RS -11- I - 4

TARGET IIT JEE

CHEMISTRY, MATHEMATICS & PHYSICS

Time : 3 : 00 Hrs. MAX MARKS: 243

Name : _____________________________________ Roll No. : __________________________ Date : _____________

INSTRUCTIONS TO CANDIDATE
A.GENERAL :
1. Please read the instructions given for each question carefully and mark the correct answers against the question
numbers on the answer sheet in the respective subjects.
2. The answer sheet, a machine readable Optical Mark Recognition (OMR) is provided separately.

SEAL
3. Do not break the seal of the question-paper booklet before being instructed to do so by the invigilators.
B. MARKING SCHEME :
Each subject in this paper consists of following types of questions:-
Section - I
4. Multiple choice questions with only one correct answer. 3 marks will be awarded for each correct answer and 1 mark for
each wrong answer.
5. Multiple choice questions with multiple correct option. 3 marks will be awarded for each correct answer and No negative
marking.
6. Passage based single correct type questions. 3 marks will be awarded for each correct answer and 1 mark for each wrong
answer.
Section - III
7. Numerical response (single digit integer answer) questions. 3 marks will be awarded for each correct answer and No
negative marking for wrong answer. Answers to this Section are to be given in the form of single integer only (0 to 9)
C.FILLING THE OMR :
8. Fill your Name, Roll No., Batch, Course and Centre of Examination in the blocks of OMR sheet and darken circle properly.
9. Use only HB pencil or blue/black pen (avoid gel pen) for darking the bubbles.
10. While filling the bubbles please be careful about SECTIONS [i.e. Section-I (include single correct, reason type, multiple
correct answers), Section II ( column matching type), Section-III (include integer answer type)]

Section I Section-II Section-III

For example if only 'A' choice is For example if Correct match for (A) Ensure that all columns are filled.
correct then, the correct method for is P; for (B) is R, S; for (C) is Q; for Answers, having blank column will be treated as
filling the bubbles is (D) is P, Q, S then the correct method incorrect. Insert leading zeros (s)
A B C D E for filling the bubbles is '6' should be '86' should be '1857' should be
P Q R S T filled as 0006 filled as 0086 filled as 1857
For example if only 'A & C' choices A 0 0 0 0
are correct then, the correct method B 0 0 0 0 0 0 0 0 0 0 0 0
for filling the bublles is 1 1 1 1 1 1 1 1 1 1 1 1
C 2 2 2 2 2 2 2
A B C D E 2 2 2 2 2
D 3 3 3 3 3 3 3 3 3 3 3 3
the wrong method for filling the 4 4 4 4 4 4 4 4 4 4 4 4
bubble are 5 5 5 5 5 5 5 5 5 5 5 5
6 6 6 6 6 6 6 6 6 6 6 6
The answer of the questions in 7 7 7 7 7 7 7 7 7 7 7 7
wrong or any other manner will be 8 8 8 8 8 8 8 8 8 8 8 8
treated as wrong.
9 9 9 9 9 9 9 9 9 9 9 9

CAREER POINT, CP Tower, Road No.1, IPIA, Kota (Raj.), Ph: 0744-3040000, Fax (0744) 3040050
1 email : info@careerpointgroup.com; Website : www.careerpointgroup.com
Important Data (egRoiw.kZ vkdM+s)

Atomic Masses: H = 1, C = 12, K = 39, O = 16, Fe= 56, N= 14, I = 127, Ca = 40, Mg = 24, Al = 27, F = 19, Cl = 35.5, S = 32,
(ijek.kq nzO;eku) Na = 23
Constants : R = 8.314 Jk1mol1, h = 6.63 1034 Js , C = 3 108 m/s, e = 1.6 1019 Cb,me = 9.1 1031Kg,
(fu;rkad) : RH = 1.1 107 m1, log 2 = 0.3010, log 3 = 0.4771, log(5.05) = 0.7032; ln2 = 0.693; ln 1.5 = 0.405; ln3 = 1.098

Space for Rough Work (jQ+ dk;Z gsrq LFkku)

Space for rough work

CAREER POINT, CP Tower, Road No.1, IPIA, Kota (Raj.), Ph: 0744-3040000 Page # 1
 CHEMISTRY
Section I
Questions 1 to 8 are multiple choice questions. Each
question has four choices (A), (B), (C) and (D), out of
which ONLY ONE is correct. Mark your response in
OMR sheet against the question number of that
question. + 3 marks will be given for correct answer and
1 mark for each wrong answer.
Q.1 A bubble of gas released at the bottom of a lake
increases to eight times its volume when it reaches
the surface. Assuming that atmospheric pressure is
equivalent to the pressure exerted by a column of
water 10 m high, what is the depth of the lake ?
(A) 90 m (B) 10 m (C) 70 m (D) 80 m
[k.M - I
iz'u 1 ls 8 rd cgqfodYih iz'u gSaA izR;sd iz'u ds pkj
fodYi (A), (B), (C) rFkk (D) gSa, ftuesa ls dsoy ,d fodYi
lgh gSA OMR 'khV esa iz'u dh iz'u la[;k ds le{k viuk
mkj vafdr dhft;sA izR;sd lgh mkj ds fy, + 3 vad fn;s
tk;asxs rFkk izR;sd xyr mkj ds fy, 1 vad ?kVk;k tk;sxkA
Q.1 xSl ds ,d cqycqys dks >hy ds iSans ls NksM+k tkrk gS]
rks lrg ij igqpus ij ;g vk;ru dk vkB xquk c<+
tkrk gSA ;g ekurs gq, fd nkc] ty ds ,d 10 ehVj
ps LrEHk ds }kjk vkjksfir nkc ds rqY; gS] rks >hy
dh xgjkbZ D;k gS ?
(A) 90 m (B) 10 m (C) 70 m (D) 80 m

Q.2 100 ml of a buffer of 1 M NH3 and 1 M NH4+ are Q.2 1 M NH3 o 1 M NH4+ ds 100 ml cQj dks
placed in two voltaic cells separately. A current of iFkd&iFkd nks okWYVh; lsyksa esa Hkjk tkrk gSA 1.5 A
1.5 A is passed through both cells for 20 minutes. dh /kkjk dks nksuksa lsyksa esa ls 20 feuV rd xqtkjk
If electrolysis of water only takes place
tkrk gSA ;fn dsoy ty dk fo|qr vi?kVu gks
2H2O + O2 + 4e
4(OH) (R.H.S.)
2H2O + O2 + 4e
4(OH) (R.H.S.)
+
2H2O 4H + O2 + 4e (L.H.S.) 4H+ + O2 + 4e (L.H.S.)
2H2O
then pH of the : rks pH :
(A) L.H.S. will increase
(A) ck;h rjQ c<+sxh
(B) R.H.S. will increase
(C) Both sides will increase (B) nk;h rjQ c<+sxh
(D) Both sides will decrease (C) nksuksa rjQ c<+sxh
(D) nksuksa rjQ ?kVsxh
Space for rough work

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Q.3 The rate constant for two parallel reactions were Q.3 nks lekukUrj vfHkf;kvksa ds osx fu;rkad
found to be 1.0 102 litre mol1 s1 and 3.0 102
1.0 10 litre mol1 s1 o 3.0 102 litre mol1 s1
2
litre mol1 s1 . If the corresponding energies of
activation of the parallel reactions are 60.0 kJ mol1 Ikk;s x;sA ;fn lEcfU/kr lekukUrj vfHkf;kvksa dh
and 70.0 kJ mol1 respectively, what is apparent lf;.k tkZ,sa e'k% 60.0 kJ mol1 o 70.0 kJ mol1
overall energy of activation ? gks] rks lEiw.kZ lf;.k tkZ D;k gS ?
(A) 130.0 kJ mol1 (B) 67.5 kJ mol1 (A) 130.0 kJ mol1 (B) 67.5 kJ mol1
1
(C) 100.0 kJ mol (D) 65.0 kJ mol1 (C) 100.0 kJ mol1 (D) 65.0 kJ mol1

Q.4 Which of the following statement is incorrect? Q.4 fuEu esa ls dkSulk dFku xyr gS ?
(A) B(OH)3 partially reacts with water to form (A) B(OH)3 vkaf'kd :Ik ls ty ds lkFk f;k dj
H3O+ and [B(OH)4], and behaves like a weak H3O+ o [B(OH)4] cukrk gS] rFkk ,d nqcZy
acid vEy dh rjg O;ogkj djrk gS
(B) B(OH)3 behaves like a strong monobasic acid (B) B(OH)3 'kdZjk dh mifLFkfr esa ,d izcy
in the presence of sugars, and this acid can be ,d{kkjh; vEy dh rjg O;ogkj djrk gS] rFkk
titrated against an NaOH solution using bl vEy dk vuqekiu NaOH foy;u ds lkFk
phenolphthalein as an indicator fQuksFksyhu dks lwpd ds :Ik esa iz;qDr djrs
(C) B(OH)3 does not donate a proton and does not gq, fd;k tk ldrk gS
form any salt with NaOH (C) B(OH)3 izksVksu ugha nsrk gS rFkk NaOH ds lkFk
(D) B(OH)3 reacts with NaOH, forming dksbZ Hkh yo.k ugha cukrk gS
Na [B(OH)4] (D) B(OH)3 ,NaOH ds lkFk f;k dj Na[B(OH)4]
cukrk gS

Space for rough work

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Q.5 Which is correct about the nucleophilicity of halide
ion ?
(A) In DMSO order of nucleophilicity is
F() > Cl() > Br() > I() while in water it is
I() > Br() > Cl() > F()
(B) In DMSO order of nucleophilicity is
I() > Br() > Cl() > F() while in water it is
F() > Cl() > Br() > I()
(C) Order of nucleophilicity is same
F() > Cl() > Br() > I() in both water and
DMSO
(D) Order of nucleophilicity is same
I() > Br() > Cl() > F() in both water and
DMSO
Q.5 gSykbM vk;u dh ukfHkdLusgrk ds lUnHkZ esa dkSulk
lgh gS ?
(A) DMSO esa ukfHkdLusgrk dk e
F() > Cl() > Br() > I() tcfd ty esa
I() > Br() > Cl() > F() gS
(B) DMSO esa ukfHkdLusgrk dk e
I() > Br() > Cl() > F() tcfd ty esa
F() > Cl() > Br() > I() gS
(C) ukfHkdLusgrk dk e F() > Cl() >
Br() > I() ty o DMSO nksuksa esa leku gS
(D) ukfHkdLusgrk dk e I() > Br() > Cl() > F()
ty o DMSO nksuksa esa leku gS

Q.6 Consider the following four isomers Q.6 fuEu pkj leko;oh;ksa ij fopkj dhft,
CH3 CH3 CH3 H
CH3 CH3 CH3 H
C=C C=C
C=C C=C H H H CH3
H H H CH3
(1) (2)
(1) (2)
C2H2 BF3
C2H2 BF3 (3) (4)
(3) (4) dkSulk lgh gS -
Which is correct -
(A) 2 and 4 possess centre of symmetry (A) 2 o 4 eas dsUnzh; leferh mifLFkr gS
(B) 1, 2, 3 and 4 contain axis of symmetry (B) 1, 2, 3 o 4 esa v{kh; leferh mifLFkr gS
(C) 2 and 3 possess alternating axis of symmetry (C) 2 o 3 esa ,dkUrfjr v{kh; leferh mifLFkr gS
(D) 4 contains centre of symmetry while 2 contains (D) 4 esa dsUnzh; leferh tcfd 2 esa ry leferh
plane of symmetry mifLFkr gS
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CAREER POINT, CP Tower, Road No.1, IPIA, Kota (Raj.), Ph: 0744-3040000 Page # 3
 (+) (+)
Q.7 (
i) H
[X], [X] may be Q.7 (
i) H
[X], [X] gks ldrk gS
( ii ) ( ii )

(A) (B) (A) (B)

(C) (D) None (C) (D) dksbZ ugha

Q.8 Cis-but-2-ene KMnO

4 ( cold )
(X) Q.8 lei{k-C;wV-2-bZu KMnO
4( cold)
(X)
Me Me OH
OH
(A) (A)
H H H H
Me HO Me
HO
OH Me
OH Me
(B)
(B) H H
H H OH
Me
Me OH
Me Me
Me Me
(C)
(C) H H
H H HO OH
HO OH
(D) (A) o (B) nksuksa
(D) Both (A) and (B)

Questions 9 to 12 are multiple choice questions. Each
question has four choices (A), (B), (C) and (D), out of
which MULTIPLE (ONE OR MORE) is correct. Mark
your response in OMR sheet against the question
number of that question. + 4 marks will be given for
correct answer and 1 mark for each wrong answer.
iz'u 9 ls 12 rd cgqfodYih iz'u gaSA izR;sd iz'u ds pkj
fodYi (A), (B), (C) rFkk (D) gSa] ftuesa ls ,d ;k ,d ls
vf/kd fodYi lgh gaSA OMR 'khV esa iz'u dh iz'u la[;k ds
le{k vius mkj vafdr dhft,A izR;sd lgh mkj ds fy, +
4 vad fn;s tk;saxs rFkk izR;sd xyr mkj ds fy, 1 vad
?kVk;k tk;sxkA

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Q.9 Which of the following mixtures can act as a
buffer ?
(A) NaOH + CH3COONa (1 : 1 molar ratio)
(B) CH3COOH + NaOH (2 : 1 molar ratio)
(C) CH3COOH + NaOH (3 : 1 molar ratio)
(D) CH3COOH + NaOH (1 : 1 molar ratio)
Q.9 fuEu esa ls dkSulk feJ.k ,d cQj dh rjg dk;Z dj
ldrk gS ?
(A) NaOH + CH3COONa (1 : 1 eksyj vuqikr)
(B) CH3COOH + NaOH (2 : 1 eksyj vuqikr)
(C) CH3COOH + NaOH (3 : 1 eksyj vuqikr)
(D) CH3COOH + NaOH (1 : 1 eksyj vuqikr)

Q.10 When one mole of gas is heated at constant volume Q.10 fLFkj vk;ru ij] tc ,d eksy xSl ds rki dks 298
temperature is raised from 298 to 309 K. Heat ls 309 K rd c<+k;k tkrk gSaA xSl dks nh xbZ "ek
supplied to the gas is 500 joule. Then which 500 twy gSA rc dkSulk dFku lgh gS ?
statement is correct ? (A) q = w = 500 J, U = 0
(A) q = w = 500 J, U = 0 (B) q = U = 500 J w = 0
(B) q = U = 500 J w = 0 (C) q = w 500 J, U = 0
(C) q = w 500 J, U = 0
(D) U = 0, q = w = 500 J
(D) U = 0, q = w = 500 J

Q.11 Acetone (CH3COCH3) is the major product in : Q.11 ,lhVksu (CH3COCH3) fdlesa eq[; mRikn gS :

(I) CH2=C=CH2 H3O (I) CH2=C=CH2 H3O

(II) CH3CCH H2SO / HgSO 4 / H 2 O

4 (II) CH3CCH H2SO / HgSO 4 / H 2 O
4
(III) CH3CCH BH .THF
3
(III) CH3CCH BH .THF
3 H 2 O 2 / OH
H 2 O 2 / OH
(A) I (B) II (A) I (B) II
(C) III (D) None of these (C) III (D) buesa ls dksbZ ugha

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Q.12 Which of the following ion will be aromatic in Q.12 fuEu esa ls dkSuls vk;u dh ,sjksesfVd izdfr gksxh ?
nature ?
Cl
Cl
(A) (B) H
(A) (B) H +
+ N H
N H |
|
H
H
N N
(C) (D) +
(C) (D) + N
N
H H H H

This section contains 2 paragraphs, each has 3 multiple
choice questions. (Questions 13 to 18) Each question has
4 choices (A), (B), (C) and (D) out of which ONLY ONE
is correct. Mark your response in OMR sheet against the
question number of that question. + 4 marks will be
given for correct answer and 1 mark for each wrong
answer..
bl [k.M esa 2 vuqPNsn fn;s x;s gSa] izR;sd esa 3 cgqfodYih
iz'u gSaA (iz'u 13 ls 18) izR;sd iz'u ds pkj fodYi (A), (B),
(C) rFkk (D) gSa, ftuesa ls dsoy ,d fodYi lgh gSA OMR
'khV esa iz'u dh iz'u la[;k ds le{k viuk mkj vafdr
dhft;sA izR;sd lgh mkj ds fy;s + 4 vad fn;s tk,saxs rFkk
izR;sd xyr mkj ds fy, 1 vad ?kVk;k tk;sxkA

Passage # 1 (Ques. 13 to 15) vuqPNsn # 1 (iz'u la[;k 13 ls 15)

The percentage labeling of oleum is a unique
process by means of which, the percentage
composition of H2SO4, SO3 (free) and SO3
(combined) is calculated.
Oleum is nothing but it is a mixture of H2SO4 and
SO3 i.e., H2S2O7, which is obtained by passing SO3
in solution of H2SO4. In order to didssolve free SO3
in oleum, dilution of oleum is done, in which oleum
converts into pure H2SO4. It is shown by the
reaction as under :
Space for rough work
vkWfy;e dh izfr'krrk dk vadu fo'ks"k fof/k }kjk fd;k
tkrk gS ftlds QyLo:i H2SO4, SO3 (eq) rFkk SO3
(la;q) ds laxBu dks ifjdfyr fd;k tkrk gSA
vkWfy;e okLro esa dqN ugha cfYd H2SO4 o SO3 dk
feJ.k gS vFkkZr~ H2S2O7 tks H2SO4 foy;u esa SO3 dks
xqtkjus ls izkIr gksrk gSA vkWfy;e esa eq SO3 dks
?kksyus ds lUnHkZ esa vkWfy;e dk ruqdj.k gksrk gSA
ftlesa vkWfy;e 'kq) H2SO4 esa cny tkrk gSA bls
fuEu vfHkf;k }kjk n'kkZ;k x;k gS :

CAREER POINT, CP Tower, Road No.1, IPIA, Kota (Raj.), Ph: 0744-3040000 Page # 6
 H2SO4 + SO3 + H2O
2 H2SO4 (pure)
or, SO3 + H2O H2SO4 (pure)
When 100 g sample of oleum is diluted with
desired weight of H2O (in g), then the total mass of
pure H2SO4 obtained after dilution is known as
percentage labeling in oleum.
For example, if the oleum sample is labelled as
"109% H2SO4" it means that 100 g of oleum on
dilution with 9 g of H2O provides 109 g pure
H2SO4, in which all free SO3 in 100 g of oleum is
dissolved.
H2SO4 + SO3 + H2O
2 H2SO4 ('kq))
;k] SO3 + H2O H2SO4 ('kq))
tc 100 g vkWfy;e ds uewus dks H2O (g esa), ds
,fPNd Hkkj dk ruq fd;k tkrk gS rc ruqrk ds
i'pkr~ o 'kq) H2SO4 dk dqy nzO;eku izkIr gksrk gS
ftls vkWfy;e esa izfr'krrk vadu dgk tkrk gSA
mnkgj.k ds fy,] ;fn vkWfy;e ds uewus dk vadu
"109% H2SO4" gks rks bldk rkRi;Z gS fd 100 g vkWfy;e
9 g H2O ds lkFk ruqrk ij 109 g 'kq) H2SO4 nsrk gS
ftlesa lHkh eq SO3, 100 g vkWfy;e esa ?kqyh gksrh gSA

Q.13 For 109% labeled oleum if the number of moles of Q.13 109% vafdr vkWfy;e ds fy, ;fn H2SO4 o eq SO3
H2SO4 and free SO3 be x and y respectively, then x+y
x+y
ds eksyksa dh la[;k e'k% x o y gS] rks dk eku
what will be the value of ? xy
xy D;k gksxk ?
(A) 1 (B) 18 (C) 1/3 (D) 9.93 (A) 1 (B) 18 (C) 1/3 (D) 9.93
Q.14 In the above question, what is the percentage of Q.14 mijks iz'u esa] vkWfy;e uewus esa eq SO3 rFkk H2SO4
free SO3 and H2SO4 in the oleum sample dh izfr'krrk D;k gS ?
respectively?
(A) 60%, 40% (B) 30%, 70%
(A) 60%, 40% (B) 30%, 70%
(C) 85%, 15% (D) 40%, 60%
(C) 85%, 15% (D) 40%, 60%
Q.15 What volume of 1 M NaOH (in mL) will be Q.15 109% vafdr vkWfy;e esa H2SO4 o SO3 ds lkFk iw.kZ
required to react completely with H2SO4 and SO3 in vfHkf;k djus ds fy, 1 M NaOH (mL esa) dk
109% labelled oleum ? vko';d vk;ru D;k gksxk ?
(A) 250 mL (B) 2224 mL (A) 250 mL (B) 2224 mL
(C) 750 mL (D) 1800 mL (C) 750 mL (D) 1800 mL

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Passage # 2 (Ques. 16 to 18) vuqPNsn # 2 (iz'u la[;k 16 ls 18)
Ethyl acetoacetate and malonic ester are used for ,fFky ,lhVks,lhVsV o esyksfud ,LVj dk mi;ksx
the synthesis of various important organic fofHkUu egRoiw.kZ dkcZfud ;kSfxdksa tSls dhVksu o
compound like ketone and substituted carboxylic izfrLFkkfir dkckZsfDlfyd vEy ds la'ys"k.k esa fd;k
acid. It contains active methylene (CH2) group.
tkrk gSA buesa lf; esFkhfyu (CH2) lewg mifLFkr
If contains acidic hydrogen and can be replaced
gksrk gSA ;fn vEyh; gkbMkstu mifLFkr gks] rks fuEu
as -
( )
izdkj ls foLFkkfir gksrk gS -
B &&
CH3COCH2COOC2H5 CH 3CO C HCO 2 Et B && ()
CH3COCH2COOC2H5 CH 3CO C HCO 2 Et
R
| R
RX |
CH3COCHCO2Et RX
X() CH3COCHCO2Et
X()
This alkyl substituted ethyl acetoacetate on
;g ,fYdy izfrLFkkfir ,fFky ,lhVks,lhVsV
hydrolysis produces acids
tyvi?kVu ij vEy nsrk gS
CH 3COCHCO 2 Et dil
NaOH
CH 3COCH COOH
| H(+) | CH 3COCHCO 2 Et dil
NaOH
CH 3COCH COOH
R R | H( +) |
R R

Q.16 Malonic ester CH2(COOEt)2 can be converted in to Q.16 esyksfud ,LVj CH2(COOEt)2 dk ifjorZu
CH3CH = CH COOH by treating malonic ester CH3CH = CH COOH esa esyksfud ,LVj dh fdlds
with : lkFk vfHkf;k ls gksrk gS :
(A) EtONa / CH3CHO / , H3O+ / (A) EtONa / CH3CHO / , H3O+ /
+
(B) EtONa / CH3Cl, H3O / (B) EtONa / CH3Cl, H3O+ /
(C) EtONa / CH2Cl2, H3O+, , alc KOH (C) EtONa / CH2Cl2, H3O+, , alc KOH
(D) All of these (D) mijks lHkh

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Q.17 CH3COCH2COOC2H5 EtONa
Q.17 CH3COCH2COOC2H5 EtONa

RX RX

H 3O ( + )
CH3CO C HCOOC2H5 H3O
X
(+)
CH3CO C HCOOC2H5
X
| |
R R
O3
O3
CH3COCOOH + HCOOH CH3COCOOH + HCOOH
H 2O
H 2O
+ CH3COCH(CH2COOH)COOH
+ CH3COCH(CH2COOH)COOH
RX would be - RX gksxk -

(A) XCH=CH C = CH 2 (A) XCH=CH C = CH 2

| |
CH 3 CH 3
(B) XCH2CH = CCH3CH = CH2
(B) XCH2CH = CCH3CH = CH2
(C) XCH2 C CH =CHCH3
(C) XCH2 C CH =CHCH3 ||
|| CH 2
CH 2
(D) XCH2 C = CH CH=CH2
(D) XCH2 C = CH CH=CH2 |
| CH 3
CH 3

Q.18 CH3COCH2COOC2H5 can be converted in to 1, 3 di Q.18 CH3COCH2COOC2H5 dk ifjorZu 1, 3 MkbZdhVksu esa

ketone by treating it with - bldh fdlds lkFk vfHkf;k ls gks ldrk gS -
(A) EtONa / CH3COCl, H3O+ / (A) EtONa / CH3COCl, H3O+ /
+
(B) EtONa / CH3COCH2COCl, H3O / (B) EtONa / CH3COCH2COCl, H3O+ /
+
(C) EtONa / CH3CH2COCl, H3O / (C) EtONa / CH3CH2COCl, H3O+ /
(D) EtONa / CH3COCH2CH2COCl, H3O+ / (D) EtONa / CH3COCH2CH2COCl, H3O+ /

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 Section - II [k.M - II
This section contains 2 questions (Questions 1, 2). Each bl [k.M esa 2 iz'u (iz'u 1, 2) gSaA izR;sd iz'u esa nks LrEHkksa
question contains statements given in two columns which esa dFku fn;s x;s gSa] ftUgsa lqesfyr djuk gSA LrEHk-I
have to be matched. Statements (A, B, C, D) in Column I (Column I ) esa fn;s x;s dFkuksa (A, B, C, D) dks LrEHk-II
have to be matched with statements (P, Q, R, S, T) in (Column II) esa fn;s x;s dFkuksa (P, Q, R, S,T) ls lqesy
Column II. The answers to these questions have to be djuk gSA bu iz'uksa ds mkj uhps fn;s x;s mnkgj.k ds
appropriately bubbled as illustrated in the following vuqlkj mfpr xksyksa dks dkyk djds n'kkZuk gSA ;fn lgh
example. If the correct matches are A-P, A-S, A-T; lqeys A-P, A-S, A-T; B-Q, B-R; C-P, C-Q rFkk D-S, D-T gS,
B-Q, B-R; C-P, C-Q and D-S, D-T then the correctly rks lgh fof/k ls dkys fd;s x;s xksyksa dk 4 5 eSfVDl uhps
bubbled 4 5 matrix should be as follows : n'kkZ;s vuqlkj gksxk :
P Q R S T P Q R S T
A P Q R S T A P Q R S T
B P Q R S T B P Q R S T
C P Q R S T C P Q R S T
D P Q R S T D P Q R S T

Mark your response in OMR sheet against the question
number of that question in section-II. + 8 marks will be
given for complete correct answer (i.e. +2 marks for each
correct row) and No Negative marks for wrong answer.
vr% OMR 'khV esa iz'u dh iz'u la[;k ds le{k viuk mkj
[k.M-II esa vafdr dhft;sA izR;sd iw.kZ lgh mkj ds fy;s + 8
vad fn;s tk;saxs (vFkkZr~ izR;sd lgh iafDr feyku ds fy, +2
vad fn, tk,asxs) rFkk xyr mkj ds fy;s dksbZ _.kkRed
vadu ugha gS (vFkkZr~ dksbZ vad ugha ?kVk;k tk;sxk)A

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Q.1 Match the column Q.1 LrEHk lqesfyr dhft,
Column-I Column-II LrEHk-I LrEHk-II
(A) [Co(NH3)6]2+ (P) sp3
(A) [Co(NH3)6]2+ (P) sp3
(B) [Cu(NH3)4]2+ (Q) dsp2 (B) [Cu(NH3)4]2+ (Q) dsp2
(C) [Mn Cl4]2 (R) d2sp3 (C) [Mn Cl4]2 (R) d2sp3
(D) [PtCl4]2 (S) Diamagnetic (D) [PtCl4]2 (S) izfrpqEcdh;
(T) Paramagnetic (T) vuqpqEcdh;

Q.2 Column-I Column-II Q.2 LrEHk-I LrEHk-II

(Pair of compounds) (Reagent by which (;kSfxdksa dk ;qXe) (vfHkdeZd ftlds
distinction can be }kjk foHksn dj
made)
OH
ldrs gS)
OH
(A) OH and (P) Na
(A) OH o (P) Na
(B) and Acetone (Q) [Ag(NH3)2](+)OH()
(B) o ,lhVksu (Q) [Ag(NH3)2](+)OH()
OH
OH
OH
(C) and CH3CH (R) NaBrO(Br2/NaOH) OH
|| (C) o CH3CH (R) NaBrO(Br2/NaOH)
O ||
O
OH OH
(D) (S) PhNHNH2 (D) (S) PhNHNH2
and o
(T) None (T) dksbZ ugha

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 MATHEMATICS
Section I
Questions 1 to 8 are multiple choice questions. Each
question has four choices (A), (B), (C) and (D), out of
which ONLY ONE is correct. Mark your response in
OMR sheet against the question number of that
question. + 3 marks will be given for each correct
answer and 1 mark for each wrong answer.
r r r r
f
[k.M - I
iz'u 1 ls 8 rd cgqfodYih iz'u gSaA izR;sd iz'u ds pkj
fodYi (A), (B), (C) rFkk (D) gSa, ftuesa ls dsoy ,d fodYi
lgh gSA OMR 'khV esa iz'u dh iz'u la[;k ds le{k viuk
mkj vafdr dhft;sA izR;sd lgh mkj ds fy, + 3 vad fn;s
tk;asxs rFkk izR;sd xyr mkj ds fy, 1 vad ?kVk;k tk;sxkA
lfn'k ar, b ,oa cr ftuds ifjek.k e'k% 2, 3 ,oa 4 gS]

Q.1 Vectors a , b and c with magnitude 2, 3 & 4 respectively Q.1

r r
are coplanar. A unit vector d is perpendicular to all of leryh; gSA ,d bdkbZ lfn'k d bu lHkh lfn'kksa ds
r r r r i j k r r
them. If (a b) (c d ) = +
6 3 3
and the angle yEcor~ gSA ;fn (ar b) (cr d) = i j + k rFkk ar
6 3 3
r r r r r r
between a and b is 30 then | c.i | + | c.j | + | c.k | is ds e/; dks.k 30 gS] rc | cr.i | + | cr. j | + | cr.k | dk
,oa b
equal to
eku gS -
5 5 5 5
(A) (B) (C) (D)
3 9 12 18 5 5 5 5
(A) (B) (C) (D)
3 9 12 18

Q.2 Every line of the family x (a + 2) + y(1 + 3) = (1 + 2) Q.2 js[kk lewg x (a + 2) + y(1 + 3) = (1 + 2) dh izR;sd
intersects the line 3x 2y = 3 at the same point, js[kk] js[kk 3x 2y = 3 dks leku fcUnq ij izfrPNsnu
where is a parameter and 'a' is constant, then the djrh gS tgk ,d izkpy rFkk 'a' vpjkad gS] rc a
dk eku gS -
value of a is
(A) 0 (B) 4
(A) 0 (B) 4
(C) 2 (D) buesa ls dksbZ ugha
(C) 2 (D) None of these

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 cos 4 x cos x cos 6 x cos 9 x cos 4 x cos x cos 6 x cos 9 x
Q.3 Lim is equal to Q.3 Lim dk eku gS -
x 0 2
ln (1 + sin 4 x ) x 0 ln 2 (1 + sin 4 x )

25 25 25 25
(A) (B) (A) (B)
4 8 4 8
25 25 25 25
(C) (D) (C) (D)
2 4 2 4

Q.4 Circumradius of a ABC is 2, O is the Q.4 ,d ABC dh ifjf=kT;k 2 gS, O ifjdsUnz gS] H yEcdsUnz
circumcentre, H is the orthocentre then
1
gS] rc 1 (AH2 + BC2) (BH2 + AC2) (CH2 + AB2) dk
(AH2 + BC2) (BH2 + AC2) (CH2 + AB2) is 64
64
eku gS -
equal to
(A) 64 (B) 16
(A) 64 (B) 16
1
1 (C) (D) 1
(C) (D) 1 64
64

Q.5 The sum of the infinitely decreasing geometric Q.5 ,d vuUr kleku xq.kkskj Js<+h dk ;ksx] vUrjky
progression is equal to the greatest value of the
[0, 3] esa Qyu f(x) = 3x3 x 76 ds egke eku ds
3
function f(x) = 3x x 76 on interval [0, 3]; the
cjkcj gSA Js<+h dk izFke in lkoZvuqikr ds oxZ ds
first term of the progression is equal to the square
of the common ratio. The common ratio of the cjkcj gSA xq- Js- dk lkoZ vuqikr gS -
G.P. is- (A) 2 1 (B) 3 1
(A) 2 1 (B) 3 1 1
(C) 2 +1 (D)
1 3 +1
(C) 2 +1 (D)
3 +1
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Q.6 The number of values of k for which, the equation Q.6 k ds ekuksa dh la[;k ftuds fy, lehdj.k
f(x) = x3 12x + k = 0 has two real distinct roots in f(x) = x3 12x + k = 0 ds nks fofHkUu okLrfod ewy
the interval (2, 3) is-
vUrjky (2, 3) esa fLFkr gks] gksxh -
(A) 0 (B) 1 (A) 0 (B) 1
(C) 2 (D) 3 (C) 2 (D) 3
1 1 1 1 1 1 1 1
Q.7 lim + + + ..... + is equal to Q.7 lim + + + ..... + dk eku gS -
n n 2n 3n 2n n n 2n 3n 2n
(A) 0 (B) 1 (A) 0 (B) 1
(C) 2 (D) 4 (C) 2 (D) 4
Q.8 Consider f(x) = log441 (sin2 x 20 cos x + 1), then- Q.8 ekukfd f(x) = log441 (sin2 x 20 cos x + 1), rc -
(A) f(x) is many one & bounded function (A) f(x) cgq,sdh ,oa ifjc) Qyu gS
(B) f(x) is many one & unbounded function
(B) f(x) cgq,sdh ,oa vifjc) Qyu gS
(C) f(x) is one-one & bounded function
(D) f(x) is one-one & unbounded function (C) f(x) ,dSdh ,oa ifjc) Qyu gS
(D) f(x) ,dSdh ,oa vifjc) Qyu gS
Questions 9 to 12 are multiple choice questions. Each iz'u 9 ls 12 rd cgqfodYih iz'u gaSA izR;sd iz'u ds pkj
question has four choices (A), (B), (C) and (D), out of fodYi (A), (B), (C) rFkk (D) gSa] ftuesa ls ,d ;k ,d ls
which MULTIPLE (ONE OR MORE) is correct. Mark vf/kd fodYi lgh gaSA OMR 'khV esa iz'u dh iz'u la[;k ds
your response in OMR sheet against the question le{k vius mkj vafdr dhft,A izR;sd lgh mkj ds fy,
number of that question. + 4 marks will be given for each + 4 vad fn;s tk;saxs rFkk izR;sd xyr mkj ds fy, 1 vad
correct answer and 1 mark for each wrong answer. ?kVk;k tk;sxkA
Q.9 If f(x) and g(x) are two increasing and differentiable Q.9 ;fn f(x) ,oa g(x) nks o/kZeku rFkk vodyuh; Qyu
function such that f(x), g(x) > 0 x R, then- bl izdkj gSa] fd f(x), g(x) > 0 x R, rc -
(A) (f(x))g(x) is always increasing (A) (f(x))g(x) ges'kk o/kZeku gS
(B) If f(x) > 1, then (f(x))g(x) is increasing (B) ;fn f(x) > 1, rc (f(x))g(x) o/kZeku gS
(C) If (f(x))g(x) is decreasing then f(x) < 1 (C) ;fn (f(x))g(x) kleku gS] rc f(x) < 1
(D) If (f(x))g(x) is decreasing then f(x) > 1 (D) ;fn (f(x))g(x) kleku gS] rc f(x) > 1

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 3x 1 x 2 x 2
If f(x) = ln (3x + 9 x 2 + 1) + Q. 10 ;fn f(x) = ln (3x + 9x 2 + 1) + 3x 1 + x ,
3x + 1 + 2m + 1
Q. 10
3 + 1 2m + 1

is an odd function x [ 8 , 8 ] , (where [] x [ 8 , 8 ] , ,d fo"ke Qyu gS (tgk [] egke
denotes greatest integer function) then possible iw.kkd Qyu dks O;Dr djrk gS) rc m ds lEHko
integer value(s) of m is (are)- iw.kkd eku gSa -
(A) 4 (B) 5
(C) 6 (D) 9 (A) 4 (B) 5
(C) 6 (D) 9
Q.11 The general solution of the differential equation Q.11 vody lehdj.k ex dx = 1 e 2 x dy dk O;kid
x
e dx = 1 e 2 x dy is- gy gS -
(A) y = k cos1 (ex) (A) y = k cos1 (ex)
(B) y = sin1(ex) + c (B) y = sin1(ex) + c
(C) y = sin1 1 e 2 x + c (C) y = sin1 1 e 2 x + c
(D) y = cos 1 1 e 2 x + c (D) y = cos 1 1 e 2 x + c

1 1
Q.12 Consider the equation 2 = k , now which Q.12 ekukfd lehdj.k 2 =k, fuEu esa ls dkSulk
| x 1| | x 1|
of the following is true- dFku lR; gS -
(A) The given equation has 4 solution if k (0, 2) (A) nh xbZ lehdj.k ds 4 gy gksaxs ;fn k (0, 2)
(B) There is no value of k for which given equation (B) ;gk k dk dksbZ eku ugha gS ftlds fy, nh xbZ
has exactly two solutions lehdj.k ds Bhd nks gy gks
(C) There is no value of k for which given equation (C) ;gk k dk dksbZ eku ugha gS ftlds fy, nh xbZ
has exactly one solution
lehdj.k dk Bhd ,d gy gks
(D) buesa ls dksbZ ugha
(D) None of these

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 This section contains 2 paragraphs; each has 3 multiple
choice questions. (Questions 13 to 18) Each question has
4 choices (A), (B), (C) and (D) out of which ONLY ONE
is correct. Mark your response in OMR sheet against the
question number of that question. + 4 marks will be
given for each correct answer and 1 mark for each
wrong answer.
Passage # 1 (Ques. 13 to 15)
The base of a pyramid is rectangular, three of its
vertices of the base are A(2, 2, 1), B(3, 1, 2) and
C(1, 1, 1) (may or may not be in order). Its vertex at
26 10
the top is P 4, , and fourth vertex of the
3 3
base is D.
bl [k.M esa 2 vuqPNsn fn;s x;s gSa] izR;sd esa 3 cgqfodYih
iz'u gSaA (iz'u 13 ls 18) izR;sd iz'u ds pkj fodYi (A), (B),
(C) rFkk (D) gSa, ftuesa ls dsoy ,d fodYi lgh gSA OMR
'khV esa iz'u dh iz'u la[;k ds le{k viuk mkj vafdr
dhft;sA izR;sd lgh mkj ds fy;s + 4 vad fn;s tk,saxs rFkk
izR;sd xyr mkj ds fy, 1 vad ?kVk;k tk;sxkA
x|ka'k # 1 (iz- 13 ls 15)
,d fijkfeM dk vk/kkj vk;rkdkj gS] blds vk/kkj ds
rhu 'kh"kZ A(2, 2, 1), B(3, 1, 2) ,oa C(1, 1, 1) gS (e
esa gks Hkh ldrs gSa vkSj ugha Hkh), blds f'k[kj dk 'kh"kZ
26 10
P 4, , gS rFkk vk/kkj dk pkSFkk 'kh"kZ D gSA
3 3

Q.13 Coordinates of D are Q.13 D ds funsZ'kkad gS -

(A) (4, 0, 2) (B) (4, 2, 0) (A) (4, 0, 2) (B) (4, 2, 0)
(C) (2, 0, 4) (D) (0, 2, 4) (C) (2, 0, 4) (D) (0, 2, 4)

Q.14 Coordinates of foot of the normal drawn from P on Q.14 P ls fijkfeM ds vk/kkj ij Mkys x, yEc ds ikn ds
the base of the pyramid are-
funsZ'kkad gS -
(A) 2, , (B) 2, ,
4 2 2 4
(A) 2, , (B) 2, ,
4 2 2 4
3 3 3 3
3 3 3 3
(C) ,2, (D) , ,2
4 2 2 4
(C) ,2, (D) , ,2
4 2 2 4
3 3 3 3
3 3 3 3

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Q.15 Volume of the pyramid is (in cubic units) Q.15 fijkfeM dk vk;ru (?ku bdkbZ esa) gS
(A) 20 (B) 10 (C) 40 (D) 30 (A) 20 (B) 10 (C) 40 (D) 30

Passage # 2 (Ques. 16 to 18) x|ka'k # 2 (iz- 16 ls 18)

If set of values of 'p' for which the straight line ;fn 'p' ds ekuksa dk leqPp; ftuds fy, ljy js[kk
2px 2y p = 0 intersects the curve y = sin1(2x 1) 2px 2y p = 0 o y = sin1(2x 1) dks rhu fofHkUu
at three distinct points is [, ]. Let C1 & C2 be two fcUnqvksa ij izfrPNsnu djrh gS] [, ] gSA ekuk C1 ,oa
curves as: C2 nks o bl izdkj gS] fd
x2 y2 4
C1 : + = 1 , C2: y = [] + x2 y2 4
2
([] 1) 2
x C1 : + = 1 , C2: y = [] +
2
([] 1) 2
x
Where [] denotes greatest integer function tgk []egke iw.kkd Qyu dks O;Dr djrk gSA
+ 2 + 2
Q.16


(| sin x | cos x )dx is equal to- Q.16
(| sin x | cos x)dx dk eku gS -

(A) 0 (B) 2 (A) 0 (B) 2
(C) 4 (D) 8 (C) 4 (D) 8

Q.17 The probability that a point is chosen which lie Q.17 ,d fcUnq dks pquus dh izkf;drk tks o C1 ds vUnj
inside the curve C1 but at a distance greater than
fLFkr gks ijUrq ewyfcUnq ls ftldh nwjh 2 bdkbZ ls
2 units from the origin is- vf/kd gks] gksxh -
1 1 1 2
(A) (B) (C) (D) 1 1 1 2
2 3 4 3 (A) (B) (C) (D)
2 3 4 3
Q.18 If a tangent is drawn to the curve C2 which is Q.18 ;fn o C2 dh ,d Li'kZjs[kk [khaph tkrh gS] tks fcUnq
passing through the point ([], 3 + 1) and meets ([], 3 + 1) ls xqtjrh gS rFkk js[kkvksa x = ,oa
the lines x = and y = [] at P and Q, then mid y = []dks fcUnq P ,oa Q ij feyrh gS] rc PQ dk
point of PQ is- e/; fcUnq gS -
(A) (, []) (B) (2 1, 2[] + 1) (A) (, []) (B) (2 1, 2[] + 1)
(C) ([], ) (D) (2 + 1, 3[] 1) (C) ([], ) (D) (2 + 1, 3[] 1)

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 Section - II
This section contains 2 questions (Questions 1,
Each question contains statements given in two
columns which have to be matched. Statements (A, B,
C, D) in Column I have to be matched with statements
(P, Q, R, S, T) in Column II. The answers to these
questions have to be appropriately bubbled as
illustrated in the following example. If the correct
matches are A-P, A-S, A-T; B-Q, B-R; C-P, C-Q and
D-S, D-T then the correctly bubbled 4 5 matrix
should be as follows :
[k.M - II
2).
bl [k.M esa 2 iz'u (iz'u 1, 2) gSaA izR;sd iz'u esa nks
LrEHkksa esa dFku fn;s x;s gSa] ftUgsa lqesfyr djuk gSA
LrEHk-I (Column I ) esa fn;s x;s dFkuksa (A, B, C, D) dks
LrEHk-II (Column II) esa fn;s x;s dFkuksa (P, Q, R, S,T) ls
lqesy djuk gSA bu iz'uksa ds mkj uhps fn;s x;s mnkgj.k
ds vuqlkj mfpr xksyksa dks dkyk djds n'kkZuk gSA ;fn
lgh lqesy A-P, A-S, A-T; B-Q, B-R; C-P, C-Q rFkk
D-S, D-T gS, rks lgh fof/k ls dkys fd;s x;s xksyksa dk
4 5 eSfVDl uhps n'kkZ;s vuqlkj gksxk

P Q R S T P Q R S T
A P Q R S T A P Q R S T
B P Q R S T B P Q R S T
C P Q R S T C P Q R S T
D P Q R S T D P Q R S T

Mark your response in OMR sheet against the
question number of that question in section-II. + 8
marks will be given for complete correct answer (i.e.
+2 marks for each correct row) and No Negative
marks for wrong answer.
vr% OMR 'khV esa iz'u dh iz'u la[;k ds le{k viuk mkj
[k.M-II esa vafdr dhft;sA izR;sd iw.kZ lgh mkj ds fy;s + 8
vad fn;s tk;saxs (vFkkZr~ izR;sd lgh iafDr feyku ds fy, +2
vad fn, tk,asxs) rFkk xyr mkj ds fy;s dksbZ _.kkRed vadu
ugha gS (vFkkZr~ dksbZ vad ugha ?kVk;k tk;sxk)A

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Q.1 Column-I Column-II Q.1 LrEHk-I LrEHk-II
(A) Let x be the set of all 15 digit (P) 1 (A) ekuk x lHkh 15 vadh; iw.kkdksa (P) 1

integers. An integer is chosen dk leqPp; gSA x esa ls ;knPN;k

at random for x. The probability ,d iw.kkd pquk tkrk gSA blds
1 palindrome (og iw.kkd tks mYVk
that it is a palindrome is
10 n rFkk lh/kk ,d leku i<+k tk,)
then the value of n is gksus dh izkf;drk 1n gS] rc n
n
(B) If the coefficient of x in the expansion (Q) 4 10
dk eku gS
(1 + x )3
of is 102, then the value
(1 x )3 (1 + x )3
(B) ;fn ds izlkj esa xn dk (Q) 4
(1 x )3
of n equals to
(C) The least distance of a point on (R) 5 xq.kkad 102 gS] rc n dk eku gS
the ellipse x2 + 2y2 = 6 from the (C) nh?kZok x2 + 2y2 = 6 ij fLFkr (R) 5

n ,d fcUnq dh js[kk x + y = 7 ls
line x + y = 7 is , then n is
2 U;wure nwjh n gS] rc n cjkcj gS
2
(D) f : R R and satisfies f(2) = 1, (S) 7
3
(D) f : R R rFkk f(2) = 1, f '(2) = 4 (S) 7
f '(2) = 4. If
(3 x) f "(x) = 7
2
dks lUrq"V djrk gSA ;fn
3

then f(3) has the value equal to (T) 10 (3 x) f "(x) = 7 rc f(3)

2

dk eku gS (T) 10

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Q.2 Column-I Column-II Q.2 LrEHk-I LrEHk-II
(A) A line l intersect the graph of (P) 0
(A) ,d js[kk l Qyu (P) 0
4 3
f(x) = 2x + 7x + 3x 5 at 4 3
f(x) = 2x + 7x + 3x 5 ds xzkQ
four points (xr, yr) where dks pkj fcUnqvksa (xr, yr) tgk
4 r = 1, 2, 3, 4 ij izfrPNsn
r = 1, 2, 3, 4 then 2 x r
is 4
r =1 djrh gS] rc 2 x r dk eku gS
r =1
(B) f(x) = 10 + 4x ln9 33x 3x1 (Q) 7
(B) f(x) = 10 + 4x ln9 33x 3x1 (Q) 7
is greatest at x = a,
dk egke eku x = a ij gS] rc
then a is a cjkcj gS
(C) If y = ax3 + bx2 + cx + d has (R) 5 (C) ;fn y = ax3 + bx2 + cx + d (R) 5
horizontal tangent at (2, 6) fcUnq (2, 6) ,oa (2, 0) ij
and (2, 0) then 'd' is Li'kZ js[kk {kSfrt gS] rc
1/ 2
'd' dk eku gS
8x e 2 x
(D) If
dx = a then [a] is (S) 3 1/ 2
8x e 2 x
0
(1 + 2 x ) 2 (D) ;fn

0
(1 + 2 x ) 2
dx = a rc [a] (S) 3

equal to where [] is greatest integer

cjkcj gS tgk [] egke iw.kkd
function Qyu gS
(T) 9 (T) 9

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 PHYSICS
Section I
Questions 1 to 8 are multiple choice questions. Each
question has four choices (A), (B), (C) and (D), out of
which ONLY ONE is correct. Mark your response in
OMR sheet against the question number of that
question. + 3 marks will be given for each correct
answer and 1 mark for each wrong answer.
Q.1 An ideal gas obey the relation of P1/2V2 = constant.
The coefficient of volume expansion of the gas is :
(where T is the absolute temperature)
(A) 1/3T (B) 1/3T (C) 1/2T (D) 1/2T
[k.M - I
iz'u 1 ls 8 rd cgqfodYih iz'u gSaA izR;sd iz'u ds pkj
fodYi (A), (B), (C) rFkk (D) gSa, ftuesa ls dsoy ,d fodYi
lgh gSA OMR 'khV esa iz'u dh iz'u la[;k ds le{k viuk
mkj vafdr dhft;sA izR;sd lgh mkj ds fy, + 3 vad fn;s
tk;asxs rFkk izR;sd xyr mkj ds fy, 1 vad ?kVk;k tk;sxkA
Q.1 ,d vkn'kZ xSl lEcU/k P1/2V2 = fu;rkad dk ikyu
djrh gSA xSl dk vk;ru izlkj xq.kkad gksxk (tgk T
ije rki gS)
(A) 1/3T (B) 1/3T (C) 1/2T (D) 1/2T

Q.2 Two lights beams of different colours pass through Q.2 fHkUu-fHkUu jaxksa dh nks izdk'k iqat fizTe ls xqtjrh gSA
the prism. Inside the prism, their paths are shown fizTe ds vUnj] muds iFk fp=k esa n'kkZ;s x;s gSA fuEUk
in the figure. Which of the following statements is esa ls dkSulk dFku xyr gS
wrong :

Air 100 Air Air 100 Air

40 40 40 40
Yellow light
Yellow light
beam
40 40 40 beam 40
blue light
blue light
beam
beam

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 (A) The yellow light beam suffers minimum (A) ihyh izdk'k iqt
a U;wure fopyu iznf'kZr djrh gS
deviation (B) uhyh izdk'k iaqt dk fopyu ihys ls vf/kd gS
(B) The blue light beam suffers deviation larger
(C) nksuksa iaqt U;wure fopyu dk leku ifjek.k
than yellow
j[krh gS
(C) Both the beams have same magnitude of
(D) nksuksa iqat nf{k.kkorZ fn'kk eas fopyu iznf'kZr
minimum deviation

(D) Both the beams suffer deviation in clockwise djrh gS

sense

Q.3 If the power dissipated in the resister configuration Q.3 ;fn izfrjks/kksa ds vfHkfoU;kl I, II, III esa O;f;r 'kfDr
I, II, III is P1, P2, P3 respectively, then correct order e'k% P1, P2, P3 gS] rc mudk lgh e gS
of them is

1 1 5V
1 1
1 1 5V
1 1
1 4 2 2 5V 1
1 1
1
4 2 2 5V 1
1 1
3
(II)
3
(I)
(II)
(I)

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 1 1

1 1
3 2 3 2

2 2

5V 5V
(III) (III)
(A) P1 > P2 > P3 (B) P3 > P2 > P1 (A) P1 > P2 > P3 (B) P3 > P2 > P1
(C) P1 > P2 = P3 (D) P2 > P3 > P1 (C) P1 > P2 = P3 (D) P2 > P3 > P1

Q.4 Three point charges are located on circumference of Q.4 fp=kkuqlkj 2.5 m f=kT;k ds ok dh ifjf/k ij nks fcUnq
circle of radius 2.5 m as shown in figure. The vkos'k j[ks x;s gSA vkos'k 2q dh fLFkjoS/kqfrdh
electrostatic interaction potential energy of charge 2q is- var%f;k fLFkfrt tkZ gksxh
y (metre) y (metre)

( 5 , 2) ( 5 , 2)
2q 2q
x q x
q (0, 0) O
(0, 0) O (metre) (metre)

q q

16 2 37 2 16 2 37 2
(A) kq (B) kq (A) kq (B) kq
15 30 15 30

43 2 28 2 43 2 28 2
(C) kq (D) kq (C) kq (D) kq
30 45 30 45

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Q.5 The open glass tube has uniform cross-section and Q.5 dkp dh [kqyh uyh ,dleku vuqizLFk dkV j[krh gS
a valve separating the two identical ends. The valve
rFkk nks le:i fljksa ds ,d okYo iFkd djrk gSA
is initially closed end 1 has planer film of soap
izkjEHk eas okYo cUn gS rc fljk 1 lkcqu ds cqycqys
bubble and end 2 has a soap bubble having radius
of curvature r. Immediately after opening the dh lery fQYe gS rFkk fljk 2, r ork f=kT;k dk
valve. lkcwu dk cqycqyk gSA okYo dks [kksyus ds rqjUr ckn
valve valve
2 2
r r
1 1
Planer soap film Planer soap film
(A) ok;q fljs 1 ls fljs 2 dh vksj izokfgr gksrh gSA
(A) Air from end 1 flows towards end 2. The
volume of soap bubble at end 2 increases fljs 2 ij lkcwu ds cqycqys dk vk;ru c<+rk gS
(B) Air from end 2 flows towards end 1. The (B) ok;q fljs 2 ls fljs 1 dh vksj izokfgr gksrh gSA
volume of soap bubble at end 2 increases fljs 2 ij lkcwu ds cqycqys dk vk;ru c<+rk gS
(C) Air from end 2 flow towards end 1. The (C) ok;q fljs 2 ls fljs 1 dh vksj izokfgr gksrh gSA
volume of soap bubble at end 2 decreases fljs 2 ij lkcwu ds cqycqys dk vk;ru ?kVrk gSA
(D) no change occurs (D) dksbZ ifjorZu izkIr ugha gksrk gS

Q.6 A small block describes the vertical circular motion Q.6
inside the smooth spherical cavity of radius R. The
speed at the lowest position A is just sufficient to
make it reach the highest point B. The angle at
which the speed of the block is three fifth of the
largest speed satisfies
Space for rough work
,d NksVk CykWd R f=kT;k dh ?k"kZ.kghu xksykdkj xqfgdk
ds vUnj /okZ/kj okh; xfr djrk gSA fuEure fLFkr
A ij pky mls mPpre fcUnq B rd igqpus ds fy;s
Bhd i;kZIr gSA dks.k ftl ij CykWd dh pky
vf/kdre pky dh 3/5 gS] rks lUrq"V djrk gS

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 B B

R R
C C

A A

3 3
(A) << (B) << (A) << (B) <<
4 3 3 4 4 3 3 4
3 5 5 3 5 5
(C) << (D) << (C) << (D) <<
4 6 6 4 6 6
Q.7 A parallel plate capacitor has plate area A and Q.7 ,d lekUrj IysV la/kkfj=k dk IysV {ks=kQy A rFkk
separation d. Initially it is completely filled with iFkdj.k d gSA izkjEHk esa mls K = 3 ijkoS|qrkad ds
material of dielectric constant K = 3. The width x inkFkZ ls iw.kZr;k Hkjk x;k gSA Hkjs gq;s inkFkZ dh
of filled material decreases at a constant speed v as pkSM+kbZ x fp=kkuqlkj fu;r pky v ls ?kVrh gSA le;
shown in figure. For time interval 0 < t < l , time vUrjky 0 < t < l ds fy;s] ifjiFk dk le;
v v

constant of circuit varies as

fu;rkad fuEu ds vuqlkj ifjofrZr gksrk gS
R
R

d
d v
v x
x
l
l
R 0 A 2 vt R 0 A 2 vt
R 0 A 2 vt R 0 A 2 vt (A) 3 (B) 1+
(A) 3 (B) 1+ d l d l
d l d l
R 0 A 2 vt R 0 A 2 vt
R 0 A 2 vt R 0 A 2 vt (C) 3+ (D) 1
(C) 3+ (D) 1 d l d l
d l d l
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Q.8 A transparent cube of 0.21 m edge contains a small Q.8 0.21 ehVj Hkqtk dk ,d ikjn'khZ ?ku ,d NksVk ok;q
air bubble. Its apparent distance when viewed dk cqycwyk j[krk gSA bldh vkHkklh nwjh tc bls
through one face of cube is 0.1 m and viewed from ?ku ds ,d Qyd ls ns[kk tk,] 0.1 m gS rFkk
opposite face is 0.04 m. The actual distance of the foijhr Qyd ls ns[kus ij 0.04 m gSA ?ku ds f}rh;
bubble from the second face of the cube is- Qyd ls cqycwys dh okLrfod nwjh gS -
(A) 0.06 m (B) 0.17 m (A) 0.06 m (B) 0.17 m
(C) 0.05 m (D) 0.04 m (C) 0.05 m (D) 0.04 m

Questions 9 to 12 are multiple choice questions. Each
question has four choices (A), (B), (C) and (D), out of
which MULTIPLE (ONE OR MORE) is correct. Mark
your response in OMR sheet against the question
number of that question. + 4 marks will be given for each
correct answer and 1 mark for each wrong answer.
Q.9 The coefficient of friction between the block and
plank is and its value is such that block becomes
stationary with respect to plank before it reaches
the other end. Then-
m v0
M M
(A) the work done by friction on the block is
negative
(B) the work done by friction on the plank is
positive
(C) the net work done by friction is negative
(D) net work done by the friction is zero
iz'u 9 ls 12 rd cgqfodYih iz'u gaSA izR;sd iz'u ds pkj
fodYi (A), (B), (C) rFkk (D) gSa] ftuesa ls ,d ;k ,d ls
vf/kd fodYi lgh gaSA OMR 'khV esa iz'u dh iz'u la[;k ds
le{k vius mkj vafdr dhft,A izR;sd lgh mkj ds fy,
+ 4 vad fn;s tk;saxs rFkk izR;sd xyr mkj ds fy, 1 vad
?kVk;k tk;sxkA
Q.9 CykWd rFkk r[rsa ds e/; ?k"kZ.k xq.kkad gS rFkk
mldk eku bl izdkj gS fd CykWd r[rsa ds nwljs fljs
rd igqpus rd r[rs ds lkis{k fLFkj gks tkrk gSA rc
v0
m
(A) CykWd ij ?k"kZ.k }kjk fd;k x;k dk;Z _.kkRed gS
(B) r[rs ij ?k"kZ.k }kjk fd;k x;k dk;Z /kukRed gS
(C) ?k"kZ.k }kjk fd;k x;k usV dk;Z _.kkRed gS
(D) ?k"kZ.k }kjk fd;k x;k usV dk;Z 'kwU; gS

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Q.10 A charged particle of unit mass and unit charge
moves with velocity of v = (8 ^i + 6 ^j) m/s in a
magnetic field of B = 2 k^ T . Choose the correct
alternative(s).
(A) The path of the particle may be
x2 + y2 4x 21 = 0
(B) The path of the particle may be x2 + y2 = 25
(C) The path of the particle may be y2 + z2 = 25
(D) The time period of the particle will be 3.14s
Q.11 An object of length 1 cm is placed on a principle
axis of biconvex lens of radius 5 cm. Distance
between the lens and object is 20 cm. Space
between the lens and object is filled with medium
of two different refractive index 2 and 1 as shown
in the figure. Refractive index is 1 on the left of the
object and on the right side of the lens. Boundary of
both medium is mid-way between the object and
lens as shown in figure.
1 cm =2 =1 =1
1.5
10 cm 10 cm
(A) The image will be formed at distance of
7.5 cm from the optical centre
(B) The image will be formed at distance of
10 cm from the optical centre
(C) The size of the image is 0.5 cm
(D) The size of the image is 0.4 cm
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Q.10 bdkbZ nzO;eku rFkk bdkbZ vkos'k dk ,d vkosf'kr
d.k osx v = (8 ^i + 6 ^j) m/s ls B = 2 k^ T ds pqEcdh;
{ks=k esa xfr djrk gSA lgh fodYi@fodYiksa dk p;u
dhft,A
(A) d.k dk iFk fuEu gks ldrk gS
x2 + y2 4x 21 = 0
(B) d.k dk iFk x2 + y2 = 25 gks ldrk gS
(C) d.k dk iFk y2 + z2 = 25 gks ldrk gS
(D) d.k dk vkorZdky 3.14s gksxk
Q.11 1 cm yEckbZ dh ,d oLrq dks 5 cm f=kT;k ds f}mky
ysUl dh eq[; v{k ij j[kk tkrk gSA ysUl rFkk oLrq
ds e/; nwjh 20 cm gSA ysUl rFkk oLrq ds e/; ds
LFkku dks nks fHkUu-fHkUu viorZukadksa ds ek/;e 1 o 2
ls fp=kkuqlkj Hkjk x;k gSA oLrq ds ck;as ij rFkk ysUl
dh nk;ha rjQ viorZukad 1 gSA nksuksa ek/;e dh lhek
fp=kkuqlkj oLrq o ysUl ds ek/; esa gSA
1 cm =2 =1 =1
1.5
10 cm 10 cm
(A) izfrfcEc izdkf'kd dsUnz ls 7.5 cm dh nwjh ij
cusxk
(B) izfrfcEc izdkf'kd dsUnz ls 10 cm dh nwjh ij cusxk
(C) izfrfcEc dk vkdkj 0.5 cm gS
(D) izfrfcEc dk vkdkj 0.4 cm gS
Page # 27
Q.12 Radiations of monochromatic waves of
wavelength 400 nm are made incident on the
surface of metals Zn, Fe and Ni of work
functions 3.4 eV, 4.8 eV and 5.9 eV
respectively (take hc = 12400 eV-) :
(A) maximum KE associated with
photoelectrons from the surface of any
metal is 0.3 eV
(B) no photoelectrons are emitted from the
surface of Ni
(C) if the wavelength of source of radiation is
doubled then KE of photoelectrons is also
doubled
(D) photoelectrons will be emitted from the
surface of all the three metals if the
wavelength of incident radiations is less
than 200 nm
This section contains 2 paragraphs; each has 3
multiple choice questions. (Questions 13 to 18) Each
question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct. Mark your response
in OMR sheet against the question number of that
question. + 4 marks will be given for each correct
answer and 1 mark for each wrong answer.
Space for rough work
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Q.12 400 nm rjaxnS/;Z dh ,do.khZ rjaxksa dh fofdj.ksa
Zn, Fe rFkk Ni /kkrqvksa dh lrg ij vkifrr gksrh
gS rFkk ftudk dk;ZQyu e'k% 3.4 eV, 4.8 eV o
5.9 eV gS (hc = 12400 eV- ysa) :
(A) fdlh Hkh /kkrq dh lrg ls QksVksbysDVkWuksa ls
lEcfU/kr vf/kdre KE, 0.3 eV gS
(B) Ni dh lrg ls QksVksbysDVkWu mRlftZr ugha
gksrs gS
(C) ;fn fofdj.k ds L=kksr dh rjaxnS/;Z nqxquh dj
nh tk;s rc QksVksbysDVkWuksa dh KE Hkh nqxquh
gks tkrh gS
(D) lHkh rhu /kkrqvksa dh lrg ls QksVksbysDVkWu
mRlftZr gksxsa ;fn vkifrr fofdj.kksa dh
rjaxnS/;Z 200 nm ls de gksrh gS
bl [k.M esa 2 vuqPNsn fn;s x;s gSa] izR;sd esa 3
cgqfodYih iz'u gSaA (iz'u 13 ls 18) izR;sd iz'u ds pkj
fodYi (A), (B), (C) rFkk (D) gSa, ftuesa ls dsoy ,d
fodYi lgh gSA OMR 'khV esa iz'u dh iz'u la[;k ds
le{k viuk mkj vafdr dhft;sA izR;sd lgh mkj ds
fy;s + 4 vad fn;s tk,saxs rFkk izR;sd xyr mkj ds fy,
1 vad ?kVk;k tk;sxkA
Page # 28
Passage # 1 (Ques. 13 to 15) x|ka'k # 1 (iz- 13 ls 15)
A hydrogen atom in third excited state makes a rhljh mksftr voLFkk esa fLFkr ,d gkbMkstu
transition to first excited state and emit photon. ijek.kq igyh mksfrt voLFkk esa lae.k dj
This emitted photon is absorbed by He+ ion QksVkWu mRlftZr djrk gSA ;g mRlftZr QksVkWu
He+ vk;u }kjk vo'kksf"kr gksrk gS tks igys ls
which was already in seventh excited state.
lkroha mksftr voLFkk FkkA QksVkWu ds vo'kks"k.k ds
After absorption of photon He+ ion jumps from ckn He+ vk;u lkroha mksftr voLFkk ls n
seventh excited state to an excited state having Dok.Ve la[;k okyh ,d mksftr voLFkk esa Nykax
quantum number nf. yxkrk gSA
Q.13 The quantum number nf of the state finally Q.13 He+ vk;u esa vfUre voLFkk esa mifLFkr Dok.Ve
populated in He+ ion la[;k n gS
(A) 8 (B) 10 (A) 8 (B) 10
(C) 16 (D) 20 (C) 16 (D) 20

Q.14 Now He+ ion jumps to lower state by emitting Q.14 vc He+ vk;u n`'; izdk'k ds ,dy QksVkWu P
single photon P of visible light. The energy of ds mRltZu }kjk fupys Lrj esa Nykax yxkrk gSA
this photon is as possible as close to energy of bl QksVkWu dh tkZ He+ vk;u (x|ka'k esa O;k[;k
the absorbed photon by He+ ion (as mentioned ds vuqlkj) }kjk vo'kksf"kr QksVkWu dh tkZ ds
in paragraph). Then wavelength of this photon yxHkx cjkcj gksrh gSA rc bl QksVkWu P dh
P is nearly. rjaxnS/;Z yxHkx gS
(A) 6760 (B) 5000 (A) 6760 (B) 5000
(C) 4480 (D) 3500 (C) 4480 (D) 3500

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Q.15 The ratio of the kinetic energy of the n = 4
electron for H atom to that He+ ion is P1 and the
ratio of the total energy of the n = 6 electron for
the H atom to that of He+ ion is P2. Then ratio
P1/P2 is
(A) 1 (B) 9/4
(C) 4/9 (D) 4
Passage # 2 (Ques. 16 to 18)
A uniform solid sphere of mass M and radius R
is attached to four identical light springs of
spring constant k which are fixed to walls as
shown in figure. The springs are attached
symmetrically to the axle of the sphere as
shown in figure. The axle is mass less and all
the springs and the axle are in horizontal plane.
The unstretched length of each spring is L. The
sphere is initially at its equilibrium position
with its centre of mass (CM) at a distance L
from the each wall. The sphere rolls without
^
slipping with initial velocity v 0 = v 0 i and
angular velocity 0. The coefficient of friction
is .
Space for rough work
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Q.15 H ijek.kq rFkk He+ vk;u ds fy;s n = 4 bysDVkWu
dh xfrt tkZ dk vuqikr P1 gS rFkk H ijek.kq
o He+ vk;u ds fy;s n = 6 bysDVkWu dh dqy
tkZ dk vuqikr P2 gSA rc vuqikr P1/P2 gS
(A) 1 (B) 9/4
(C) 4/9 (D) 4
x|ka'k # 2 (iz- 16 ls 18)
M nzO;eku rFkk R f=kT;k ds ,d ,dleku Bksl
xksys dks k cy fu;rkad dh pkj le:i gYdh
fLizaxksa tks fp=kkuqlkj nhokjksa ls dlh gqbZ gS ls
tksM+k x;k gSA fLiazxsa xksys dh v{k (axle) ls
fp=kkuqlkj lefer :i ls tksM+h xbZ gSA v{k
nzO;ekughu rFkk lHkh fLizaxsa rFkk v{k {kSfrt ry
esa gSA izR;sd fLiazx dh vfoLrkfjr yEckbZ L gSA
xksyk izkjEHk esa izR;sd nhokj ls L nwjh ij mlds
nzO;eku dsUnz (CM) ls viuh lkE;koLFkk fLFkfr
^
ij gSA xksyk izkjfEHkd osx v 0 = v 0 i rFkk dks.kh;
osx 0 ls fcuk fQlys yq<+drk gSA ?k"kZ.k xq.kkad
gSA
Page # 30
 y y
2d k 2d k
k k k k
v0 v0
k k
2d 2d
x x
Q.16 The net external force acting on the sphere Q.16 xksys ij dk;Zjr usV ckg~; cy tc mldh
when its centre of mass is at displacement x lkE;koLFkk fLFkfr ds lkis{k mldk nzO;eku dsUnz
with respect to its equilibrium position is x foLFkkiu ij gS-
(A) 10 kx (B) 20/7 kx
(A) 10 kx (B) 20/7 kx
(C) 2/5 kx (D) 7/5 kx
(C) 2/5 kx (D) 7/5 kx
Q.17 The centre of mass of the sphere undergoes Q.17 xksys dk nzO;eku dsUnz T vkorZdky ls ljy
simple harmonic motion time period T equal to vkorZ xfr djrk gS] T cjkcj gS
7M M 7M M
(A) 2 (B) 2 (A) 2 (B) 2
20k 10k 20k 10k

5M 5M 5M 5M
(C) 2 (D) 2 (C) 2 (D) 2
2k 7k 2k 7k

Q.18 The maximum value of angular velocity 0 Q.18 nzO;eku dsUnz ds lkis{k dks.kh; osx 0 dk
about centre of mass for which sphere will roll vf/kdre eku ftlds fy,s xksyk fcuk fQlys
without slipping is yq<dsxk] gS
g 7M g 7M g 7M g 7M
(A) (B) (A) (B)
R 5k R 20k R 5k R 20k
g 49M g 35M
g 49M g 35M (C) (D)
(C) (D) R 5k R 16k
R 5k R 16k
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 Section - II [k.M - II
This section contains 2 questions (Questions 1, 2). bl [k.M esa 2 iz'u (iz'u 1, 2) gSaA izR;sd iz'u esa nks
Each question contains statements given in two LrEHkksa esa dFku fn;s x;s gSa] ftUgsa lqesfyr djuk gSA
columns which have to be matched. Statements (A, B,
LrEHk-I (Column I ) esa fn;s x;s dFkuksa (A, B, C, D) dks
C, D) in Column I have to be matched with
LrEHk-II (Column II) esa fn;s x;s dFkuksa (P, Q, R, S,T) ls
statements (P, Q, R, S, T) in Column II. The answers
lqesy djuk gSA bu iz'uksa ds mkj uhps fn;s x;s
to these questions have to be appropriately bubbled
mnkgj.k ds vuqlkj mfpr xksyksa dks dkyk djds n'kkZuk
as illustrated in the following example. If the correct
matches are A-P, A-S, A-T; B-Q, B-R; C-P, C-Q and
gSA ;fn lgh lqesy A-P, A-S, A-T; B-Q, B-R; C-P, C-
D-S, D-T then the correctly bubbled 4 5 matrix Q rFkk D-S, D-T gS, rks lgh fof/k ls dkys fd;s x;s
should be as follows : xksyksa dk 4 5 eSfVDl uhps n'kkZ;s vuqlkj gksxk
P Q R S T P Q R S T
A P Q R S T A P Q R S T
B P Q R S T B P Q R S T
C P Q R S T C P Q R S T
D P Q R S T D P Q R S T

Mark your response in OMR sheet against the
question number of that question in section-II. + 8
marks will be given for complete correct answer (i.e.
+2 marks for each correct row) and No Negative
marks for wrong answer.
vr% OMR 'khV esa iz'u dh iz'u la[;k ds le{k viuk mkj
[k.M-II esa vafdr dhft;sA izR;sd iw.kZ lgh mkj ds fy;s + 8
vad fn;s tk;saxs (vFkkZr~ izR;sd lgh iafDr feyku ds fy, +2
vad fn, tk,asxs) rFkk xyr mkj ds fy;s dksbZ _.kkRed vadu
ugha gS (vFkkZr~ dksbZ vad ugha ?kVk;k tk;sxk)A

Space for rough work

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Q.1 An real object S is placed on the optic axis an
optical instrument as shown in column-I. The
distance between the object and the instrument
can be varied. Some statements are given in
column-II about image. f is the magnitude of
focal length of the instrument. Match the optical
instruments given in column-I with the
appropriate properties of images given in
column-II.
Column-I Column-II
Q.1 ,d okLrfod oLrq S dks LrEHk-I esa n'kkZ;s
izdkf'k;h midj.k dh izdkf'kd v{k ij j[kk x;k
gSA oLrq rFkk midj.k ds e/; dh nwjh ifjofrZr
gks ldrh gSA LrEHk-II eas izfrfcEc ds lkis{k dqN
dFku fn;s x;s gSA f midj.k dh Qksdl nwjh dk
ifjek.k gSA LrEHk-I esa fn;s x;s izdkf'k; midj.kksa
dks LrEHk-II esa fn;s x;s izfrfcEcksa ds mi;qDr
xq.kksa ds lkFk lqesfyr dhft,A
LrEHk-I LrEHk-II

(A) (P) If image distance (A) (P) ;fn /kzqo ls

S S

r from pole lies in izfrfcEc dh nwjh r

range 0 < r < f, ijkl 0 < r < f eas
then image must be gS, rks izfrfcEc
virtual vo'; vkHkklh gksxk

(B) (Q) If image distance (B) (Q) ;fn /kzqo ls

S S

r from pole lies izfrfcEc dh nwjh r

0 < r < f, then ijkl 0 < r < f esa
image must be gS, rks izfrfcEc vo';
magnified vko/khZr gksxk

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 (C) (R) If object distance (C) (R) ;fn /kzqo ls oLrq
S S

r from pole is in dh nwjh r ijkl

range f < r < 2f, f < r < 2f esa

then image must gS, rks izfrfcEc

be real vo'; okLrfod gksxk

(D) (S) ;fn /kqzo ls oLrq

(D) (S) If object distance r
S
S

dh nwjh r ijkl
from the pole is in
2f < r < eas gksrh
the range 2f < r < ,
gS, rks izfrfcEc
then image must
vo'; NksVk gksxk
be diminished
(T);fn /kzqo ls izfrfcEc
(T) If image distance
dh nwjh ijkl
from the pole is in
2f < r < esa gksrh
the range of
gS] rks izfrfcEc
2f < r < , the image
vo'; okLrfod
must be real.
gksxk
Space for rough work

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Q.2 In column I, some thermodynamic processes are Q.2 LrEHk-I esa] ,d vkn'kZ xSl ds fy;s dqN "ekxfrdh
given for an ideal gas. Match the processes ize fn;s x;s gSA LrEHk-I esa fn;s x;s izeksa dks
given in column I with corresponding LrEHk-II esa fn;s x;s lEcfU/kr "ekxfrdh ifjorZuksa
thermodynamic change given in column II. ls feyku dhft,A
Column- I Column-II LrEHk- I LrEHk-II
(A) An insulated container (P) The pressure of (A) ,d dqpkyd ik=k esa (P) xSl dk nkc ?kVrk gS
has two chambers the gas decreases nks psEcj gS tks gYds
separated by a light fiLVu }kjk iFkd gS
piston. The chamber I psEcj- I esa vkn'kZ xSl
contains an ideal gas
rFkk psEcj-II esa fuokZr
and the chamber II
gSA fiLVu ?k"kZ.kghu gSA
has vacuum. Piston
is frictionless. The
fiLVu dks n'kkZ;h fLFkfr
piston is released from ls NksM+k x;k gS
shown position Ideal gas vacuum
Ideal gas vacuum
piston
piston (B) ,d vkn'kZ ,dyijek.kq (Q) xSl dh vkUrfjd
(B) An ideal monoatomic (Q) The internal xSl dks mlds izkjfEHkd tkZ ?kVrh gS
gas expands to thrice energy of gas vk;ru ds rhu xqus
its original volume decreases rd bl izdkj izlkfjr
such that its pressure fd;k tkrk gS fd mldk nkc
1 1
P where V is P gS tgk V xSl
V3 V3
the volume of gas dk vk;ru gS
Space for rough work

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 (C) An ideal monoatomic (R) The gas loses heat (C) ,d vkn'kZ ,dy (R) xSl "ek [kksrh gS
gas expands to twice ijek.kq xSl dks mlds
its original volume
izkjfEHkd vk;ru ds
nqxqus rd bl izdkj
such that its temperature
izlkfjr fd;k tkrk gS
1 1
T , where V mldk rki T
2/3
V V2/3
is the volume of gas gS, tgk V xSl dk
vk;ru gS
(D) An ideal monoatomic (S) The gas neither
(D) ,d vkn'kZ ,dy (S) xSl u rks "ek
gas expands such that loses heat nor
ijek.kqd xSl bl [kksrh gS u gh xzg.k
its temperature T and gains heat izdkj izlkfjr gksrh gS djrh gS
V follows the behaviour fd mldk rki T o V
shown in the graph (T) Work done is xzkQ esa n'kkZ;k O;ogkj
djrh gS rFkk T V2 (T) fd;k x;k dk;Z
and T V2 positive
/kukRed gS
T T

V V
V1 V2 V1 V2

Space for rough work

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 Space for Rough Work (jQ+ dk;Z gsrq LFkku)

Space for rough work

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 Time : 3 : 00 Hrs. MAX MARKS: 243

INSTRUCTIONS TO CANDIDATE
A. lkekU; :
1. i;k izR;sd iz'u ds fy, fn, x, funsZ'kksa dks lko/kkuhiwoZd if<+;s rFkk lEcfU/kr fo"k;kas esa mkj&iqfLrdk ij iz'u
la[;k ds le{k lgh mkj fpfUgr dhft,A
2. mRrj ds fy,] OMR vyx ls nh tk jgh gSA
3. ifjoh{kdksa }kjk funsZ'k fn;s tkus ls iwoZ iz'u&i=k iqfLrdk dh lhy dks ugha [kksysaA
B. vadu i)fr:
bl iz'ui=k esa izR;sd fo"k; esa fuEu izdkj ds iz'u gSa:-
[k.M I
SEAL

4. cgqfodYih izdkj ds iz'u ftuesa ls dsoy ,d fodYi lgh gSA izR;sd lgh mkj ds fy, 3 vad fn;s tk;saxs o izR;sd xyr mkj ds
fy, 1 vad ?kVk;k tk,xkA
5. cgqfodYih izdkj ds iz'u ftuesa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA izR;sd lgh mkj ds fy, 3 vad fn, tk;saxs rFkk dksbZ
_.kkRed vadu ugha gSA
6. x|ka'k ij vk/kkfjr cgqfodYih izdkj ds iz'u ftuesa ls dsoy ,d gh fodYi lgh gSaA izR;sd lgh mkj ds fy, 3 vad fn, tk;saxs
rFkk izR;sd xyr mkj ds fy, 1 vad ?kVk;k tk;sxkA
[k.M III
7. x.kukRed izdkj ds iz'u gSaA izR;sd lgh mkj ds fy, 3 vad fn;s tk;saxs rFkk xyr mkj ds fy, dksbZ _.kkRed vadu ugha gSA bl
[k.M esa mkj bdkbZ iw.kkd esa nhft, (tSls 0 ls 9)A
C. OMR dh iwfrZ :
8. OMR 'khV ds CykWdksa esa viuk uke] vuqekd] cSp] dkslZ rFkk ijh{kk dk dsUnz Hkjsa rFkk xksyksa dks mi;qDr :i ls dkyk djsaA
9. xksyks dks dkyk djus ds fy, dsoy HB isfUly ;k uhys/dkys isu (tsy isu iz;ksx u djsa) dk iz;ksx djsaA
10. di;k xksyks dks Hkjrs le; [k.Mks dks lko/kkuh iwoZd ns[k ysa [vFkkZr [k.M I (,dy p;ukRed iz'u] dFku izdkj ds iz'u]
Space for rough work
cgqp;ukRed iz'u), [k.M II (LrEHk lqesyu izdkj ds iz'u), [k.M-III (iw.kkZd mkj izdkj ds iz'u]

Section I Section-II Section-III

For example if only 'A' choice is For example if Correct match for (A) Ensure that all columns are filled.
correct then, the correct method for is P; for (B) is R, S; for (C) is Q; for Answers, having blank column will be treated as
filling the bubbles is (D) is P, Q, S then the correct method incorrect. Insert leading zeros (s)
A B C D E for filling the bubbles is '6' should be '86' should be '1857' should be
P Q R S T filled as 0006 filled as 0086 filled as 1857
For example if only 'A & C' choices A 0 0 0 0
are correct then, the correct method B 0 0 0 0 0 0 0 0 0 0 0 0
for filling the bublles is 1 1 1 1 1 1 1 1 1 1 1 1
C 2 2
A B C D E 2 2 2 2 2 2 2 2 2 2
D 3 3 3 3 3 3 3 3 3 3 3 3
the wrong method for filling the 4 4 4 4 4 4 4 4 4 4 4 4
bubble are 5 5 5 5 5 5 5 5 5 5 5 5
6 6 6 6 6 6 6 6 6 6 6 6
The answer of the questions in 7 7 7 7 7 7 7 7 7 7 7 7
wrong or any other manner will be 8 8 8 8 8 8 8 8 8 8 8 8
treated as wrong.
9 9 9 9 9 9 9 9 9 9 9 9

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