Disha Publication 2016 Jee-Advanced Solved-Paper. V526057483

JEE ADVANCED 2016 PAPER
This Paper JEE Advanced 2016 Paper is taken from our:
ISBN : 9789386146168
JEE ADVANCED 2016
1. The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of three
sections.
2. Section 1 contains 5 questions. Each question has four choices (a), (b), (c) and (d). ONLY ONE of these four
options is correct.
4. Section 3 contains 5 questions. The answer to each of the questions is a single-digit integer ranging from 0 to 9
(both inclusive).
3. Section 2 contains 8 multiple choice questions. Each question has four choices (a), (b), (c) and (d) out of which
ONE OR MORE THAN ONE are correct.
PAPER - 1
PHYSICS 3. A water cooler of storage capacity 120 litres can cool water
at a constant rate of P watts. In a closed circulation system
SECTION - I (as shown schematically in the figure), the water from the
cooler is used to cool an external device that generates
This section contains 5 multiple choice questions. Each question
constantly 3 kW of heat (thermal load). The temperature of
has four choices (a), (b), (c) and (d) out of which ONLY ONE
water fed into the device cannot exceed 30C and the entire
option is correct.
stored 120 litres of water is initially cooled to 10C. The
1. In a historical experiment to determine Planck's constant, a entire system is thermally insulated. The minimum value of
metal surface was irradiated with light of different P (in watts) for which the device can be operated for 3 hours
wavelengths. The emitted photoelectron energies were is
measured by applying a stopping potential. The relevant
data for the wavelength (l) of incident light and the
corresponding stopping potential (V0) are given below :
l (mm) V0 (Volt)
0.3 2.0
0.4 1.0 (Specific heat of water is 4.2 kJ kg1K1 and the density of
0.5 0.4 water is 1000 kg m3)
(a) 1600 (b) 2067
Given that c = 3 108m s1 and e = 1.6 1019 C , Planck's (c) 2533 (d) 3933
constant (in units of J s) found from such an experiment is 4. A parallel beam of light is incident from air at an angle a on
(a) 6.0 1034 (b) 6.4 1034 the side PQ of a right angled triangular prism of refractive
(c) 6.6 10 34 (d) 6.8 1034
index n = 2 . Light undergoes total internal reflection in
2. A uniform wooden stick of mass 1.6 kg and length l rests in
an inclined manner on a smooth, vertical wall of height h(< the prism at the face PR when a has a minimum value of 45.
l) such that a small portion of the stick extends beyond the The angle q of the prism is
wall. The reaction force of the wall on the stick is
perpendicular to the stick. The stick makes an angle of 30 P
with the wall and the bottom of the stick is on a rough floor.
The reaction of the wall on the stick is equal in magnitude to q
the reaction of the floor on the stick. The ratio h/l and the a
frictional force f at the bottom of the stick are
(g = 10 m s2)
n= 2
h 3 16 3 h 3 16 3
(a) = ,f = N (b) = ,f = N Q R
l 16 3 l 16 3
h 3 3 8 3 h 3 3 16 3 (a) 15 (b) 22.5

(c) = ,f = N (d) = ,f = N (c) 30 (d) 45
l 16 3 l 16 3
2016-2 JEE Advanced 2016 Solved Paper
5. An infinite line charge of uniform electric charge density l (c) The plot below represents schematically the variation
lies along the axis of an electrically conducting infinite of beat frequency with time
cylindrical shell of radius R. At time t = 0, the space inside
the cylinder is filled with a material of permittivity e and v(t)
electrical conductivity s. The electrical conduction in the
material follows Ohm's law. Which one of the following P
graphs best describes the subsequent variation of the Q
magnitude of current density j(t) at any point in the material? vQ
j(t)
j(t) R
t
(a) (b)
(d) The plot below represents schematically the variation
of beat frequency with time
t
t (0, 0)
(0, 0) v(t)
j(t) j(t)
P
vQ
(c) (d) Q
t t
R
(0, 0) (0, 0)
t
SECTION - II 8. An incandescent bulb has a thin filament of tungsten that is
This section contains 8 multiple choice questions. Each question heated to high temperature by passing an electric current.
has 4 choices (a), (b), (c) and (d) out of which ONE or MORE The hot filament emits blackbody radiation. The filament
is observed to break up at random locations after a
THAN ONE are correct.
sufficiently long time of operation due to nonuniform
6. Highly excited states for hydrogenlike atoms (also called evaporation of tungsten from the filament. If the bulb is
Rydberg states) with nuclear charge Ze are defined by their powered at constant voltage, which of the following
principal quantum number n, where n>>1. Which of the statement(s) is(are) true?
following statement(s) is(are) true? (a) The temperature distribution over the filament is
(a) Relative change in the radii of two consecutive orbitals uniform
does not depend on Z (b) The resistance over small sections of the filament
(b) Relative change in the radii of two consecutive orbitals decreases with time
varies as 1/n (c) The filament emits more light at higher band of
(c) Relative change in the energy of two consecutive frequencies before it breaks up
orbitals varies as 1/ n 3 (d) The filament consumes less electrical power towards
(d) Relative change in the angular momenta of two the end of the life of the bulb
9. A planoconvex lens is made of a material of refractive index
consecutive orbitals varies as 1/n
n. When a small object is placed 30 cm away in front of the
7. Two loudspeakers M and N are located 20 m apart and emit
curved surface of the lens, an image of double the size of
sound at frequencies 118 Hz and 121 Hz, respectively. A car the object is produced. Due to reflection from the convex
is initially at a point P , 1800 m away from the midpoint Q of surface of the lens, another faint image is observed at a
the line MN and moves towards Q constantly at 60 km/hr distance of 10 cm away from the lens. Which of the following
along the perpendicular bisector of MN. It crosses Q and statement(s) is(are) true?
eventually reaches a point R, 1800 m away from Q. Let v(t) (a) The refractive index of the lens is 2.5
represent the beat frequency measured by a person sitting (b) The radius of curvature of the convex surface is 45 cm
in the car at time t. Let vP , vQ and vR be the beat frequencies (c) The faint image is erect and real
measured at locations P, Q and R, respectively. The speed (d) The focal length of the lens is 20 cm
of sound in air is 330 ms1 . Which of the following 10. A lengthscale (l) depends on the permittivity (e) of a
statement(s) is(are) true regarding the sound heard by the dielectric material. Boltzmann constant (kB), the absolute
person? temperature (T), the number per unit volume (n) of certain
(a) vP + vR = 2 vQ charged particles, and the charge (q) carried by each of the
(b) The rate of change in beat frequency is maximum when particles. Which of the following expression(s) for I is(are)
dimensionally correct?
the car passes through Q
JEE Advanced 2016 Solved Paper 2016-3
nq 2 ek T
(a) l= (b) l = B2
ek BT nq

q2 q2
(c) l= (d) l=
en 2/3 k T en1/3 k T
B B
11. A conducting loop in the shape of a right angled isosceles

triangle of height 10 cm is kept such that the 90 vertex is
very close to an infinitely long conducting wire (see the Which of the following statement(s) is(are) true?
figure). The wire is electrically insulated from the loop. The (a) nl sinqi = n2 sinqf
hypotenuse of the triangle is parallel to the wire. The current (b) n1 sin qi = (n 2 n 1) sinqf
in the triangular loop is in counterclockwise direction and (c) l is independent of n2
increased at a constant rate of 10 A s1. Which of the (d) l is dependent on n(z)
following statement(s) is(are) true?
SECTION - III
10 cm This section contains 5 questions. Each question, when worked

90
out will result in one integer from 0 to 9 (both inclusive).
m0 14. A metal is heated in a furnace where a sensor is kept above

(a) The magnitude of induced emf in the wire is the metal surface to read the power radiated (P) by the metal.
p
The sensor has a scale that displays log 2, (P/P0 ), where P0
volt
is a constant. When the metal surface is at a temperature of
(b) If the loop is rotated at a constant angular speed about
487C, the sensor shows a value 1. Assume that the
m0 emissivity of the metallic surface remains constant. What is
the wire, an additional emf of volt is induced in the value displayed by the sensor when the temperature of
p
the wire the metal surface is raised to 2767C?
(c) The induced current in the wire is in opposite direction 15. The isotope 12 having a mass 12.014 u undergoes
5 B
to the current along the hypotenuse
(d) There is a repulsive force between the wire and the bdecay to 12 12 has an excited state of the nucleus
6 C. 6 C
loop
12. The position vector rr of a particle of mass m is given by the
following equation
( 126 C*) at 4.041 MeV above its ground state. If 125 E decays
r 12
r (t) = at 3i + bt 2j , to 6 C * , the maximum kinetic energy of the bparticle in
where a = 10/3 ms3, b = 5 ms2 and m = 0.1 kg. At t = 1 s, units of MeV is (1 u = 931.5 MeV/c2, where c is the speed of
which of the following statement(s) is(are) true about the light in vacuum).
particle? 16. A hydrogen atom in its ground state is irradiated by light of
(a) The velocity vr is given by vr = (10i + 10j) ms1 wavelength 970 . Taking hc/e = 1.237 106 eV m and the
r ground state energy of hydrogen atom as 13.6 eV, the
(b) The angular momentum L with respect to the origin is number of lines present in the emission spectrum is
r 17. Consider two solid spheres P and Q each of density 8 gm
given by L = 5/3) k N m s
r r cm3 and diameters 1 cm and 0.5 cm, respectively. Sphere P
(c) The force F is given by F = (i + 2j) N is dropped into a liquid of density 0.8 gm cm3 and viscosity
r h = 3 poiseulles. Sphere Q is dropped into a liquid of density
(d) The torque t with respect to the origin is given by
r 1.6 gm cm3 and viscosity h = 2 poiseulles. The ratio of the
t = (20/3) k N m terminal velocities of P and Q is
13. A transparent slab of thickness d has a refractive index n(z) 18. Two inductors L1 (inductance 1 mH, internal resistance 3
that increases with z. Here z is the vertical distance inside
W) and L2 (inductance 2 mH, internal resistance 4 W), and a
the slab, measured from the top. The slab is placed between
resistor R (resistance 12 W) are all connected in parallel
two media with uniform refractive indices n1 and n 2 (> n1),
across a 5 V battery. The circuit is switched on at time t = 0.
as shown in the figure. A ray of light is incident with angle
qi, from medium 1 and emerges in medium 2 with refraction The ratio of the maximum to the minimum current
angle qt with a lateral displacement l. (Imax / I min) drawn from the battery is
CHEMISTRY (c) higher the magnitude of activation energy, stronger is
the temperature dependence of the rate constant.
SECTION - I (d) the preexponential factor is a measure of the rate at
which collisions occur, irrespective of their energy.
25. A plot of the number of neutrons (N ) against the number of
protons (P) of stable nuclei exhibits upward deviation from
option is correct.
linearity for atomic number, Z > 20. For an unstable nucleus
19. P is the probability of finding the 1s electron of hydrogen having N/P ratio less than 1, the possible mode(s) of decay
atom in a spherical shell of infinitesimal thickness, dr, at a is(are)
distance r from the nucleus. The volume of this shell is (a) b decay (b emission)
4p r2dr. The qualitative sketch of the dependence of P on r is (b) orbital or Kelectron capture
(c) neutron emission
P P (d) b-decay (positron emission)
26. The crystalline form of borax has
(a) tetranuclear [B4O5(OH)4]2 unit
(b) all boron atoms in the same plane
(a) (b) (c) equal number of sp2 and sp3 hybridized boron atoms
(d) one terminal hydroxide per boron atom
27. The compound(s) with TWO lone pairs of electrons on the
0 r 0 r
central atom is(are)
(a) BrF5 (b) ClF3
P P (c) XeF4 (d) SF4
28. The reagent(s) that can selectively precipitate S2 from a
mixture of S2 and SO42 in aqueous solution is(are)
(a) CuCl2 (b) BaCl2
(c) (d) (c) Pb(OOCCH3)2 (d) Na2[Fe(CN)5NO]
29. Positive Tollens test is observed for
0 r 0 r H O
20. One mole of an ideal gas at 300 K in thermal contact with CHO
surroundings expands isothermally from 1.0 L to 2.0 L against (a) H (b)
a constant pressure of 3.0 atm. In this process, the change H
in entropy of surroundings (DSsurr) in JK1 is H
(1 L atm = 101.3 J)
OH
(a) 5.763 (b) 1.013 O
(c) 1.013 (d) 5.763 Ph
(c) Ph (d)
21. The increasing order of atomic radii of the following Group
13 elements is O Ph Ph
(a) Al < Ga < In < Tl (b) Ga < Al < In < Tl 30. The product(s) of the following reaction sequence is(are)
(c) Al < In < Ga < Tl (d) Al < Ga < Tl < In
NH2
22. Among [Ni(CO) 4 ], [NiCl 4 ] 2 , [Co(NH 3 ) 4 Cl 2 ]Cl,
(i) Acetic anhydride/pyridine
Na 3[CoF 6 ], Na 2 O 2 and CsO 2, the total number of (ii) KBrO 3/HBr
paramagnetic compounds is
(iii) H 3O +, heat
(a) 2 (b) 3
(iv) NaNO 2/ HCl, 273-278 K
(c) 4 (d) 5
(v) Cu/HBr
23. On complete hydrogenation, natural rubber produces
(a) ethylenepropylene copolymer Br
(b) vulcanised rubber Br
(c) polypropylene
(d) polybutylene
(a) (b)
SECTION - II
Br Br
has 4 choices (a), (b), (c) and (d) out of which ONE or MORE
THAN ONE are correct. Br
24. According to the Arrhenius equation, Br Br Br
(a) a high activation energy usually implies a fast reaction. Br Br
(b) rate constant increases with increase in temperature. (c) (d)
This is due to a greater number of collisions whose
energy exceeds the activation energy. Br
31. The correct statement(s) about the following reaction the equation x2 + 2x tan q 1 = 0. If a1 > b1 and a2 > b2, then
sequence is(are) a1 + b2 equals
(i) O CHCl / NaOH (a) 2 (sec q tan q) (b) 2 sec q
Cumene(C9 H12 )
2
+
P
3 (c) 2 tanq (d) 0
(ii)H3O
38. A debate club consists of 6 girls and 4 boys. A team of 4
Q (major) + R (minor) members is to be selected from this club including the
NaOH selection of a captain (from among these 4 members) for the
Q
PhCH Br
S
team. If the team has to include at most one boy, then the
2
(a) R is steam Volatile number of ways of selecting the team is
(b) Q gives dark violet coloration with 1% aqueous FeCl3 (a) 380 (b) 320
solution (c) 260 (d) 95
(c) S gives yellow precipitate with 2, 4dinitro- p
phenylhydrazine 39. Let S = x ( -p, p) : x 0, . The sum of all distinct
2
(d) S gives dark violet coloration with 1% aqueous FeCl3
solutions of the equation 3 sec x + cosec x + 2(tan x cot
solution x) = 0 in the set S is equal to
SECTION - III
7p 2p
This section contains 5 questions. Each question, when worked (a) (b) -
9 9
out will result in one integer from 0 to 9 (both inclusive).
5p
(c) 0 (d)
32. The mole fraction of a solute in a solution is 0.1. At 298 K, 9
molarity of this solution is the same as its molality. Density 40. A computer producing factory has only two plants T1 and
of this solution at 298 K is 2.0 g cm3 . The ratio of the T2. Plant T1 produces 20% and plant T2 produces 80% of
the total computers produced. 7% of computers produced
MWsolute in the factory turn out to be defective. It is known that
molecular weights of the solute and solvent, MW , P (computer turns out to be defective given that it is produced
solvent
in plant T1)
is = 10P
33. The diffusion coefficient of an ideal gas is proportional to (computer turns out to be defective given that it is produced
its mean free path and mean speed. The absolute temperature in plant T2),
of an ideal gas is increased 4 times and its pressure is where P(E) denotes the probability of an event E. A computer
increased 2 times. As a result, the diffusion coefficient of produced in the factory is randomly selected and it does
this gas increases x times. The value of x is not turn out to be defective. Then the probability that it is
34. In neutral or faintly alkaline solution, 8 moles of permanganate produced in plant T2 is
anion quantitatively oxidize thiosulphate anions to produce
X moles of a sulphur containing product. The magnitude of 36 47
(a) (b)
X is 73 79
35. The number of geometric isomers possible for the complex 78 75
[CoL2Cl2] (L = H2NCH2CH2O) is (c) (d)
93 83
36. In the following monobromination reaction, the number of
possible chiral products is 1
41. The least value of a for which 4ax2 + 1 , for all x > 0,
x
CH2CH2CH3
is
H Br Br2 (1.0 mole)
300C 1 1
CH3 (a) (b)
64 32
(1.0 mole)
(enantiomerically pure) 1 1
(c) (d)
27 25
MATHEMATICS
SECTION - II
SECTION - I
This section contains 5 multiple choice questions. Each question has 4 choices (a), (b), (c) and (d) out of which ONE or MORE
has four choices (a), (b), (c) and (d) out of which ONLY ONE THAN ONE are correct.
option is correct.
42. Consider a pyramid OPQRS located in the first octant (x 0,
p p y 0, z 0) with O as origin, and OP and OR along the xaxis
37. Let - < q < - . Suppose a1 and B1are the roots of the and the yaxis, respectively. The base OPQR of the pyramid
6 12
is a square with OP = 3. The point S is directly above the
equation x2 2x sec q + 1 = 0 and a2 and b2 are the roots of mid-point T of diagonal OQ such that TS = 3. Then
46. A solution curve of the differential equation (x2 +xy + 4x +2y
p
(a) the acute angle between OQ and OS is
3 dy
+ 4) y2 = 0, x > 0, passes through the point (1, 3). Then
(b) the equation of the plane containing the triangle OQS dx
is x y = 0 the solution curve
(c) the length of the perpendicular from P to the plane (a) intersects y = x + 2 exactly at one point
(b) intersects y = x + 2 exactly at two points
3
containing the triangle OQS is (c) intersects y = (x + 2)2
2 (d) does NOT intersect y = (x +3)2
(d) the perpendicular distance from O to the straight line 47. Let f : , g : and h : be
differentiable functions such that
15
containing RS is
2 f(x) = x3 + 3x + 2, g(f(x)) = x and h (g(g(x))) = x for all x .
Then
43. Let f : (0, ) be a differentiable function such that
1
f (x) (a) g(2) = (b) h(1) = 666
f '(x) = 2 - for all x (0, ) and f(1) 1. Then 15
x
(c) h(0) = 16 (d) h(g(3)) = 36
48. 2 2
The circle C1 : x + y = 3, with centre at O, intersects the
1 1
(a) lim f = 1 (b) lim xf = 2 parabola x2 = 2y at the point P in the first quadrant. Let the
x 0 + x x 0 + x
tangent to the circle C1 at P touches other two circles C2
and C3 at R2 and R3, respectively. Suppose C2 and C3 have
(c) lim x 2 f (x) = 0 (d) |f(x)| 2 for all x (0, 2)
x 0 + equal radii 2 3 and centres Q2 and Q3, respectively. If Q2
and Q3 lie on the yaxis, then
3 -1 -2
2 0 a (a) Q2Q3 = 12
44. Let P = , where a . Suppose Q = [qij] is a (b) R2R3 = 4 6
3 -5 0
(c) area of the triangle OR2R3 is 6 2
matrix such that PQ = kI, where k , k 0 and I is the
(d) area of the triangle PQ2Q3 is 4 2
k k2 49. Let RS be the diameter of the circle x2 + y2 = 1, where S is the
identity matrix of order 3. If q23 = and det(Q) = ,
8 2 point (1, 0). Let P be a variable point (other than R and S) on
then the circle and tangents to the circle at S and P meet at the
(a) a = 0, k = 8 (b) 4a k + 8 = 0 point Q. The normal to the circle at P intersects a line drawn
(c) det (P adj (Q)) = 2 9 (d) det (Q adj (P)) = 213 through Q parallel to RS at point E. Then the locus of E
45. In a triangle XYZ, let x, y, z be the lengths of sides opposite passes through the point(s)
to the angles X,Y, Z, respectively, and 2s = x + y + z.
1 1 1 1
s-x s-y s-z (a) 3 , (b) ,
3 4 2
If = = and area of incircle of the triangle
4 3 2
1 1 1 1
8p (c) 3 , - (d) , -
XYZ is , then 3 4 2
3
SECTION - III
(a) area of the triangle XYZ is 6 6
This section contains 5 questions. Each question, when worked
35 out will result in one integer from 0 to 9 (both inclusive).
(b) the radius of circumcircle of the triangle XYZ is 6
6 50. The total number of distinct x for which
X Y Z 4
(c) sin sin sin = x x2 1 + x3
2 2 2 35
2x 4x 2 1 + 8x 3
= 10 is
X + Y 3 3x 9x 2 1 + 27x 3
sin 2 =
(d) 2 5
51. Let m be the smallest positive integer such that the

coefficient of x2 in the expansion of (1 + x)2 + (1 + x)3 + ... + x 2 sin(bx)
53. Let a, b be such that lim = 1. Then
(1 + x)49 + (1 + mx)50 is (3n + 1) 51C3 for some positive x 0 ax - sin x
integer n. Then the value of n is 6 (a + b) equals.
52. The total number of distinct x [0, 1] for which
-1 + 3i
x 2 54. Let z = , where i = -1 , and r, s {1, 2, 3}. Let
t 2
1+ t 4
dt = 2x 1 is
0 ( - z)r z 2s
P = 2s and I be the identity matrix of order 2.
z z r
Then the total number of ordered pairs (r, s) for which
P2 = I is
PAPER - 2
1. The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of three
sections.
2. Section 1 contains 6 questions. Each question has four options (a), (b), (c) and (d). ONLY ONE of these four
options is correct.
3. Section 2 contains 8 multiple choice questions. Each question has four choice (a), (b), (c) and (d) out of which
ONE OR MORE THAN ONE are correct.
4. Section 3 contains 2 paragraphs each describing theory, experiment and data etc. four questions relate to two
paragraphs with two questions on each paragraph. Each question pertaining to a particular passage should have
ONLY ONE correct answer among the four given choices (a), (b), (c) and (d).
PHYSICS process at volume Vf . The amount of heat supplied to the

system in the two-step process is approximately
SECTION - I (a) 112 J (b) 294 J
This section contains 6 multiple choice questions. Each question (c) 588 J (d) 813 J
has four choices (a), (b), (c) and (d) out of which ONLY ONE 4. The ends Q and R of two thin wires, PQ and RS, are soldered
option is correct. (joined) together. Initially each of the wires has a length of 1
m at 10C. Now the end P is maintained at 10C, while the
1. The electrostatic energy of Z protons uniformly distributed end S is heated and maintained at 400 C. The system is
throughout a spherical nucleus of radius R is given by thermally insulated from its surroundings. If the thermal
2 conductivity of wire PQ is twice that of the wire RS and the
3 Z (Z - 1) e coefficient of linear thermal expansion of PQ is 1.2 105
E=
5 4 0R K1, the change in length of the wire PQ is
(a) 0.78 mm (b) 0.90 mm
The measured masses of the neutron 11 H, 15 15
7 N and 8 O are (c) 1.56 mm (d) 2.34 mm
1.008665 u, 1.007825 u, 15.000109 u and 15.003065 u, 5. A small object is placed 50 cm to the left of a thin convex
15 15 lens of focal length 30 cm. A convex spherical mirror of radius
respectively. Given that the radii of both the 7 N and 8 O of curvature 100 cm is placed to the right of the lens at a
nuclei are same, 1 u = 931.5 Me V/c2 (c is the speed of light) distance of 50 cm.The mirror is tilted such that the axis of
and e2/(4 pe0) = 1.44 MeV fm. Assuming that the difference the mirror is at an angle q =30 to the axis of the lens, as
between the binding energies of 15 15 shown in the figure.
7 N and 8 O is purely due
to the electrostatic energy, the radius of either of the nuclei f = 30 cm
is
(1 fm = 1015 m)
(a) 2.85 fm (b) 3.03 fm q x
(50,0) (0, 0) R
(c) 3.42 fm (d) 3.80 fm =
2. An accident in a nuclear laboratory resulted in deposition 10
0
50 cm cm
of a certain amount of radioactive material of half-life 18
days inside the laboratory. Tests revealed that the radiation
was 64 times more than the permissible level required for
safe operation of the laboratory. What is the minimum number (50 + 50 3, -50)
of days after which the laboratory can be considered safe
for use? If the origin of the coordinate system is taken to be at the
(a) 64 (b) 90 centre of the lens, the coordinates (in cm) of the point (x, y)
(c) 108 (d) 120 at which the image is formed are
3. A gas is enclosed in a cylinder with a movable frictionless
piston. Its initial thermodynamic state at pressure Pi = 105 (a) (0, 0) (b) (50 - 25 3, 25)
Pa and volume Vi = 103 m3 changes to a final state at Pf = (1/
32) 105 Pa and Vf = 8 103 m3 in an adiabatic quasi-static (c) (25, 25 3) (d) (125 / 3,25 3)
process, such that P3V5 = constant. Consider another 6. There are two Vernier calipers both of which have 1 cm
thermodynamic process that brings the system from the same divided into 10 equal divisions on the main scale. The Vernier
initial state to the same final state in two steps: an isobaric scale of one of the calipers (C1) has 10 equal divisions that
expansion at Pi followed by an isochoric (isovolumetric) correspond to 9 main scale divisions. The Vernier scale of
the other caliper (C2) has 10 equal divisions that correspond

to 11 main scale divisions. The readings of the two calipers
are shown in the figure. The measured values (in cm) by
calipers C1 and C2, respectively, are Light
2 3 4
C1
Electrons
0 5 10
2 3 4
V
C2 +
0 5 10
(a) 2.85 and 2.82 (b) 2.87 and 2.83

(a) le decreases with increase in f and lph
(c) 2.87 and 2.86 (d) 2.87 and 2.87
(b) le is approximately halved, if d is doubled
SECTION - II (c) For large potential difference (V >> f/e), le is
approximately halved if V is made four times
has 4 choices (a), (b), (c) and (d) out of which ONE or MORE (d) le increases at the same rate as lph for lph < hc/f
THAN ONE are correct. 9. In an experiment to determine the acceleration due to gravity
7. Two thin circular discs of mass m and 4m, having radii of a g, the formula used for the time period of a periodic motion
and 2a, respectively, are rigidly fixed by a massless, rigid
7 (R - r)
rod of length l = 24a through their centres. This assembly is T = 2p . The values of R and r are measured to
5g
is laid on a firm and flat surface, and set rolling without
slipping on the surface so that the angular speed about the be (60 1) mm and (10 1) mm, respectively. In five
axis of the rod is w. The angular momentum of the entire successive measurements, the time period is found to be
ur
assembly about the point O is L (see the figure). Which 0.52s, 0.56s, 0.57s, 0.54s and 0.59s. The least count of the
of the following statement(s) is (are) true? watch used for the measurement of time period is 0.01s.
Which of the following statement(s) is (are) true?
4m
(a) The error in the measurement of r is 10%
(b) The error in the measurement of T is 3.75%
m (c) The error in the measurement of T is 2%
z w
l (d) The error in the determined value of g is 11%
2a
l a 10. Consider two identical galvanometers and two identical
O resistors with resistance R. If the internal resistance of the
galvanometers RC < R/2, which of the following statement(s)
about any one of the galvanometers is (are) true?
(a) The centre of mass of the assembly rotates about the
(a) The maximum voltage range is obtained when all the
z-axis with an angular speed of w/5
(b) The magnitude of angular momentum of center of mass components are connected in series
of the assembly about the point O is 81 ma2w (b) The maximum voltage range is obtained when the two
(c) The magnitude of angular momentum of the assembly resistors and one galvanometer are connected in series,
about its center of mass is 17 ma2w/2. and the second galvanometer is connected in parallel
ur
(d) The magnitude of the z-component of L is 55 ma2w. to the first galvanometer
8. Light of wavelength lph falls on a cathode plate inside a (c) The maximum current range is obtained when all the
vacuum tube as shown in the figure. The work function of components are connected in parallel
the cathode surface is f and the anode is a wire mesh of
(d) The maximum current range is obtained when the two
conducting material kept at a distance d from the cathode. A
potential difference V is maintained between the electrodes. galvanometers are connected in series and the
If the minimum de Broglie wavelength of the electrons combination is connected in parallel with both the
passing through the anode is le, which of the following resistors
statement(s) is (are) true?
11. In the circuit shown below, the key is pressed at time t = 0.
Which of the following statement(s) is(are) true?
Screen
z
40 mF 25 kW
O
y

v S1 S2
+ d x
D
A 50 W 20 mF (a) Straight bright and dark bands parallel to the x-axis
(b) The region very close to the point O will be dark
(c) Hyperbolic bright and dark bands with foci
+ symmetrically placed about O in the x-direction
Key (d) Semi circular bright and dark bands centered at point.
5V
14. A rigid wire loop of square shape having side of length L
and resistance R is moving along the x-axis with a constant
(a) The voltmeter displays 5V as soon as the key is velocity v0 in the plane of the paper. At t = 0, the right edge
pressed, and displays +5V after a long time of the loop enters a region of length 3L where there is a
(b) The voltmeter will display 0V at time t = ln 2 seconds uniform magnetic field B0 into the plane of the paper, as
(c) The current in the ammeter becomes 1/e of the initial shown in the figure. For sufficiently large v0. the loop
value after 1 second eventually crosses the region. Let x be the location of the
(d) The current in the ammeter becomes zero after a long right edge of the loop. Let v(x), I(x) and F(x) represent the
time. velocity of the loop, current in the loop, and force on the
12. A block with mass M is connected by a massless spring loop, respectively, as a function of x. Counter-clockwise
current is taken as positive.
with stiffness constant k to a rigid wall and moves without
friction on a horizontal surface. The block oscillates with
small amplitude A about an equilibrium position x0. Consider
two cases: (i) when the block is at x0; and (ii) when the block
is at x = x0 + A. In both the cases, a particle with mass m(<M) R
is softly placed on the block after which they stick to each L
other. Which of the following statement(s) is (are) true about v0
the motion after the mass m is placed on the mass M?
x
(a) The amplitude of oscillation in the first case changes 0 2L 4L
L 3L
M Which of the following schematic plot(s) is (are) correct?
by a factor of , whereas in the second case it
m+M (Ignore gravity)
remains unchanged.
v(x)
(b) The final time period of oscillation in both the cases is
same. v0
(c) The total energy decreases in both the cases.
(d) The instantaneous speed at x0 of the combined masses (a)
decreases in both the cases
13. While conducting the Youngs double slit experiment, a 0 L 2L 3L 4L x
student replaced the two slits with a large opaque plate in
the x-y plane containing two small holes that act as two I(x)
coherent point sources (S1, S2) emitting light of wavelength
600 nm. The student mistakenly placed the screen parallel
to the x-z plane (for z > 0) at a distance D = 3 m from the mid-
point of S1S2, as shown schematically in the figure. The
3L 4L
distance between the sources d = 0.6003 mm. The origin O is
(b) x
at the intersection of the screen and the line joining S1S2. 0 L 2L
Which of the following is(are) true of the intensity pattern
on the screen?
I(x) w
R
(c)
m
0 x
L 2L 3L 4L R/2
F(x)
15. The distance r of the block at time t is
R wt -wt R
(a)
4 (
e +e
) (b)
2
cos wt
R 2wt R
+ e -2wt
4( )
(c) e cos 2wt (d)
x 2
0 L 2L 3L 4L
16. The net reaction of the disc on the block is
(d)
1
mw2 R e2wt - e -2wt j + mgk
(
(a)
2 )
1
mw R (e2 wt
- e-wt j + mgk
(b)
2 )
(c) - mw2 R coswt j - mgk
SECTION - II (d) mw2 R sinswt j - mgk
This section contains 2 paragraphs, each describing theory, PARAGRAPH 2
experiments, data etc. four questions related to the two paragraphs Consider an evacuated cylindrical chamber of height h having
with two questions on each paragraph. Each question has only rigid conducting plates at the ends and an insulating curved
one correct answer among the four given options (a), (b), (c) and surface as shown in the figure. A number of spherical balls made
(d). of a light weight and soft material and coated with a conducting
PARAGRAPH 1 material are placed on the bottom plate. The balls have a radius r
A frame of reference that is accelerated with respect to an inertial <<h. Now a high voltage source (HV) is connected across the
frame of reference is called a non-inertial frame of reference. A conducting plates such that the bottom plate is at +V0 and the
coordinate system fixed on a circular disc rotating about a fixed top plate at V0 . Due to their conducting surface, the balls will
axis with a constant angular velocity w is an example of non- get charged, will become equipotential with the plate and are
inertial frame of reference. The relationship between the force repelled by it. The balls will eventually collide with the top plate,
r where the coefficient of restitution can be taken to be zero due to
Frot experienced by a particle of mass m moving on the rotating the soft nature of the material of the balls. The electric field in the
r chamber can be considered to be that of a parallel plate capacitor.
disc and the force Fin experienced by the particle in an inertial
Assume that there are no collisions between the balls and the
frame of reference is
r r r ur ur r ur interaction between them is negligible. (Ignore gravity)
( ) ( )
Frot = Fin + 2m v rot w + m w r w. A
r
where v rot is the velocity of the particle in the rotating frame of
r
reference and r is the position vector of the particle with respect HV
to the centre of the disc.
+
Now consider a smooth slot along a diameter of a disc of radius
R rotating counter-clockwise with a constant angular speed w
about its vertical axis through its center. We assign a coordinate 17. Which one of the following statements is correct?
system with the origin at the center of the disc, the x-axis along (a) The balls will stick to the top plate and remain there
the slot, the y-axis perpendicular to the slot and the z-axis along (b) The balls will bounce back to the bottom plate carrying
ur
the same charge they went up with
( )
the rotation axis w = wk . A small block of mass m is gently
(c) The balls will bounce back to the bottom plate carrying
r
placed in the slot at r (R / 2) i at t = 0 and is constrained to move the opposite charge they went up with
(d) The balls will execute simple harmonic motion between
only along the slot.
the two plates
18. The average current in the steady state registered by the 22. The geometries of the ammonia complexes of Ni2+ , Pt2+ and
ammeter in the circuit will be Zn2+ respectively, are
(a) zero (a) octahedral, square planar and tetrahedral
(b) proportional to the potential V0 (b) square planar, octahedral and tetrahedral
(c) tetrahedral, square planar and octahedral
(c) proportional to V01/2
(d) octahedral, tetrahedral and square planar
(d) proportional to V02 23. The correct order of acidity for the following compounds is
CO2H CO2H
CO2H CO2H
CHEMISTRY HO OH OH
SECTION - I
OH
This section contains 6 multiple choice questions. Each question OH
I II III IV
(a) I > II > III > IV (b) III> I > II > IV
option is correct.
(c) III > IV > II > I (d) I > III > IV > II
19. For the following electrochemical cell at 298 K, 24. The major product of the following reaction sequence is
Pt(s)|H2(g, 1 bar)| H+ (aq, 1 M) || M4+ (aq), M2+ (aq)|Pt(s) O
M 2+ aq (i) HCHO (excess)/NaOH, heat

( ) x +
Ecell = 0.092 V when 4+ = 10 . (ii) HCHO/H (catalytic amount)
M (aq)
O O O O OH
RT (a) (b)
Given : EM 4- /M 2+ = 0.151 V; 2.303 = 0.059V
F
The value of x is O OH
(a) 2 (b) 1 HO O O
(c) 1 (d) 2
20. The qualitative sketches I, II and III given below show the (c) (d)
variation of surface tension with molar concentration of
OH
three different aqueous solutions of KCl, CH3OH and
SECTION - II
CH3(CH2)11OSO3 Na+ at room temperature. The correct
assignment of the sketches is This section contains 8 multiple choice questions. Each question
I II III THAN ONE are correct.
Surface tension
Surface tension
Surface tension
25. According to Molecular Orbital Theory,

(a) C22 - is expected to be diamagnetic
(b) O22+ is expected to have a longer bond length than O2
Concentration Concentration Concentration
(c) N+2 and N -2 have the same bond order
(a) I : KCl II : CH3OH III : CH3(CH2)11OSO3 Na+
(b) I : CH3(CH2)11OSO3 Na+ II : CH3OH III : KCl (d) He+2 has the same energy as two isolated He atoms
+
(c) I : KCl II : CH3(CH2)11OSO3 Na III : CH3OH 26. Mixture(s) showing positive deviation from Raoults law at
35 C is (are)
(d) I : CH3OH II : KCl III : CH3(CH2)11OSO3 Na+ (a) carbon tetrachloride + methanol
21. In the following reaction sequence in aqueous solution, the (b) carbon disulphide + acetone
species X, Y and Z, respectively, are (c) benzene + toluene
(d) phenol + aniline
Ag+ Ag + 27. The CORRECT statement(s) for cubic close packed (ccp)
S2 O32 - X Y
clear white three dimensional structure is (are)
solution precipitate
(a) The number of the nearest neighbours of an atom
with time
Z present in the topmost layer is 12
black precipitate (b) The efficiency of atom packing is 74%
(a) [Ag(S2O3)2]3, Ag2S2O3, Ag2S (c) The number of octahedral and tetrahedral voids per
(b) [Ag(S2O3)3]5, Ag2SO3, Ag2S atom are 1 and 2, respectively
(c) [Ag(SO3)2]3, Ag2S2O3, Ag (d) The unit cell edge length is 2 2 times the radius of
(d) [Ag(SO3)3]3, Ag2SO4, Ag the atom
28. Extraction of copper from copper pyrite (CuFeS2) involves The standard reaction Gibbs energy, DrG, of this reaction is
(a) crushing followed by concentration of the ore by froth- positive. At the start of the reaction, there is one mole of X 2 and
flotation no X. As the reaction proceeds, the number of moles of X formed
(b) removal of iron as slag is given by b. Thus, bequilibrium is the number of moles of X formed
(c) self-reduction step to produce blister copper at equilibrium. The reaction is carried out at a constant total
following evolution of SO2 pressure of 2 bar. Consider the gases to behave ideally.
(d) refining of blister copper by carbon reduction (Given R = 0.083 L bar K1 mol1)
29. The nitrogen containing compound produced in the reaction 33. The equilibrium constant Kp for this reaction at 298 K, in
of HNO3 with P4O10 terms of bequilibrium, is
(a) can also be prepared by reaction of P4 and HNO3
(b) is diamagnetic 8b2
equilibrium 8b2
equilibrium
(c) contains one N-N bond (a)
2-bequilibrium
(b)
2

4 -bequilibrium
(d) reacts with Na metal producing a brown gas
30. For invert sugar, the correct statement(s) is(are) 4b2 4b2
equilibrium
equilibrium
(Given : specific rotations of (+) -sucrose, (+)-maltose, (c)
2 -bequilibrium
(d)
2
4 -bequilibrium
L-(-)-glucose and L-(+) fructose in aqueous solution are
+ 66, +140, 52 and +92, respectively) 34. The INCORRECT statement among the following, for this
(a) invert sugar is prepared by acid catalyzed hydrolysis reaction, is
of maltose (a) Decrease in the total pressure will result in formation
(b) invert sugar is an equimolar mixture of D-(+)-glucose of more moles of gaseous X
and D-(-)-fructose (b) At the start of the reaction, dissociation of gaseous
(c) specific rotation of invert sugar is 20 X2 takes place spontaneously
(d) on reaction with Br 2 water, invert sugar forms (c) bequilibrium = 0.7
saccharic acid as one of the products
(d) KC < 1
31. Reagent(s) which can be used to bring about the following
PARAGRAPH 2
transformation is (are)
Treatment of compound O with KMnO4/H+ gave P, which on
heating with ammonia gave Q. The compound Q on treatment
O O O with Br2/NaOH produced R. On strong heating, Q gave S, which
O O C
C on further treatment with ethyl 2-bromopropanoate in the
presence of KOH followed by acidification, gave a compound T.
H OH
O O
COOH COOH
(a) LiAlH4 in (C2H5)2O (b) BH3 in THF
(c) NaBH4 in C2H5OH (d) Raney Ni/H2 in THF
32. Among the following, reaction(s) which gives(give)
tert-butyl benzene as the major product is(are)
Br Cl
(O)
(a) (b)
NaOC2H5 AlCl3
35. The compound R is
OH O
(c) (d) NH2
H2SO4 BF3OEt2 Br
(a) (b) Br
NH2
SECTION - III O
This section contains 2 paragraphs, each describing theory,
experiments, data etc. four questions related to the two paragraphs O O
with two questions on each paragraph. Each question has one or NHBr
NBr
more than one correct answer(s) among the four given options (c) NHBr (d)
(a), (b), (c) and (d).
O O
PARAGRAPH 1 36. The compound T is
Thermal decomposition of gaseous X2 to gaseous X at 298 K (a) glycine (b) alanine
takes place according to the following equation:
(c) valine (d) serine
X 2 (g) 2X (g)
MATHEMATICS SECTION - II
SECTION - I
This section contains 6 multiple choice questions. Each question THAN ONE are correct.
option is correct. x
n
n n
1 0 0 n n ( x + n ) x + ... x +
2 n
43. Let f ( x ) = lim , for
37. Let P = 4 1 0 and I be the identity matrix of order 3. 2 2
( )
n
2 2 2 n 2 n
16 4 1 n! x + n x + 4 ... x + n 2

q 31 + q32 all x > 0. Then
If Q = [qij] is a matrix such that P50 Q =I, then
q 21
1 1 2
equals (a) f f (1) (b) f f
(a) 52 (b) 103 2 3 3
(c) 201 (d) 205
38. Let bi > 1 for i = 1, 2, ..., 101. Suppose loge b1, logeb2, ...., loge f ' ( 3) f '(2)
(c) f ' (2) < 0 (d)
b101 are in Arithmetic Progression (A.P.) with the common f ( 3) f ( 2)
difference loge 2. Suppose a1, a2, ...., a101 are in A.P. such that
a1= b1 and a51= b51. If t= b1+b2 + .... + b51 and s= a1+a2+ .... + 44. Let a, b and f : be defined by
a51, then f (x) = a cos (|x3 x|) + b |x| sin (|x3 +x|).
(a) s > t and a101> b101 (b) s > t and a101 < b101 Then f is.
(c) s < t and a101 > b101 (d) s < t and a101 < b101 (a) differentiable at x = 0 if a = 0 and b = 1
13
1 (b) differentiable at x = 1 if a = 1 and b = 0
39. The value of
k =1 p ( k - 1) p p kp
is equal (c) NOT differentiable at x = 0 if a = 1, b = 0
sin + sin + (d) NOT differentiable at x = 1 if a = 1 and b = 1
4 6 4 6 45. Let f : (0, ) and g : be twice differentiable
to functions such that f" and g" are continuous functions on
(a) 3- 3 ( )
(b) 2 3 - 3 . Suppose f '(2) = g(2) = 0, f"(2) 0 and g'(2) 0. If
f (x)g(x)
(c) 2 ( 3 -1 ) (d) 2 (2 - 3 ) lim
x 2 f '(x)g '(x)
= 1 , then.
p (a) f has a local minimum at x = 2

x 2 cos x
2
(b) f has a local maximum at x = 2
40. The value of dx is equal to
p 1+ e
x
(c) f "(2) > f (2)
-
2 (d) f (x) f "(x) = 0 for at least one x R
p2 p2 1 1
(a) -2 (b) +2 46. Let f : - , 2 and g : - , 2 be functions
4 4 2 2
p p
(c) (d) p2 + e 2 defined by f (x) = [x 3] and g(x) = |x| f (x) + |4x7 | f (x), where
2
p2 - e 2
[y] denotes the greatest integer less than or equal to y for
41. Area of the region {( x, y ) : y
2
}
x + 3 , 5y x + 9 15 y . Then
is equal to 1
(a) f is discontinuous exactly at three points in - , 2
1 4 2
(a) (b)
6 3
1
3 5 (b) f is discontinuous exactly at four points in - , 2
2
(c) (d)
2 3 (c) g is NOT differentiable exactly at four points in
42. Let P be the image of the point (3,1,7) with respect to the
plane xy+z = 3. Then the equation of the plane passing 1
- , 2
x y z 2
through P and containing the straight line = = is.
1 2 1 1
(a) x + y 3z = 0 (b) 3x + z = 0 (d) g is NOT differentiable exactly at five points in - , 2
2
(c) x 4y + 7z = 0 (d) 2x y = 0
47. Let a, b and a + b 0. 2 2

SECTION - III
1 This section contains 2 paragraphs, each describing theory,
Suppose S = Z C : Z = , + , t 0 , where experiments, data etc. four questions related to the two paragraphs
a + ibt
with two questions on each paragraph. Each question has only one
i= -1 . If z = x+ iy and z S, then (x, y) lies on correct answer among the four given options (a), (b), (c) and (d).
1 1 PARAGRAPH 1
(a) the circle with radius and centre , 0 for a > 0,
2a 2a Football teams T1 and T2 have to play two games against each
b 0 other. It is assumed that the outcomes of the two games are
independent. The probabilities of T1 winning, drawing and losing
1 1
(b) the circle with radius - and centre - , 0 for 1 1 1
2a 2a a game against T2 are , and respectively. Each team gets 3
2 6 3
a < 0, b 0
(c) the x-axis for a 0, b = 0 points for a win, 1 point for a draw and 0 point for a loss in a game.
(d) the y-axis for a = 0, b 0 Let X and Y denote the total points scored by teams T1 and T2
48. Let P be the point on the parabola y2 = 4x which is at the respectively after two games.
shortest distance from the center S of the circle x 2 + y2 4x 51. P (X > Y) is
16y + 64 = 0.
1 5
Let Q be the point on the circle dividing the line segment SP (a) (b)
internally. Then 4 12
(a) SP = 2 5 1 7
(c) (d)
(b) SQ : QP = ( )
5 +1 : 2 2
52. P (X = Y) is
12
(c) the x-intercept of the normal to the parabola at P is 6

11 1
1 (a) (b)
(d) the slope of the tangent to the circle at Q is 36 3
2
49. Let a, l, m, . Consider the system of linear equations 13 1
(c) (d)
ax + 2y = l 36 2
3x 2y = m
PARAGRAPH 2
Which of the following statement(s) is (are) correct?
(a) If a = 3, then the system has infinitely many solutions Let F1(x1, 0) and F2(x2, 0) for x1 < 0 and x2 > 0, be the foci of the
for all values of l and
x2 y 2
(b) If a 3, then the system has a unique solution for all ellipse + = 1 . Suppose a parabola having vertex at the
9 8
values of l and
(c) If l + = 0, then the system has infinitely many origin and focus at F2 intersects the ellipse at point M in the first
solutions for a = 3 quadrant and at point N in the fourth quadrant.
(d) If l + 0, then the system has no solution for
a = 3 53. The orthocentre of the triangle F1MN is

50. Let u = u1i + u 2 j + u 3 k be a unit vector in 3 and 9 2
(a) - ,0 (b) , 0
1 10 3
w= i + j + 2k . Given that there exists a vector v in

6 9 2
(c) ,0 (d) , 6

10 3
3 such that u v =1 and w . u v =1 . Which of the
54. If the tangents to the ellipse at M and N meet at R and the
following statement(s) is (are) correct? normal to the parabola at M meets the x-axis at Q, then the
ratio of area of the triangle MQR to area of the quadrilateral
(a) There is exactly one choice for such v MF1NF2 is
(a) 3 : 4 (b) 4 : 5
(b) There are infinitely many choices for such v
(c) 5 : 8 (d) 2 : 3

(c) If u lies in the xy-plane then |u1| = |u2|

(d) If u lies in the xz-plane then 2 |u1| = |u3|
SOLUTIONS
Paper - 1
PHYSICS h h
But cos 30 = \ x= (iii)
hc f hc f x cos 30
1. (b) - = V01 and - = V02
el1 e el 2 e
h 3l h 3 3
From (ii) and (iii) = \ =
hc 1 1 cos 30 8 l 16
\ e l - l = V01 - V02
1 2
mC DT V rC DT
3. (b) Pheater Pcooler = =
e(V01 - V02 )l1l 2 t t
\ h=
(l 2 l1 )c 0.12 1000 4.2 103 20
From the first two values given in data \ (3000 Pcooler) =
3 60 60
1.6 10-19 [2 - 1] 0.4 0.3 10 -6 \ Pcooler = 2067W
h=
0.1 3 108 4. (a) Applying Snell's law at A
h = 0.64 10 -33 = 6.4 10-34 J-s

1 sin 45 = 2 sin r1
Similarly if we calculate h for the last two values of \ r1 = 30 (i)
data h = 6.4 1034J-s
2. (d) Considering the normal reaction of the floor and wall
to be N and with reference to the figure.
q
Nsin 30 90 q
45 M
N 30 A r1 90
+q
Ncos 30 c B
30
n= 2
x
h
l/2 1.6g Applying Snell's law at B

N
2 sin C = 1 sin 90
A f B \ C = 45 (ii)
In D AMB, 90 + q + r1 + (90 C) = 180 (From fig.)
By vertical equilibrium. \ q = 15
3.2 g I dV / dR
N + N sin 30 = 1.6 g N = (i) 5. (c) J= = (i)
3 2pr l 2 pr l
By horizontal equilibrium
dr 1 dr
dR = r = (ii)
3 16 3 2pr l s 2 pr l
f = Ncos 30 = N= From (i)
2 3
dV
Taking torque about A we get Now E = -
dr
1.6g AB = N x
l 3.2 g 3l l
1.6 g cos 60 = x \ = x (ii) \ dV = Edr = dr (iii)
2 3 8 2p r
Relative change in the energy of two consecutive orbitals
En En -1 E n2 -2 n + 1 - 2
= 1 - n -1 = 1 - 2
=
En En (n - 1) (n - 1) 2 n
+
+ V
+ Ln - Ln -1 L (n - 1) 1
+ = 1 - n -1 = 1 - =
+ I Ln Ln n n
+ V + dV
l + 7. (a,b, c)
+
+
+ r P
+ vccos q q vc
+ dr
+ A
+ a Vx
+
+ 118Hz c
121Hz
+ 10 Q
+ M N
+
R
From (i), (ii), and (iii)
1 ldr s 2p r l ls v + v cos q
J= = (iv) n P = 121 - 118 =
2pr l 2l r dr 2p r v
dV -l s 2pr l -lsl nq = 121 - 118 = 3

Also I = = dr = (v)
dR 2 p r dr
v - vc cos q
Here negative sign signifies that the current is n R = (121 118)
decreasing v
d ( q ) d ( ll ) dl \ n P + n R = 2 n Q ( A ) is correct option
But I = = =l (vi)
dt dt dt In general when the car is passing through A
From (v) and (vi) v + vc cos a
n = 3 (i)
dl lsl d l -s v
l =- = dt
dt l l
dn v sin a dn
On integrating \ = -3 c is max when sin a = 1
da v da
l t
dl s i.e., a =90 (at Q)
l
= - dt
0 (b) is correct option.
l0
d n 3vc da
l st s
- t From (i) = ( sin a) (ii)
\ loge =- \ l = l0 e dt v dt
l0
Substituting this value in (iv) we get 10 2 da 10 dx
Also tan a = \ sec a =- 2
x dt x dt
s
sl0 - t
J= e da -10v
2p r \ = 2 (iii)
6. (a, b, d)
dt x sec 2 a
From (ii) & (iii)
2
n2 E = - 13.6 Z nh
We know that r = r0 , n , Ln = dn 3v -10v 30Vc sin a
z n 2 2p = - c sin a 2 =
dt v x sec 2 a x 2 sec 2 a
Relative change in the radii of two consecutive orbitals
rn rn -1 r (n - 1) 2 dn 30vc sin a
= 1 - n -1 = 1 - \ dt = 2 2
= 0.3vc sin 3 a . At a = 90
does not depend on Z (10 cot a ) sec a
rn rn n2
2n - 1 2 dn
= = max
(Q n > > 1) dt
n2 n
\ (c) is the correct option
8. (c, d) With the use of filament and the evaporation involved, A B
m0i
the filament will become thinner thereby decreasing f= = Mi
10p x
the area of cross-section and increasing the resistance.
Therefore the filament will consume less power m0 10 cm x x dx
towards the end of life. \M =
10p
As the evaporation is non-uniform, the area of cross- Induced emf in the wire
section will be different at different cross-section. dI
Therefore temperature distribution will be non- di m 0 m = 10 AS -1
=M = 10 = 0 dt
uniform. The filament will break at the point where the dt 10 p p
temperature is maximum. As the current in the triangular wire is decreasing the
1 induced current in AB is in the same direction as the
When the filament temperature is higher l n , current in the hypotenuse of the triangular wire.
T
Therefore force will be repulsive.
it emits light of lower wavelength or higher band of
r
frequencies. 12. (a, b) r = at 3i + bt 2 j
9. (a, d) For lens
r 10
1 1 1 1 1 1 r = t 3i + 5t 2 jm
- = - = 3
v u f v -30 f r
r dr
v= = 10t 2i + 10tj ms 1
v v dt
Also, m = -2 =
u u r
r dv
On solving we get f = + 20 cm a= = 20ti + 10 jms -2
dt
and v = 60 cm.
For reflection At t = 1s
n r 10
1 1 1 2
+ = =
1
+
1
=
2 rt =1 = i + 5 jm ;
v u f R 10 -30 R 3
r
R = 30 cm vt =1 = 10i + 10 j ms 1
The image formed by convex side is faint erect and r
pt =1 = i + j kgms 1
virtual.
By lens maker formula r
at =1 = 20i + 10 j ms -2
1 nl 1 1
= - 1 - i j k
f ns R1 R2 r r r
L = r p = 10 5 0 = k 10 - 5 = - 5 k kgms -1
3 3 3
1 nl 1
\ = - 1 \ n = 2.5 1 1 0
20 1 30 l
r r
q2 F = ma = (2i + j ) N
10. (b, d) We know that, dimensionally = ,
l2 F
RT i j k
k BT = = PV = F l
NA r r r 10 10 -20
t = r F = 5 0 = k - 10 = k Nm
3 3 3
1/2
ek BT q2 F l 2 1 0
Now = 2 3 2 =l
nq 2 l F l q 13. (a, c, d)
1/2 n1 sin qi = n2 sin q f [Q 1 and 2 interfaces are parallel]
q2 l2 F q2
Also = =l l depends on the refractive index of transparent slab
n1/3 k BT q 2 l -1 F l but not on n 2 . In fact qf depends on n2.
11. (a, d) The flux passing through the triangular wire if i current 14. (9) Here P T 4 or P = P0T 4
flows through the inifinitely long conducting wire
0.1 P
m0 i \ log 2 P = log 2 P0 + log 2 T 4 \ log 2 = 4log 2 T
= 2px
2pdx P0
0
P CHEMISTRY
At T = 487C = 760 K, log 2 = 4 log 2 760 = 1 (1)
P0 19. (d) Radial probability function curve for 1s is (D).
Here P is 4pr 2R2.
At T = 2767C = 3040K,
r
loge = 4log 2 3040 = 4 log 2 (760 4)
r0
P
= 4 log 2 760 + log 2 22
= 4log 2 760 + 8 = 1 + 8 = 9
20. (c) From 1st law of thermodynamics
15. (9) Maximum kinetic energy of b-particle qsys = DU w = 0 [Pext.DV]
= [mass of 12 12 = 3.0 atm (2.0 L 1.0 L) = 3.0 L-atm
5 B mass of 6 C ] 931.5 4.041
= [12.014 12] 931.5 4.041] = 9MeV (q rev )surr qsys
\ DSsurr = =-
hc 1.237 10-6 T T
16. (6) E= = eV = 12.75eV
l 970 10 -10 3.0 101.3J
=- = 1.013 J/K
\ The energy of electron after absorbing this photon 300 K
= 13.6 + 12.75 = 0.85eV 21. (b) Atomic radii increases on moving down a group.
This corresponds to n = 4 However due to poor shielding effect of d orbit, atomic
radius of Ga is smaller than Al (anomaly). Thus the
n(n - 1) 4(4 - 1) correct order is Ga < Al < In < Tl
Number of spectral line = = =6
2 2 22. (b) Compound/Ion Magnetic nature of compound
1. [Ni(CO)4] Diamagnetic
2r12 (s - r1 ) g 2. [NiCl4]2 Paramagnetic
VP 9h1 r 2 (s - r1 ) h2 3. [Co(NH3)4Cl2]Cl Diamagnetic
17. (3) = 2 = 12 4. Na3[CoF6] Paramagnetic
VQ 2 r2 (s - r 2 ) g r2 (s - r 2 ) h1
5. Na2O2 Diamagnetic
9h2 6. CsO2 Paramagnetic
So total number of paramagnetic compounds is 3.
12 [8 - 0.8] 2 23. (a)
= =3
(0.5) [8 - 1.6] 3
2
CH3 CH3
| |
Polymerisation
CH 2 = C - CH = CH 2 -( CH 2 - C = CH - CH 2 -)
1mH 3W Isoprene Natural rubber
H2(excess)
2mH 4W catalyst
18. (8) CH3 CH3

12W |
Copolymerisation
|
CH 2 = CH 2 + CH 2 = CH
-( CH 2 - CH - CH2- CH 2-)
Ethylene Propylene Completely hydrogenated
Naturalrubber
24. (b, c, d)
5V (A) High activation energy usually implies a slow reaction.
(B) Rate constant of a reaction increases with increase in
temperature due to increase in number of collisions
5
At t = 0 Imin = whose energy exceeds the activation energy.
12
(C) k < P Z e, Ea RT
5 5 10 (D) So, pre-exponential factor (A) = P Z and it is
At t = a Imax = R = 3 / 2 = 3 independent of activation energy or energy of
eq
molecules.
1 1 1 1 8 25. (b, d) When N/P ratio is less than one, then proton changes
R = 3 + 4 + 12 = 12 into neutron.
eq
Position emission : 11 H 01 n + +01b
I max 10 12
\ I = =8 k-electron capture : 11 H + 0
01 n + X-rays
-1 e
min 3 5
26. (a, c, d) 30. (b)
Structure of borax
O O
HO O
NH2 NH C CH3 NH C CH3
sp 3 B
OH Ac2O KBrO 3/HBr
O O
B Pyridine
B O B O sp 2
Acetanilide
HO HO Br
sp 2 3 sp (Major)
+
Correct formula of borax is Na2[B4O5(OH)4].8H2O NH2 N NCl Br
(A) Borax has tetranuclear. [B4O5(OH)4]2 unit H 3O+ NaNO2/HCl Cu
(B) Only two 'B' atom lie in same plane 273 278 K HBr
(diazotisation)
(C) two Boron are sp2 and two are sp3 hybridised.
(D) one terminal hydroxide per boran atom. Br Br Br
27. (b, c) Compound Number of lone pairs
on central atom 31. (b, c)
BrF5 1
OH OH OH
ClF3 2 CHO
(i) O2 CHCl3/NaOH
XeF4 2 +
(ii) H 3O+
SF4 1
P Q
28. (a or a, c) (Major) CHO
R (Minor)
OH O CH2Ph
S2- SO 42- CHO CHO
NaOH
Cu 2+ CuS(ppt) CuSO4 (Soluble) PhCH 2Br
Ba 2+ BaS(Soluble) BaSO 4 (ppt) S
Pb(OAc) 2 PbS(ppt) PbSO 4 (ppt) Q is steam volatile not R.

Na 2 [Fe(CN)5 NO] Na 4 [Fe(CN)5(NOS)] ____ Q and R show positive test with 1% aqueous FeCl3
Colour (not a ppt) solution.
Q, R, S give yellow precipitate with 2, 4-dinitrophenyl
29. (a, b, c) hydrazine.
Aldehydes and a-Hydroxyketones show positive 32. (9) 1 mole solution has 0.1 mole solute and 0.9 mole solvent.
Tollen's test. Let M1 = Molar mass solute
M2 = Molar mass solvent
H O
Tollen's 0.1
H Silver mirror Molality, m = 1000 ....... (1)
H
Reagent 0.9M 2
H 0.1
Molarity, M = 0.1M + 0.9M 2 1000 ....... (2)
CHO 1 2
Tollen's
Silver mirror Q m= M
Reagent
0.1 1000 200
=
OH 0.9M 2 0.1M1 + 0.9M 2
Ph Tollen's
Ph Silver mirror M1
Reagent
=9
O M2
O 33. (4) Diffusion coefficient l
Ph
+ Ph T
Since l and m T
O P
Diketone
MATHEMATICS
T T
\ Diffusion coefficient 37. (c) x2 2x sec q + 1 = 0 x = sec q tan q
P
and x2 + 2x tan q 1 = 0 x = tan q sec q
T T p p
Di 1 1 Q - <q< -
Thus = P = = 6 12
Df 4T 4T (4 2) 2 4
p p
2P sec > sec q > sec
6 12
Df 4
or = p tan p
Di 1 and - tan < tan q < -
6 12
34. (6) 8MnO -4 + 3S2O 32 - + H 2 O
p p
also tan < - tan q < tan
12 6
8MnO 2 + 6SO24 - + 2OH -
a1,b1 are roots of x2 2x secq + 1 = 0
\ 8 moles of MnO4 form 6 moles of SO42 and a1> b1
35. (5) [CoL2Cl2] (L = H2NCH2CH2O) \ a1 = secq tanq and b1 = secq + tanq
L is unsymmetrical didentate ligand. a2, b2 are roots of x2 + 2x tan q 1 = 0 and a2 > b2
So the complete is equivalent to [M(AB)2a2] Possible \ a2 = -tanq + secq, b2 = tanq secq
G..I. are \ a1 + b2 = secq tanq tanq secq = 2tanq
a a 38. (a) Either one boy will be selected or no boy will be
A B A A selected. Also out of four members one captain is to
M M be selected.
B A B B \ Required number of ways = (4C1 6C3+ 6C4) 4C1
a a = (80 + 15) 4 = 380
39. (c) 3 sec x + cosec x + 2 (tan x cot x) = 0
a a B
A a B a A a 3 1
sin x + cos x = cos2x sin2 x
M M M 2 2
B A A B B a
p
B A A cos x - = cos 2x
3
3 4 5
CH2CH2CH3 CH2CH2CH3 p
x- = 2np 2x
Br2(1.0 mole)
3
2
36. (5) H Br H Br
300C 2np p p
1 x= + or x = -2np -
CH
3 CH2 Br 3 9 3
1
(1.0 mole) (Chiral) p p
(enantiomerically pure) For x S, n = 0 x = ,-
9 3
CH2CH2CH3 CH2CH3 CH2CH3 7p
3 3 n=1x=
2 H Br Br H 9
+ Br Br + +
H Br H Br -5p
n = 1 x =
CH3 CH3 CH3 9
(Achiral) (Chiral) (Chiral)
p p 7 p 5p
\ Sum of all values of x = - + - =0
5
9 3 9 9
CH3 CH3 CH2 Br
4 4 20 80 7
H Br Br H H H 40. (c) P(T1) = , P(T2) = , P(D) =
100 100 100
+ H H + H H + H H
H Br H Br H Br D D
CH3 CH3 CH3 Let P = x, then P = 10x
T2 T1
(Achiral) (Chiral) (Chiral)
length of perpendicular from P (3, 0, 0) to plane x y = 0
D D
Also P(D) = P(T1) P + P(T2 ) P 3-0 3
T1 T2 is = =
2 2
7 20 80
= 10x + x x y -3 z x y-3 z
100 100 100 Eqn of RS : = = or = = =l
3 -3 3 1 -1 2
7 1 2 2
= x or x =
280 40 If ON is perpendicular to RS, then N (l, -l + 3, 2l)
D D Q ON ^ RS 1 l - 1(-l + 3) + 2 2l = 0
P = 10 and P = 1
T1 40 T2 40 1 1 5
l = N , ,1
D 39 2 2 2
D 30
P = and P T = 40
T1 40 2 1 25 15
\ ON = + +1 =
4 4 2
D
P P(T2 )
T T2 f (x)
P 2 = 43. (a) f (x) = 2 -
D D D x
P P ( T1 ) + P P(T2 )
T1 T2 1
f (x) + f (x) = 2
x
80 39 If = elog x = x

100 40 156 26
= = = \ f(x).x = 2x dx = x2 + C
20 30 80 39 186 31
+
100 40 100 40
C
or f(x) = x + , C 0 as f(x) 1
78 26 x
Also =
93 31
1
1 (a) lim f = lim (1 - Cx 2 ) = 1
2 x 0 + x x 0+
41. (c) Let f(x) = 4ax +
x
For x > 0, fmin = 1 1 1 2
(b) lim xf = lim+ x + Cx lim+ 1 + Cx = 1
x0 + x x 0 x x 0
f (x) = 8ax 1 = 0 x = 1
x2 2a1/3 (c) lim x 2 f x
x 0+
2
1
fmin = 1 4a + 2a1/3 = 1
1/3 C 2
2a = lim x 2 1 - 2 = lim+ x - C = - C
x 0 + x x 0
1
1 (d) for C 0, f(x) is unbounded as 0 < x < 2
3a 3 = 1 or a =
27 C C C C
42. (b, c, d) < < <x+ <
The coordinates of vertices of pyramid OPQRS will be 2 x 2 x
3 3 P.Q Q
O(0, 0, 0), P (3, 0, 0), Q (3, 3, 0), R (0, 3, 0), S , , 3 44. (b,c) PQ = kI = I P -1 =
2 2 k k
dr's of OQ = 1, 1, 0 Also |P| = 12a + 20
dr's of OS = 1, 1, 2 Comparing the third elements of 2nd low on both sides,
\ acute angle between OQ and OS we get
-1 2 1 p 3a + 4 1 - k
= cos = cos -1 - =
2 6 3 3 12a + 20 k 8
24a + 32 = 12a + 20 a = 1
x y z \ |P| = 8
Eqn of plane OQS =
1 1 0
=0 Also PQ = kI |P| |Q| = k3
1 1 2
k2 k2
8 = k3 k = 4 |Q| = =8
2x 2y = 0 or x y = 0 2 2
(b) 4a k + 8 = 4 (1) 4 + 8 = 0 1
(c) Now det (P adj Q) = |P| adj Q| \ Solution is : u y = y y2 dy = log y + C
= |P| |Q|2 = 8 82 = 29
(d) |Q adj P| = |Q| |P|2 = 29 -y
= log y + C
s-x s- y s -z s-x +s- y+s-z s x+2
45. (a, c, d) = = = =
4 3 2 4+3+ 2 9 As it passes through (1, 3) C = 1 log 3
5s 6s 7s -y
\x= ,y= ,z= \ = log y 1 log 3
9 9 9 x+2
y y
D2 8p log = 1- ...(1)
Area of incircle = pr2 = p 2
= 3 x+2
s 3
Intersection of (1) and y = x + 2
s(s - x)(s - y)(s - z) 8 y
2
= log = 0 y= 3 x = 1
s 3 3
\ (1, 3) is the only intersection point.
4 3 2s3 8 Intersection of (1) and y = (x + 2)2
= or s = 9
9 9 9s 3
(x + 2)2 (x + 2)2
\ x = 5, y = 6, z = 7 log = 1 (x + 2) or log + (x + 2) = 1
3 3
(a) Area of Dxyz = s(s - x)(s - y)(s - z)
(x + 2)2 4
9 4 3 2 = 6 6 Q > > 1, "x > 0
3 3
xyz \ LHS > 2, " x > 0 no solution.
(b) Radius of circumcircle, R =
4D 47. (b, c) f(x) = x3 + 3x + 2 f (x) = 3x2 + 3
Also f(0) = 2, f (1) = 6, f(2) = 16, f(3) = 38, f(6) = 236
5 6 7 35 6 4 And g(f(x)) = x g(2) = 0, g(6) = 1, g(16) = 2, g (38) = 2,
= = =
4 6 6 24 35 g (236) = 6
(a) g (f(x)) = x g (f(x)). f (x) = 1
x y z x y z r For g(2), f(x) = 2 x = 0
(c) r = 4 R sin sin sin sin sin sin =
2 2 2 2 2 2 4R \ Putting x = 0, we get g(f (0)) f(0) = 1
2 2 24 1
= g(2) =
3 4 35 6 3
(b) h (g(g(x))) = x h(g(g(x))). g(g(x)). g(x) = 1
x+y
2 z For h(1), we need g (g(x)) = 1
(d) sin = cos2
2 2 g (x) = 6 x = 236
\ Putting x = 236, we get
s(s - z) 9 2 3
= = = 1
xy 5 6 5 h [g(g(236))] =
g (g(236)).g (236)
dy
46. (a, d) [(x + 2)2 + y (x + 2)] = y2 1
dx h (g(6)) = g(6) g(236)
2 dx
y - (x + 2)y = (x + 2) 2 1
dy
h (1) = = f (1) f (6)
g(f (1)) g(f (6))
1 dx 1 1
- = = 6 111 = 666
(x + 2) 2
dy (x + 2)y y2 (c) h [g(g(x))] = x
For h (0), g (g(x)) 0 g(x) = 2 x = 16
-1 1 dx du \ Putting x = 16, we get
Let =u =
x+2 2
(x + 2) dy dy h(g(g(16))) = 16
\ Eqn becomes h(0) = 16
(d) h[g(g(x))] = x
du 1 1 For h(g(3)), we need g(x) = 3 x = 38
+ u=
dy y y2 \ Putting x = 38, we get
If = elog = y = y h [g(g(38))] = 38 h (g(3)) = 38
48. (a, b, c) \ Intersection point E of normal and y = tanq
C1 : x2 + y2 = 3 ..(i)
parabola : x2 = 2y ...(ii) tan q 1 - tan 2 q / 2
= x tan q x =
Intersection point of (i) and (ii) in first quadrant 2 2
y2 + 2y 3 = 0 y = 1 (Q y -3) 1 - y2
\ Locus of E : x = or y2 = 1 2x
\x= 2 2
P( 2,1) 1 1 1 -1
It is satisfied by the points 3 , and 3 ,
3 3
Equation of tangent to circle C1 at P is 2x + y - 3 = 0
Let centre of circle C2 be (0, k); r = 2 3 x x2 1 + x3
k -3 50. (2) 2x 4x 2 1 + 8x3 = 10
\ = 2 3 K = 9 or 3
3 3x 9x 2 1 + 27x 3
\ Q2 (0, 9), Q3 (0, 3)
(a) Q2 Q3 = 12
1 1 1 1 1 1
(b) R2R3 = length of transverse common tangent 3 6
x 2 4 1 + x 2 4 8 = 10
= (Q2 Q3 ) 2 - (r1 + r2 ) 2 = (12)2 - (4 3)2 = 4 6 3 9 1 3 9 27
1 Operating C2 C1, C3 C1 for both the determinants,
(c) Area (DOR2R3) = R2R3 length of ^ from origin we get
2
to tangent 1 0 0 1 0 0
1 3
x 2 2 -1 + x 2 2 6 = 10 6
= 4 6 3 = 6 2
2 3 6 -2 3 6 24
1 x3 (4 + 6) + x6 (48 36) = 10
(d) Area (DPQ2Q3) = Q2Q3 ^ distance of P from
2 2x3 + 12x6 = 10
1 6x6 + x3 5 = 0
yaxis = 12 2 = 6 2
2 1
49. (a, c) Circle : x2 + y2 = 1 5 3
(6x3 5) (x3 + 1) = 0 x = , 1
Equation of tangent at P(cos q, sin q) 6
x cos q + y sin q = 1 ...(1) 51. (5) (1 + x)2 + (1 + x)3 + .... + (1 + x)49 + (1 + mx)50
Equation of normal at P
y = x tan q ...(2) (1 + x)48 - 1
Equation of tangent at S is x = 1 = (1 + x)2 (1 + x) - 1 + (1 + mx)50

1 - cos q tan q
\ Q 1, = Q 1, 2 1
sin q = (1 + x)50 - (1 + x)2 + (1 + mx)50
x
2
Coeff. of x in the above expansion
Y
= Coeff. of x3 in (1 + x)50 + Coeff. of x2 in (1 + mx)50
(cos q, sin q) 50C3 + 50C2 m2
P
\ (3n + 1) 51C3 = 50C3 + 50C2 m2
Q (1, tan q/2)
50 50
E C3 C2
(3n + 1) = + m2
51 51
X C3 C3
R O S (1, 0)
16 1 2 m2 - 1
3n + 1 = + m n=
17 17 51
Least positive integer m for which n is an integer is
m = 16 and then n = 5
x t2
\ Equation of line through Q and parallel to RS is 52. (1) Let f(x) = 0 dt - 2x + 1
1+ t4
tan q
y= x2
2 f (x) = - 2 < 0 " x [0,1]
1+ x4
\ f is decreasing on [0, 1] For above to be possible, we should have

Also f(0) = 1 1
2
a 1 = 0 and b =
1 t 3!
and f(1) = 0 dt - 1
1 + t4 1
a = 1 and b =
6
t2 1
For 0 t 1 0 4
< 1
1+ t 2 \ 6 (a + b) = 6 1 + = 7
6
1 t2 1
\ 0 4
dt < -1 + i 3
1+ t 2 54. (1) z= z3 = 1 and 1 + z + z2 = 0
2
f(1) < 0
\ f(x) crosses x-axis exactly once in [0, 1] (- z) r z 2s ( - z)r z 2s
\ f(x) = 0 has exactly one root in [0, 1] P2 =
z 2s z r z 2s z r
x 2 sin bx
( )
53. (7) lim =1
x 0 ax - sin x z 2r + z 4s z 2s (- z)5 + z r

=
lim
x 3b
=1
2s
(
r
z (-z) + z
r
) 4s
z +z 2r

x 0 ax - sin x
For P2 = I we should have
x 3b z2r + z4s = 1 and z2s ((z)r + zr) = 0
lim =1 z2r + zs + 1 = 0
x 0 x 3 x5 x 7
ax - x - + - + .... r is odd and s = r but not a multiple of 3.
3! 5! 7! Which is possible when s = r = 1
\ only one pair is there.
x 3b
lim =1
x 0 x 3 x5
(a - 1)x + - + ....
3! 5!
Paper - 2
PHYSICS A 1
1. (c) Binding energy of nitrogen atom 2. (c) =
A 0 2n
= [8 1.008665 + 7 1.007825 15.000109 931]
n A 0 64
Binding energy of oxygen atom \2 = = = 26 n = 6
= [7 1.008665 + 8 1.007825 15.003065] 931 A 1
\ Difference = 0.0037960 931 MeV ...(I) \ time = 6 t 1 = 6 18 = 108
2
3 8 7 e2 3 56
E
Also O = = 1.44MeV 5
2 R 4p0 5 R 3. (c) P3V5 = constant PV5/3 = constant g =
3
monoatomic gas
3 76 e2 3 42 For adiabatic process
EN = = 1.44MeV
5 R 4p0 5 R
P PiVi 1
3 14
\ E O - E N = 1.44MeV ...(II)
5 R
2
From (i) & (ii) adiabatic
3 14
1.44 = 0.0037960 931 PfVf
5 R
\ R = 3.42 fm
V
Therefore object distance for mirror is 25 cm and object
1
105 8 10-3 - 105 10-3 is virtual
Pf Vf - Pi Vi 32
W= = 1 1 1 1 1 1
1- g 5 + = \ + =
1- For minor \ v = 50 cm
3 v u f v 25 50
The image I would have formed as shown had the mirror
25 - 100 75 3 have been straight. But here the mirror is tilted by 30.
\ W = ( 3 - 5 ) / 3 = 2 = 112.5J Therefore the image will be tilted by 60 and will be
From first law of thermodynamics q = Du + w formed at A.
\ Du = w Here MA = 50 cos 60 = 25 cm
\ Du = 112.5 J and IA = 50 sin 60 = 25 3 cm
Now applying first law of thermodynamics for process 6. (b) For C1
1 & 2 and adding q1 + q2 = DU + Pi(Vf Vi) L.C. = 1MSD 1VSD
= 112.5 + 105 (8 1) 10 3 = 587.55 = 1mm 0.9 mm = 0.1 mm = 0.01 cm [10 VS D = 9 mm]
4. (a) The heat flow rate is same Reading = MSR + L.C Verni scale division coinciding
T Main scale division = 2.8 + (0.01) 7 = 2.87 cm
M 2K
P Q K For C2
10C 400C L.C = 1 mm 1.1 mm [10 VSD = 11 mm]
R H S L.C = 0.1 mm = 0.01 cm
x H
dx Reading = 2.8 + (10 7) 0.01 = 2.83 cm
KA ( 400 - T ) 2KA ( T - 10 ) 7. (a, c) In DOAM, OM = l2 + a 2 = 2ha 2 + a 2 = 5a

\ = The circumference of a circle of radius OM will be 2p(5a)
l l
\ T = 140C = 10pa.
The temperature gradient access Pd is z
Sm Vc r^
dT 140 - 10
= \ dt = 130 dx w
dx 1
Therefore change temperature at a cross-section M A l
q c
distant x from P is l a
DT = 130 x q
Extension in a small elemental length dx is O M
dl = dx DT = dx (130x ) For completing this circle once, the smaller disc will
1 10pa
have to take = 5 rounds.
2pa
\ dl = 130 xdx
0 Therefore the C.M. of the assembly rotates about z-
axis with an angular speed of w/5.
1 The angular momentum about the C.M. of the system
\ Dl = 130 1.2 105 = 78 10 5 m
2
1 2
1 1 1 Lc = Icw = ma w
5. (c) For lens - = 2
v u f
1 2 17ma 2w
1
-
1
=
1 + 4m ( 2a ) w =
2 2
v -50 30
\ v = 75 cm m wa + 4m 2wa 9wa
Now vc = =
5m 5
Principal axis of mirror
I ml + 4m 2l 9l
and r1 = =
5m 5
50 cm 5m 9wa 9l 24
30 L of C.M = = 81mwa 2
5 5 5
30
I A M 81mwa 2 24
LZ = cos q - Icwsin q
Principal 5
axis of
lens 24 24 17ma 2 w 1134
MIRROR = 81mwa
2
- = mwa 2
5 5 10 50
8. (c) The wavelength of emitted photoelectron as per de 11. (a, b, c, d)

Broglie is At t=0, Capacitors act as short circuit and voltmeter
display 5v
h h
le = = At t = a , Capacitor acts as open circuit and no current
p 2m ( K.E ) flows through voltmeter (Q very high resistance of
When f increases, K.E. decreases and therefore le voltmeter)
increases so it display +5v. (A) is the correct option
( ) , i = VR e
t
When lph increases, N ph decreases , K.E decreases and -t -
q1 = 2Cv 1 - e 2CR
1
2CR
therefore le increases.
),
le is independent of the distance d.
(
t
-t V - t 2CR
q2 = Cv 1 - e 2CR
i2 = e
hc h2 h 2R
Also l + eV - f = l =
2 e
ph 2mle 2 mk. E
2C R
hc f h2 i1
\ +V- = ...(1)
el ph e 2mele2
V
i2 2R
f
For V >> , f << eV C
e
hc
Also << V . Then from eq (1).
el Ph 5V
1 21 -t
2CR
le \ D V = i2 2R + 2 = V 1 - 2e =0
V C
Therefore if V is made from times, le is approximately (b) is the correct option
half.
io Q i = io e - t t
9. (a, b, d) At t = 1sec, i =
e
1 \ (c) is the correct option
% error in measurement of r = 100 = 10%
10 After a long time no current flows since both capcitor
0.52 + 0.56 + 0.57 + 0.54 + 0.59 and voltmeter does not allow current to flow.
Tmean = = 0.556 0.56 S 12. (a, b, d)
6
Case (i) : Applying conservation of linear momentum.
0.04 + 0 + 0.01 + 0.02 + 0.03
DT = = 0.016 0.02S
6 MV1 = (M + m) V2 (1) \ V2 = M V1
\ % error in the measurement of T M+m
0.02
= 100 = 3.57% v1 v2
0.56
% error in the value of g
From (1)
DT DR + Dr M (A1 w1) = (M+m) (A2w2)
=2 100 + 100
T R -r K K
\ MA1 = (M+m) A2
M M+m
= 2 ( 3.57 ) + 1 + 1 100 11%
60 - 10 M
10. (a, c) The range of voltmeter V is given by the expression \ A2 = = A1
M+m
V = Ig [Rc + (Rc + R + R)]
V is max in this case as RHS is maximum. Thus (A) is 1
correct. Also E1 = MV12
2
The range of ammeter I is given by the expression
1 1
Ig R c and E2= (M+m)V22 = (M+m)
Ig 1 1 1 1 2 2
I= Where <
R eq R eq R c R R
M 2 V12 2
1 M 2
Here Req is minimum and therefore I is maximum. Thus
(M + m) 2
= V1
2M+m
(c) is the correct option.
Clearly E2 < E1
dv
15. (a) Force on the block along flot = m rw2 = m v
m+M dr
The new time Period T2 = 2
K
v r
R 2 dr
vdv = w2 rdr v = w r - =
2
m+M \
Case (ii) : The new time Period T2 = 2 o R 4 dt
K 2
Also A2 = A1 r t
dr
Here E2 = E1 \ R2
= w dt
The instantaneous value of speed at X o of the R
4 r2 -
o
combined masses decreases in both the cases. 4

13. (b, d) Path difference at O = d = 0.6003mm
On solving we get
l 600 10 -6
Now, = mm = 300106 mm
2 2 R2 R wt
r + r2 - = e
4 2
l 0.6003
For n = d we get n= =2001
2 300 10 -6 R 2 R 2 2wt 2 R wt
or r2 = e + r - 2r e
As n is a whole number, the condition for minima is 4 4 I
satisfied.
Therefore O will be dark. R wt
Also, as the screen is perpendicular to the plane
\ r=
4
( e + e-wt )
containing the slits, therefore fringes obtained will be
semi-circular (Top half of the screen is available)

16. (b) Frot = Fin + 2m Vrot i w k + m w k r i w k
BLV
14. (a, b) i = ...(i)
R

\ m rw2 i = Fin + 2m Vrot w - j + mw2 r i
[Counter clockwise direction while entering, Zero when

completely inside and clockwise while exiting]
B 2 L2 V

F = iLB = ....(ii) Fin = mrV ...(i)
R rot w j
[Toward left while entering and exiting and R wt
zero when completely inside] But r = e + e - wt
4
dv B 2 L2 V
\ - mV = dr R
dx R \ dt = Vr = we - we
wt - wt
...(ii)
4
v 2 2 x
BL
\ dV = - mR dx
v0 0
From (i) and (ii)
Rw wt - wt
2 2
Fin = 2m
4
(e - e ) w j
BL
V V0 = x
mR

mRw2 wt
BLx2 2 \ Fin =
2
( e - e - wt ) j
\ V= V0 ...(iii)
mR
mR w2 wt
[V decreases from x=0 to x=L, remains constant \ Freaction =
2
( e - e - wt ) j+ mg K
for x = L to x= 3L again decreases from x=3L to x=4L]
From (i) and (iii) 17. (c) After colliding the top plate, the ball will gain negative
charge and get repelled by the top plate and bounce
BL B2 L2 x
i = R V0 - mR back to the bottom plate.

Q
[i decreases from x=0 to x=Li becomes zero from x = L to x = 3L 18. (d) Iav a ...(i)
i changes direction and decreases from x = 3L to x = 4L] t
These characteristics are shown in graph (a) and (b) Here Q V0 ...(ii)
only.
1 2 So, X, Y and Z are [Ag (S2O3)2]3, Ag2S2O3 and Ag2S

Also S = ut + at respectively.
2
22. (a) Ni2+ with NH3 shows CN = 6 forming [Ni(NH3)6]2+
1 QE 2 1 Q 2V0 2 (Octahedral)
h= t = t
2 m 2 mh Pt2+ with NH3 shows CN = 4 forming [Pt(NH3)4]2+
(5d series CMA, square planner)
1
\ ta (iii) [Q Q a V0] Zn2+ with NH3 shows CN = 4 forming [Zn(NH3)4]2+
V0 (3d10 configuration, tetrahedral)
From (i), (ii) and (iii) 23. (a)
V0
O O
Iav 1 = Iav V02 H H
V0 COOH C
HO OH O O
CHEMISTRY
2H+ (aq) + 2e
19. (d) At anode : H2(g)
(I) (stabilizes by more H-bonding)
M2+ (aq)
At cathode : M4+ (aq) + 2e

O O
COOH H
2H+ (aq) +
Net cell reaction : H2(g) + M4+ (aq)
OH O
M2+ (aq)
Now, Ecell = E (

M
4+
/M 2 +
- E +
H /H 2 ) (II) (stabilizes by H-bonding)
2
H + M 2+
0.059 log COOH COO
. 4+
n
PH2 . M

2+
0.059 12 M OH OH
. log (III) (stabilizes by I effect)
or, 0.092 = (0.151 0)
2 1 M 4+

COOH COO
M 2+

\ +
= 102 x = 2
M 4

20. (d)
A solution of CH3OH and water shows positive OH OH
(IV) (destabilizes by +M effect)
deviation from Raoult's law, it means by adding CH3OH
intermolecular force of attraction decreases and hence
surface tension decreases. \ acidity order is I > II > III > IV
By adding KCl in water, intermolecular force of 24. (a)
attraction bit increases, so surface tension increases OH
by small value. O O
O CH2
By adding surfactant like CH3(CH2)11OSO3 Na +,
surface tension decreases rapidly and after forming HCH / NaOH
H
micelle it slightly increases. [Cross aldol reaction]
+ 3- Ag +
S2 O32 - Ag (S2 O3 )2
Ag
21. (a)
OH
OH
(X)
clear solution O CH2
HCH / NaOH
+ HCOO
on standing [Cross cannizaro
Ag 2S2 O3 Ag 2S reaction]
(Y) (Z)
white precipitate black precipitate
OH 4
OH O O 4 pr 3
CH2 O
3 = (0.74)
3
HCH / H
+ (B) Packing fraction = 4r

Acetal formation 2
(C) Each FCC unit has effective no of atoms = 4
25. (a, c) Octahedral void = 4
(A) The molecular orbital energy configuration of C2
2 is Tetrahedral void = 8
2 *2 2
s1s , s1s , s 2s , s*2 2 2 2
2s , p2p = p2p , s2p (D) 4r = a 2
x y z
In the MO of C2 28. (a, b, c)
2 there is no unpaired electron hence it
is diamagnetic Copper pyrite [CuFeS2]
(B) Bond order of O2+2 is 3 and O2 is 2 therefore bond length Crushing into fine powder
of O2 is greater than O2+2
(C) The molecular orbital energy configuration of N+2 is
Concentrated by froth floatation process
2 *2 2
s1s , s1s , s2s , s*2 2
2s , p2p x = p22p , s12p
y z
1
Bond order of N+2 = (9 - 4) = 2.5 Roasting take place in reverberatory furnace
2
The molecular orbital energy configuration of N2 is 2CuFeS2 + O2 D
Cu 2 S + 2FeS + SO 2
2 *2 2 (air)
s1s , s1s , s2s , s*2 2 2 2 *1 *
2s , p2p = p2p , s2p , p2p = p2p y
x y z x D
FeS + O 2 FeO + SO 2
1
Bond order of N2 = (10 - 5) = 2.5
2
Iron is removed as slag of FeSiO 3
(D) He+2 has less energy in comparison to two isolated He Smelting
FeO + SiO (flux)
2
D
FeSiO 3 ( l)(slag)
atoms because some energy is released during the
formation of He+2 from 2 He atoms.
Copper matte (Cu2S + FeS)
26. (a, b)
(A) H-bonding of methanol breaks when CCl4 is added so
bonds become weaker, resulting positive deviation. Self reduction occurs in Bessemer converter
(B) Mixing of polar and non-polar liquids will produce a Self reduction 2Cu S + 3O 2Cu 2 S + 2SO 2 ( )
2 2
solution of weaker interaction, resulting positive Cu 2 S + 2Cu 2 O 6Cu + SO 2 ( )
deviation
(C) Ideal solution (Blister copper)
(D) ve deviation because stronger H-bond is formed.
27. (b, c, d)
CCP is ABC ABC type packing
(A) In topmost layer, each atom is in contact with 6 atoms Refining of blister copper is done by poling followed by
in same layer and 3 atoms below this layer electrorefining but not by carbon reduction method.
dehydration of HNO
29. (b, d) P4 O10 + 4HNO3
3 4(HPO ) +2 N O
3 2 5
(required product)
(A) P4 + 20HNO3
4 H 3 PO 4 + 20NO 2 + 4H 2 O
(B) N2O5 is diamagnetic in nature
O O
(C) N2O5 N N
O O O
N2O5 contains one NON bond not NN bond.
(D) Na + N2O5 NaNO3 + NO2
(Brown gas)
30. (b,c) Invert sugar is an equimolar mixture of D-(+) glucose and D() glucose.
H+ +
C12 H 22 O11 + H 2 O
C6 H12 O6 + H 2 O
C 6 H12O6
+ sucrose D(+ ) -glucose D( + ) -glucose
( +52) ( -92)
1444444 2444444 3
Invert sugar
-92 + 52
Specific rotation of invert sugar = = -20
2
D-glucose on oxidation with Br2-water produces gluconic acid and not saccharic acid.
31. (c, d)
LiAlH4/(C2H5)2O : Reduces to esters, carboxylic acid, epoxides and aldehydes and ketones.
BH3 in T.H.F : Reduces to COOH and aldehydes into alcohols but do not reduce to esters and epoxides.
NaBH4 in C2H5OH : Reduces only aldehydes and ketones into alcohols but not to others.
Raney Ni in T.H.F. : Do not reduce to COOH, COOR and epoxide but it can reduce aldehyde into alcohols.
Br
32. (b, c, d) +
NaOEt

AlCl3 + 1, 2 H +
Shift
Cl
+
H +
BF 3 1, 2 H

+ +
OH Shift
H
X 2 (g)
2X(g)
33. (b)
Initial mole : 1 0
beqbm
moles at equilibrium : 1 - beqbm
2
beqbm
1- beqbm
2 P
Partial pressure : P beqbm
beqbm 1 +
1 + 2
2
2
(Px )2 beqbm P
\ Kp = =
Px 2 beqbm
2
1 -
4

2
4beqbm P
(
\ Kp = 4 - b 2
eqbm )
Since P = 2 bar
8b2eqbm
So, K p =
( 4 - beqbm
2
)
34. (c) (A) Correct statement.
As on decrease in pressure reaction move indirection where no. of gaseous molecules increase.
(B) Correct statement
At the start of reaction QP < KP so dissociation of X2 take place spontaneousely.
(C) Incorrect statement as
2
8beq 8 (0.7) 2
KP = = >1
4 - b2eq 4 - (0.7) 2
35. (a)
36. (b)
O
COOH CNH2 NH2

NH3 /D Br2 / NaOH
KMnO /H

4

COOH CNH2 NH2

(O) (P) (Q) (R)
O
O O
CH3 Br O
CH3 - CH -C -OC 2H 5
NCHCOC2H5 NH
KOH
O
(S)
O O

H 3O
CH3CHCOOH Alanine
NH2
(T)
MATHEMATICS q32 = 50 4 = 200
1 0 0 0 0 0 q31 + q32 20600

\ = = 103
37. (b) P = 4 1 0 = I + 4 0 0 = I + A
q 21 200

16 4 1
16 4 0
38. (b) logc b1, logc b2,...., logcb101 are in A.P.
b1, b2,...., b101 are in G.P.
0 0 0 0 0 0 Also a1, a2,...., a101 are in A.P.
2 3
A = 0 0 0 and A = 0 0 0
where a1 = b1 are a51 = b51.

16 0 0
0 0 0
\ b2, b3,...., b50 are GMs and a2, a3,...., a50 are AMs
between b1 and b51.
\ An = O, n 3
Q GM < AM b2 < a2, b3 < a3,...., b50 < a50
Now P50 = (I + A)50 = 50C0 I50 + 50C1 I49 A + 50C2
Q b1 + b2 +....+ b51 < a1 + a2 +....+ a51
+ I48 A2 + O
t<s
= I + 50A + 25 49 A2.
Also a1, a51, a101 are in AP
\ Q = P50 I = 50A + 25 49 A2.
b1, b51, b101 are in GP
q21 = 50 4 = 200
Q a1 = b1 and a51 = b51
q31 = 50 16 + 25 49 16 = 20400
\ b101 > a101
The graph of given region is as follows-

13 1
39. (c) p p p kp
k =1 sin + k - 1 sin
(
4
) +
6 4 6

(1, 2)
p kp p p ( 4, 1)
sin + - + (k - 1) P
Q
13 1 4 6 4 6

= k =1 sin p p p p kp

sin
+ k - 1 sin
( ) 6 4 6
+ S T R
6 4 ( 3, 0)
13 p p p kp
2 cot 4 + (k - 1) 6 - cot 4 +
6
k =1 Required area = Area (trap PQRS) Area (PST + TQR)
p p p 2p 1 -3 1
p p p = (1 + 2)5 - -4 - x - 3 dx +-3 x + 3 dx
= 2 cot - cot + + cot + - cot
+ 2

4 4 6
4 6 4 6
3/2 -3 3/2 1

p 12p p 13p 15 2 (- x - 3) 2 (x + 3)
= - +
+ ...... + cot 4 + 6 - cot 4 + 6 2 -3 3

-4 -3
p p 13p 5p 15 2 16 15 3
= 2 cot - cot + = 2 1 - cot
= - + = - 6 = sq.units
4 4 6

12 2 3 3 2 2
42. (c) P, the image of point (3, 1, 7) in the plane x y + z = 3 is
given by
1 - 3 - 1 = 2 1 - 2 - 3 = 2
2
=
3 + 1 ( ) ( 3 -1 ) x - 3 y -1 z - 7 -2 (3 - 1 + 7 - 3)
= = =
2 1 -1 1 12 + 12 + 12
p/2 x cos x
40. (a) I = dx ....(i) x - 3 y -1 z - 7
-p/2
1 + ex = = =4
1 -1 1
Applying a f (x) dx
b x = 1, y = 5, z = 3
\ P(1, 5, 3)
Now equation of plane through (1, 5, 3) and containing
b
= a f (a + b - x ) dx, we get
x y z
the line = = is
x 2 1 2 1
p/2 e x cos x
I = dx ....(ii)
-p/2
1 + ex x y z
-1 5 3 = 0 x + 4y 7z = 0
Adding (i) and (ii)
1 2 1
p/2
2 p/2 2
2I =-p/2 x cos x dx = 20 x cos x dx or x 4y + 7z = 0
43. (b, c)
2 p
I= x 2
sin x + 2x cos x - 2 sin x 2 = p - 2 x /n
0 4 n n n
n (x + n) x + ...
x +
2 n
41. (c) y x + 3 y2 = x + 3 f(x) = lim
n 2 2
2 2 n n
( x2 + x2 + 2
2 - (x + 3) if x < -3
n! x + n

)...
4
n

y = ....(i)
(x + 3) if x -3
x/n
2n x x 1 x 1
x+9 n n + 1
n + 2 ....
n + n
Also y and x 6 ....(ii)
5 = lim
n x 2 x 2 1 x 2 1
2n
Solving (i) and (ii) we get intersection points as (1, 2), n n!
n 2 + 1 n 2 + 22 .... n 2 + n 2
(6, 3), ( 4, 1), (39, 6)

44. (a, b) f(x) = a cos (|x x|) + b |x| sin (|x3 + x|)
3 3
x /n (a) If a = 0, b = 1

x x 1 x 1
+ 1
+ ....
+ f(x) = |x| sin |x3 + x|
= lim n n 2 n n = x sin (x3 + x), x R
x 2 1 x 2 1
n x 2
1. + 1 2. + .... n. + \ f is differentiable every where
2 2 2 2 n
n
n n (b), (c) If a = 1, b = 0 f(x) = cos3 (|x3 x|)
= cos3(x3 x)
which is differentiable every where.
x n x 1 n rx 2 1
ln f(x) = n n ln n + r - ln 2 + r
lim (d) when a = 1, b = 1, f(x) = cos(x3 x) + x sin (x3 + x)
r =1 r =1 n which is differentiable at x = 1
\ Only a and b are the correct options.
rx 1 r 2 x 2
x n 1
lim ln + ln + 1 - ln + ln 2 + 1 f ( x) g ( x ) 0
= n n r =1 r n r n
45. (a, d) lim =1 form
x 2 f ( x) g ( x ) 0

n r 2 x 2
x ln 1 + rx 1 + f ( x ) g ( x ) + f ( x ) g ( x )
= nlim
n
- ln
2 xlim =1
r =1 n n 2 f ( x ) g ( x ) + f ( x ) g ( x )
1 1 g (2) f (2)
= xln (1 + xy) dy - xln 1 + x 2 y2 dy
( ) f 2 g 2 =1 f ( 2 ) = f ( 2 )
0 0 () ()
Let xy = t x dy = dt \ f(x) f ( x ) = 0 for atleast one x R.
x x 2
\ ( )
ln f(x) = 0 ln (1 + t ) dt -0 ln 1 + t dt Q Range of f(x) is ( 0, )
\ f(x) > 0, x R
x 1+ t
ln f (x ) =
0
ln
dt
f(2) > 0 f ( 2 ) > 0
1 + t 2
f has a local minimum at x = 2
f (x) 1+ x 46. (b, c) f(x) = [x2 3] is discontinuous at all integral points in
= ln
f (x ) 1 + x 2 1
- 2 , 2

f (2) 3
= ln < 0
f (2) 5 Which happens when x = 1, 2, 3 ,2
f (2) < 0 \ (c) is correct 1

\ f is discontinuous exactly at four points in - , 2
2
f (3)
2 f (2)
= ln <
( ) 5 f (2) \ (d) is not correct
and f 3
Also g ( x ) = ( x + 4x - 7 ) f ( x )
1+ x 1
Also f (x) = f(x) ln > 0, , x (0, 1) Here f is not differentiable at x = 1, 2, 3 - 2 , 2
1 + x 2
\ f is an increasing function. 7
and |x| + |4x 7| is not differentiable at O and
1 1 4
\ <1 f f (1)

2 2 But f(x) = 0, x
3 , 2

\ (a) is not correct
7
1 2 1 2 \ g(x) becomes differentiable at x =
and < f
f

4
3 3 3 3
Hence g(x) is non-differentiable at four points i.e.,
\ (b) is correct
0,1, 2, 3
Hence (b) and (c) are the correct options.
49. (b, c, d)
1
47. (a, c, d) z = = x + iy ax + 2y = l
a + ibt
3x 2y = m
a - ibt
x + iy = a 2
a + b2 t 2
2
For unique solution, a 3
3 -2
a -bt \ (b) is the correct option.
x= 2 , y= 2
2 2
a +b t a + b2 t 2 For infinite many solutions and a = 3
1 x -3 2 l l
x 2 + y2 = 2 2 2
= = = =-1 or l + m = 0
a +b t a 3 -2 m m
x \ (c) is the correct option.
x 2 + y2 - =0
a
-3 2 l
Also if l + m 0, then =
1 3 -2 m
\ Locus of z is a circle with centre , 0 and
2a system has no solution.
1 \ (d) is the correct option.
radius = 2 a irrespective of a +ve or ve r
50. (b, c) u v = 1 v sin q = 1 ...(i)
Also for b = 0, a 0, we get, y = 0
r
\ locus is x-axis
and for a = 0, b 0 we get x = 0
( )
u v = 1 v sin q cos a = 1
w. ...(ii)
locus is y-axis. where a is the angle between w and a vector ^ lat to

\ a, c, d are the correct options. r r
48. (a, c, d) u&v .
Let point P on parabola y2 = 4x be (t2, 2t) From (i) and (ii) cos a = 1 a = 0
... PS is shortest distance, therefore PS should be the r r
w is perpendicular to the plane containing u & v
normal to parabola.
r
w is perpendicular to u
r
2 Clearly there can be infinite many choices for v .
P(t , 2t)
Also if u lies in xy plane i.e., u = u1i + u 2 j then
Q r
w.u = 0
S(2, 8) u1 + u2 = 0 u1 = u 2
Also if u lies in xz plane, i.e., u = u1i + u 3k then

r
Equation of normal to y2 = 4x at P (t2, 2t) is w.u = 0 u1 + 2u3 = 0 |u1| =2|u3|
y 2t = t(x t2) Hence (b) and (c) are the correct options.
It passes through S(2, 8)
For (Qs. 51-52)
\ 8 2t = t(2 t2) t3 = 8 or t = 2
\ P(4, 4) (X, Y) = {(6, 0), (4, 1), (3, 3), (2, 2), (4, 4), (0, 6)}
51. (b) P(X > Y) = P(T1 wins 2 games or T1 win one game other
-1 1
Also slope of tangent to circle at Q = = is a draw)
Slope of PS 2
1 1 1 1 1 1 1 1 5
Equation of normal at t = 2 is 2x + y = 12 = +
+ = + =
Clearly x-intercept = 6 2 2 2 6 6 2 4 6 12
SP = 2 5 and SQ = r = 2 52. (c) P(X = Y) = P(T1 wins 1 game loses other game or both
\ Q divides SP in the ratio SQ : PQ the games draw)
= 2: 2 ( ) (
5 - 1 or 5 +1 : 4) 1 1 1 1 1 1 1 1 13
= + + = + =
Hence a, c , d are the correct options. 2 3 3 2 6 6 3 36 36
For (Qs. 53-54) Putting y = 0 in above equation, we get
x 2 y2 8 1 x =-
9
For ellipse + =1, e = 1 - =
9 8 9 3 10
\ F1( 1, 0) and F2 (1, 0) 9
Parabola with vertex at (0, 0) and focus at F2(1, 0) is y2 = 4x. \ Orthocentre - , 0
10
3 54. (c) Tangents to ellipse at M and N are
Intersection points of ellipse and parabola are M
, 6

2
x y 6 x y 6
+ = 1 and - =1
3 6 8 6 8
and N
,- 6

2 Their intersection point is R (6, 0)
3
3 Also normal to parabola at M , 6 is
M , 6 2
2
6 3
y- 6 = - x -
2 2
Q
7
F1(1, 0) F2(1, 0) Its intersection with x-axis is Q
, 0

2
1 5 5 6
3 Now ar (DMQR) = 6=
N ,- 6 2 2 4
2
Also area (MF1NF2) = 2 Ar (F1MF2)
53. (a) For orthocentre of DF1MN, clearly one altitude is x- 1
= 2 2 6 = 2 6
axis i.e. y = 0 and altitude from M to F1N is y - 6 2
5 3 ar (DMQR ) 5 6
\ = =5 : 8
= x-
ar (MF1NF2 ) 42 6
2 6 2

Disha Publication 2016 Jee-Advanced Solved-Paper. V526057483

Caricato da

Informazioni sul documento

Titolo originale

Copyright

Formati disponibili

Condividi questo documento

Condividi o incorpora il documento

Opzioni di condivisione

Hai trovato utile questo documento?

Questo contenuto è inappropriato?

Copyright:

Formati disponibili

Disha Publication 2016 Jee-Advanced Solved-Paper. V526057483

Caricato da

Copyright:

Formati disponibili

JEE ADVANCED 2016 PAPER

This Paper JEE Advanced 2016 Paper is taken from our:

h 3 3 8 3 h 3 3 16 3 (a) 15 (b) 22.5

11. A conducting loop in the shape of a right angled isosceles

10 cm This section contains 5 questions. Each question, when worked

m0 14. A metal is heated in a furnace where a sensor is kept above

51. Let m be the smallest positive integer such that the

PHYSICS process at volume Vf . The amount of heat supplied to the

the other caliper (C2) has 10 equal divisions that correspond

(a) 2.85 and 2.82 (b) 2.87 and 2.83

25. According to Molecular Orbital Theory,

p (a) f has a local minimum at x = 2

47. Let a, b and a + b 0. 2 2

(c) the x-intercept of the normal to the parabola at P is 6

h = 0.64 10 -33 = 6.4 10-34 J-s

l/2 1.6g Applying Snell's law at B

Relative change in the energy of two consecutive orbitals

dV -l s 2pr l -lsl nq = 121 - 118 = 3

18. (8) CH3 CH3

Ba 2+ BaS(Soluble) BaSO 4 (ppt) S

Pb(OAc) 2 PbS(ppt) PbSO 4 (ppt) Q is steam volatile not R.

\ f is decreasing on [0, 1] For above to be possible, we should have

KA ( 400 - T ) 2KA ( T - 10 ) 7. (a, c) In DOAM, OM = l2 + a 2 = 2ha 2 + a 2 = 5a

8. (c) The wavelength of emitted photoelectron as per de 11. (a, b, c, d)

combined masses decreases in both the cases. 4

1 2 So, X, Y and Z are [Ag (S2O3)2]3, Ag2S2O3 and Ag2S

COOH CNH2 NH2

COOH CNH2 NH2

MATHEMATICS q32 = 50 4 = 200

1 0 0 0 0 0 q31 + q32 20600

The graph of given region is as follows-

f (2) < 0 \ (c) is correct 1

locus is y-axis. where a is the angle between w and a vector ^ lat to

Also if u lies in xz plane, i.e., u = u1i + u 3k then

Potrebbero piacerti anche