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Type 1 contains 8 Single Correct Answer Type Questions. Each question has 4 choices (A), (B), (C) and (D),
out of which ONLY ONE CHOICE is correct.
Marking scheme [3 Marks for Correct answer & 1 NEGATIVE MARKING for wrong answer]
Type 2 contains 5 Multiple Correct Answer Type Questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONE OR MORE CHOICES may be correct.
Marking scheme [5 Marks for All Correct answers & 2 NEGATIVE MARKING for wrong answer]
3. Type 3 contains 2 Match the following Objective type Questions. Each question contains statements
given in 2 lists. Statements in the first list have to be matched with statements in the second list and
then option with the appropriate code is to be marked in the answer sheet. The options for the
correct match are provided as (A), (B), (C) and (D) out of which ONLY ONE Choice is Correct.
Marking scheme [3 Marks for Correct answer & 1 NEGATIVE MARKING for wrong answer]
4. Section II contains 5 Single Integer Value Type Questions. The answer to each of the questions is a
single-digit integer, ranging from 0 to 9 (both inclusive).
Marking scheme [4 Marks for Correct answer & NO NEGATIVE MARKING for wrong answer]
5. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your
Test Code, Roll No. and Group Properly in the space given in the ANSWER SHEET.
2. If the enthalpy change for the reaction : CH4 (g) Cl2 (g)
CH3Cl(g) HCl(g) H 25 kcal
1
Given that bond energy of C H bond is 20 kcal mol greater than that of bond energy of C Cl bond
whereas bond energies of H H and H Cl bond is nearly same. What would be the enthalpy change
for following reaction using above information?
1 1
H 2 (g) Cl2 (g) HCl(g)
2 2
(A) 22.5 kcal/mol (B) 20.5 kcal/mol
(C) 32.5 kcal/mol (D) 12.5 kcal/mol
3. 1 mole each of three different gases A, B and C having Vander Waals constant a
(in atmL2 mol2) as 1.5, 3.2 and 2.7 respectively are separately present in three identical vessel at same
temperature. What would be correctly said regarding their pressure in the given three vessels while
ignoring the effect of b?
(A) PA = PB = PC (B) PB > PC > PA (C) PB < PC < PA (D) PA < PB < PC
4. Let 1 be the frequency of the series limit of the Lyman series, 2 be the frequency of the first line of
the Lyman series, and 3 be the frequency of the series limit of the Balmer series. Which of the
following relation is correct w.r.t. hydrogen atom?
1
(A) 1 2 3 (B) 2 1 3 (C) 2 (1 3 ) (D) 1 2 3
2
SPACE FOR ROUGH WORK
6. Which of the following statement concerning oxygen and neon gas is true in the beginning, when the
stopcock was just opened ?
(A) O2 moved at faster rate towards flask B (B) Ne moved at faster rate towards flask A
(C) Both O2 and Ne gases moved at equal rate
(D) Insufficient information to compare the rate of effusion
SECTION - I | Type-2
MULTIPLE CORRECT ANSWERS TYPE
This Section contains 5 Multiple Choice Question. Each Question has 4 choices A, B, C & D, out of which
One or More Choices may be Correct :
9. Two bulbs (A) and (B) of equal capacity are filled with He and SO 2 respectively at the same
temperature. What could be rightly said about them? (Atomic mass of He = 4, S = 32, O = 16)
(A) (rms) of He is 4 times (rms) of SO2 at same temperature
(B) At 1200 K, (rms) of SO2 is half of (rms) of He at 27C
(C) If volume of B is made four times at same temperature (rms) of SO2 becomes four times
(D) If half of the He is removed from (A), their (rms) wont change
11. Which of the following reaction(s) may involve a change in hybridization of underlined atom ?
(A) SO 2 1/ 2O 2 SO3 (B) H 2CO3 H 2O CO 2
(C) PCl5
PCl3 Cl 2 (D) H 2 SO 4 2NaOH
Na 2SO 4 H 2 O
13. During a transition of an electron from N-shell to L-shell in a hydrogen like species, what could be
rightly said?
(A) With increase in nuclear charge (Z), wavelength of spectral lines would decrease
(B) Energy difference between these two shells decrease with increase in nuclear charge (Z)
(C) When Z = 1, this transition falls in the visible region
(D) Maximum number of spectral line produced during this transition per atom or ion would be 3
SECTION - I | Type-3
COLUMN MATCHING TYPE
This section contains 2 Single Choice Questions. Each question has matching lists. The codes for the lists
have 4 choices (A), (B), (C) and (D) out of which ONLY ONE Choice is Correct. Each wrong answer will be
given 1 (NEGATIVE MARKING).
14. MATCH THE FOLLOWING LISTS : [Molecular mass of SF6 = 146, XeF4 = 207]
List 1 [Gaseous Substance] List 2
Codes :
P Q R S P Q R S
(A) 1 2 1 4 (B) 3 4 2 1
(C) 3 4 1 3 (D) 2 4 2 2
SECTION - II
SUBJECTIVE TYPE
This Section contains 5 Subjective Question. Each question has an integer answer between 0 and 9. Fill the
answer bubbles in OMR Sheet appropriately and CAREFULLY.
1. The number of lone pairs of electron present around central atom of I3 is ___________.
(Atomic Number of I = 53)
2. n-factor of Fe(HC2O4)2 in reaction with acidified potassium dichromate is ______________
3. The change in pressure, p (increase or decrease) when 4L of water in added to 10 L vessel
containing 160 g of oxygen gas at 300 K assuming 40% of gas has been dissolved and there is
negligible aqueous tension of water would be___________.
4. The purity of H2O2 in a given sample is 34 %. The weight (in gms) of impure sample of H 2O2 which
requires 100 mL of M/5 KMnO4 solution in a titration in a strongly basic medium is ________.
(Molar mass of H2O2 = 34)
5. How many of the following species are both Polar and Planar ?
SOCl2 , SO 2 , NH 3 , BCl 2 F, COCl 2 NCl3 , CO 2 , NO 2
2. A semicircular wire of mass m is hinged at its top on a vertical wall. What is the
O
horizontal force exerted by wall on the lower end?
mg
(A) mg (B)
2mg 3mg
(C) (D)
4
3. An annular ring with inner and outer radii R1 and R2 is rolling without slipping with a uniform angular
speed. The ratio of the forces experienced by the two particles of same mass situated on the inner and
F
outer parts of the ring, 1 is :
F2
2
R2 R1 R1
(A) (B) (C) 1 (D)
R1 R2 R2
4. In the figure shown, the pistons interconnected by an inextensible thread can slide without friction.
The ends of the cylinder are open to the atmosphere. The gas enclosed within the pistons is being heated
at a constant rate so that the pistons are moving with a constant speed. Then, which of the following is
not true ?
(A) The pistons shift to the left
(B) Work done by gas > 0
(C) Thread tension is > 0
(D) Thread tension is zero
SECTION - I | Type-2
MULTIPLE CORRECT ANSWERS TYPE
This Section contains 5 Multiple Choice Question. Each Question has 4 choices A, B, C & D, out of which
One or More Choices may be Correct :
9. A uniform rod of mass m and length l is free to rotate about a fixed horizontal axis
passing through point O. A small ball of mass m moving horizontally with velocity
v strikes the rod at depth y from O as shown in figure if angular velocity of rod
and velocity of ball just after collision, are and v respectively then which of the
following statements are wrong ?
l v v
(A) If y , then in case of elastic collision, v and
2 2 l
l
(B) If y , then in case of elastic collision, momentum of ball rod system remains conserved
2
(C) If momentum of ball + rod system remains conserved then y l 2
(D) Ball can not rebound back whatever is the value of y
10. A 0.1 kg block is pressed against a horizontal spring fixed at one end to compress the spring through
5cm. The spring constant is 100 N/m. The ground is 2m below the spring. Which of the following is/are
correct ? {g = 10 m/s2}
1
(A) When block leaves contact with spring its kinetic energy is J .
8
5
(B) The initial horizontal velocity of the block is m/ s
2
2
(C) The block will reach the ground in see
5
(D) The block will hit the ground at a horizontal distance of 1m from the free end of the spring.
11. A gas is contained in a metallic cylinder fitted with a piston. The piston is suddenly moved in to
compress the gas and is maintained at this position. As time passes the pressure and temperature of the
gas in the cylinder :
(A) Pressure increases (B) Pressure decreases
(C) Temperature increases (D) Temperature decreases
SECTION - I | Type-3
COLUMN MATCHING TYPE
This section contains 2 Single Choice Questions. Each question has matching lists. The codes for the lists
have 4 choices (A), (B), (C) and (D) out of which ONLY ONE Choice is Correct. Each wrong answer will be
given 1 (NEGATIVE MARKING).
14. MATCH THE FOLLOWING LISTS :
List 1 List 2
(P) Force of 10t is applied. 'A' 1. A is constant
is normal force applied by ground
(Q) A block of ice at 20C is heated in a container. 2. A is increasing with time and then
'A' is its temperature. becomes constant at least for some
time.
(R) The velocity - position 3. A is decreasing with time and then
graph of a particle becomes constant at least for some
moving on a straight line time.
is shown here. 'A' is
magnitude of its
acceleration
(S) 4. A is constant for some time, then
decreases at least for some time
15. A body initially, moving towards right explodes into two pieces 1 and 2. Direction of motion of the
pieces is shown in List 1 and possible mass ratio are shown in List 2.
List 1 (Cause) List 2 (Effect)
(P) 1.
m1 m2
(Q) 2.
m1 m2
(R) 3.
m1 m2
(S) 4.
Impossible for any masses
Codes :
P Q R S P Q R S
(A) 3 3 2 1 (B) 4 4 1 1
(C) 4 4 1 3 (D) 3 3 2 2
SECTION - II
SUBJECTIVE TYPE
This Section contains 5 Subjective Question. Each question has an integer answer between 0 and 9. Fill the
answer bubbles in OMR Sheet appropriately and CAREFULLY.
3. A particle having position coordinates (3m, 7m) is moving with constant velocity v1 2i 3 j m / s
and another particle having position coordinate (6m, 3m) at the same time is moving with constant
velocity v2 3i 4 j m / s . Then the time after at which both particles have minimum distance
a
between them is s . Then value of a is ________.
2
4. A body is projected with velocity u at an angle of projection with the horizontal the direction of
velocity of the body makes angle 30 with the horizontal at t = 2s and then after 1s it reaches the
maximum height. The angle of projection is where n is : {g = 10 m/s}
n
5. A monoatomic gas at pressure P is adiabatically compressed so that its density becomes four times.
1
The final pressure of the gas becomes n 2 3 its initial pressure where n is _______.
6
8. n n n is equal to :
n 1
SECTION - I | Type-2
MULTIPLE CORRECT ANSWERS TYPE
This Section contains 5 Multiple Choice Question. Each Question has 4 choices A, B, C & D, out of which
One or More Choices may be Correct :
9. A circle S passes through the point (0, 1) and is orthogonal to the circles x 12 y 2 16 and
x 2 y 2 1 . Then,
(A) Radius of S is 8 (B) Radius of S is 7
(C) Centre of S is 7 , 1 (D) Centre of S is 8, 1
10. A is the point (1, 1) and any point P on x y 4 gives the area of PAB 3 units. If AB is parallel to
the given line, then coordinates of B can be :
(A) 4, 2 (B) 4, 2 (C) 2, 4 (D) (7, 11)
100
100 Ck x 2
100 k
11. The coefficient of x50 in the expansion of 3k is also equal to :
k 0
(A) Number of ways in which 50 identical books can be distributed in 100 students, if each student
can get atmost one book
(B) Number of ways in which 100 different white balls and 50 identical red balls can be arranged in
a circle, if no two red balls are together
2 6 10 14 . . . . . 198
(C)
50!
(D) None of these
100 x
12. If C6 4 . 100C7 6 . 100C8 4 . 100C9 100
C10 has the value equal to C y ; then the possible
value(s) of x + y can be :
(A) 112 (B) 114 (C) 196 (D) 198
13. If cot tan x and sec cos y , then which of the following is(are) true?
(where 2n 1 , nI )
2
(A) x sin cos 1 (B) sin 2 y cos
x y x y xy
13 13 23 23
2
(C) xy 2 1 (D) 2
2
1
SECTION - I | Type-3
COLUMN MATCHING TYPE
This section contains 2 questions. Each question contains statements given in two columns which have to be
matched. Statements in Column 1 are labelled as (A), (B), (C) & (D) whereas statements in Column 2 are
labeled as p, q, r, s. The answers to these questions have to be appropriately bubbled.
14. MATCH THE FOLLOWING LISTS :
List 1 List 2
There are 2n white and 2n red counters. Counters are alike except for
(P) colour. If number of ways in which they can be arranged in a line so 1. 12
that they are symmetric w.r.t. a central mark is 70, then n equals
If one quarter of all three element subsets of the set
(Q) 2. 4
A a1 a2 a3 . . . . an contains the element a3, then n is equal to
If k and d (d being variable) are the nth term and common difference
th th
of an A.P. If multiplication of n 1 and n 3 term of an A.P.
(R) 3. 5
k
is maximum, then equals.
d
n
r 2 n 28 1
(S) If Cr then n is 4. 3
r 0 r 1 6
Codes :
P Q R S P Q R S
(A) 2 4 3 1 (B) 2 1 4 3
(C) 2 1 3 4 (D) 1 2 4 3
a
(P) a, b 0, and sin 6 a 3 sin 2 a cos 2 b cos 6 b 1 , then 1. 3
2 b
cos 54 sin 72
8 x3 4 x 2 4 x k
(Q) cos 18 sin 18 2. 4
where x cos 18 , then value of k
SECTION - II
SUBJECTIVE TYPE
This Section contains 5 Subjective Question. Each question has an integer answer between 0 and 9. Fill the
answer bubbles in OMR Sheet appropriately and CAREFULLY.
1. Let two parallel lines L1 and L2 with positive slope are tangent to the circle
C1 : x 2 y 2 2 x 16 y 64 0 . If L1 is also tangent to the circle C2 : x 2 y 2 2 x 2 y 2 0 and
abc
equation of L2 is a ax by c a a 0 where a, b, c N , then the value of is
2
_________.
2. If 1, 1 , 2 , 3 & 4 be the roots of x5 1 0 and be a complex root of unity, and the value of
1 2 3 4 b
2 . 2 . 2 . 2 is then the least positive value of b is __________.
1 2 3 4
3. The equation of a line through the mid points of the sides AB and AD of rhombus ABCD, whose one
diagonal is 3 x 4 y 5 0 and one vertex is A 3, 1 , is ax by c 0 . Find the absolute value of
a b c where a, b, c are integers expressed in lowest form.
4. A firm of Charter Accountants in Bombay has to send 10 clerks to 5 different companies, two clerks in
each. Two of the companies are in Bombay and the others outside. Two of the clerks prefer to work in
Bombay while three others prefer to work outside. If number of ways in which assignment be made if
the preferences are to be satisfied is abcd then a b c d is __________. (where abcd represents
4 digit number)
a
5. The infinite geometric series , where y x 2 6 x 11 has a finite sum then,
y
r 1
2
r0 4y 5
x cannot be equal to ___________.