Chem JUJ K1 K2 K3 Skema Jawapan SET 2

SKEMA PRAKTIS BESTARI JUJ
KIMIA SET 2 KERTAS 1, 2 & 3
SKEMA JAWAPAN KERTAS 1
JUJ KIMIA SET 2 - 2017
1 D 11 C 21 A 31 D 41 C
2 C 12 B 22 D 32 C 42 A
3 C 13 B 23 C 33 A 43 B
4 C 14 B 24 D 34 A 44 B
5 A 15 C 25 A 35 A 45 A
6 B 16 C 26 C 36 B 46 D
7 B 17 C 27 C 37 A 47 A
8 C 18 A 28 B 38 D 48 B
9 C 19 D 29 D 39 B 49 B
10 B 20 B 30 B 40 C 50 C
4541 Set 2 Hak Cipta JUJ Pahang 2017 1

MARKING SCHEME PAPER 2 SET 2 JUJ CHEMISTRY 2017
Sub Mark
Question No Mark Scheme
Mark
1 (a) (i) smallest neutral particles 1 1
(ii) 1 1
(iii) electron 1 1
(iv) 1. One similarity 1 2
2. one different 1
Sample answer :
1. Same number of proton /proton number // same number of
electron
2. Different number of neutron / nucleon number
(b) (i) 70 / 70oC 1 1
(ii) 1. Heat energy absorbed 1 2
2. is used to overcome the forces of attraction between particles 1
(iii) Correct arrangement (at least 3x3 with same size & do not 1 1
overlapping each other)
Total marks 9
Sub Mark
Question No Mark Scheme
Mark
2 (a) (i) The chemical formula that shows the simplest ratio of atoms of each 1 1
element in the compound
(ii) C2H4O 1 1
(b) 1. value of n 1
2. Molecular formula 1 2
Sample answer :
(CH2) n = 42 // (12+ 2(1))n = 42 // 14n = 42 // n = 3
Molecular formula = C3H6
(c) (i) Mass 1 1
(ii) 64 + 2(14)+ 6(16) // 188 1 1
(iii) Correct value with unit 1 1
Answer : 1.2 X 188 g // 225.6 g
(iv) 1. Correct formula of reactants and product 1
2. balanced 1
Answer : 2Cu(NO3)2 2CuO + 4NO2 + O2 2
Total marks 9

Question No Mark scheme Sub mark

mark
3 (a) (i) Chlorine/Cl 1 1
(ii) Aluminium 1 1
(iii) Argon atom has achieved stable octet electron arrangement 1 1
(b) (i) Cl 1 1
(ii) The forces of attraction between nucleus and electron in Cl 1 1
atoms is stronger than Na atom.
(c) (i) Ionic bond 1 1
(ii)
+ -
Na Cl
1.Correct number of ion and nucleus is labelled 1

2.Correct electron arrangement and charged 1 2
(iii) 1. Soluble in water// 1+1 2

2. High melting and boiling point//
3. Conduct electricity in aqueous and molten state
Any two
Total marks 10

mark
4 (a) (i) Silicon dioxide / silica 1 1
(ii) stabiliser /emulsifier 1 1
(iii) Flavouring agent//thickening agent//colouring agent 1 1
(iv) Analgesic // paracetamol 1 1
(b) (i) N2+3H2 2NH3
1. Correct formula of reactants and products 1
2. Balanced equation 1 2
(ii) 1. Type of fertilizer
2. % of N in urea
3. % of N in ammonium sulphate
4. Conclusion
Answer:
Urea. 1
4
% of N in urea %of N in ammonium sulphate
=(28/60) x100% =(28/132) x 100% 1+1
=46.67% = 21.21%
% of nitrogen atom by mass for urea is higher than 1

ammonium sulphate
Total marks 10

Sub
Question No Mark Scheme Mark
Mark
5 (a) (i) Increase of hydrogen gas per unit time // decrease of mass of 1 1
zinc per unit time
(b) (i) 1. draw the triangle 1
2. calculation
43.5-29 cm3 // 14.5 cm3 // 0.242 cm3 s-1 1 2

120-60 s 60 s
(ii) 41-26 cm3 s-1 // 15 cm3 s-1 // 0.25 cm3 s-1 1 1
120-60 60
(iii) Because the concentration of acid decrease with time 1 1
(c) (i) Volume of gas / cm3
Set II
1 1
Set I
Time / s
(ii) 1. size of zinc is smaller 1 2
2. remain the volume and concentration of hydrochloric acid. 1
(d) (i) Put 5 g/a packet of fine sugar in hot water and cold water in two 1 1
cups. Sugar in hot water dissolve faster.
(ii) 1. temperature higher in hot water 1 2
2. water particles has higher kinetic energy 1
Total Marks 11
Sub
Mark
6(a) (i) Na+ , NO3- , H+ , OH- (accept name of ions) 1 1
(ii) 1. hydrogen ions 1 1
(iii) 1. put glowing wooden splinter into a test tube 1 2
2. The wooden splinter lights up 1
(iv) 1. Suggest the suitable electrode (can infer from diagram) 1 3
2. functional diagram 1
3. correct label : 1
Anode : silver electrode ; Cathode : iron spoon
Electrolyte : silver nitrate solution
silver
Iron
spoon Silver nitrate
solution

Sub
Mark
(b) (i) 1. Anode : Zn Zn2+ + 2e 1
2. Cathode : Cu2+ + 2e Cu 1 2
(iii) 1. Change copper electrode to silver electrode // change zinc 1

electrode to magnesium electrode// any suitaible pair of
electrodes
2. Reason : 2
Distance between Ag and Zinc / Mg and Cu in 1
electrochemical series is further
Total Marks 11
Sub
Mark
7 (a) (i) 1. structural formula
2. name
1+1
1+1
Butan -2-ol 2-methylpropan-2-ol
2-methylpropan-1-ol
*Any two isomer 4
(ii) 1. Reaction I = esterification 1
Functional Homologous name
group series
X Alkene But-1-ene
// 1+1+1
Carbon-carbon
double bond
Y Carboxylic acid Butanoic acid
1+1+1
//
Carboxyl group
z ester Butyl 1+1+1
etanoate
//
carboxylate 10
group

Sub
Mark
(b) 1. Correct formula of reactants and product 1
2. balanced 1
C3H8 + 5O2 3CO2 + 4H2O
3 & 4. Calculation
Propene Propane 1+1

% of carbon 3(12) x 100 3(12) x 100
42 44
= 85.71% = 81.81%
5. % of carbon atom by mass in propene is higher than 1

propane.
6. Propene produces more soot than propane 1 6
Total Marks 20

mark
8 (a) 1. V = sodium carbonate 1
2. W= copper(II) sulphate 1
3. X = nitric acid 1
4. Y = copper(II) oxide 1
5. Z= Carbon dioxide 1
6. Double decomposition reaction // precipitation reaction 1
Correct formula of reactants 2+2
7 & 8. Reaction I : Na2CO3 + CuSO4 CuCO3 + Na2SO4
9& 10. Reaction II : CuCO3 + HNO3 Cu(NO3)2 + CO2 +H2O 10
(b) Compare and contrast :
Similarities :
1. Both experiment produce black residue 1+1+1
2. Both experiment released gas when heated
Differences:
3. Exp I produced colourless gas and Exp II produced brown gas
4. Exp 1 turns the limewater chalky and Exp II turns moist blue
litmus paper to red
* Choose any 3
4. mole
5. ratio mole
6. correct answer with unit
Answer :
Mol = 6.2/124 // 0.05 1
Ratio : 1 mol CuCO3 : 1 mol CO2 1
0.05 mol CuCO3 : 0.05 mol CO2
Answer : 0.05 x 24 dm3 // 1.2 dm3 1
6


mark
(c) 1.Egg shells contain calcium carbonate 1
2. Calcium carbonate can react with acid 1
3. Calcium carbonate can dissolved in acid 1
4. Egg shell becomes soft//easier to insert in the bottle 1 4
Total Marks 20
Question Mark scheme Sub mark

No mark
9 (a) Elephant Toothpaste Cold Pack
Types Exothermic Endothermic
of 1+1
reaction
Energy
profile
diagram
-Correct level and label -Correct level and label 1+1

energy energy
-correct equation & H -correct equation & H 1+1
Total Total energy content of the Total energy content of
energy reactants is higher than the products is higher 1+1
content products than reactants 8
(b) (i) 1. State solution A,
2. solution B
3. precipitate D (can infer from procedure)
4-9. procedure
10. data
11-12. calculation
Sample answer :
1. Solution A = sodium chloride solution 1
2. solution B silver nitrate solution, 1
3. Precipitate D = silver chloride 1
Procedure :
4. Measure [20 100 cm3] of sodium chloride [any suitable 1
solution] [0.5 2.0 moldm-3] solution and pour the solution into a
plastic/polystryrene cup
5.Measure [20 100 cm3] of silver nitrate [any suitable solution] 1
[0.5 2.0 moldm-3] solution and pour the solution into another
plastic/polystryrene cup
6. record initial temperature for both solutions 1

Question Mark scheme Sub mark

No mark
7. pour sodium chloride solution quickly into the silver nitrate 1
solution
8.stir the mixture 1
9. record the highest temperature reached 1
10. Initial temperature of sodium chloride solution = T1oC 1

Initial temperature of silver nitrate solution = T2 oC
Average Initial temperature = (T1+ T2)/2 = Ta oC
Highest temperature = Tb oC
11. heat given out = mc = 200 x 4.2 x (Tb Ta) 1

1000
= w kJ
1
12. number of mol = 50 x 1 /1000 = 0.05
13. Heat of precipitation = - w/0.05 = -X kJmol-1 1 max12
Total Marks 20
Question Answer Sub marks

mark
10 (a)(i) 1. suitable metal R : Zn/Mg 1
Zn/Mg CuSO4
Types of 2. oxidation 3. reduction 1+1
reaction
Half 4. Zn Zn2+ + 2e 5. Cu2+ + 2e Cu
equation 1+1
6. Name the ion present in the colourless solution = copper(II) ions 1 6

(a)(ii)
Zn/Mg CuSO4
Change in 1. 0 +2 2. +2 0
oxidation 1+1
number
Role 3. Reducing agent 4. Oxidizing agent 1+1 4
(b) Sample answer : 1
1. Metal : Zn/Al
Procedure :
2. Clean Zn/Al strip and iron nail with sand paper 1
3. Coil Zn/Al strip around the iron nail and put in a test tube 1
4. Put the iron nail only into another test tube. 1
5. Pour the hot agar-agar/jelly solution that has been mixed with 1
potassium hexacyanoferrate(III) and phenolphthalein indicator until
the iron nail immersed into both test tube.

Question Answer Sub marks

mark
6. Leave the test tubes aside for a few days. 1
7. Observation
Pair of metal Observation 1
Zn/Al and iron nail pink spot form
Iron nail Blue spot form
Half equation for oxidation of metals

8. Test tube I : Zn Zn2+ + 2e 1
9. Test Tube II : Fe Fe2+ + 2e 1
10. Conclusion
When a more electropositive metal is in contact with iron, the metal 1
inhibits rusting //
10
iron does not rust when in contact with a more electropositive metal
Total marks 20
END OF MARKING SCHEME PAPER 2

PERATURAN PEMARKAHAN KIMIA KERTAS 3 JUJ SET 2 2017

Question Rubric Score
Able to state the colour change correctly
Answer: 3
Pink colour change to colourless
Able to state the colour change less correctly

1(a)
Sample answer: 2
Purple to colourless
Able to state an idea of colour

1
Sample Answer:
Pink // Colourless// Purple
No response or wrong response 0

Able to record all burette readings accurately to 2 decimal
places 3
Answer:
Titration Initial reading (cm3) Final reading (cm3)

1(b) I 0.00 26.00
II 0.50 24.50
III 5.50 30.50
Able to record all the burette readings correctly to 1 decimal

places or able to record at least 4 reading correctly // uniform 2
decimal places
Able to record at least 2 burette reading correctly without

decimal places 1


Able to consruct a table that contains the following information.
1. Hading in the table : Set, Initil reading/cm3, Final reading/cm3,

Volume of acid/cm3
2. Transfer all the burette readings from 1(b) correctly
3. With unit at the heading
Sample answer: 3
1(c)
Titration Initil reading/cm3 Final Volume of
Bacaan awal/cm3 reading/cm3 acid/cm3
Bacaan Isipadu asid/cm3
akhir/cm3
I 0.00 26.00 26.00
II 0.50 24.50 24.00
III 5.50 30.50 25.00
Able to construct a table less correctly

2
Able to construct a table that contains the following information
1. Headings in the table : suitable heading

1
2. 2 column with heading without data/
2 column only
Sample answer:
Initial reading Final reading


Able to calculate the average volume and concentration of
hydrochloric acid with unit correctly
Answer:
Average volume of hydrochloric acid
= 26.00 + 24.00 + 25.00
---------------------------- = 25.00 cm3 --- p1
3 3
1(d)
Concentration of hydrochloric acid
MHCl VHCl = 1
MNaOH VNaOH 1
MHCl X 25.00 = 1
1.0 X 50.00 1 ---- p2
// 25.00 MHCl = 50.00
MHCl = 50.00
25.00
= 2.0 mol dm-3 ---- p3
Able to calculate the average volume and concentration of

hydrochloric acid correctly without unit 2
Able to calculate volume of acid OR concentration of acid
correctly 1

Able to classify all the acids into strong and weak acid correctly
Strong acids Weak acids

Asid kuat Asid lemah 3
1(e) Sulfuric acid Citric acid

Nitric acid Ethanoic acid
Able to classify at least 3 acids correctly 2

Able to classify at least 2 acids correctly/reverse 1


Able to state all inferences correctly
2(a) Test tube A B C D 3

Inference Iron nail Iron nail Iron nail Iron nail
does not rust // Fe2+ does not rust // Fe2+
rust //Fe2+ Present / rust // Fe2+ Present /
does not formed does not formed
present present
Able to state 3 inferences correctly 2
Able to state 2 inferences correctly 1

Able to state the relationship between manipulated varible and
responding variable with direction correctly
2(b)
Sample answer: 3
When a more/less electropositive metal / higher/lower than iron
in Electrochemical series is in contact with iron, iron (nail) does
not rust/rust
Able to state the hypothesis less correctly
Sample answer:
The rusting of iron is faster / slower, if a less / more
2
electropositive metal is in contact with iron/Fe
Able to give an idea of hypothesis
Sample answer:
Iron rust when in contact with other metal // other metal affect
the rusting of iron.
1

Able to state all the variables correctly
2(c) Sample answer:

Manipulated variable : Type / different electropositive metal
Responding variable : Rusting // presence of blue sport 3
Constant variable : Type of iron nail // iron //medium in
which the iron are kept
Able to state any two of variables in this experiment correctly 2
Able to state any two of variables in this experiment correctly 1


Able to give one operational definition of the experiment
correctly with the following aspects:
i) what you do 3
ii) what you observe
Sample answer:
1. when iron nail is coiled/in contact with a less
2(d) electropositive metal (copper)/metal located below iron in
electrochemical series
2. Rusting of iron is the formation of blue spot/colouration
Able to state at least two criteria correctly
Sample answer:
Rusting of iron is the formation of blue spot /colouration 2
or
when iron nail is coiled/in contact with a less electropositive
metal
Able to state an idea of operational definition
Sample answer:
Blue spot/rusting occur 1

Able to predict the observation correctly
2(e) Answer: 3
The intensity of blue spot/colouration is very high//higher than
test tube B.
Able to predict the observation
Sample answer: 2
The intensity of blue spot/colouration is high
Able to predict the observation 1
Sample answer:
Blue spot/colour


Able to state the relationship correctly between the time taken
and the amount of rust form correctly
1. Time taken
2. Formation of rust
3. Comparison
3
Sample answer:
The longer the time taken, the bigger/greater/larger the rust form
2(f) //the longger the time taken, more rust is form
//the rust form is greater/bigger/larger when the time taken is
longer
//the rust form in one week is more/bigger/greater/larger than one
day
Able to state the relationship between the time taken and the
amount of rust form less correctly
1. Time taken/Formation of rust
2
Sample answer:
The rust form is bigger/greater/larger

//the form is directly proportional to the time taken
Able to state any idea of relationship

Sample answer:
1
The rust is form/change//rust is small/less


Able to give the problem statement correctly
Sample answer:
3
How does the effectiveness of cleansing action of two different
types of cleansing agent in hard water?
// What is the difference in effectiveness of cleansing action in

hard water using soap and detergent?
Able to give the problem statement less correctly
Sample answer:
3(a)
How does different type of cleansing agent affect the 2
effectiveness of cleansing action in hard water?
// To investigate the effectiveness of different type of cleansing

agent in hard water.
Able to give an idea of statement of the problem
Sample answer: 1
To study the effectiveness of cleansing action in hard water

Able to state all variables correctly
Sample answer:
Manipulated variable :Types of cleansing agent//soap and 3

3(b) detergent
Responding variable : Effectiveness of cleansing agent//ability
to remove the oily stains on cloth
Constant variable : Hard water//Cloth with oily stains//Size
of cloth
Able to state any two variables correctly 2

Able to state any one variable correctly 1


Able to state the relationship between the manipulated variable
and the responding variable correctly
Sample answer:
Detergent is more effective than soap in hard water. 3
// Detergent in hard water can remove the oily stains on cloth
while soap cannot.
Able to state the relationship between the manipulated variable

and the responding variable incorrectly
Sample answer:
Detergent is more effective 2
3(c) // Soap is less effective
// Detergent in hard water can remove the oily stains on
cloth
//soap cannot remove stain on cloth.
Able to state an idea of hypothesis 1

Able to give the completely list of the apparatus and materials
Answer:
Apparatus:
Beakers, measuring cylinder, glass rod
Material:
Soap, detergent, [cleansing agent X dan cleansing agent Y], 3
0.5 - 1 mol dm-3 magnesium sulphate solution/[sea water/hard
water], 2 pieces of cloth with oily stains.
3(d) Able to give the list of the apparatus and materials correctly but
not completely
Answer: 2
Apparatus:
Any containers, glass rod
Material:
Cleansing agent, cloth with oily stains.
Able to give two materials and at least one apparatus

Answer :
Material: 1
Soap solution / detergent, hard water
[any container]
No response or wrong response
0


Able to state all procedures correctly
Sample answer :
1. Label 2 beakers as A and B respectively

2. Fill all the beakers with [50 - 100 cm3 ]of hard water /
magnesium sulphate solution 3
3. Add cleansing agent X/detergent in beaker A and
cleansing agent Y/soap in bikar B.
3(e) 4. Place a piece of cloth with oily stain into each beaker
5. Stir the solution in each beaker using glass rod until no
change can be observed
6. Wash the oily stain on each piece of cloth using the
solution in each beaker
7. Record the observation.
Able to state three steps of procedures correctly 2

Steps 2, 3, 5, 6,
Able to state two steps of procedures correctly 1
Steps 2, 3, 6

Able to exhibit the tabulation of data that includes the following
information.
1. Headings
Sample answer : 2
3(f) Beaker Observation

A
B
Able to tabulate the data incompletely
1. Titles without unit 1

Sample answer:
Beaker
No response given / wrong response 0
PERATURAN PEMARKAHAN TAMAT

Chem JUJ K1 K2 K3 Skema Jawapan SET 2

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SKEMA PRAKTIS BESTARI JUJ

KIMIA SET 2 KERTAS 1, 2 & 3

SKEMA JAWAPAN KERTAS 1

JUJ KIMIA SET 2 - 2017

4541 Set 2 Hak Cipta JUJ Pahang 2017 1

MARKING SCHEME PAPER 2 SET 2 JUJ CHEMISTRY 2017

4541 Set 2 Hak Cipta JUJ Pahang 2017 2

Question No Mark scheme Sub mark

1.Correct number of ion and nucleus is labelled 1

(iii) 1. Soluble in water// 1+1 2

Question No Mark scheme Sub mark

% of nitrogen atom by mass for urea is higher than 1

4541 Set 2 Hak Cipta JUJ Pahang 2017 3

43.5-29 cm3 // 14.5 cm3 // 0.242 cm3 s-1 1 2

4541 Set 2 Hak Cipta JUJ Pahang 2017 4

(iii) 1. Change copper electrode to silver electrode // change zinc 1

4541 Set 2 Hak Cipta JUJ Pahang 2017 5

C3H8 + 5O2 3CO2 + 4H2O

Propene Propane 1+1

5. % of carbon atom by mass in propene is higher than 1

Question No Mark scheme Sub mark

4541 Set 2 Hak Cipta JUJ Pahang 2017 6

Question No Mark scheme Sub mark

Question Mark scheme Sub mark

-Correct level and label -Correct level and label 1+1

4541 Set 2 Hak Cipta JUJ Pahang 2017 7

Question Mark scheme Sub mark

10. Initial temperature of sodium chloride solution = T1oC 1

11. heat given out = mc = 200 x 4.2 x (Tb Ta) 1

13. Heat of precipitation = - w/0.05 = -X kJmol-1 1 max12

Question Answer Sub marks

6. Name the ion present in the colourless solution = copper(II) ions 1 6

4541 Set 2 Hak Cipta JUJ Pahang 2017 8

Question Answer Sub marks

Half equation for oxidation of metals

END OF MARKING SCHEME PAPER 2

4541 Set 2 Hak Cipta JUJ Pahang 2017 9

PERATURAN PEMARKAHAN KIMIA KERTAS 3 JUJ SET 2 2017

Able to state the colour change less correctly

Able to state an idea of colour

No response or wrong response 0

Question Rubric Score

Titration Initial reading (cm3) Final reading (cm3)

Able to record all the burette readings correctly to 1 decimal

Able to record at least 2 burette reading correctly without

4541 Set 2 Hak Cipta JUJ Pahang 2017 10

Question Rubric Score

1. Hading in the table : Set, Initil reading/cm3, Final reading/cm3,

II 0.50 24.50 24.00

III 5.50 30.50 25.00

Able to construct a table less correctly

1. Headings in the table : suitable heading

No response or wrong response 0

4541 Set 2 Hak Cipta JUJ Pahang 2017 11

Question Rubric Score

// 25.00 MHCl = 50.00

= 2.0 mol dm-3 ---- p3

Able to calculate the average volume and concentration of

Question Rubric Score

Strong acids Weak acids

1(e) Sulfuric acid Citric acid

Able to classify at least 3 acids correctly 2

4541 Set 2 Hak Cipta JUJ Pahang 2017 12