2.

21

2.2. Given the reaction 2N02 + 1/2O2 = N205, what is the relation
between 2 the rates of formation and disappearance of the three
reaction components?
1 2 2
2 = = [ 3 ]
()()
1 2 2
2 = = [ 3 ]
()()
1 2 5 2 5
2 5 = = [ 3 ]
()()
Dengan:
2 2 2 5
= =
2 1 1
2

2.4 For the enzyme-substrate reaction of Example 2, the rate of

disappearance
of substrate is given by

What are the units of the two constants?

Dari Contoh 2 Levenspiel diperoleh:

 Dengan 2 asumsi:
[0 ] = [ ] + []
[ ]
=0

[ ]
= 3 []

[ ]
= 1 [][ ] 2 [] 3 []

[ ]
= 1 []([0 ] []) 2 [] 3 []

[ ]
= 1 [][0 ] 1 [][] 2 [] 3 []

Karena
[ ]
=0

1 [][] + 2 [] + 3 [] = 1 [][0 ]
[](1 [] + 2 + 3 ) = 1 [][0 ]
1 [][0 ]
[ ] =
(2 + 3 )+1 []

[ ]
= 3 []

[ ] 1 3 [][0 ]
=
(2 + 3 ) + 1 []

[ ] [ ] 1 3 [][0 ]
= = =
(2 + 3 ) + 1 []
1 3 [][0 ] 1760[][0 ]
=
(2 + 3 ) + 1 [] 6 + [ ]

Diperoleh:
1 = 1
2 = -1754
3 = 1760

2.8 The decomposition of nitrous oxide is found to proceed as

follows:

What is the order of this reaction with respect to N2O, and overall?

2.17

Tebak =
Ada 3 variabel yang tidak diketahui k,a, dan b
Tapi kita mempunyai 3 persamaan
50 = 2 125 (1)
32 = 2 64 (2)
48 = 3 64 (3)
Bagi persamaan 3 dan 2 untuk memperoleh nilai a
48 = 3 64
32 = 2 64
48
= 3 2
32
 48
= 3 2
32
48
= (3 2)
32
48
( )
= 32
(3 2)
=1

Bagi persamaan 1 dan 2 untuk memperoleh nilai b

50 = 2 (125)
32 = 2 64
50 125
( ) = log ( )
32 64

(50/32)
=
125
log ( )
64
= 2/3
Substitusikan nilai a dan b ke persamaan (1)
50 = 2 125
50 = 21 1252/3
50 = (2)(25)
=1
Maka persamaan laju reaksi menjadi
= 1 2/3
3.19

3.2 Liquid A decomposes by first-order kinetics, and in a batch

reactor 50% of A is converted in a 5-minute run. How much longer
would it take to reach 75% conversion?
ANS: 10 menit

= =

0 (1 )
= 0 (1 )

( )
= (1 )


( )
=
(1 )
0 0
Untuk XA=0,5 dan t=5menit dicari nilai k
0,5 5
( )
=
(1 )
0 0
ln(1 0,5) = (5)
ln(0,5) = (5)
= 0,13863

Untuk XA=0,75 dan k=0,13863 dicari nilai t

0,75
( )
=
(1 )
0 0

ln(1 0,75) = 0,13863()

ln(0,25) = 0,13863()
1,3863 = 0,13863()
t = 10
3.10 Aqueous A reacts to form R (A R) and in the first minute in a
batch reactor its concentration drops from CAo = 2.03 mollliter to
CAf = 1.97 mollliter. Find the rate equation for the reaction if the
kinetics are secondorder with respect to A.
Reaksi orde 2

= = 2




=
2 0
0

1 1
= ()
0
1 1
= (1)
1,97 2,03
1 1
= (1)
1,97 2,03
= 0,015
= 2
= 0,015 2

3.13 Betahundert Bashby likes to play the gaming tables for

relaxation. He does not expect to win, and he doesn't, so he picks
games in which losses are a given small fraction of the money bet. He
plays steadily without a break, and the sizes of his bets are
proportional to the money he has. If at "galloping dominoes" it takes
him 4 hours to lose half of his money and it takes him 2 hours to lose
half of his money at "chuk-a-luck," how long can he play both games
simultaneously if he starts with $1000 and quits when he has $10 left,
which is just enough for a quick nip and carfare home?