PART II : CHEMISTRY

Section I : Single Correct Answer Type

This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.

21. The most probable major product of following reaction is at position

(A) 2 (B) 4 (C) 5 (D) 7

OH
22. OH
OH OH

(I) (II) (III) (IV)

What is the decreasing order of ease of dehydration of the above alcohols?
(A) IV > II > I > III (B) I > III > IV > II
(C) II > III > I > IV (D) I > III > II > IV

CH2
Cl2 excess
23.
Major disubstituted product x
O

FeCl3
C O

The major disubstituted product formed in the above reaction is:

Cl
CH 2
CH 2 O
O
(A) (B) C O
C O Cl
Cl
Cl
Cl Cl CH 2
O
CH 2
(C) O (D) C O
C O
Cl Cl

24. Cl
Anhy.AlCl3
X Y
KOH

H2O

Z
Cu
o
300 C

Choose correct statement regarding compound [Z]

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 (A) It displays electrophilic substitution reaction.
(B) It decolorizes bromine water
(C) It forms alkane nitrile when reacts with alcoholic KCN.
(D) It undergoes nucleophilic substitution reaction.

25.
NBS
Monosubstituted products

How many maximum number of monosubstituted products can be formed in the above reactions
(ignore stereoisomerism)?
(A) 3 (B) 2 (C) 4 (D) None

26. CH 2Br ( II )

H2O
Pr oducts
C2H5OH
Br CH 2CH 2Br ( I )
( III )
What is the decreasing order of leaving tendency of the above marked bromine atoms of the reactant
towards above reaction?
(A) I II III (B) II I III
(C) III I II (D) III II I

27.
Anhy. AlCl3
Cl CH2 CH2 Cl
Pr oducts

Which of the following products is not formed in the above reaction?

CH 2CH 2Cl

(A) (B) CH 2 CH 2

CH2CH3 CH 3 CH CI

(C) (D)

28. 200 ml of 0.2M HNO3 oxidizes 0.248g of elemental phosphorus to a new compound and itself
reduces to NO2. What is the oxidation number of phosphorus in the new compound?
[At. wt. of P = 31]
(A) +3 (B) +5 (C) +1 (D) +4
29. In which of the following both the central atoms exhibit same type of hybridization?
(A) CF4 and SF4 (B) N3 and I3
(C) CO2 and SiO2 (D) NO2 and SO2

30. The number of monochloro derivatives of following compounds are respectively

(A) 1, 2, 3, 4 (B) 1, 3, 4, 5 (C) 1, 2, 4, 5 (D) 1, 2, 3, 5

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 SECTION II: Multiple Correct Answer(s) Type

This section contains 5 multiple choice questions. Each question has four choices (A),
(B), (C) or (D) out of which ONE or MORE are correct.

31. Which of the following is/are correct?

(A) diamond is a good conductor of heat
(B) Al4C3 gives CH4 on hydrolysis
(C) Considering solubility in water, Be(OH)2 > Mg(OH)2 > Ca(OH)2
(D) (HPO3)n contains P O P linkage

32. Which of the following give/s basic Solution?

(A) NH4Cl (B) FeCl3 (C) Na2CO3 (D) Na2 S

33. Which of the following compound will produce more than one acid in aq. solution:
(A) P4O8 (B) N2O4 (C) P4O6 (D) Cl2O7

34. In which of the following complexes oxidation number of central metal is +2 & Co ordination
number is 6.
(A) K4[Fe(CN)6] (B) [Ni(en)2]Cl2
(C) K2[Cr(Py)(gly)(NH)(en) Cl] (D) K2 [Pt(DMG)2 Cl2 ]

35. 4.5g of Al (atomic mass = 27 amu) is deposited at cathode from Al+3 solution by a certain quantity of
charge. The correct statement/s is are:
(A)The volume of H2 produced at 0C and 1atm pressure from H+ ions in solution by the same
quantity of charge will be 5.6 l.
(B)The volume of H2 produced at 0C and 1atm pressure from H+ ions in solution by the same
quantity of charge will be 22.4 l.
(C)The number of moles of Al deposited will be 0.166 moles.
3
(D)The number of faraday used for reduction of 1 mole of Al+3 is F.
18

SECTION III: Integer Answer Type

This section contains 5 questions. The answer to each question is a single digit
integer, ranging from 0 to 9 (both inclusive)

36. i NaNH2 Y Lindlar ' s catalyst

X
CH
5 8
ii CH3Br C H H2
6 10

CH 3 CH 3 O / Zn
CHO
Z O3 / Zn
CH3CHO
H2O C6H12 H2O
CH 3

How many 1o carbon atoms are present in a molecule of [Y]?

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37. CH 2 CH CH CH 3
NBS Mg / ether
X Y
CH 3

HCHO
Z


H2O / H

How many sp3 hybridized carbon atoms are present in one molecule of compound (Z)?

38. CH 2 CH 2 CH 2Cl

Zn / ether excess
X Y
Alc.KOH
Cl C CH CH3

Cl
Cl CH CH CH 2 CH3

Cl
How many allylic hydrogen atoms are present in one molecule of compound[Y]

39. What is the value of x in the following reaction?

HOCH O
CHOH
x.HIO4
CHOH
CHOH
CH
CH2OH

40. How many moles of CH3MgBr is required for complete reaction of one mole of the above
compound?
O OH
CH CH3

OC2H5
C
O O

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