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UOP offers four alkylation routes, three direct and one indi-
rect route to alkylate.
Demand for alkylate will increase in the near future as a alkylate, but usually higher in octane. Control of the
result of more stringent gasoline specifications and con- polymerization conditions minimizes low-octane isomer
cerns about MTBE contamination of ground water. The production.
decision to ban MTBE in California starting in 2003
will force refiners there to look for a new source of CATALYST SELECTION
paraffinic gasoline blendstocks alkylate.
Either resin or solid phosphoric acid (SPA) catalysts are
UOPs Indirect Alkylation (InAlk) process uses com- used to polymerize the olefins. Resin catalyst primarily
mercial solid catalysts to convert mainly C4 but also C3 converts iso-butene. SPA catalyst also converts normal
and C5 olefins to alkylate. Inclusion of a dehydrogena- butenes. Hydrogenation uses either a base or noble
tion step can significantly increase alkylate production metal catalyst. Base-metal catalyst is less sensitive to
by producing additional olefins from butane. feed contaminants than noble-metal catalyst, but
requires a higher capital investment.
The InAlk process is an attractive, low-cost way to con-
vert refinery based MTBE units or dehydrogenation- MTBE COMPLEX REVAMP
based MTBE complexes to the production of premium MTBE complexes can be easily revamped to InAlk
alkylate. service with some minor changes to the MTBE section.
Figure 1 shows an MTBE complex that has been con-
The InAlk process:
verted to InAlk service.
J Improves gasoline quality by increasing the
availability of clean-burning, mid-boiling-range Figure 1
iso-paraffins. Inalk Complex Process Flow Scheme
J Upgrades low-value butanes to a premium paraf- H2
Reactor
plant are Olefin Capital investment, - - 7.7 7.0
Section Saturation
shown in the Unit
$MM
following Alkylate Product
Payback, years - - 0.4 0.3
table. Product
octane can vary somewhat, depending on the flow scheme EXPERIENCE
and overall conversion desired. The InAlk process produces high quality alkylate from
olefins and is a simple extension of UOPs catalytic con-
Butane Conversion densation and olefin saturation technologies. UOP has
MTBE InAlk Complex licensed and designed more than 400 catalytic condensa-
Complex Resin SPA tion units for the production of polygasoline and petro-
Feed chemical olefins and more than 200 hydrogenation units
Field butanes, BPSD 17,570 17,570 17,570 of various types. UOP offers the Oleflex process to
Methanol, BPSD 6,030 - - dehydrogenate butanes to butene and propane to propy-
lene. Twelve Oleflex units have been licensed. Nine units
Products
are currently in operation and three others are in design.
MTBE, BPSD 17,700 - -
C5+ alkylate, BPSD - 11,570 11,850 The InAlk technology has been chosen by companies in
Hydrogen, MMSCFD 13 8 7
North America, Asia and the Middle East for the produc-
Product properties tion of premium alkylate.
RONC 118 99 101
MONC 100 97 96
FOR MORE INFORMATION
For more information, contact your UOP representative or
UOP at:
Phone: 847-391-2000
Fax: 847-391-2253
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