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ABSTRACT next best crop, palm oil [2]. Biodiesel from algae seems to be
Algae is a very promising source of biomass in this context as it only renewable biofuel that has the potential to completely
sequester a significant quantity of carbon from atmosphere and displace petroleum-derived transport fuels without adversely
industrial gases and is also very efficient in utilizing the affecting supply of food and other crop products. The table 1
nutrients from industrial effluents and municipal wastewater. shows the comparison of production of different oils per hector.
Therefore cultivation of algal biomass provide dual benefit, it Table 1: Comparison of Production of Different Oils per
provides biomass for the production of biofuels and also save Hector [2]
our environment from air and water pollution. Source Oil Yield (l/ha)
Algae are the fastest-growing plants in the world. Industrial Cotton 325
reactors for algal culture are open ponds, photobioreactors and Soyabean 446
closed systems. Algae are very important as a biomass source. Mustard Seed 572
Algae will some day be competitive as a source for biofuel. Sunflower 952
Algae are among the fastest-growing plants in the world, and Oil Palm 1,892
about 50% of dry algae weight is oil. This liquid oil can be used Jatropha 5,950
to make biodiesel for cars, trucks, and airplanes. Algae have Canola 1,190
much faster growth-rates than terrestrial crops. the per unit area Algae 98,500
yield of oil from algae is estimated to be from 20,000 to 80,000 l
per acre, per year; this is 731 times greater than the next best 2. BIODIESEL
crop, palm oil.
Biodiesel is an esterified version of vegetable oil, which could
The experimental investigation was conducted on a single
be edible or non edible. B20 (a blend of 20 % by volume
cylinder, four stroke, vertical, air-cooled diesel engine. It is
biodiesel and 80 % by volume diesel) has demonstrated
concluded from the experiment that the brake thermal efficiency
significant environmental benefits in the U.S. within a minimum
with algae biodiesel was found lower than that of diesel fuel at
increase in the cost for fleet operation and other consumers.
all load conditions. There is a significant reduction in the
Biodisel is registered as a fuel and fuel additive with the U. S.
emission of CO, HC and Smoke intensity, which make this
Environmental Protection Agency, and it meets clean diesel
biodiesel as environmental friendly. On the other hand, NOx
standards established by the Califorina Air Resources Board.
emission is higher for this biodiesel compared to neat diesel
Neat (100%) biodiesel has been designated as an alternative fuel
operation.
by the U.S. Department of Energy and the Department of
Keywords Transportation. Studies conducted with biodiesel on engines
Biodiesel, Algae, Biofuels and Transesterification have shown substantial reduction in PM (25% - 50%). However,
1. INTRODUCTION a marginal increase in NOx (1%-6%) is also reported; but it can
Due to depleting reserves and rising prices of fossil fuels, be taken care of either by optimization of engine parts or by
interest has rightly begun in the development of renewable using De-NOx catalyst. HC and CO emission were also reported
energy sources. In year 2010, fossil fuels accounted for 88% of to be lower. No-regulated emissions like poly aromatic
the global primary energy consumption [1]. The current hydrocarbons were also found to be lower. [10]
technological progress, potential reserves, and increased 3. FIRST AND SECOND-GENERATION
exploitation leads to energy insecurity and climate change by BIOFUELS
increasing greenhouse gas (GHGs) emissions due to First-generation biofuels which have attained economic levels of
consumption of energy at a higher rate. The use of fossil fuels is commercial production, have been mainly extracted from food
now widely accepted as unsustainable due to depleting resources and oil crops (viz. rapeseed oil, palm oil, sugarcane, sugar beet,
and the accumulation of GHGs in the environment that have wheat, barley, maize, etc.) as well as animal fats using
already exceeded the dangerously high threshold of 450 ppm conventional technology.
CO2 [8].. Second-generation biofuel crops and production technologies
Biodiesel has become a sustainable substitute to diesel fuel as are more efficient; their production could become unsustainable
biodiesel is produced from vegetable oil or animal fat through a if they compete with food crops for available land. Thus, their
chemical process known as transesterification. The research on sustainability will depend on whether producers comply with
different aspect of biodiesel production and utilization in diesel criteria like minimum lifecycle GHG reductions, including land
engine has been reported by a number of researchers [2]. Algae use change, and social standards [8]. The limitations of first-
have much faster growth-rates than terrestrial crops. the per unit generation biofuels produced from food crops have caused
area yield of oil from algae is estimated to be from 20,000 to greater emphasis to be placed on second generation biofuels
80,000 l per acre, per year; this is 731 times greater than the
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National Conference on Innovative Paradigms in Engineering & Technology (NCIPET-2012)
Proceedings published by International Journal of Computer Applications (IJCA)
system was used for injecting diesel or biodiesel, and the fuel
injection timing was not adjusted throughout the test. At each
engine mode, the engine was allowed to run for a few minutes
the exhaust gas temperature, the lubricating oil temperature and
the gaseous emission concentration reached steady state values
and data was measured subsequently. [9]
9. RESULT AND DISCUSSION
A graph of brake thermal efficiency (BTE) vs. brake mean
effective pressure (BMEP) is shown in figure 4. From the test
results of algae biodiesel, it was observed that brake thermal
efficiency of mineral diesel is higher than algae biodiesel (AB).
Fig. 3: Expeller press
It was also observed that the power produced by algae biodiesel
is lower than that by mineral diesel. This may be due to the
8. PRODUCTION OF BIODIESEL FROM lower calorific value of algae biodiesel and its higher density
ALGAE OIL and kinematic viscosity. The lower brake thermal efficiency
Biodiesel is defined as the mono-alkyl esters of vegetable oils or obtained for AB100 fuel could be due to the reduction in
animal fats. Biodiesel is produced by transesterifying the parent calorific value and increase in fuel consumption as compared to
oil or fat to achieve a viscosity close to that of petrodiesel. The diesel fuel. This indicates that the thermal efficiency is a better
chemical conversion of the oil to its corresponding fatty ester representative reflection of the fuel economy by using the diesel
(biodiesel) is called transesterification. Biodiesel is a biofuel equivalent energy consumption rate when operated on
commonly consisting of methyl esters that are derived from oxygenated fuels like algae biodiesel.[9]
organic oils, plant or animal, through the process of
transesterification. The biodiesel transesterification reaction is
very simple [2]
Triglyceride + 3 methanol Catalyst Glycerine + 3 methyl
esters (Biodiesel)
An excess of methanol is used to force the reaction to favor the
right side of the above equation. The excess methanol is later
recovered and reused. The energy density of biodiesel is
comparable to petroleum diesel. The higher heating value of
petroleum diesel is 42.7 MJ/kg. Values for biodiesel vary
depending on the source of biomass. Typically, biodiesel
derived from seed oils, such as rapeseed or soybean produces,
39.6 MJ/kg, while biomass derived from algae yields 39.5
MJ/kg [2]. Although the lower energy biodiesels based on seed Fig 4: Brake Thermal Efficiency (BTE) Vs. Brake Mean
oils are the most common, they have enough energy density to Effective Pressure (BMEP)
make them a viable alternative to petroleum diesel. The lower
heating value of algae biodiesel is compared with the other 10. CO EMISSION
biodiesel and diesel in table 2. Figure 5 depicts the CO emission versus brake mean effective
Table 2: Comparison of Calorific Value of Diesel with pressure for different biodiesel fuels. CO emissions were found
Different Biodiesel [2] to be lower for algae biodiesel. As the load is increased on the
Oil Lower Heating Value (MJ/kg) engine, there is an increase in CO emission for both fuels. The
Diesel 42.7 increase in CO emission levels at higher load is due to richer
Jatropha 39.7 load condition than at lower level which results in incomplete
Sunflower Oil 39.6 combustion of fuels. Within the experimental range, the lower
Soya bean 39.6 CO emissions have been observed with AB100 sample. This is
Karnja 38.8 possible since biodiesel contains more oxygen than diesel most
Algae 39.5 of the carbon monoxide is converted into carbon dioxide and
hence complete combustion takes place. The maximum value of
8. Experimental Investigation of Algae carbon monoxide present in Algae Biodiesel (AB100) is 0.4%
and corresponding value of CO present in diesel is 0.61% which
Biodiesel as an alternative fuel for diesel is significantly higher than that in algae biodiesel.[9]
engine
The experimental investigation has been carried out by the
researcher on a single cylinder, four strokes, vertical, air-cooled
diesel engine. The compression ratio is 17.5. It develops 7.4 kW
brake power at rated speed of 1500 rpm with algae biodiesel as
fuel. [9] The test were carried out at steady state with different
loads of 0%, 20%, 40%, 60%, 80% and 100% at the engine
maximum torque speed of 1500 rpm. The engine was initially
run on diesel fuel to generate base line data and after that it was
run on algae biodiesel. Similar loading conditions were used for
both the fuels. The smoke opacity was measured with an AVL
437 smoke meter and exhaust emission were by AVL 4000 light
5 gas analyzer. The original mechanical inline fuel injection
9
National Conference on Innovative Paradigms in Engineering & Technology (NCIPET-2012)
Proceedings published by International Journal of Computer Applications (IJCA)
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National Conference on Innovative Paradigms in Engineering & Technology (NCIPET-2012)
Proceedings published by International Journal of Computer Applications (IJCA)
5. REFERENCES [6] Goh, C.S., Lee, K.T., 2010. A visionary and conceptual
[1] Anoop Singh, Poonam Singh Nigam, Jerry D. Murphy macroalgae-based thirdgeneration bioethanol (TGB)
Renewable fuels from algae: An answer to debatable land biorefinery in Sabah, Malaysia as an underlay for renewable
based fuels Bioresource Technology 102 (2011) 1016 and sustainable development. Renew. Sustain.Energy Rev. 14,
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[2] Ayhan Demirbas, M. Fatih Demirbas, Importance of algae oil
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52 (2011) 163170 J. Legrand Systematic investigation of biomass and lipid
productivity by microalgae in photobioreactors for biodiesel
[3] Brennan, L., Owende, P., 2010. Biofuels from microalgae-a application Bioresource Technology 102 (2011) 150158
review of technologies for production, processing, and
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Energy Rev. 14, 557577. Mussgnug, J.H., Posten, C., Kruse, O., Hankamer, B., 2008.
Second generation biofuels: high-efficiency microalgae for
[4] Chun-Yen Chen, Kuei-Ling Yeh, Rifka Aisyah, Duu-Jong Lee, biodiesel production. Bioenergy Res. 1, 2043
Jo-Shu Chang, Cultivation, photobioreactor design and
harvesting of microalgae for biodiesel production: A critical [9] Sharma P. B., et. Al. Biodiesel Production from Microalgae A
review Bioresource Technology 102 (2011) 7181 Sustainable Fuel New Frontiers in Bio Fuels, Scitech
Publications (India) PVT. LTD., New Delhi.
[5] David Sieg Making Algae Biodiesel at home
[10] S.S. Tipse., Alternative fuels Jaico Book publisher.
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