Tarea #3.

5: RESOLVER EL PROBLEMA 4-9 DEL LIBRO DE TEXTO

= [ ]

= 0 (1 )

= 0 (1 )

= 0

0 = [ ]

0 = 0 (1 )0 (1 )

0 = 0 (1 )2
 1
2 (2 + ) + 1 = 0
0

Solving for :

= 0.80

Now the equilibrium concentrations :

= 2/3 (1 0.80) = 0.4/3

= 2/3 (1 0.80) = 0.4/3 )

= 2/3 (0.80) = 1.6/3

b) The gas-phase reaction

A < ------- > 3C

Carried out in a flow reactor with no pressure drop. Pure A enters at a temperature of 400K and a
pressure of 10 atm. At this temperature, KC = 0.25(mol/dm3)2.

3
= ( )

= 0 = (1)(3 1) = 2

0 (1 ) (1 )
= = = 0
0 (1 + ) (1 + 2)
 30 3
= = = 0
0 (1 + ) (1 + 2)

0 1(10)
0 = = = 0.304/3
(0.082. 3 /. )(400)

3
0 = ( )

3 =

3
3 (1 )
[0 ] = 0
(1 + 2 ) (1 + 2 )

(1 )(1 + 2 )2 = 2720 3

(1 )(1 + 2 )2 2720 3 = 0

Solving for :

= 0.58

Now the equilibrium concentrations :

(1 0.58)
= 0.304/3 = 0.059mol/dm3
(1 + 2 0.58)
 3(0.58)
= 0.304/3 = 0.246mol/dm3
(1 + 2 0.58)

c) The gas-phase reaction in part (b) carried out in a contant-volume batch reactor.

3
= ( )

0 (1 )
= = = 0 (1 )
0

30
= = = 30
0

0 1(10)
0 = = = 0.304/3
(0.082. 3 /. )(400)

3
0 = ( )

3 =

(30 )3 = 0 (1 )

Solving for :

= 0.39
Now the equilibrium concentrations :

= . / ( . ) = . /

= (. / )(. ) = . /

c) The gas-phase reaction in part (b) carried out in a contant-pressure batch reactor.

3
= ( )

= 0 = (1)(3 1) = 2

0 (1 ) (1 )
= = = 0
0 (1 + ) (1 + 2)

30 3
= = = 0
0 (1 + ) (1 + 2)

0 1(10)
0 = = = 0.304/3
(0.082. 3 /. )(400)

3
0 = ( )

3 =

3
3 (1 )
[0 ] = 0
(1 + 2 ) (1 + 2 )

(1 )(1 + 2 )2 = 2720 3

(1 )(1 + 2 )2 2720 3 = 0

Solving for :

= 0.58

Now the equilibrium concentrations :

(1 0.58)
= 0.304/3 = 0.059mol/dm3
(1 + 2 0.58)

3(0.58)
= 0.304/3 = 0.246mol/dm3
(1 + 2 0.58)