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Outline
Outline
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1.System description
WAS
O2
1. System description
Wastewater Behaviour of
composition microorganisms M
O
D
Sizing, performance E
and control L
S
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1. System description
Basic approach
Level of organization: Generalized, simplified concepts to
describe behaviour of bacteria in WWTP:
Organisms Collective behaviour grouped by bio-process of
importance (e.g. ordinary heterotrophs, nitrifying organisms)
depending on objectives.
1. System description
Basic approach
Models have high and low levels of complexity depending on objectives:
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1. system description
Wastewater composition
Wastewater comprises both organic (COD, BOD) and inorganic
(ISS) materials (measured in influent).
1. System description
Wastewater composition
Wastewater organic and inorganic constituents are:
1. Settleable (settle out < 2 h)
2. Non-setteable (colloidal)
3. Dissolved
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1. System description Wastewater composition
ASM model notation
XI
(2) Non-settleable Biodegradable
(PART. COLLOIDAL) Unbiodegradable
(0.45-1.2 um) SS
1. System description
Wastewater composition
Question
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1. system description
2. Transformations
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2. Transformations
COD fractions
Total COD (Total Escape with
Organics) effluent !
Soluble
organics
Ss SI
Biodegradable Unbiodegradable
0.45um
pore size Soluble Soluble
filters
Xs XI
(e.g.
Biodegradable Unbiodegradable
STOWA
protocol) Particulate Particulate Particulate
organics
Transformed to
biomass Enmeshed in
sludge and
accumulated
2. Transformations
COD EXIT ROUTES
WAS
XBH
Ss SI
XI Effluent
Xs XI COD
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EXAMPLE WW: COD - RAW
The following parameters have been determined for a given raw (non-settled)
WW:
Total COD = 750 mg/L
Filtered COD (0.45 um) = 199 mg/L
fuso = SI/CODtot = 0.07; and fupo = XI/CODtot = 0.15
- What are the different organic concentrations in the influent?
750
199
Ss146 53 SI
For a given settled WW, the following parameters have been determined :
Total COD = 450 mg/L
Filtered COD (0.45 mm) = 199 mg/L
fuso = XI/CODtot = 0.117; and fupo = SI/CODtot = 0.04
- What are the different organic concentrations in the influent?
450
Ss 146 53 XI
199
Xs 233 18 SI 251
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EXERCISE WW: COD - SETTLED
If the influent wastewater flowrate (Qi) is 20 MLD (million of liters per day ~
20000 m3/d), then:
= Qi (XS+SS)
= 20 (233+146) = 7580 kg COD/d
FSI = Qi (SI)
= 20 (18) = 360 kg COD/d
If the effluent discharge standard is 50 mg/L, will the plant comply with
this limit?
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3. System constraints
3. System constraints
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3. System constraints
3.1. MIXING CONDITIONS
1) Mixing regimes Two extremes
3. system constraints
3.2. HYDRAULIC RETENTION TIME (Rhn, HRT)
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3. system constraints
XQ
W
3. system constraints
3.3. SLUDGE AGE
Qw
(3) Sludge age (Rs)
length of time solids stay
in reactor (SRT)
Vp
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3. system constraints
Vp X
t
QW
XSST
Vp Xt
Rs=
QW XSST
3. system constraints
EXERCISE
- Q = 20 MLD
- Xt = 4.5 kg/m3 (TSS in the main reactor tank)
- Vp = 67500 m3
- XSST = 12.5 kg/m3 (TSS at the bottom of the secondary settler)
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4. Biological behaviour
4. Biological behaviour
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Growth Stoichiometry
e- donated by
organics
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endogenous respiration
4.8%
76% remain
organism loss
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4. biological behaviour
4. biological behaviour
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4. biological behaviour
4. biological behaviour
But, it is very slow and does not reach completion (even at very
long SRT) its stoichiometry and kinetics are needed.
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5. reactor solids concentration
TSS
XI: Unbiodegradable particulate COD
The VSS mass in the reactor (MXv) is the VSS concentration (Xv) x
reactor volume (Vp):
M Xv = XBH Vp + XEH Vp + XI Vp
M Xv = Xv Vp [kgVSS]
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5.1.1. Unbiodegradable particulate organics (XI)
Xs XI
At steady state:
Q Xii = XI QW VSS out
Qw
And, if QW = VP/RS:
Q Xii = XI VP/RS
VSS in XI
XI VP = Q XIi RS Qi XIi
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5.1.1. Unbiodegradable particulate organics (XI)
Xs XI
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5.1.2. Active biomass OHO (XBH)
But there is also an exit (loss) rate via the endogenous process:
1/(1+bHRs), i.e.
the longer the Rs, the greater the loss.
The net entry rate combines the entry (growth) and exit (loss) rates
per day:
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5.1.2. Active biomass OHO (XBH)
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5.1.3. Endogenous Residue (XE)
1.10
0.50
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5.1. reactor VSS (organic)
NOTE: Do not need to know the reactor volume (Vp) to calculate the
VSS mass in reactor, only the WW chars and Rs !
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5.2. reactor ISS (inorganic)
1) influent ISS accumulates in reactor linearly with sludge age just like
XI:
Vp XIo = Qi XIoi Rs [kgISS]
(2) biomass (OHOs) adds about 0.15 (fiOHO) times their mass to
measured ISS:
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5.2. reactor ISS (inorganic)
If influent ISS is not known, can choose a VSS/TSS ratio (f i) for the
AS:
ISS = MXIO
(INORGANICS)
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5. reactor solids concentration
6. effluent COD
Ss SI
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EXERCISE:
For the WW fractionation given below and Rs=10 d , calculate [in kg]:
- MXBH
- MXE
- MXI
- MXV
- If XIO = 54 mg ISS/L, determine MXIO and MXt.
7. oxygen demand
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7.1. oxygen for growth
ANABOLISM
Organics e- through
CATABOLISM
catabolism passed to
e- donated by oxygen.
organics
e- of biomass (XBH)
biodeg. organics
lost passed to
oxygen catabolic
energy generation.
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7.2. oxygen for endogenous respiration
7. oxygen demand
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7. oxygen demand
8. AS design model
From the basic equations, MXv, MXt, MOc, and (Ste) are all functions
of:
Needs good determination
(1) WW characteristics [fupo, fuso, XIoi],
(2) WW COD load Qi CODtot [kgCOD/d]
(3) System sludge age [Rs, d] !!!
(4) OHO stoichiometric constants [YHv, fcv, f] fixed
(5) OHO kinetic constant [ bH ] Just dependent on temperature
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values of constants
Stoichiometric:
YHv = OHO yield = 0.45 mgVSS/mgCOD
fcv = COD/VSS = 1.48 mgCOD/mgVSS
f = OHO unbiodegradable fraction = 0.20
Kinetics:
only the endogenous rate
bHT = bH20(1.029)(T-20) /d ; bH20=0.24/d
(valid between 12 and 30oC)
System boundary
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9. COD (e-) balance
Qw
Qi Oc
Q
e
Water balance Qw + Qe =
Qi
And Qw=Vp/Rs
1
Influent
COD - MS ti
0.8
Oxygen - COD
0.6 removed as heat -
e- transferred to
oxygen
0.4
Sludge - COD
0.2 removed as Effluent - COD
wasted VSS in effluent
0
0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30
Sludge Age (d)
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9. COD (e-) balance
If Rs :
Qw and mass of VSS (TSS)
If Rs :
mass of VSS (TSS) , endogenous
and oxygen consumption
EXERCISE:
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10. reactor volume
Note: As SRT, Vp
As Xt , Vp
Vp Raw > Vp Settled
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10. retention time
For the same COD load (and sludge age) retention time will be short
for the high flow case and long for the low flow case.
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12. active fraction
fav raw
0.8 settled
0.6
0.4
0.2
fat raw
settled
0
0 5 10 15 20 25 30
Sludge Age (d)
Active fraction:
Higher for settled WW than for raw WW because there is much less
influent UPO in settled WW (Raw XI = 113, Settled XI = 18).
decreases with sludge age because endogenous process continues for
longer.
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13. sludge production
(1) Recall mass VSS wasted/d = MXv = MXv /Rs = QwXv [kgVSS/d]
(2) N and P content of VSS fn = 0.10 gN/gVSS and fp = 0.025
[gP/gVSS]
(3) So Ns = fn MXv /(Rs Qi) [mgN/l] influent
(4) Ns = TKN conc in influent to meet sludge production N reqmts
(more in Chap 5).
(5) Similarly Ps = fp MXv /(Rs Qi) [mgP/L] infl.
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15. design procedure
characterize ww
146 53 199
Ss XI
0.45 filtered -
113 Sol COD =199
438 Xs SI 551 fuso= SI/CODtot
= 0.07
fupo= XI/CODtot
= 0.15
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calculate reactor masses from ww loads
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15. design procedure
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16. system control
Its best to waste from reactor
and establish sludge age Qi
hydraulically!
Qs =1xQi
X
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17. hydraulic control
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17. hydraulic control
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18. selection of sludge age
TYPE 1: Short Rs
TYPE 2 : Long Rs
Extended Aeration
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21. closure
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