SILICATO DE ALUMINIO IMPORTADO

COAL SLAG
PARA LIMPIEZA A CHORRO EN SUPERFICIES DE ACERO Y HORMIGON

A. BUSTAMANTE PONIENTE #1201 COL. BELLAVISTA, MONTERREY NUEVO LEON, C.P. 64410
TELEFONO 01 818 114 0797 Email: ventas@americangrit.cc
THE ORIGINAL

Tough love for your surfaces.

THE BEST VALUE

[ Get more done with less product ]

THE MOST TRUSTED

[ The original - for nearly 80 years ]

THE #1 ABRASIVE
[ Often imitated, never duplicated ]
 There is Only One Original BLACK BEAUTY Blasting Abrasive.
Harscos BLACK BEAUTY blasting abrasive has been number one in the industry for nearly 80 years. Our high quality, chemically inert, low free
silica and low dusting BLACK BEAUTY abrasives are utilized in a wide range of applications. This includes the removal of surface coatings such
as rust, paint, and scale, from a variety of substrates, especially structural steel and concrete. Imitation maybe the sincerest form of flattery,
but there is only one original BLACK BEAUTY abrasive.
Fast cutting, low dusting, tough enough to get the job done Harsco has been recycling coal
Uniform density combustion by-products to
Angular particle shape minimize landfilling of coal slag
Chemically inert across the United States since
Less than 0.1% free silica* the 1930s.
A 100% recycled, green product
* High free silica products have been found to increase the risk of silicosis. BLACK BEAUTY abrasives are classified as a low free
silica abrasive and can be used when low free silica abrasives are specified.

BLACK BEAUTY Product Grades

Available in 50lb bags at 60 bags per pallet, 100lb bags at 30 bags per pallet, Jumbo bags loaded up to 2 tons (4,000lbs) and bulk.

EXTRA FINE (30/60): FINE (20/40): MEDIUM (12/40):

Use Extra Fine to clean surfaces and create Use Fine for new construction, light paint
a smooth finish, brush-off blast or in a high and rust removal, and for special
pressure water blast system. maintenance applications requiring reduced
profiles. Bridge maintenance, light mill
scale, paint and rust, new structural steel.
Use Medium for general purpose repair
and maintenance blasting for the removal
of paint and rust, structural steel, mill scale
and aggregate exposure.

BLACK BEAUTY Abrasive Profile Guide

Minimum
Nozzle Size 1/8 3/16 1/4

Profile (Mils) (1.0-2.6 Mils) (2.0-3.8 Mils) (3.0-4.8 Mils)

This BLACK BEAUTY abrasive profile guide shows profile ranges achieved with different grades of BLACK BEAUTY abrasives in a controlled environment using a blast cabinet

designed by Harscos technical team. The controlled environment consisted of 90-100 psi at the nozzle, nozzle to surface distance of 18, a 1/4 orifice venturi nozzle, on new 1/8 grade A36
steel, with a blast angle of 75 degrees to 105 degrees.

Some variance in the profile can be noted by the profile ranges even in a controlled environment. Harsco cannot guarantee identical profile results with BLACK BEAUTY abrasives in
the field where variability exists.

Also Available ELITE Grade: If your project requires an abrasive that meets a specific sizing specification, we can help.
Using our proprietary processes and superior blending capabilities, we can fine-tune your BLACK BEAUTY blasting media to
Elite gradations. Contact us for assistance.

AL, Satsuma ( 800) 731-7982

FL, Tampa ( 800) 731-7982

IL, Pawnee ( 217) 237-4335

IL, Pekin ( 309) 347-1962

IN, Gary ( 219) 944-6250

KS, LaCygne (913) 757-4561

KY, Drakesboro (270) 476-8020

MD, Baltimore (888) 733-3646

NY, Buffalo (888) 733-3646

OH, Gallipolis (304) 845-0211

PA, Mechanicsburg: HQ
(888) 733-3646

PA, Philadelphia
f i n d b l a c k b e a u t y . c o m

b l a c k b e a u t y a b r a s i v e s . c o m

1 - 8 8 8 - 7 3 3 - 3 6 4 6

(215) 295-8675

TN, Memphis 901-789-0700

TX, Houston (800) 731-7982

TX, Rockdale (800) 731-7982

VA, Virginia Beach

A high quality abrasive from a company you can trust. (888) 733-3646

WV, Moundsville (304) 845-0211

 BLACK BEAUTY Abrasives VICE OMER SER T CUS

Product Specification Sheet -888-733-3646 1

Grades

MEDIUM: For general purpose repair and maintenance

blasting for the removal of paint and rust, structural steel,
mill scale and aggregate exposure.

FINE: For new construction, light paint and rust removal,

and for special maintenance applications requiring reduced
profiles. Bridge maintenance, light mill scale,paint and rust,
new structural steel.

X-FINE: To clean surfaces and create a smooth finish,

brush-off blast, or in a high pressure water blast system.

ELITE: If project requires a specialized blasting abrasive,

we can help. Using our proprietary processes and superior
blending capabilities, we can fine-tune your BLACK
BEAUTY blasting abrasive to Elite Gradations. Contact 1 (304) 845-021

our customer service group (1-888-733-3646) for immediate

assistance.

Profile Guide -4335 7) 237 (21

-789-070 0 1 90

The guide shows profile ranges achieved with different

grades of BLACK BEAUTY abrasives with a controlled
environment in a blast cabinet designed by Harscos 962 -1 (309) 347
(888) 733-3646

technical team. The controlled environment consisted of 90-

100 psi at the nozzle, nozzle to the surface distance of 18,
a 1/4 orifice venturi nozzle, on new 1/8 grade A36 steel,
o o
with a blast angle of 75 to 105 . (888) 733-3646
-7982 (80 0) 731

Some variance in the profile can be noted by the profile ranges even in a
controlled environment. Harsco cannot guarantee identical profile results
with BLACK BEAUTY abrasives in the field where variability exists.
(888) 733-3646

-7982 (80 0) 731

5
4.5
4 3.5 - 4.8 6-8020 (270) 47

3.5
(888) 733 -3646
Profile (Mils)

3
2.5 2.0 - 3.8
2
1.5 1.0 - 2.6 (888) 733-3646

1 1 (304) 845-021

0.5
0
suggested
minimum
1/4 3/16 1/8
nozzle size MEDIUM FINE X-FINE
A 7055 US A1 hanicsburg ,P es.com Mec kbeaut abrasiv y .blac -888-733-3646 www 1
BLACK BEAUTY Abrasives
Product Specification Sheet Cont.

Product Data (Typical)

Free Silica...less than 0.1%

Particle Shape...angular, sharp
Hardness...6 to 7 on the Mohs scale
Bulk Density...75-100 lbs per cubic ft
Specific Gravity...2.73
Moisture Content...less than 0.5%

Chemical Analysis (Typical)

Silicon Dioxide 48.78%

Aluminum Oxide 20.97%
Ferric Oxide 19.08%
Calcium Oxide 6.02%
Potassium Oxide 1.67%
Titanium Dioxide 0.94%
Magnesium Oxide 0.90%
Sodium Oxide 0.62%

Specific data may be obtained by contacting Harsco -888-733-3646. at 1

Features & Benefits

Less than 0.1% free silica
Hard angular particles
Uniform density
Low friability
Low dusting
Chemically inert
Passes 40CFR 261.a (TCLP)
Passes California Title 17 (CARB) (selected certified plants)
QPL Approved: MIL-A-2262B(SH) (selected plants only) SSPC AB-1
(all plants)

Proven. Trusted. Reliable.

For nearly 80 years.

A 7055 US A1 hanicsburg ,P es.com Mec kbeaut abrasiv y .blac -888-733-3646 www 1

 Informe No: 1052-1 OS-1/2013
(Inform)
INFORME DE RESULTADOS Fecha: 22-jul-13
( Analysis Inform) (Date)
Hoja: 1 DE 1
(Page)

Cliente: AMERICAN GRIT, S.A. DE C.V.

(Customer)
Identificacin: ABRASIVO MARCA BLACK BEAUTY SILICATO DE ALUMINIO ( COAL SLAG )
(Identification)
Especificacin del material: NO PROPORCIONADO
(Material specification)
Mtodo de referencia: ISO 11127
(Reference method)
Estandar de aceptacin: ISO 11126-4
(Acceptance standard )

Resultados Requerimiento

Humedad %( peso) 0.033 0,2% Max.

Densidad g/cm3 2.57 2,4 a 2.6

Dureza (MOHS) 7 6.0 Min.

Contaminantes solubles en agua mili S/m 9 25 Max.

Contenido de Silica libre % (peso) 0.06 1.0 Max.

Cloruros solubles en agua %(m/m) 0,001 0,0025 Max.

Conductividad (microSiemens) 17 25 Max

Observaciones:
(Remarks)

Realizado Por: Ing. Miguel A. Burgos G. Revisado Por: Ing. Jorge Petisme Malcon
(Tested by) (Reviewed by)
Puesto: G.L. Puesto: D.G.
(Position) (Position)
 MATERIAL SAFETY DATA SHEET

1. Product and Company Identification

Material name THE ORIGINAL BLACK BEAUTY
Version # 01
Issue date 11-30-2012
Revision date -
Supersedes date -
CAS # 68476-96-0
Product code Slag, coal
Product use Abrasives and Roofing Products and Other Aggregate Uses.
Manufacturer/Supplier Harsco
P.O. Box 0515, Camp Hill, PA 17001-0515
reedcs@harsco.com
Contact Person: Steve Stanislawczyk
717-506-4666
Emergency 855-393-9889
Access code 13793

2. Hazards Identification
Physical state Solid.
Appearance Black granular solid.
Emergency overview WARNING

Abrasive blasting agents may cause inflammation and pulmonary fibrosis. Dust may irritate the
respiratory tract, skin and eyes.
OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.
Potential health effects
Routes of exposure Inhalation. Eye contact. Skin contact.
Eyes Dust in the eyes will cause irritation. May cause redness and pain.
Skin Dust may irritate skin.
Inhalation Abrasive blasting agents may cause inflammation and pulmonary fibrosis. Dust may irritate throat
and respiratory system and cause coughing.
Ingestion Ingestion of dusts generated during working operations may cause nausea and vomiting.
Target organs Eyes. Respiratory system.
Chronic effects Frequent inhalation of fume/dust over a long period of time increases the risk of developing lung
diseases.
Signs and symptoms Irritation of nose and throat. Irritation of eyes and mucous membranes.
Potential environmental effects The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.

3. Composition / Information on Ingredients

Components CAS # Percent
Coal, slag 68476-96-0 100
Constituents CAS # Percent
Silicon dioxide 7631-86-9 41-53
Iron oxide 1309-37-1 7-31
Aluminum oxide 1344-28-1 17-25
Calcium oxide 1305-78-8 3-15
Magnesium oxide 1309-48-4 0-4
Potassium Oxide 12136-45-7 0-3
BLACK BEAUTY CPHCPH
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Constituents
Titanium dioxide
Silicon dioxide, crystalline
Manganese
Beryllium
Cadmium
Composition comments
4. First Aid Measures
First aid procedures
Eye contact
Skin contact
Inhalation
Ingestion
Notes to physician
General advice
5. Fire Fighting Measures
Flammable properties
Extinguishing media
Suitable extinguishing
media
Unsuitable extinguishing
media
Protection of firefighters
Specific hazards arising
from the chemical
Protective equipment and
precautions for firefighters
Fire fighting
equipment/instructions
6. Accidental Release Measures
Personal precautions
Environmental precautions
Methods for containment
Methods for cleaning up
Other information
7. Handling and Storage
Handling
Storage
BLACK BEAUTY
911790 Version #: 01 Revision date: -
CAS # Percent
13463-67-7 0-2
14808-60-7 <0.1
7439-96-5 0-0.05
7440-41-7 0-0.001
7440-43-9 0-0.001
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Do not rub eyes. Remove any contact lenses. Flush eyes thoroughly with water, taking care to
rinse under eyelids. If irritation persists, continue flushing for 15 minutes, rinsing from time to time
under eyelids. If discomfort continues, consult a physician.
Contact with dust: Wash with soap and water. Get medical attention if irritation develops or
persists.
Move to fresh air. Get medical attention if discomfort persists.
Rinse mouth thoroughly if dust is ingested. Do not induce vomiting. Get medical attention if any
discomfort continues.
Treat symptomatically.
Show this safety data sheet to the doctor in attendance.
The product is non-combustible.
Use fire-extinguishing media appropriate for surrounding materials.
None known.
None known.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Move container from fire area if it can be done without risk. Cool containers with flooding
quantities of water until well after fire is out.
Avoid generation and spreading of dust. Avoid inhalation of dust and contact with skin and eyes.
Wear suitable protective clothing. Use personal protection recommended in Section 8 of the
MSDS.
Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air).
Collect dust using a vacuum cleaner equipped with HEPA filter. If not possible, gently moisten
dust with water fog before it is collected with shovel, broom or the like. Avoid dust formation. After
removal flush contaminated area thoroughly with water.
Never return spills to original containers for re-use.
Clean up in accordance with all applicable regulations.
Avoid inhalation of dust and contact with skin and eyes. Use only with adequate ventilation. Use
work methods which minimize dust production. Keep the workplace clean. Observe good
industrial hygiene practices.
Keep container tightly closed. Store away from incompatible materials.
CPHCPH
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Issue date: 11-30-2012 2 / 10
8. Exposure Controls / Personal Protection
Occupational exposure limits
US. ACGIH Threshold Limit Values

Constituents Type Value Form

Beryllium (CAS 7440-41-7) TWA 0.00005 mg/m3 Inhalable fraction.
Cadmium (CAS 7440-43-9) TWA 0.01 mg/m3
0.002 mg/m3 Respirable fraction.
Manganese (CAS TWA 0.2 mg/m3
7439-96-5)
Silicon dioxide, crystalline TWA 0.025 mg/m3 Respirable fraction.
(CAS 14808-60-7)
Titanium dioxide (CAS TWA 10 mg/m3
13463-67-7)
Calcium oxide (CAS TWA 2 mg/m3
1305-78-8)
Magnesium oxide (CAS TWA 10 mg/m3 Inhalable fraction.
1309-48-4)
Aluminum oxide (CAS TWA 1 mg/m3 Respirable fraction.
1344-28-1)
Iron oxide (CAS 1309-37-1) TWA 5 mg/m3 Respirable fraction.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Constituents Type Value

Cadmium (CAS 7440-43-9) TWA 0.005 mg/m3
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Constituents Type Value Form

Manganese (CAS Ceiling 5 mg/m3 Fume.
7439-96-5)
Titanium dioxide (CAS PEL 15 mg/m3 Total dust.
13463-67-7)
Calcium oxide (CAS PEL 5 mg/m3
1305-78-8)
Magnesium oxide (CAS PEL 15 mg/m3 Total particulate.
1309-48-4)
Aluminum oxide (CAS PEL 5 mg/m3 Respirable fraction.
1344-28-1)
15 mg/m3 Total dust.
Iron oxide (CAS 1309-37-1) PEL 10 mg/m3 Fume.
US. OSHA Table Z-2 (29 CFR 1910.1000)

Constituents Type Value Form

Beryllium (CAS 7440-41-7) Ceiling 0.005 mg/m3
TWA 0.002 mg/m3
Cadmium (CAS 7440-43-9) Ceiling 0.6 mg/m3 Dust.
0.3 mg/m3 Fume.
TWA 0.2 mg/m3 Dust.
0.1 mg/m3 Fume.
US. OSHA Table Z-3 (29 CFR 1910.1000)

Constituents Type Value Form

Silicon dioxide, crystalline TWA 0.3 mg/m3 Total dust.
(CAS 14808-60-7)
0.1 mg/m3 Respirable.
2.4 mppcf Respirable.
Silicon dioxide (CAS TWA 0.8 mg/m3
7631-86-9)
20 mppcf

BLACK BEAUTY CPHCPH

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 Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)

Constituents Type Value Form

Beryllium (CAS 7440-41-7) STEL 0.01 mg/m3
TWA 0.002 mg/m3
Cadmium (CAS 7440-43-9) TWA 0.01 mg/m3
Manganese (CAS TWA 0.2 mg/m3
7439-96-5)
Silicon dioxide, crystalline TWA 0.025 mg/m3 Respirable particles.
(CAS 14808-60-7)
Titanium dioxide (CAS TWA 10 mg/m3
13463-67-7)
Calcium oxide (CAS TWA 2 mg/m3
1305-78-8)
Magnesium oxide (CAS TWA 10 mg/m3 Fume.
1309-48-4)
Aluminum oxide (CAS TWA 10 mg/m3
1344-28-1)
Iron oxide (CAS 1309-37-1) TWA 5 mg/m3 Respirable.
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)

Constituents Type Value Form

Beryllium (CAS 7440-41-7) STEL 0.01 mg/m3
TWA 0.002 mg/m3
Cadmium (CAS 7440-43-9) TWA 0.01 mg/m3
0.002 mg/m3 Respirable.
Manganese (CAS TWA 0.2 mg/m3
7439-96-5)
Silicon dioxide, crystalline TWA 0.025 mg/m3 Respirable fraction.
(CAS 14808-60-7)
Titanium dioxide (CAS TWA 3 mg/m3 Respirable fraction.
13463-67-7)
10 mg/m3 Total dust.
Calcium oxide (CAS TWA 2 mg/m3
1305-78-8)
Magnesium oxide (CAS STEL 10 mg/m3 Respirable dust and/or
1309-48-4) fume.
TWA 3 mg/m3 Respirable dust and/or
fume.
10 mg/m3 Inhalable fume.
Aluminum oxide (CAS TWA 1 mg/m3 Respirable.
1344-28-1)
Iron oxide (CAS 1309-37-1) STEL 10 mg/m3 Fume.
TWA 5 mg/m3 Fume.
5 mg/m3 Dust.
3 mg/m3 Respirable fraction.
10 mg/m3 Total dust.
Silicon dioxide (CAS TWA 4 mg/m3 Total
7631-86-9)
1.5 mg/m3 Respirable.
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)

Constituents Type Value Form

Beryllium (CAS 7440-41-7) STEL 0.01 mg/m3
TWA 0.002 mg/m3
Cadmium (CAS 7440-43-9) TWA 0.01 mg/m3
Manganese (CAS TWA 0.2 mg/m3
7439-96-5)
Silicon dioxide, crystalline TWA 0.1 mg/m3 Respirable.
(CAS 14808-60-7)
Titanium dioxide (CAS TWA 10 mg/m3
13463-67-7)

BLACK BEAUTY CPHCPH

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 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)

Constituents Type Value Form

Calcium oxide (CAS TWA 2 mg/m3
1305-78-8)
Magnesium oxide (CAS TWA 10 mg/m3 Inhalable fraction.
1309-48-4)
Aluminum oxide (CAS TWA 1 mg/m3 Respirable fraction.
1344-28-1)
Iron oxide (CAS 1309-37-1) TWA 5 mg/m3 Respirable fraction.
Silicon dioxide (CAS TWA 10 mg/m3
7631-86-9)
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)

Constituents Type Value Form

Beryllium (CAS 7440-41-7) TWA 0.00015 mg/m3
Cadmium (CAS 7440-43-9) TWA 0.025 mg/m3
Manganese (CAS STEL 3 mg/m3 Fume.
7439-96-5)
TWA 5 mg/m3 Dust.
1 mg/m3 Fume.
Silicon dioxide, crystalline TWA 0.1 mg/m3 Respirable dust.
(CAS 14808-60-7)
Titanium dioxide (CAS TWA 10 mg/m3 Total dust.
13463-67-7)
Calcium oxide (CAS TWA 2 mg/m3
1305-78-8)
Magnesium oxide (CAS TWA 10 mg/m3 Fume.
1309-48-4)
Aluminum oxide (CAS TWA 10 mg/m3 Total dust.
1344-28-1)
Iron oxide (CAS 1309-37-1) TWA 5 mg/m3 Dust and fume.
10 mg/m3 Total dust.
Silicon dioxide (CAS TWA 6 mg/m3 Respirable dust.
7631-86-9)
Mexico. Occupational Exposure Limit Values

Constituents Type Value Form

Beryllium (CAS 7440-41-7) TWA 0.002 mg/m3
Cadmium (CAS 7440-43-9) TWA 0.01 mg/m3 Total dust.
0.002 mg/m3 Respirable dust.
Manganese (CAS STEL 3 mg/m3 Fume.
7439-96-5)
TWA 1 mg/m3 Fume.
0.2 mg/m3
Silicon dioxide, crystalline TWA 0.1 mg/m3
(CAS 14808-60-7)
Titanium dioxide (CAS STEL 20 mg/m3
13463-67-7)
TWA 10 mg/m3
Calcium oxide (CAS TWA 2 mg/m3
1305-78-8)
Magnesium oxide (CAS TWA 10 mg/m3 Fume.
1309-48-4)
Aluminum oxide (CAS TWA 10 mg/m3
1344-28-1)
Iron oxide (CAS 1309-37-1) STEL 10 mg/m3
TWA 5 mg/m3
Engineering controls Use process enclosures, local exhaust ventilation, or other engineering controls to control
airborne levels below recommended exposure limits.
Personal protective equipment
Eye / face protection Wear safety glasses with side shields. Use tight fitting goggles if dust is generated.
Skin protection Use protective gloves. Wear suitable protective clothing.

BLACK BEAUTY CPHCPH

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 Respiratory protection Selection and use of respiratory protective equipment should be in accordance with OSHA
General Industry Standard 29 CFR 1910.134; or in Canada with CSA Standard Z94.4.
General hygiene Wash hands after handling. Routinely wash work clothing and protective equipment to remove
considerations contaminants. Handle in accordance with good industrial hygiene and safety practice.

9. Physical & Chemical Properties

Appearance Black granular solid.
Physical state Solid.
Form Solid.
Color Black.
Odor Odorless.
Odor threshold Not available.
pH Not available.
Vapor pressure Not available.
Vapor density Not available.
Boiling point Not available.
Melting point/Freezing point > 2500 F (> 1371.1 C)
Solubility (water) Negligible.
Specific gravity 2.7
Flash point Not available.
Flammability limits in air, Not available.
upper, % by volume
Flammability limits in air, Not available.
lower, % by volume
Auto-ignition temperature Not available.

10. Chemical Stability & Reactivity Information

Chemical stability The product is stable and non reactive under normal conditions of use, storage and transport.
Conditions to avoid None known.
Incompatible materials Strong acids.
Hazardous decomposition None known.
products
Possibility of hazardous Hazardous polymerization does not occur.
reactions

11. Toxicological Information

Toxicological data
Constituents Species Test Results
Cadmium (CAS 7440-43-9)
Acute
Inhalation
LC50 Rat 0.025 mg/l, 900 Days
Oral
LD50 Rat 225 mg/kg
Silicon dioxide (CAS 7631-86-9)
Acute
Oral
LD50 Mouse > 15000 mg/kg
Rat > 22500 mg/kg
Sensitization Not a skin or respiratory sensitizer.
ACGIH Sensitizer
Beryllium (CAS 7440-41-7) Sensitizer.

BLACK BEAUTY CPHCPH

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Acute effects Abrasive blasting agents may cause inflammation and pulmonary fibrosis. Ingestion of dusts
generated during working operations may cause nausea and vomiting.
Local effects May cause eye, skin and respiratory tract irritation.
US. ACGIH Threshold Limit Values
Beryllium (CAS 7440-41-7) Can be absorbed through the skin.
Chronic effects Frequent inhalation of fume/dust over a long period of time increases the risk of developing lung
diseases.
Carcinogenicity
ACGIH Carcinogens
Aluminum oxide (CAS 1344-28-1) A4 Not classifiable as a human carcinogen.
Beryllium (CAS 7440-41-7) A1 Confirmed human carcinogen.
Cadmium (CAS 7440-43-9) A2 Suspected human carcinogen.
Iron oxide (CAS 1309-37-1) A4 Not classifiable as a human carcinogen.
Magnesium oxide (CAS 1309-48-4) A4 Not classifiable as a human carcinogen.
Silicon dioxide, crystalline (CAS 14808-60-7) A2 Suspected human carcinogen.
Titanium dioxide (CAS 13463-67-7) A4 Not classifiable as a human carcinogen.
IARC Monographs. Overall Evaluation of Carcinogenicity
Beryllium (CAS 7440-41-7) 1 Carcinogenic to humans.
Cadmium (CAS 7440-43-9) 1 Carcinogenic to humans.
Iron oxide (CAS 1309-37-1) 3 Not classifiable as to carcinogenicity to humans.
Silicon dioxide (CAS 7631-86-9) 3 Not classifiable as to carcinogenicity to humans.
Silicon dioxide, crystalline (CAS 14808-60-7) 1 Carcinogenic to humans.
Titanium dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans.
US NTP Report on Carcinogens: Known carcinogen
Beryllium (CAS 7440-41-7) Known To Be Human Carcinogen.
Cadmium (CAS 7440-43-9) Known To Be Human Carcinogen.
Silicon dioxide, crystalline (CAS 14808-60-7) Known To Be Human Carcinogen.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Cadmium (CAS 7440-43-9) Cancer hazard.
Mutagenicity No data available.
Reproductive effects No data available.
Symptoms and target organs Irritation of nose and throat. Irritation of eyes and mucous membranes. May cause respiratory
tract irritation. Shortness of breath.

12. Ecological Information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Environmental effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Persistence and degradability The product is not biodegradable.
Bioaccumulation / The product is not bioaccumulating.
Accumulation

13. Disposal Considerations

Waste codes
Disposal instructions
Waste from residues / unused
products
Contaminated packaging
The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose in accordance with all applicable regulations.
Dispose in accordance with all applicable regulations.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport Information

DOT
Not regulated as a hazardous material by DOT.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.

BLACK BEAUTY CPHCPH

MSDS
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TDG
Not regulated as dangerous goods.

15. Regulatory Information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Beryllium (CAS 7440-41-7)
Cadmium (CAS 7440-43-9)
Manganese (CAS 7439-96-5)
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration
Aluminum oxide (CAS 1344-28-1) 1.0 %
Beryllium (CAS 7440-41-7) 0.1 %
Cadmium (CAS 7440-43-9) 0.1 %
Manganese (CAS 7439-96-5) 1.0 %
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Aluminum oxide (CAS 1344-28-1) Listed.
Beryllium (CAS 7440-41-7) Listed.
Cadmium (CAS 7440-43-9) Listed.
Manganese (CAS 7439-96-5) Listed.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
Section 302 extremely No
hazardous substance (40
CFR 355, Appendix A)
Section 311/312 (40 CFR Yes
370)
Drug Enforcement Not controlled
Administration (DEA) (21 CFR
1308.11-15)
Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDS
contains all the information required by the CPR.
WHMIS status Non-controlled

Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) No
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) No
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory No

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 Country(s) or region Inventory name On inventory (yes/no)*
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)
State regulations WARNING: This product contains chemical(s) known to the State of California to cause cancer
and birth defects or other reproductive harm.
US - California Hazardous Substances (Director's): Listed substance
Aluminum oxide (CAS 1344-28-1) Listed.
Beryllium (CAS 7440-41-7) Listed.
Cadmium (CAS 7440-43-9) Listed.
Calcium oxide (CAS 1305-78-8) Listed.
Iron oxide (CAS 1309-37-1) Listed.
Magnesium oxide (CAS 1309-48-4) Listed.
Manganese (CAS 7439-96-5) Listed.
Silicon dioxide (CAS 7631-86-9) Listed.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Beryllium (CAS 7440-41-7) Listed.
Cadmium (CAS 7440-43-9) Listed.
Silicon dioxide, crystalline (CAS 14808-60-7) Listed.
Titanium dioxide (CAS 13463-67-7) Listed.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Beryllium (CAS 7440-41-7) Listed: October 1, 1987 Carcinogenic.
Cadmium (CAS 7440-43-9) Listed: October 1, 1987 Carcinogenic.
Silicon dioxide, crystalline (CAS 14808-60-7) Listed: October 1, 1988 Carcinogenic.
Titanium dioxide (CAS 13463-67-7) Listed: September 2, 2011 Carcinogenic.
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Cadmium (CAS 7440-43-9) Listed: May 1, 1997 Developmental toxin.
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
Cadmium (CAS 7440-43-9) Listed: May 1, 1997 Male reproductive toxin.
US - New Jersey RTK - Substances: Listed substance
Aluminum oxide (CAS 1344-28-1) Listed.
Beryllium (CAS 7440-41-7) Listed.
Cadmium (CAS 7440-43-9) Listed.
Calcium oxide (CAS 1305-78-8) Listed.
Iron oxide (CAS 1309-37-1) Listed.
Magnesium oxide (CAS 1309-48-4) Listed.
Manganese (CAS 7439-96-5) Listed.
Potassium Oxide (CAS 12136-45-7) Listed.
Silicon dioxide (CAS 7631-86-9) Listed.
Silicon dioxide, crystalline (CAS 14808-60-7) Listed.
Titanium dioxide (CAS 13463-67-7) Listed.
US - Pennsylvania RTK - Hazardous Substances: All compounds of this substance are considered environmental
hazards
Beryllium (CAS 7440-41-7) LISTED
Cadmium (CAS 7440-43-9) LISTED
Manganese (CAS 7439-96-5) LISTED
US - Pennsylvania RTK - Hazardous Substances: Special hazard
Beryllium (CAS 7440-41-7) Special hazard.
Cadmium (CAS 7440-43-9) Special hazard.
US. Massachusetts RTK - Substance List
Aluminum oxide (CAS 1344-28-1) Listed.
Beryllium (CAS 7440-41-7) Listed.
Cadmium (CAS 7440-43-9) Listed.
Calcium oxide (CAS 1305-78-8) Listed.
Iron oxide (CAS 1309-37-1) Listed.
Magnesium oxide (CAS 1309-48-4) Listed.
Manganese (CAS 7439-96-5) Listed.
Silicon dioxide (CAS 7631-86-9) Listed.
Silicon dioxide, crystalline (CAS 14808-60-7) Listed.
Titanium dioxide (CAS 13463-67-7) Listed.
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 US. New Jersey Worker and Community Right-to-Know Act
Aluminum oxide (CAS 1344-28-1) 500 LBS
Beryllium (CAS 7440-41-7) 500 LBS
Cadmium (CAS 7440-43-9) 500 LBS
Manganese (CAS 7439-96-5) 500 LBS
US. Pennsylvania RTK - Hazardous Substances
Aluminum oxide (CAS 1344-28-1) Listed.
Beryllium (CAS 7440-41-7) Listed.
Cadmium (CAS 7440-43-9) Listed.
Calcium oxide (CAS 1305-78-8) Listed.
Iron oxide (CAS 1309-37-1) Listed.
Magnesium oxide (CAS 1309-48-4) Listed.
Manganese (CAS 7439-96-5) Listed.
Silicon dioxide (CAS 7631-86-9) Listed.
Silicon dioxide, crystalline (CAS 14808-60-7) Listed.
Titanium dioxide (CAS 13463-67-7) Listed.
Mexico regulations This safety data sheet was prepared in accordance with the Official Mexican Standard
(NOM-018-STPS-2000).

16. Other Information

Further information HMIS is a registered trade and service mark of the NPCA.
A HMIS Health rating including an * indicates a chronic hazard.
HMIS ratings Health: 2*
Flammability: 0
Physical hazard: 0
NFPA ratings Health: 1
Flammability: 0
Instability: 0
Disclaimer The information in the sheet was written based on the best knowledge and experience currently
available.

BLACK BEAUTY CPHCPH

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