Question1.

Thebondenergy(inkcalmol1)ofaCCsinglebondisapproximately
[A] 1
[B] 10
[C] 100
[D] 1000

Question2.
ThespecieswhichbydefinitionhasZEROstandardmolarenthalpyofformationat298Kis
[A] Br 2(g)
[B] Cl2(g)
[C] H2O(g)
[D] CH4(g)

Question3.
Theionizationisomerof[Cr(H2O) 4Cl(NO 2)]Clis

[A] [Cr(H2O)4(O 2N)]Cl2

[B] [Cr(H2O) 4Cl2](NO 2)
[C] [Cr(H2O) 4Cl(ONO)]Cl
[D] [Cr(H2O) 4Cl2(NO 2)]H2O

Question4.
Thecorrectstructureofethylenediaminetetraaceticacid(EDTA)is

[A]

[B]

[C]

[D]

Question5.
Thesynthesisof3octyneisachievedbyaddingabromoalkaneintoamixtureofsodiumamideandanalkyne.Thebromoalkane
andalkynerespectivelyare

[A]
[B]
[C]
[D]
Question6.
Thecorrectstatementaboutthefollowingdisaccharideis

[A] Ring(a)ispyranonsewith glycosidiclink

[B] Ring(a)isfuranonsewith glycosidiclink
[C] Ring(b)isfuranonsewith glycosidiclink
[D] Ring(b)ispyranonsewith glycosidiclink

Question7.
Plotsshowingthevariationoftherateconstant(k)withtemperature(T)aregivenbelow.TheplotthatfollowsArrheniusequationis

[A]

[B]

[C]
[D]

Question8.

Inthereaction theproductsare

[A]

[B]

[C]

[D]

Question9.

Inthereaction theintermediate(s)is(are)

[A]

[B]
[C]

[D]

Question10.
Thereagent(s)usedforsofteningthetemporaryhardnessofwateris(are)
[A] Ca3(PO 4) 2
[B] Ca(OH) 2
[C] Na2CO 3
[D] NaOCl

Question11.
AqueoussolutionsofHNO 3,KOH,CH3COOH,andCH3COONaofidenticalconcentrationsareprovided.
Thepair(s)ofsolutionswhichformabufferuponmixingis(are)
[A] HNO 3andCH3COOH
[B] KOHandCH3COONa
[C] HNO 3andCH3COONa
[D] CH3COOHandCH3COONa

Question12.
IntheNewmanprojectionfor2,2dimethylbutane

XandYcanrespectivelybe
[A] HandH
[B] HandC2H5
[C] C2H5andH
[D] CH3andCH3

Question13.
Amongthefollowing,theintensivepropertyis(propertiesare)
[A] molarconductivity
[B] electromotiveforce
[C] resistance
[D] heatcapacity

Question14.
Theconcentrationofpotassiumionsinsideabiologicalcellisatleasttwentytimeshigherthantheoutside.Theresultingpotential
differenceacrossthecellisimportantinseveralprocessessuchastransmissionofnerveimpulsesandmaintainingtheionbalance.
AsimplemodelforsuchaconcentrationcellinvolvingametalMis:

Fortheaboveelectrolyticcellthemagnitudeofthecellpotential

Fortheabovecell

[A]
[B]
[C]
[D]

Question15.
Theconcentrationofpotassiumionsinsideabiologicalcellisatleasttwentytimeshigherthantheoutside.Theresultingpotential
differenceacrossthecellisimportantinseveralprocessessuchastransmissionofnerveimpulsesandmaintainingtheionbalance.
AsimplemodelforsuchaconcentrationcellinvolvingametalMis:

Fortheaboveelectrolyticcellthemagnitudeofthecellpotential

Ifthe0.05molarsolutionof isreplacedby0.0025molar solution,thenthemagnitudeofthecellpotentialwouldbe

[A] 35mV
[B] 70mV
[C] 140mV
[D] 700mV

Question16.
Copperisthemostnobleofthefirstrowtransitionmetalsandoccursinsmalldepositsinseveralcountries.Oresofcopperinclude
chalcanthite atacamite ,cuprite ,copperglance andmalachite

.However,80%oftheworldcopperproductioncomesfromtheoreofchalcopyrite .The
extractionofcopperfromchalcopyriteinvolvespartialroasting,removalofironandselfreduction

Partialroastingofchalcopyriteproduces
[A] Cu2SandFeO
[B] Cu2OandFeO
[C] CuSandFe2O 3
[D] Cu2OandFe2O 3

Question17.
Copperisthemostnobleofthefirstrowtransitionmetalsandoccursinsmalldepositsinseveralcountries.Oresofcopperinclude
chalcanthite atacamite ,cuprite ,copperglance andmalachite

.However,80%oftheworldcopperproductioncomesfromtheoreofchalcopyrite .The
extractionofcopperfromchalcopyriteinvolvespartialroasting,removalofironandselfreduction

Ironisremovedfromchalcopyriteas
[A] FeO
[B] FeS
[C] Fe2O 3
[D] FeSiO 3
Question18.
Copperisthemostnobleofthefirstrowtransitionmetalsandoccursinsmalldepositsinseveralcountries.Oresofcopperinclude
chalcanthite atacamite ,cuprite ,copperglance andmalachite

.However,80%oftheworldcopperproductioncomesfromtheoreofchalcopyrite .The
extractionofcopperfromchalcopyriteinvolvespartialroasting,removalofironandselfreduction

Inselfreduction,thereducingspeciesis
[A] S
[B] O 2
[C] S2
[D] SO 2

Question19.
Thenumberofneutronsemittedwhen undergoescontrollednuclearfissionto

Question20.
Thetotalnumberofbasicgroupsinthefollowingformoflysineis

Question21.
ThetotalnumberofcyclicisomerspossibleforahydrocarbonwiththemolecularformulaC4H6is

Question22.
Intheschemegivenbelow,thetotalnumberofintramolecularaldolcondensationproductsformedfrom'Y'is

Question23.
Amongstthefollowing,thetotalnumberofcompoundsolubleinaqueousNaOHis
Question24.
Amongstthefollowing,thetotalnumberofcompoundswhoseaqueoussolutionturnsredlitmuspaperblueis

Question25.
BasedonVSEPRtheory,thenumberof90degreeFBrFanglesinBrF5is

Question26.
Thevalueofninthemolecularformula

Question27.
Astudentperformsatitrationwithdifferentburettesandfindstitrevaluesof25.2mL,25.25mLand25.0mL.Thenumberof
significantfiguresintheaveragetitrevalueis

Question28.
TheconcentrationofRinthereactionR Pwasmeasuredasafunctionoftimeandthefollowingdataisobtained:

Theorderofthereactionis

Question29.
Letf,gandhberealvaluedfunctionsdefinedontheinterval[0,1]by

Ifa,bandcdenote,respectively,theabsolutemaximumoff,gandhon[0,1],then

[A] a=bandc b
[B] a=canda b
[C] a bandc b
[D] a=b=c

Question30.
Letpandqberealnumberssuchthat .If arenonzerocomplexnumberssatisfying

thenaquadraticequationhaving asitsrootsis

[A] (p3+q)x 2(p3+2q)x+(p3+q)=0

[B] (p3+q)x 2(p32q)x+(p3+q)=0
[C] (p3q)x 2(5p32q)x+(p3q)=0
[D] (p3q)x 2(5p3+2q)x+(p3q)=0

Question31.

Equationoftheplanecontainingthestraightline andperpendiculartotheplanecontainingthestraightlines

[A] x+2y2z=0
[B] 3x+2y2z=0
[C] x2y+z=0
[D] 5x+2y4z=0

Question32.
IftheanglesA,BandCofatriangleareinanarithmeticprogressionandifa,bandcdenotethelengthsofthesidesoppositetoA,B
andCrespectively,thenthevalueoftheexpression

[A] 1/2

[B]

[C] 1
[D]

Question33.
Let beacomplexcuberootofunitywith Afairdieisthrownthreetimes.Ifr 1,r 2andr 3arethenumbersobtainedon
thedie,thentheprobabilitythat

[A]

[B]

[C]

[D]

Question34.

LetP,Q,RandSbethepointsontheplanewithpositionvectors respectively.The
quadrilateralPQRSmustbea
[A] parallelogram,whichisneitherarhombusnorarectangle
[B] square
[C] rectangle,butnotasquare
[D] rhombus,butnotasquare

Question35.

Thevalueof

[A] 0
[B]

[C]

[D]

Question36.

Thenumberof3x3matricesAwhoseentriesareeither0or1andforwhichthesystem hasexactlytwodistinct

solutions,is
[A] 0
[B] 291
[C] 168
[D] 2

Question37.

LetABCbeatrianglesuchthat andleta,bandcdenotethelengthsofthesidesoppositetoA,BandC

respectively.Thevalue(s)ofxforwhicha=x 2+x+1,b=x 21andc=2x+1is(are)

[A]
[B]
[C]
[D]

Question38.
LetAandBbetwodistinctpointsontheparabolay 2=4x.IftheaxisoftheparabolatouchesacircleofradiusrhavingABasits
diameter,thentheslopeofthelinejoiningAandBcanbe

Question39.

Thevalue(s)of is(are)

[A]

[B]

[C] 0

[D]

Question40.
Letz 1andz 2betwodistinctcomplexnumbersandletz=(1t)z 1+tz 2forsomerealnumbertwith0<t<1.IfArg(w)denotesthe
principalargumentofanonzerocomplexnumberw,then

Question41.

Letfbearealvaluedfunctiondefinedontheinterval by Thenwhichofthefollowing

statement(s)is(are)true?
Question42.

Thecirclex 2+y 28x=0andhyperbola intersectatthepointsAandB.

Equationofacommontangentwithpositiveslopetothecircleaswellastothehyperbolais

Question43.

Thecirclex 2+y 28x=0andhyperbola intersectatthepointsAandB.

EquationofthecirclewithABasitsdiameteris

Question44.
LetpbeanoddprimenumberandTpbethefollowingsetof2x2matrices:

ThenumberofAinTpsuchthatAiseithersymmetricorskewsymmetricorboth,anddet(A)divisiblebypis

Question45.
LetpbeanoddprimenumberandTpbethefollowingsetof2x2matrices:

ThenumberofAinTpsuchthatthetraceofAisnotdivisiblebypbutdet(A)isdivisiblebypis[Note:Thetraceofamatrixisthe
sumofitsdiagonalentries.

Question46.
LetpbeanoddprimenumberandTpbethefollowingsetof2x2matrices:

ThenumberofAinTpsuchthatdet(A)isnotdivisiblebypis

Question47.
LetfbearealvalueddifferentiablefunctiononR(thesetofallrealnumbers)suchthatf(1)=1.Iftheyinterceptofthetangentatany
pointP(x,y)onthecurvey=f(x)isequaltothecubeoftheabscissaofP,thenthevalueoff(3)isequalto

Question48.

Thenumberofvaluesof intheinterval suchthat aswellas

Question49.
Themaximumvalueoftheexpression

Question50.

If arevectorsinspacegivenby thenthevalueof

Question51.

Theline2x+y=1istangenttothehyperbola Ifthislinepassesthroughthepointofintersectionofthenearest

directrixandthexaxis,thentheeccentricityofthehyperbolais

Question52.

IfthedistancebetweentheplaneAx2y+z=dandtheplanecontainingthelines

then|d|is

Question53.
Foranyrealnumberx,let|x|denotethelargestintegerlessthanorequaltox.Letfbearealvaluedfunctiondefinedontheinterval
[10,10]by

Thenthevalueof

Question54.

Let bethecomplexnumber Thenthenumberofdistinctcomplexnumberszsatisfy

isequalto

Question55.

LetSk ,k=1,2,.....,100,denotethesumoftheinfinitegeometricserieswhosefirsttermis andthecommonratiois

Thenthevalueof

Question56.
Thenumberofallpossiblevaluesof where forwhichthesystemofequations

haveasolution(x 0,y 0,z 0)withy 0z 0 0,is

Question57.
Athinuniformannulardisc(seefigure)ofmassMhasouterradius4Randinnerradius3R.Theworkrequiredtotakeaunitmass
frompointPonitsaxistoinfinityis

Question58.
Ablockofmassmisonaninclinedplaneofangle .Thecoefficientoffrictionbetweentheblockandtheplaneis andtan
TheblockisheldstationarybyapplyingaforcePparalleltotheplane.Thedirectionofforcepointinguptheplaneistaken
tobepositive.AsPisvariedfromP1= thefrictionalforcefversusP
graphwilllooklike

Question59.
Arealgasbehaveslikeanidealgasifits

Question60.
ConsiderathinsquaresheetofsideLandthicknesst,madeofamaterialofresistivity Theresistancebetweentwoopposite
faces,shownbytheshadedareasinthefigureis

Question61.
Incandescentbulbsaredesignedbykeepinginmindthattheresistanceoftheirfilamentincreaseswiththeincreaseintemperature.
Ifatroomtemperature,100W,60Wand40WbulbshavefilamentresistancesR100,R60andR40,respectively,therelationbetween
theseresistancesis

Question62.
ToVerifyOhm'slaw,astudentisprovidedwithatestresistorRT,ahighresistanceR1,asmallresistanceR2,twoidentical
galvanometersG 1andG 2,andavariablevoltagesourceV.Thecorrectcircuittocarryouttheexperimentis

Question63.
AthinflexiblewireoflengthLisconnectedtotwoadjacentfixedpointsandcarriesacurrentIintheclockwisedirection,asshownin
thefigure.WhenthesystemisputinauniformmagneticfieldofstrengthBgoingintotheplaneofthepaper,thewiretakestheshape
ofacircle.Thetensioninthewireis
Question64.
AnACvoltagesourceofvariableangularfrequency andfixedamplitudeV0isconnectedinserieswithacapacitanceCandan
electricbulbofresistanceR(inductancezero).When isincreased

Question65.
Astudentusesasimplependulumofexactly1mlengthtodetermineg,theaccelerationduetogravity.Heusesastopwatchwiththe
leastcountof1secforthisandrecords40secondsfor20oscillations.Forthisobservation,whichofthefollowingstatement(s)is
(are)true?

Question66.
AfewelectricfieldlinesforasystemoftwochargesQ 1andQ 2fixedattwodifferentpointsonthexaxisareshowninthefigure.
Theselinessuggestthat

Question67.
OnemoleofanidealgasininitialstateAundergoesacyclicprocessABCA,asshowninthefigure.ItspressureatAisP0.Choose
thecorrectoption(s)fromthefollowing

Question68.
Apointmassof1kgcollideselasticallywithastationarypointmassof5kg.Aftertheircollision,the1kgmassreversesitsdirection
andmoveswithaspeedof2ms 1.Whichofthefollowingstatement(s)is(are)correctforthesystemofthesetwomasses?

Question69.
ArayOPofmonochromaticlightisincidentonthefaceABofprismABCDnearvertexBatanincidentangleof600(seefigure).Ifthe
refractiveindexofthematerialoftheprismis ,whichofthefollowingis(are)correct?


Question70.
Electricalresistanceofcertainmaterials,knownassuperconductors,changesabruptlyfromanonzerovaluetozeroastheir
temperatureisloweredbelowacriticaltemperatureTc (0).Aninterestingpropertyofsuperconductorsisthattheircriticaltemperature
becomessmallerthanTc (0)iftheyareplacedinamagneticfield,i.e.,thecriticaltemperatureTc (B)isafunctionofthemagneticfield
strengthB.ThedependenceofTc (B)onBisshowninthefigure.

Inthegraphsbelow,theresistanceRofasuperconductorisshownasafunctionofitstemperatureTfortwodifferentmagnetic
fieldsB1(solidline)andB2(dashedline).IfB2islargerthanB1whichofthefollowinggraphsshowsthecorrectvariationofRwithT
inthesefields?

Question71.
Electricalresistanceofcertainmaterials,knownassuperconductors,changesabruptlyfromanonzerovaluetozeroastheir
temperatureisloweredbelowacriticaltemperatureTc (0).Aninterestingpropertyofsuperconductorsisthattheircriticaltemperature
becomessmallerthanTc (0)iftheyareplacedinamagneticfield,i.e.,thecriticaltemperatureTc (B)isafunctionofthemagneticfield
strengthB.ThedependenceofTc (B)onBisshowninthefigure.

AsuperconductorhasTC (0)=100K.Whenamagneticfieldof7.5Teslaisapplied,itsTc decreasesto75K.Forthismaterialone

candefinitelysaythatwhen

Question72.
WhenaparticleofmassmmovesonthexaxisinapotentialoftheformV(x)=kx 2itperformssimpleharmonicmotion.

Thecorrespondingtimeperiodisproportionalto ascanbeseeneasilyusingdimensionalanalysis.However,themotionof

aparticlecanbeperiodicevenwhenitspotentialenergyincreasesonbothsidesofx=0inawaydifferentfromkx2anditstotal
energyissuchthattheparticledoesnotescapetoinfinity.Consideraparticleofmassmmovingonthexaxis.Itspotentialenergy
is neartheoriginandbecomesaconstantequaltoV0for

IfthetotalenergyoftheparticleisE,itwillperformperiodicmotiononlyif

Question73.
WhenaparticleofmassmmovesonthexaxisinapotentialoftheformV(x)=kx 2itperformssimpleharmonicmotion.

Thecorrespondingtimeperiodisproportionalto ascanbeseeneasilyusingdimensionalanalysis.However,themotionof

aparticlecanbeperiodicevenwhenitspotentialenergyincreasesonbothsidesofx=0inawaydifferentfromkx2anditstotal
energyissuchthattheparticledoesnotescapetoinfinity.Consideraparticleofmassmmovingonthexaxis.Itspotentialenergy
is neartheoriginandbecomesaconstantequaltoV0for

ForperiodicmotionofsmallamplitudeA,thetimeperiodTofthisparticleisproportionalto

Question74.
WhenaparticleofmassmmovesonthexaxisinapotentialoftheformV(x)=kx 2itperformssimpleharmonicmotion.

Thecorrespondingtimeperiodisproportionalto ascanbeseeneasilyusingdimensionalanalysis.However,themotionof

aparticlecanbeperiodicevenwhenitspotentialenergyincreasesonbothsidesofx=0inawaydifferentfromkx2anditstotal
energyissuchthattheparticledoesnotescapetoinfinity.Consideraparticleofmassmmovingonthexaxis.Itspotentialenergy
is neartheoriginandbecomesaconstantequaltoV0for

Theaccelerationofthisparticlefor
Question75.
Astationarysourceisemittingsoundatafixedfrequencyf0,whichisreflectedbytwocarsapproachingthesource.Thedifference
betweenthefrequenciesofsoundreflectedfromthecarsis1.2%off0.Whatisthedifferenceinthespeedsofthecars(inkmper
hour)tothenearestinteger?Thecarsaremovingatconstantspeedsmuchsmallerthanthespeedofsoundwhichis330ms 1.

Question76.
Thefocallengthofathinbiconvexlensis20cm.Whenanobjectismovedfromadistanceof25cminfrontofitto50cm,the
magnificationofitsimagechangesfromm25tom50.Theratio is

Question77.
An particleandaprotonareacceleratedfromrestbyapotentialdifferenceof100V.Afterthis,theirdeBrogliewavelengthsare

respectively.Theratio tothenearestinteger,is

Question78.
Whentwoidenticalbatteriesofinternalresistance eachareconnectedinseriesacrossaresistorR,therateofheatproduced
inRisJ 1.WhenthesamebatteriesareconnectedinparallelacrossR,therateisJ 2.IfJ 1=2.25J 2thenthevalueofRin is

Question79.
TwosphericalbodiesA(radius6cm)andB(radius18cm)areattemperatureT1andT2,respectively.Themaximumintensityin
theemissionspectrumofAisat500nmandinthatofBisat1500nm.Consideringthemtobeblackbodies,whatwillbetheratioof
therateoftotalenergyradiatedbyAtothatofB?

Question80.

Whentwoprogressivewavesy 1=4sin(2x6t)andy 2=3 aresuperimposed,theamplitudeoftheresultant

waveis

Question81.
A0.1kgmassissuspendedfromawireofnegligiblemass.Thelengthofthewireis1manditscrosssectionalareais4.9x107m2.
Ifthemassispulledalittleintheverticallydownwarddirectionandreleased,itperformssimpleharmonicmotionofangularfrequency
140rads 1.IftheYoung'smodulusofthematerialofthewireisnx109Nm2,thevalueofnis

Question82.
AbinarystarconsistsoftwostarsA(mass2.2Ms )andB(mass11Ms ),whereMsisthemassofthesun.Theyareseparatedby
distancedandarerotatingabouttheircentreofmass,whichisstationary.Theratioofthetotalangularmomentumofthebinarystar
totheangularmomentumofstarBaboutthecentreofmassis

Question83.

Gravitationalaccelerationonthesurfaceofaplanetis wheregisthegravitationalaccelerationonthesurfaceoftheearth.

Theaveragemassdensityoftheplanetis2/3timesthatoftheearth.Iftheescapespeedonthesurfaceoftheearthistakentobe
11kms 1,theescapespeedonthesurfaceoftheplanetinkms 1willbe

Question84.
Apieceofice(heatcapacity=2100Jkg1oC1andlatentheat=3.36x105Jkg1)ofmassmgramsisat5oCatatmospheric
pressure.Itisgiven420Jofheatsothattheicestartsmelting.Finallywhentheicewatermixtureisinequilibrium,itisfoundthat1
gmoficehasmelted.Assumingthereisnootherheatexchangeintheprocess,thevalueofmis