Chapter 7 Atomic Physics

f S 2S

\ dW \ r sinT drdT dI
2 2 2
7-23. 1
0 0 0

f f 2
Zr 2
4S \ r dr 2 2
4S C2
210 0 a0 r e
Zr / a0
dr 1
0

f
Z 2r 4
4S C210 0 a02 e
2 Zr / a0
dr 1

Letting x Zr / a0 , we have that r a0 x / Z and dr a0dx / Z and substituting

these above,
2 f
4S a03C210
\ dW 0 x e dx
2 4 x

Z3

Integrating on the right side

f

x e
4 x
dx 6
0

1/ 2
Z3 Z3
Solving for C 2
yields: C 2
o C210 3
24S a03 24S a0
210 210

3/ 2
1 Z r
7-24. \ 200 1 e
r / 2 a0
(Z = 1 for hyrdogen)
32S a0 a0
2
2 1 1 r
P r 'r \ 200 4S r 'r 2
3
1 e
r / a0
4S r 2 'r
32S a0 a0

(a) For 'r 0.02a0 , at r a0 we have

4S 1 2 1
P r 'r 1 1 e 1a02 0.02a0 0 e 1
0.02 0
32S a0
3
8

(b) For 'r 0.02a0 , at r 2a0 we have

4S 1 2 1
P r 'r 1 e 2 a02 0.02a0 1e 2
0.02 3.4 u 10 4

32S a03 8

166
 Chapter 7 Atomic Physics

Zr
7-25. \ 210 C210 e Zr / 2 a0
cosT (Equation 7-34)
a0

2 2 Z 2r 2
P r \ 210 4S r 2 4S r 2 C210 e r / a0
cos2 T
a02
2
4S C210 Z 2 / a02 r 4e r / a0
cos2 T

Ar 4e r / a0
cos2 T
2
where A 4S C210 Z 2 / a02 , a constant.

3/ 2
1 1 r
7-26. \ 200 2 e
r / 2 a0
(Z = 1 for hyrdogen)
32S a0 2a0
3/ 2
1 1 0.606 1
(a) At r a0 , \ 200 3 2 1 e
1/ 2

32S a0 32S a0

2 1 1 0.368 1
(b) At r a0 , \ 200 3 e
1

32S a0 32S a03

2 4 0.368a02 0.368
(c) At r a0 , P r \ 200 4S r 2
32S a03 8a0

7-27. For the most likely value of r, P(r) is a maximum, which requires that (see Problem 7-25)

dP Z
A cos2 T r 4 e
Zr / a0
4r 3 e Zr / a0
0
dr a0

For hydrogen Z = 1 and A cos2 T r 3 / a0 4a0 r e r / a0

0 . This is satisfied for r = 0

and r = 4a0. For r = 0, P(r) = 0 so the maximum P(r) occurs for r = 4a0.

15 iM
7-28. From Table 7-1, Y2 T ,M sinT cosT e
8S
1

r2 4 r 3 a0
From Table 7-2, R32 r 2
e
81 30a02 a0

167