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PETROLEUM REFINERY P ROCESS ECONOMICS
The reduced crude from the atmospheric tower is heated and charged
to a vacuum distillation tower. In order to reduce the production of residual
fuel oil and increase the yield of gas oil cracking stock, many refiners are
going to lower flash zone pressures (as low as 20 mm Hg) and a flash zone
temperature approaching 750F to be able to cut between gas oil and resid
at an atmospheric equivalent temperature as high as 1,100F.
Seldom is a finished product produced by the CDU today. The basic pur-
pose of the CDU is to separate the crude oil into fractions suitable for further
processing. Even the fuel gas (essentially ethane and lighter) that is to be
burned in the refinery usually must be treated or blended with sufficient
sweet gas to be in compliance with regulations covering sulfur emissions.
The disposition of the remaining streams produced by the CDU is typ-
ically as follows:
Stream Disposition
Light ends Fed to a saturate gas plant (that may
or may not be considered a part of the
CDU) producing fuel gas, propane,
butanes, light naphtha, and including
amine treating to remove acid gases
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CHAPTER 7 CRUDE OIL PROCESSING
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PETROLEUM REFINERY P ROCESS ECONOMICS
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CHAPTER 7 CRUDE OIL PROCESSING
Yields
Estimating the yields of the desired fractions that might be obtained from a
single crude is a fairly simple task. However, the refiner is rarely processing
a single crude, but a mixture of a number of crudes. Assays are usually
available for single crudes, but only for very few blends and these are
unlikely to be the ones of interest.
Performing a complete assay of a crude is an expensive (and time con-
suming) procedure. The blend being charged to the CDU could change sig-
nificantly before an assay could be completed. The refiner, therefore, must
have some other means of estimating the amounts of the various streams he
should realize from his current blend of crudes.
Fortunately, computer programs are available that can take crude assay
data and derive from them a complex of pseudo hydrocarbon components
that will satisfactorily represent the actual crude. Such pseudo assays for a
number of crudes can then be blended together in the proportion desired to
produce a pseudo assay for the blend. The refiner can then specify the boil-
ing ranges (or cut temperatures) desired for the various streams and the
computer program can determine not only the yields to be expected, but
certain properties for these streams as well (e.g., API gravity, PONA, octane
number, cetane number, etc.).
Assays
What about the individual who does not have access to such sophisticated
means? In general there are three kinds of assay data available:
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Fig. 74 Oseburg Crude Assay
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PETROLEUM REFINERY P ROCESS ECONOMICS
4. Estimate the sulfur content and the UOP K factor for each cut.
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CHAPTER 7 CRUDE OIL PROCESSING
Notes
1. Corbett, R.A., Oil & Gas Journal, July 24, 1989, pp. 56-57
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