), South America (Vila
numbers of deposits at different crustal depths, including the and Sillitoe, 1991; Billa et al., 2004) and Central America

0361-0128/98/000/000-00 $6.00 624


RESOURCES OF GOLD IN PHANEROZOIC EPITHERMAL DEPOSITS 625

Cripple Round
Tayoltita Creek Mountain Sleeper Porgera

1
Depth (km
2

3
A

35 30 25 20 15 10 5
Age (my)
Cerro Richmond
Yandan Pajingo Vanguardia Chelopech Hill

2
Depth (km

8
B
10

300 250 200 150 100 50


Age (my)
Depth (km

C
10

15

500 400 300 200 100


Age (my)
FIG. 2. Time-depth random-walk paths defined by the tectonic-diffusion model calculation showing how some known de-
posits (shaded diamonds) might have moved through crustal time-depth prior to exposure. All deposits were formed at a
depth of 0.5 km (large open diamonds to right). Panels A and B show several different spans of time since formation (deposit
ages): corresponding deposit ages are as follows: ~6 Ma (Porgera, PNG) to 38 Ma (Tayoltita, Mexico), B) ~50 Ma (Richmond
Hill, South Dakota) to 345 Ma (Yandan, Australia). Panel C shows hypothetical depth-time paths of five deposits that were
not exposed during Phanerozoic time. Note that several of these (still buried) deposits nearly reached the surface (shaded
diamonds) but were buried again and did not reemerge during the remainder of Phanerozoic time. If paths were continued
into Precambrian, several paths might emerge as older deposits, such as Hope Brook, with an age of 576 Ma (Dub et al.,
1998). Although duration of burial in these diagrams matches actual data, actual depths could have been greater or lesser.

(Nelson, 1995), and country-specific surveys for Argentina (Kouzmanov et al., 2005), Russia (Konstantinov et al., 1993;
(Echevarra et al., 2005; Roy et al., 2006), China (Mao et al., Nockelberg et al., 2005), Turkey (Yigit, 2009), and United
2007), Greece (Voudouris, 2006), Indonesia (van Leeuwen et States (Long et al., 1998; John, 2001; D.A. John, writ. com-
al., 1994), Japan (Watanabe, 2005), Mexico (Camprub et al., mun., December 2007 and March 2009). This was supple-
2003), New Zealand (Christie et al., 2007), Peru (Noble and mented by published research reports and/or corporate re-
McKee, 1999; Billa et al., 2004; Enrquez et al., 2004), Romania ports dealing with specific localities. The database used for

0361-0128/98/000/000-00 $6.00 625


626 KESLER AND WILKINSON

the model calculation contains information on 1,181 deposits deposits and showed that most of them formed between the
in 49 countries on all continents except Antarctica, and is surface and 1,200 m, with an average of about 500 m, which
available as a supporting document to this paper. is the value that we have used in our model calculations.
The database on which this calculation is based will be sub-
ject to change and debate at many levels. At the highest level, Ages of epithermal deposits
there is the question of what deposits to include. Deposits be- The age-frequency distribution used here for known (real-
longing to Carlin, skarn, porphyry copper, and orogenic Earth) epithermal deposits is based on isotopic age measure-
classes were obviously excluded, but many important deposits ments; most age ranges indicated by geological relations are
have transitional characteristics and required individual deci- too wide to be used. Almost all such age measurements for
sions. Among those are the porphyry gold deposits, including Quaternary and Tertiary-age epithermal deposits were ob-
Golden Sunlight, Kisladag and those in the Maricunga belt, tained from K-Ar or Ar-Ar analyses of K-feldspar, K-mica, or
which were included because they appear to have formed at alunite. Age measurements for a few older deposits were
approximately the same depth as other epithermal deposits based on Rb-Sr, Re-Os, or Sm-Nd methods. For a few de-
(Jensen and Barton, 2000; Muntean and Einaudi, 2000, 2001; posits in which isotopic data provided a relatively small range
Sillitoe, 2002, Fig. 1). Also included were deposits in detach- of permissible ages, an average age was used. Analytical error
ment faults such as Picacho and Mesquite in California, for most ages is within a few percent of the value used and
largely on the basis of their relatively shallow crustal setting has no effect on the log-normal form of the age-frequency
and gold-rich composition (Losh et al., 2005). The upper part distribution.
of some Bolivian tin-silver deposits such as Cerro Rico Deposits for which ages are available have a wide distribu-
formed under epithermal conditions and were also included tion in both age and geographic distribution. Most (~83%) of
(Kelly and Turneaure, 1970; Cunningham et al., 1996; Sillitoe the dated epithermal deposits in our compilation are Ceno-
et al., 1998). The Charters Towers goldfield in Queensland, zoic in age (Fig. 1A). In an age-frequency plot, numbers of
Australia, which has been described both as epithermal-to- Cenozoic deposits increase rapidly and then decrease more
shallow magmatic-hydrothermal (Allan and Yardley, 2007) slowly with increasing age (~7% decrease in number of de-
and orogenic (Goldfarb et al., 2005), was excluded on the posits per 1 Ma increase in age). The plot contains two max-
basis of the higher salinity and relatively higher pressures and ima (Fig. 1A), one between 2 and 4 Ma and another between
greater depths (relative to epithermal deposits) inferred from 11 and 17 Ma, both of which include deposits from numer-
ore-stage fluid inclusions (Kreuzer, 2005). There is also the ous geographic areas. From the standpoint of generalizations
question of how to distinguish districts, deposits, prospects, about theoretical age-frequency distributions made above,
and mines, a point that is discussed more fully below. Al- the maximum between 2 and 4 Ma, which contains more de-
though all of these issues are important at the level of indi- posits than any other similar age range, is essentially the
vidual deposits and districts, they are not sufficiently numer- same as the modal age identified in our original, much
ous to change the fact that about 103 epithermal deposits have smaller compilation of ages for epithermal deposits (Kesler
been identified worldwide or to change the general form of and Wilkinson, 2006). The maximum between 11 and 17 Ma,
the age-frequency distribution for these deposits. and especially that at 11 Ma, represents the largest departure
of real-Earth epithermal mineralization from the model-
Depths of formation of epithermal deposits based curve, which is also shown in Fig. 1A and discussed
In a few epithermal deposits, such as Ivanhoe, Buckskin, below.
and McLaughlin, the paleosurface is preserved in the form of Pre-Cenozoic epithermal deposits, which make up only
hot spring and sinter deposits, allowing direct estimation of ~19 pecent of the total (Fig. 1B) are more localized in their
depths of formation (Vikre, 1987; Sherlock et al., 1995; Wal- geographic distribution, a restriction undoubtedly reflecting
lace, 2003). More commonly, the paleosurface has been the smaller number of areas with exposed host rocks of
removed, and estimates must be based on fluid inclusion geo- appropriate age and geologic characteristics. Mesozoic-age
barometry, especially homogenization temperatures for coex- epithermal deposits and prospects are most numerous in
isting vapor and liquid inclusions indicating the presence of a southern Argentina (Cerro Vanguardia), eastern China, north-
boiling fluid (Vikre, 1985; Snger-von Oepen et al., 1989; eastern Russia, and western Canada (Toodoggone) (Diakow
Simmons and Christenson, 1994; Braithwaite and Faure, et al., 1991; Echevarra et al., 2005; Mao, 2007; Goryachev
2002). The main sources of error in these studies are uncer- and Yakubchuk, 2008). Paleozoic-age deposits are found only
tainty in measurement of homogenization temperatures, lack in a few areas, including northern Queensland (Pajingo),
of information about the composition and phase equilibria of where they are unmetamorphosed and clearly epithermal
dissolved gases, degree of communication between the rising (Baker et al., 2006), and the Lachlan fold belt (Temora, Peak
fluid and its paleosurface, and confusion between paleowater Hill) in Australia and the Slate belt (Brewer, Haile, Ridge-
tables and paleosurfaces (Roedder and Bodnar, 1980; Heden- way) in the United States, where variable degrees of defor-
quist and Henley, 1985; Simmons, 1991). Despite these un- mation and metamorphism have resulted in different inter-
certainties, where boiling curves based on fluid inclusion data pretations of their original form and setting (Thompson et
are projected to a known paleosurface, they yield geologically al., 1986; Kiff and Spence, 1987; Allibone et al., 1995; Ayuso
reasonable temperatures at or near 100C (Vikre, 1987; Sher- et al., 2005; Squire et al., 2007). Precambrian-age epithermal
lock et al., 1995; Peppard, 2002) and agree with geological re- deposits are rare, with the best examples being the Protero-
constructions. In a recent survey, Hedenquist et al. (2000) zoic-age, relatively unmetamorphosed Mahd adh Dhahab
summarized depth estimates for a large number of epithermal district in Saudi Arabia (Doebrich, 1984; Afifi, 1990) and the

0361-0128/98/000/000-00 $6.00 626


RESOURCES OF GOLD IN PHANEROZOIC EPITHERMAL DEPOSITS 627

strongly metamorphosed but still recognizable Orivesi de- the relation in equation (1) where N is the total number of
posit in Finland (Talikka and Manttari, 2005). Most possible epithermal deposits in our database,
Archean-age epithermal deposits are controversial. Epi-

Mk2
thermal models have been proposed for some deposits in the E = Ne (1)
Hemlo and Campbell-Red Lake districts in the Superior
province of Canada (Penczak and Mason, 1999; Muir, 2002) and k is the partitioning factor, expressed as equation (2),
as well as the Golden Mile in the Yilgarn province of Australia
(Clout et al., 1990), and Huston et al. (2002) has classified k =
N
/2 T, (2)
other Australian deposits including Opaline Well and related
deposits in the Mallina basin and Miralga Creek in the North where T is total amount of gold contained in the 757 deposits
Pole area as epithermal. Whether some or all of these repre- for which we have grade and tonnage information (Fig. 3A).
sent the shallow zones of a single phase of orogenic gold for- This distribution can be interpreted to be the result of a
mation (Groves et al., 2000) or younger, predeformational process that began with gold that was originally distributed
epithermal deposits in multiply mineralized terranes (Robert homogeneously in the crust and later moved into deposits
et al., 2005) remains a matter of study. From the standpoint with randomly distributed sizes.
of the resource estimate made here, it is clear that Precam- Gold contents of the epithermal deposits are also log-nor-
brian epithermal deposits are rare in the geologic record mally distributed with a log-mean of 3.9 (Fig. 3B). From the
and do not contribute significantly to global epithermal gold standpoint of crustal gold endowment, however, this log-
resources. mean value does not capture the fact that most gold in the
epithermal population is in a relatively few large deposits
Gold contents of epithermal deposits (Fig. 3B). About 5 percent of all epithermal gold is in one de-
Cataloging gold contents of epithermal deposits involves posit (Yanacocha), 25 percent is in the seven largest deposits,
two complications, defining individual deposits and arriving
at an appropriate average for the gold content of all deposits.
The problem of how to define a deposit is a well-known com-
plication of efforts to catalog all ore deposits (Singer, 2008). A
In some areas, separate mines exploited what would be con-
Exceedence

sidered a single deposit from a geological perspective, such as 100


the Valencia, Cata, and Rayas mines that operated on the Veta n = 747
Madre structure at Guanajuato (Gross, 1975). Some of these Total = 25,520 Tonnes
operations were amalgamated later in their life, such as Nues- r2 = 0.99
10
tra Senora de Candelaria and San Luis that became the Tay-
oltita mine (Smith and Hall, 1974). Some deposits, such as
Kelly, Acupan, Antamok, and Baco in the Baguio district, are
so large that, even though they are linked by common struc-
tures (Cooke and Bloom, 1990), they could be considered ei- 1 100 10, 000 1,000,000
ther a single large district or several distinct ones. In some Deposit Gold Mass (kg)
modern operations, such as Yanacocha and Pueblo Viejo
(Turner, 1997; Kesler et al., 2003), entire districts containing
several deposits are combined into a single production unit. B

Cumulative Gold Content


60
100%
Any effort to correct the data for these many complications n = 747
Number of Deposits

and to list information only on geological deposits would al- 50


Bin Size = 0.2 80%
most certainly introduce new and perhaps more controversial Mean = 3.9 1.0
40
errors, and would definitely impede future efforts to update 60%
this compilation. 30
From the standpoint of estimating global epithermal re- 40%
20
sources, it appears that exact definition of geological de-
posits is not a major problem. Our main interest is simply to 10
20%

divide Earths epithermal deposit endowment into computa-


tionally manageable units that include as much known gold
-2.0 -1.2 -0.4 0.4 1.2 2.0 2.8 3.6 4.4 5.2 6.0
mineralization as possible. Confirmation that we have accom-
plished this is seen in the fact that the size distribution of de- log Gold Content (kg)
posits in our compilation can be described by the same den- FIG. 3. Frequency distributions of gold in epithermal deposits. A. Excee-
sity function that describes size-frequencies for numerous dence (Y-axis) plot showing the number of deposits with gold contents equal
common geologic features including lakes, fluvial drainage to or greater than the X-axis values. Heavy line is the ideal size-frequency dis-
basins, geologic units on maps, and tectonic plates (e.g. tribution where metal content of deposits is only dependent on the number
McElroy et al., 2005). In this density function, gold content of designated deposits and the total gold contained in these deposits. B. Log-
plot showing frequency distribution for logarithms of gold contents (kg) of
plotted relative to tonnage exceedence (E, the number of de- epithermal deposits. Heavy black line (left axis) is the best-fit log-normal dis-
posits with gold masses greater than or equal to some value) tribution. Heavy gray line (right axis) is cumulative percent of total gold.
of any deposit with some mass (M), is closely approximated by Note that most epithermal gold is hosted in a relatively few large deposits.

0361-0128/98/000/000-00 $6.00 627


628 KESLER AND WILKINSON

and 50 percent is in the 32 largest deposits. The arithmetic The model results can be scaled to include epithermal de-
mean gold content for the deposits (34.7 t) reflects these high posits for which we do not have isotopic ages by assuming that
values more reliably and is the best estimate of the average the age-frequency distribution for all 1,181 epithermal de-
gold content of the epithermal population. The total amount posits in our database has the same form as that for the 448
of gold in the 757 deposits for which data are available is deposits for which we have isotopic ages. With this change,
about 25,800 t, somewhat larger than the 17,900 t recently es- the calculations indicate that epithermal deposits formed at a
timated for global epithermal deposits by Frimmel (2008). total rate of 562 model deposits/m.y., that a total of ~307,000
model epithermal deposits have formed throughout Phanero-
Estimated Gold Resources and Possible Errors zoic time, that ~244,000 of these were uplifted and destroyed
by erosion, and that ~63,000 currently remain in the subsur-
Estimated gold resources face and constitute Earths endowment of epithermal deposits
The modeled age-frequency distribution (shaded bars in (Table 1). The loss of such a large fraction of epithermal de-
Fig. 1A) that best fits the observed age-frequency distribution posits to erosion results in a distribution pattern in time-
(open bars in Fig. 1A) indicates an average formation rate of depth space in which the maximum number of deposits deep-
213 model deposits per m.y. for Phanerozoic epithermal de- ens slightly with increasing time (Fig. 4).
posits with an emplacement depth of 0.5 0.3 km and pro- Earths epithermal gold endowment can be estimated by
portions of uplift, subsidence and stasis of 32, 36, and 32 per- multiplying the number of model deposits in the crust
cent, respectively (Table 1). These values result in 519 (63,000) by the average gold content of known epithermal de-
Phanerozoic epithermal deposits at the model surface com- posits. Because we assume that presently known epithermal
pared to 448 known deposits (with ages) in the database (Table deposits are a random sample of the total population of de-
1). Although some epithermal deposits are known to exist be- posits in the crust, the average gold content for known de-
neath shallow cover, this does not affect the similarity between posits represents that of unknown deposits. Using this aver-
model and observed age frequencies because the calculation age value (34.7 t) indicates that epithermal deposits have a
defines the upper 295 m of the crust as the surface (the tec- gold resource of about 2.2 106 t (Table 1). Deposits that
tonic step, Table 1), which includes these blind deposits. The have been removed by uplift and erosion during Phanerozoic
calculations indicate further that the 519 exposed model de- time contained an additional 8.5 106 t of gold. Although
posits constitute only ~0.4 percent of all model epithermal de- these estimates apply strictly to Phanerozoic deposits and
posits that have formed during Phanerozoic time (~116,000), rocks, the totals will not increase significantly if we expand
and that about 17 percent (~24,000) of these Phanerozoic the estimate to include Precambrian time because there are
model deposits remain in the subsurface (Table 1). so few deposits of this age.
These results do not represent all epithermal deposits,
however, because only some of the deposits in our database Possible sources of error in the estimate
have isotopic ages and were included in the age-frequency The most obvious sources of error in this estimate of epi-
distribution that was used to calibrate the model calculation. thermal gold resources are in the number and average gold
content of known epithermal deposits. Concern about the
TABLE 1. Results of the Model Calculation and Adjusted Amounts large number of undiscovered deposits estimated by the
Based on the Ratio of Dated Phanerozoic Deposits (448) Used in model calculation results, in part, from a tendency to think of
the Model Calculation to All Deposits (1181) in the Database ore deposits as features that form in the crust and then mi-
Adjusted for grate upward to be discovered and exploited. However, the
all deposits classical series of diagrams in Lowell (1968, fig. 2), as well as
Model result Unit in database more recent studies (Stavast et al., 2008), show clearly that
burial is an important part of the history of many ore deposits.
Emplacement depth1, 2 0.50 0.3 km
Emplacement rate1 213 /Ma 562
Acknowledgement of this fact, in turn, raises the possibility
Modal age1, 2 2 My that significant numbers of deposits remain buried in the
Tectonic step1 295 m/ Ma crust. Some of these deposits, especially those in metamor-
Modal exhumation rate1 250 m/ Ma phic terranes, are probably strongly deformed and possibly
Modal deposit depth1 0.88 km unrecognizable, although the presence of old deposits con-
Up-stasis-down1 32-36-32 %
Total deposits1 116,000 100% 307,000 firms that at least some survive extended burial and remain vi-
Extant deposits1 24,000 17% 63,000 able exploration targets.
Eroded deposits1 92,000 83% 244,000 Because the tectonic-diffusion model uses the age-fre-
Model exposed deposits1 519 quency distribution of known deposits to estimate the num-
Actual exposed deposits2 448
Average gold content2 t 34.7
ber of buried deposits, any increase in the number of known
Gold in total deposits1 t 10.6 106 deposits will cause an increase in the number of buried de-
Gold in eroded deposits1 t 8.5 106 posits. Thus, the tectonic-diffusion model will always yield a
Gold in extant deposits1 t 2.2 106 minimum estimate for the number of deposits in the crust.
For instance, if the number of known epithermal gold de-
The tectonic step, which is 295 m thick, represents the average vertical posits increased by 500 percent from about 103 to 5 103,
distance moved by deposits during each million years of the calculation; it is
therefore the thickness of the surface layer in the model calculation
which would be a major challenge for explorationists, gold re-
1Model-derived parameters sources throughout the crust would increase from 2.2 106
2Data-derived parameters to 1.1 107 t.

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RESOURCES OF GOLD IN PHANEROZOIC EPITHERMAL DEPOSITS 629

Earth Surface

100

10
Dep osits/km/Ma

0.1 5 km

0.01 5 Ma

Epithermal Gold Deposits


0.001

FIG. 4. Model distribution of epithermal gold deposits in age-depth space for the last 250 m.y. of Earth history (age is on
the X-axis, maximum = 250 Ma; depth is on the Y-axis, maximum = 20 km) assuming that the number of discovered deposits
in our database (1,164) approximately represents all such deposits now exposed at the Earths surface. Color shades are log-
scaled (left column) as the number of deposits that exist in each 1 Ma 1 km time-depth area (a 5 km 5 Ma grid is
shown as the gray reference rectangles). Deposits enter the diagram at the upper right source region (star) at the rate of 562
deposits per m.y. and migrate (diffuse) across the diagram through time. Of the ~307,000 deposits that formed over Phanero-
zoic time, about 20 percent (63,000) are preserved in the crust (42,700 of those <250 Ma in age are represented here), while
83 percent have been removed by uplift and erosion. The gradual deepening of the maximum number of deposits with in-
creasing time results from the loss of large numbers of deposits to erosion.

A more accurate estimate of the average gold content for included in our epithermal compilation. Thus, according to
epithermal deposits might offset some of this increase, how- the USGS study, about 1.7 104 t of gold should be present
ever. For instance, the average gold content used here (34.7 in these (epithermal-type) deposits in the upper 1 km of the
t) might be lowered by including gold contents for uneco- United States. The United States accounts for about 6.5 per-
nomic, small deposits and prospects. The magnitude of this cent of the total continental area of the planet and our cal-
effect can be estimated by assuming that all deposits in the culations indicate that about 20 percent of the epithermal
present database for which gold contents are not available ac- deposits in the crust are in the upper 1 km (Fig. 4). If epi-
tually contain no gold (0 t). If so, the average gold content of thermal deposits are equally distributed in the continents,
the entire population of deposits drops to 22 t and this yields our estimate indicates that about 2.9 104 t of gold should
an estimated global gold resource of 1.4 106 t, which is be present in epithermal deposits in the upper 1 km of the
about two-thirds of the value (2.2 106 t) estimated here. If United States. This comparison can be adjusted to recognize
we assume that the next 1,000 deposits that are found also that most epithermal deposits are in or near volcanic rocks
contain no gold, the average gold content of epithermal de- and that North America contains more than its share (23%)
posits drops to 11.6 t and the resource to 7.4 105 t, about of the worlds total exposure of Phanerozoic volcanic rocks
33 percent of the original value. (Choubert and Faure-Mauret, 1981). Assuming that the
This comparison suggests that the two main sources of proportion of volcanic rocks in the United States is the same
error will offset each other and that the ultimate gold en- as that in North America, results in an estimate of 4.0 104
dowment estimated here is unlikely to change by more than t. Thus, our estimates of gold in the epithermal deposits in
an order of magnitude. Comparison to a recent U.S. Geo- the upper 1 km of the United States are similar in magni-
logical Survey (USGS) study provides further support for tude and only 75 to 150 percent larger than the amount es-
this error estimate. In the USGS study, mineral deposits to timated by the USGS study. The similarity between our es-
a depth of 1 km in the crust of the United States were esti- timate and one based on traditional geologic inspection and
mated to contain ~4.5 104 t of gold (Anonymous, 1998). extrapolation suggests that the model-based approach pro-
About 38 percent of this gold was estimated to be in epi- vides a geologically realistic first approximation of Earths
thermal, hot spring or Au-Ag-Te deposits, all of which are epithermal gold resources.

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630 KESLER AND WILKINSON

Significance of the Estimated Gold Resource TABLE 2. Comparison between Metal Contents of Phanerozoic Porphyry
Copper and Epithermal Gold Deposits Relative to Crustal Abundances
Estimation of the resource of gold in epithermal deposits in (data for porphyry copper deposits from Kesler and Wilkinson, 2008)
the crust provides insight into the efficiency of geological
processes that make epithermal deposits, as well as the out- Cu in Phanerozoic porphyry copper deposits 7.0 1015 Moles
Cu content of the crust 6.2 1018 Moles
look for sustainable production of gold from them. With a Fraction of crustal Cu in porphyry copper deposits 0.11%
mass of 1.52 1019 t (Lodders and Fegley, 1998) and an av- Au in Phanerozoic epithermal deposits 5.4 1010 Moles
erage gold content of about 2.1 ppb (Taylor and McLennan, Au content of the crust 1.6 1014 Moles
1995; Wedepohl, 1995; Candela, 2004; Rudnick and Gao, Fraction of crustal Au in epithermal deposits 0.03%
RatioCu fraction/Au fraction 3.4
2004), the crust contains about 3.2 1010 t of gold. Some of Au content of average epithermal deposit 1.8 105 Moles
this gold was contributed to the crust by mantle-derived mag- Cu content of average porphyry copper deposit 5.5 1010 Moles
matism during Phanerozoic time (Richards, 2009), but an RatioCu in deposits/Au in deposits 312,000
equivalent amount was probably returned by subduction.
Thus, about 0.03 percent of the gold in the crust has been Molar units are used to reflect atomic rather than mass amounts
concentrated in an epithermal deposit at one time or another
during Phanerozoic time, and 0.007 percent of that gold re- copper into porphyry copper deposits does not mean that
mains in epithermal deposits. porphyry copper deposits are more abundant than epithermal
Considerably more gold probably passes through hy- deposits, however, because the average porphyry copper de-
drothermal systems but is not trapped. Simmons and Brown posit with 5.5 1010 moles of copper contains about 300,000
(2007) showed that the magmatically induced hydrothermal times more metal on an atomic basis than the average epi-
flux of gold in the Taupo Volcanic Zone was between 8 104 thermal deposit with 1.8 105 moles of gold (Table 2). The
and 1.6 percent 105 t over a period of 1 m.y., much larger than larger number and smaller average size of epithermal de-
the amount that might be trapped in epithermal deposits. Ac- posits is consistent with their residence in the uppermost part
cording to our calculations, 562 epithermal deposits contain- of the crust, where less heat is available to sustain large, long-
ing almost 2 104 t of gold formed throughout the world dur- lived hydrothermal systems.
ing a similar million-year period of Phanerozoic time. The Finally, these estimates of epithermal endowment provide
Taupo Volcanic Zone, with a length of 250 km, constitutes a rough indication of the sustainability of Earths production
about 0.56 percent of the 4.53 104 km length of all conver- of gold from epithermal deposits. This can be evaluated in
gent margin zones. If all of these global convergent margins two ways. Most simply, we can ask how long we can mine the
behaved like the Taupo Volcanic Zone over a 1-m.y. period, estimated epithermal gold resource. Approximately 2,500 t of
the flux of gold through Earths convergent margin zones gold are mined each year of which Frimmel (2008) estimates
would be between 1.4 and 2.9 107 t, or about 1,000 to 2,000 that 13 percent, or about 325 t, comes from epithermal de-
times larger than the amount of gold concentrated in epi- posits. If future epithermal gold deposits are discovered and
thermal deposits during the same period. Even if the global mined largely from the upper kilometer of Earths crust,
convergent margin flux were decreased by an order of mag- which contains about 20 percent of the epithermal resource
nitude, and acknowledging the anomalous nature of the as noted above, they might supply their share of societal de-
Taupo Volcanic Zone (Hochstein, 1995), epithermal deposits mand for a little less than 1,400 years. Even if mining goes to
would capture only a few percent of the magmatically in- depths of 3 km, the supply appears to be sufficient for less
duced hydrothermal flux of gold in convergent margin vol- than 5,000 years at current rates of consumption. On a larger
canic zones. This underscores the fact that mineral deposits scale, we can ask how rapidly we are depleting epithermal
are highly unusual geological features that capture only a gold deposits relative to the rate at which Earth is forming
small fraction of the crustal element flux. them. Model results indicate that Earth has formed, on aver-
We can also compare the metal concentrating efficiency of age, about 562 epithermal deposits containing almost 2 104
Earths epithermal deposits to that of porphyry copper de- t of gold per million years of Earth history (Table 1) whereas
posits with which some epithermal deposits are associated we are producing gold from epithermal deposits at a rate of
(Heinrich et al., 2004). Comparisons of this type must be about 3.25 108 t per million years. Thus, we are removing
based on molar quantities rather than on the more familiar gold from epithermal deposits about 17,000 times faster than
weight units because we are interested in the movement of Earth is making new deposits.
atoms. Kesler and Wilkinson (2008) used a variant on the tec- It is apparent from this comparison that the discovery rate
tonic-diffusion model employed here to estimate that Earth for epithermal gold deposits must remain high if we are to
concentrated about 7.05 1015 moles of copper in porphyry supply societal demand. In view of the fact that we know the
copper deposits throughout Phanerozoic time, and noted that location of considerably less than 1 percent of the epithermal
this constitutes about 0.11% of the total amount of copper in deposits that are estimated to be present, it is also apparent
the crust (Table 2). These values compare to our estimate that this will require extensive exploration.
here of about 5.4 1010 moles of gold in epithermal deposits
that formed through Phanerozoic time, which constitutes Acknowledgments
about 0.03 percent of the gold content of crust. Thus, Earth We are grateful to David John and Don Singer of the U.S.
has trapped ~3 to 4 times more crustal copper in porphyry Geological Survey for sharing their databases for epithermal
copper deposits than crustal gold in epithermal deposits deposits with us and to Antonio Arribas, Jeff Mauk, John
(Table 2). The fact that Earth is more efficient in extracting Muntean, Larry Meinert, Stuart Simmons, and Noel White

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RESOURCES OF GOLD IN PHANEROZOIC EPITHERMAL DEPOSITS 631

for discussions of epithermal deposits and helpful reviews of on El Dorado-Monserrat: Journal of South American Earth Sciences, v. 19,
various versions of this paper. The generous assistance of all p. 415432.
Echavarra, L.E., Schalamuk, I.B., and Etcheverry, R.O., 2005, Geologic and
of these colleagues does not indicate that they agree with all tectonic setting of Deseado Massif epithermal deposits, Argentina, based
of the conclusions that we have reached. on El Dorado-Monserrat: Journal of South American Earth Sciences, v. 19,
p. 415432.
REFERENCES Enrquez, J.A., Rodrguez, O., and Rodrguez, R., 2004, Geologa de los ya-
Afifi, A.M., 1990, Environments of gold telluride mineralization in the Mahd cimientos epitermales del tipo baja sulfuracin en el corredor estructural
adh Dhahab district, Arabian Shield: Unpublished Ph.D. dissertation, Uni- San Pablo-Porculla norte del Per: XII Congreso Peruano de Geologica
versity of Michigan, Ann Arbor, Michiban, 299 p. Resumenes Extendidos, Sociedad del Per, p. 724727.
Allan, M.M. and Yardley, B.W.D., 2007, Tracking meteoric infiltration into a Frimmel, H.E., 2008, Earths continental crustal gold endowment: Earth and
magmatic-hydrothermal system: A cathodoluminescence, oxygen isotope Planetary Science Letters, v. 267, p. 4555.
and trace element study of quartz from Mt. Leyshon, Australia: Chemical Garwin, S., Hall, R., and Watanabe, Y., 2005, Tectonic setting, geology, and
Geology, v. 240, p. 343360. gold and copper mineralization in Cenozoic magmatic arcs of Southeast
Allibone, A.H., Cordery, G.R., Morrison, G.W., Jaireth, S., Lindhorst, J.W., Asia and the West Pacific: ECONOMIC GEOLOGY 100TH ANNIVERSARY VOL-
1995, Synchronous advanced argillic alteration and deformation in a shear UME, p. 891930.
zone-hosted magmatic hydrothermal Au-Ag deposit at the Temora (Gidg- Goldfarb, R.J., Baker, T., Dub, B., Groves, D.I., Hart, C.J.R., and Gosselin, P.,
inbung) mine, New South Wales, Australia: ECONOMIC GEOLOGY, v. 90, p. 2005, Distribution, character and genesis of gold deposits in metamorphic
15701603. terranes: ECONOMIC GEOLOGY 100TH ANNIVERSARY VOLUME, p. 407450.
Ayuso, R.A., Wooden, J.L., Foley, N.K., Seal, R.R. II, and Sinha, A.K., 2005, Gosselin, P., and Dub, B., 2005, Gold deposits of the world: Distribution,
U-Pb zircon ages and Pb isotope geochemistry of gold deposits in the Car- geological parameters and gold content; Geological Survey of Canada,
olina slate belt of South Carolina: ECONOMIC GEOLOGY, v. 100, p. 225252. Open File 4895.
Baker, T., Mustard, R., Brown, V., Pearson, N., Stanley, C.R., Radford, N.W., Goryachev, N., and Yakubchuk, A., 2008, Gold deposits of Magadan region,
and Butler, I., 2006, Textural and chemical zonation of pyrite at Pajingo: A northeastern Russia: Yesterday, today and tomorrow: Society of Economic
potential vector to epithermal gold veins: Geochemistry: Exploration, En- Geologists Newsletter, no. 74, p. 111.
vironment, Analysis, v. 6, p. 283293. Groves, D.I., Goldfarb, R.J., Knox-Robinson, C.M., Ojala, J., Gardoll, S.,
Billa, M., Cassard, D., Lips, A.L.W., Bouchot, V., Tourliere, B., Stein, G., and Yun, G.Y., and Holyland, P., 2000, Late kinematic timing of orogenic gold
Guillous-Grottier, L., 2004, Predicting gold-rich epithermal and porphyry deposits and significance for computer-based exploration techniques with
systems in the central Andes with a continental-scale metallogenic GIS: emphasis on the Yilgarn Block, Western Australia: Ore Geology Reviews, v.
Ore Geology Reviews, v. 25, p. 3967. 17, p. 138.
Braithwaite, R.L., and Faure, K., 2002, The Waihi epithermal gold-silver- Gross, W.H., 1975, New ore discovery and source of silver-gold veins, Gua-
base metal sulfide-quartz vein system, New Zealand: Temperature and najuato, Mexico: ECONOMIC GEOLOGY, v. 70, p. 11751189.
salinity controls on electrum and sulfide deposition: ECONOMIC GEOLOGY, Hedenquist, J.W. and Henley, R.W., 1985, The importance of CO2 on freez-
v. 97, p. 269290. ing point measurement of fluid inclusions: evidence from active systems
Candela, P.A., 2004, Ores in the earths crust, in Holland, H.D., and Turekian, and implications for epithermal ore deposits: ECONOMIC GEOLOGY, v. 80, p.
K.K., eds., Treatise on geochemistry: Amsterdam, Elsevier, v. 3, p. 411432. 13791406.
Camprub, A., Ferrari, L., Cosca, M.A., Cardellach, E., Canals, ., 2003. Hedenquist, J.W., White, N.C. and Sidderly, G., eds., 1990, Epithermal
Ages of epithermal deposits in Mexico: Regional significance and links with gold mineralization of the circum-Pacific: Geology, geochemistry, origin
the evolution of Tertiary volcanism: ECONOMIC GEOLOGY, v. 98, p. and exploration: Journal of Geochemical Exploration, v. 35, 446 p. and v.
10291037. 36, 474 p.
Choubert, G., and Faure-Mauret, A., 1981, Atlas gologique du monde, map: Hedenquist, J.W., Arribas, A., Jr., and Gonzalez-Urien, E., 2000, Exploration
Comm. de la Carte Gol. du Monde, Bureau de Cartograhic Gologie In- for epithermal gold deposits: Reviews in Economic Geology, v. 13, p.
ternational: United Nations Educational, Scientific and Cultural Organiza- 245277.
tion, Paris, 32 sheets. Heinrich, C.A., Driesner, T., Stefnsson, A., and Seward, T.M., 2004, Mag-
Christie, A.B., Simpson, M.P., Brathwaite, R.L., Mauk, J.L., and Simmons, matic vapor contraction and the transport of gold from the porphyry envi-
S.F., 2007, Epithermal Au-Ag and related deposits of the Hauraki Gold- ronment to epithermal ore deposits: Geology, v. 32, p. 761764.
field, Coromandel volcanic zone, New Zealand: ECONOMIC GEOLOGY, v. Hochstein, M P., 1995, Crustal heat transfer in the Taupo volcanic zone (New
102, p. 785816. Zealand): comparison with other volcanic arcs and explanatory heat source
Clout, J.M.F., Cleghorn, J.H., and Eaton, P.C., 1990, Geology of the Kal- models: Journal of Volcanology and Geothermal Research, v. 68, p. 117151.
goorlie gold field: Australasian Institute of Mining and Metallurgy, Mono- Huston, D.L., Blewett, R.S., Keillor, V., Standing, J., Smithies, R.H., Mar-
graph Series, v. 14, p. 411432. shall, A., Mernagh, T.P., and Kamprad, J., 2002, Lode gold and epithermal
Cooke, D.R., and Bloom, M.S., 1990, Epithermal and subjacent porphyry deposits of the Mallina basin, North Pilbara complex, Western Australia:
mineralization, Acupan, Bagui district, Philippines: A fluid inclusion and ECONOMIC GEOLOGY, v. 97, p. 801818.
paragenetic study: Journal of Geochemical Exploration, v. 35, p. 297340. Jensen, E.P., and Barton, M.D., 2000, Gold deposits related to alkaline mag-
Cooke, D. and Simmons, S., 2000, Characteristics and genesis of epithermal matism: Reviews in Economic Geology, v. 13, p. 279314.
gold deposits: Reviews in Economic Geology, v. 13, p. 221244. John, D.A., 2001, Miocene and Early Pliocene epithermal gold-silver de-
Cunningham, C.G., Zartman, R.E., McKee, E.H., Rye, R.O., Naeser, C.W., posits in the northern Great Basin, western United States: Characteristics,
Sanjines, V.O, Ericksen, G.E., and Tavera, V.F., 1996, The age and ther- distribution and relationship to magmatism: ECONOMIC GEOLOGY, v. 96, p.
mal history of Cerro Rico de Potosi, Bolivia: Mineralium Deposita, v. 31, p. 18271854.
374385. Kelly, W.C. and Turneaure, F.S., 1970, Mineralogy, paragenesis and geother-
Diakow, L.J., Panteleyev, A., and Schroeter, T.G., 1991, Jurassic epithermal mometry of the tin and tungsten deposits of the eastern Andes, Bolivia:
deposits in the Toodoggone River area, northern British Columbia; exam- ECONOMIC GEOLOGY, v. 65, p. 609680.
ples of well-preserved, volcanic-hosted, precious metal mineralization: Kesler, S.E., and Wilkinson, B.H., 2006, The role of exhumation in the tem-
ECONOMIC GEOLOGY, v. 86, p. 529554. poral distribution of ore deposits: ECONOMIC GEOLOGY, v. 101, p. 919922.
Doebrich, J.L., 1984, Geology and hydrothermal alteration at the Mahd Adh 2008, Earths copper resources estimated from tectonic-diffusion of por-
Dhahab precious metal deposit, Kingdom of Saudi Arabia: Unpublished phyry copper deposits: Geology, v. 36, p. 255258.
M.S. thesis, Golden, Colorado, Colorado School of Mines, 148 p. Kesler, S.E., Fortuna, J., Ye, Z., Alt, J.C., Core, D.P., Zohar, P., Borhauer, J.,
Dub, B., Dunning, G., and Lauzire, K., 1998, Geology of the Hope Brook and Chryssoulis, S., 2003, Evaluation of the role of sulfidation in deposition
mine, Newfoundland, Canada: A preserved Late Proterozoic high-sulfida- of gold, Screamer section of the Betze-Post Carlin-type deposit, Nevada:
tion epithermal gold deposit and its implications for exploration: ECO- ECONOMIC GEOLOGY, v. 98, p. 11371157.
NOMIC GEOLOGY, v. 93, p. 405436. Kiff, I.T., and Spence, W.H., 1987, Volcanogenic-epithermal-exhalative gold
Echevarra, L.E., Schalamuk, I.B., and Etcheverry, R.O., 2005, Geologic and deposits of the Haile-type in the Carolina slate belt [abs.]: Geological Soci-
tectonic setting of Deseado Massif epithermal deposits, Argentina, based ety of America Abstracts with Programs, v. 19, p. 394.

0361-0128/98/000/000-00 $6.00 631


632 KESLER AND WILKINSON

Konstantinov, M.M., Rosenblum. I.S. and Strujkov, S.F., 1993, Types of epi- Rudnick, R.L., and Gao, S., 2004, Composition of the continental crust, in
thermal silver deposits, northeastern Russia: ECONOMIC GEOLOGY, v. 88, p. Holland, H.D., and Turekian, K.K., eds., Treatise on Geochemistry: Ams-
17971809. terdam, Elsevier, v. 3, p. 164.
Kouzmanov, K., Bailly, L., Tamas, C. and Ivascanu, P., 2005, Epithermal Pb- Snger-von Oepen, P., Friedrich, G., and Vogt, J.H., 1989, Fluid evolution,
Zn-Cu-Au) deposits in the Baia Mare district, Eastern Carpathians, Roma- wallrock alteration, and ore mineralization associated with the Rodalquilar
nia: Ore Geology Reviews, v. 29, p. 4849. epithermal gold-deposit in southeast Spain: Mineralium Deposita, v. 24, p.
Kreuzer, O.P., 2005, Intrusion-hosted mineralization in the Charters Towers 235243.
goldfield, North Queensland: New isotopic and fluid inclusion constraints Sherlock, R.L., Tosdal, R.M., Lehrman, N.J., Graney, J.R., Losh, S., Jowett,
on the timing and origin of the auriferous veins: ECONOMIC GEOLOGy, v. E.C. and Kesler, S.E., 1995, Origin of the McLaughlin mine sheeted vein
100, p. 15831603. complex: metal zoning, fluid inclusion, and isotopic evidence: ECONOMIC
Lindgren, W., 1933, Mineral Deposits, 4th ed., New York, McGraw-Hill. GEOLOGY, v. 90, p. 2156-2181.
Lodders, K., and Fegley Jr., B. 1998, The planetary scientists companion: Sillitoe, R.H., 1993, Epithermal models: Genetic types, geometrical controls
New York, Oxford University Press, 371 p. and shallow features, in Kirkham, R.V., Sinclair, W.D., Thorpe, R.I., and
Long, K.R., DeYoung, Jr., J., and Ludington, S.D., 1998, Database of signif- Duke, J.M., eds., Mineral deposit modeling: Geological Association of
icant deposits of gold, silver, copper, lead, and zinc in the United States: Canada Special Paper 40, p. 403418.
Open-File Report 98-206. 2002, Some metallogenic features of gold and copper deposits related to
Losh, S., Purvance, D., Sherlock, R., and Jowett, E.C., 2005, Geologic and alkaline rocks and consequences for exploration, Mineralium Deposita, v.
geochemical study of the Picacho gold mine, California: Gold in a low- 37, p. 413.
angle normal fault environment: Mineralium Deposita, v 40, p. 137155. Sillitoe, R.H., Steele, G.B., Thompson, J.F.H., and Lang, J.R., 1998, Ad-
Lowell, J.D., 1968, Geology of the Kalamazoo orebody, San Manuel district, vanced argillic lithocaps in the Bolivian tin-silver belt: Mineralium De-
Arizona: ECONOMIC GEOLOGY, v. 63, p. 645654. posita, v. 33, p. 539546.
Mao, J., Xiaofend, L., White, N.C., Zhao, C. Zhange, Z., Wang, Y., and Hu, Simmons, S.F., 1991, Hydrologic implications of alteration and fluid inclu-
H., 2007, Types, characteristics, and geodynamic settings of mesozoic epi- sion studies in the Fresnillo district: Evidence for a descending water table
thermal gold deposits in eastern China: Resource Geology, v. 57, p. and a brine reservoir during formation of hydrothermal Ag-Pb-Zn deposits:
432454. ECONOMIC GEOLOGY, v. 86, p. 1579-1602.
McElroy, B.J., Wilkinson, B.H., and Rothman, E.D., 2005, Tectonic and Simmons, S.F., and Brown, K.L., 2007, The flux of gold and related metals
topographic framework of political division: Mathematical geology, v. 37, p. through a volcanic arc, Taupo Volcanic Zone, New Zealand: Geology, v. 35,
197206. p. 10991102.
Mosier, D.L., Menzie, W.D., and Kleinhampl, F.J., 1986, Geologic and Simmons, S.F. and Christenson, B.W., 1994, Origins of calcite in a boiling ge-
grade-tonnage information on Tertiary epithermal precious- and base- othermal system: American Journal of Science, v. 294, p. 361400.
metal vein districts associated with volcanic rocks: U.S. Geological Survey Simmons, S.F., White, N.C., and John, D.A., 2005, Geological characteristics
Bulletin, v. 1666, 39 p. of epithermal precious metal and base metal deposits: ECONOMIC GEOLOGY
Muir, T.L., 2002, The Hemlo gold deposit, Ontario, Canada; Principal de- 100TH ANNIVERSARY VOLUME, p. 45522.
posit characteristics and constraints on mineralization: Ore Geology Re- Singer, D.A., 2008, Mineral deposit densities for estimating mineral re-
views, v. 21, p.166. sources: Math Geoscience, v. 40, p. 3346.
Muntean, J.L., and Einaudi, M.T., 2000, Porphyry gold deposits of the Refu- Singer, D.A., Berger, V.I., and Moring, B.C., 2005, Porphyry copper deposits
gio district, Maricunga belt, northern Chile: ECONOMIC GEOLOGY, v. 95, p. of the world: database, map, and grade and tonnage models: U.S. Geolog-
14451472. ical Survey Open-file Report 20051060, http://pubs.usgs.gov/of/2005/
2001, Porphyry-epithermal transition: Maricunga belt, northern Chile: 1060/.
ECONOMIC GEOLOGY, v. 96, p. 743772. Smith, D.M., Jr., and Hall, D.K., 1974, Geology of the Tayoltita mine, Du-
Nelson, C., 1995, Gold and copper metallogeny of Central America, in rango, Mexico: Society of Mining Engineers of AIME, Preprint No. 74-I-
Coyner, A.R. and Fahey, P.L., eds., Geology and ore deposits of the Amer- 308, SME Fall Meeting, Acapulco, 48 p.
ican Cordillera: Geological Society of Nevada, p. 13971411. Squire, R.J., Herrmann, W., Pape, D., and Chalmers, I.D., 2007, Evolution
Noble, D.C., and McKee, E.H., 1999, The Miocene metallogenic belt of cen- of the Peak Hill high-sulfidation epithermal Au-Cu deposit, eastern Aus-
tral and northern Peru: Society of Economic Geologists, Special Publica- tralia: Mineralium Deposita, v. 42, p. 489503.
tions, v. 7, p. 155194. Stavast, W.J.A., Butler, R.F., Seedorff, E., Barton, M.D., and Ferguson, C.A.,
Nockelberg, W.J., Bundtzen, T.K., Eremin, R.A., Ratkin, V.V., Dawson, K.M., 2008, Tertiary tilting and dismemberment of the Laramide arc and related
Shpikerman, V.I., Goryachev, N.A., Byalobzhesky, S.G., Frolov, Y.F., hydrothermal systems, Sierrita Mountains, Arizona: ECONOMIC GEOLOGY,
Alexander I. Khanchuk, A.I., Koch, R.D., Monger, J.W.H., Pozdeev, A.I., v. 103, p. 629636.
Rozenblum, I.S., Rodionov, S.M., Parfenov, L.M., Scotese, C.R., and Talikka, M. and Manttari, I., 2005, Pukala intrusion, its age and connection
Sidorov, A.A., 2005, Metallogenesis and tectonics of the Russian Far East, to the hydrothermally altered domains in Orivesi, southwestern Finland:
Alaska, and the Canadian Cordillera: U.S. Geological Survey Professional Geological Survey of Finland Bulletin, v. 77, p. 165179.
Paper 1697, 429 p. Taylor, S.R., and McLennan, S.M., 1995, The geochemical evolution of the
Penczak, R.S., and Mason, R., 1999, Characteristics and origin of Archean continental crust: Reviews in Geophysics, v. 33, p. 241265.
premetamorphic hydrothermal alteration at the Campbell gold mine, Thompson, J.F.H., Lessman, J., and Thompson, A.J.B., 1986, The Temora
northwestern Ontario, Canada: ECONOMIC GEOLOGY, v. 94, p. 507528. gold-silver deposit; a newly recognized style of high sulfur mineraliza-
Peppard, B., 2002, Geology and geochemistry of the Ivanhoe vein system, tion in the lower Paleozoic of Australia: ECONOMIC GEOLOGY, v. 81, p.
Elko, Nevada: Unpublished M.Sc. thesis, Ann Arbor, University of Michi- 732738.
gan, 49 p. Turner, S.J., 1997, The Yanacocha epithermal gold deposits, northern Peru:
Richards, J.P., 2009, Postsubduction porphyry Cu-Au and epithermal Au de- High-sulfidation mineralization in a flow dome setting: Unpublished Ph.D.
posits; products of remelting of subduction-modified lithosphere: Geology, dissertation, Golden, Colorado, Colorado School of Mines, 340 p.
v. 37, p. 247250. U.S. Geological Survey, 1998, Assessment of undiscovered deposits of gold,
Robert, F., Poulsen, K.H., Cassidy, K.F., and Hodgson, C.J., 2005 Gold met- silver, copper, lead, and zinc in the United States: U.S. Geological Survey
allogeny of the Superior and Yilgarn provinces: ECONOMIC GEOLOGY 100TH Circular 1178, 19 p.
ANNIVERSARY VOLUME, p. 10011029. van Leeuwen, T.M., Hedenquist, J.W., James, L.P., and Dow, J.A.S., 1994,
Roedder, E., and Bodnar, R.J., 1980, Geologic pressure determinations from Mineral deposits of Indonesia-Discoveries of the past 25 years: Journal of
fluid inclusion studies: Annual Review of Earth and Planetary Sciences, v. Geochemical Exploration, v. 50, 500 p.
8, p. 263301. Vikre, P.G., 1985, Precious metal vein systems in the National district, Hum-
Roy, R., Cassard, D., Cobbold, P.R., Rossello, E.A., Billa, M., Bailly, L. and boldt County, Nevada: ECONOMIC GEOLOGY, v. 80, p. 360393.
Lips, A.L.W., 2006, Predictive mapping for copper-gold magmatic-hydro- 1987, Paleohydrology of Buckskin Mountain, National district, Hum-
thermal systems in NW Argentina: Use of a regional-scale GIS, application boldt County, Nevada: ECONOMIC GEOLOGY, v. 82, p. 934950.
of an expert guided data-driven approach, and comparison with results Vila, T., and Sillitoe, R.H., 1991, Gold-rich porphyry systems in the Mari-
from a continental-scale GIS: Ore Geology Reviews, v. 29, p. 260286. cunga belt, northern Chile: ECONOMIC GEOLOGY, v. 86, p. 12381260.

0361-0128/98/000/000-00 $6.00 632


RESOURCES OF GOLD IN PHANEROZOIC EPITHERMAL DEPOSITS 633

Voudouris, P., 2006, A comparative mineralogical study of Te-rich magmatic- White, N.C., Leake, M.J., McCaughey, S.N. and Parris, B.W., 1995, Epi-
hydrothermal systems in northeastern Greece: Mineralogy and Petrology, thermal gold deposit of the southwest Pacific: Journal of Geochemical Ex-
v. 87, p. 241275. ploration, v. 54, p. 87136.
Wallace, A.R., 2003, Geology of the Ivanhoe Hg-Au district, northern Wilkinson, B.H., and Kesler, S.E., 2007, Tectonism and exhumation in con-
Nevada; influence of Miocene volcanism, lakes and active faulting on epi- vergent margin orogens: Insights from ore deposits: Journal of Geology, v.
thermal mineralization: ECONOMIC GEOLOGY, v. 98, p. 409424. 115, p. 611627.
Watanabe, 2005, Late Cenozoic evolution of epithermal gold metallogenic Yigit, O., 2009, Mineral deposits of Turkey in relation to Tethyan metal-
provinces in Kyushu, Japan: Mineralium Deposita, v. 40, p. 307323. logenyimplications for future mineral exploration: ECONOMIC GEOLOGY,
Wedepohl, K.H., 1995, The composition of the continental crust: Geochim- v. 104, p. 1952.
ica et Cosmochimica Acta, v. 59, p. 12171239.

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